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1. 发明授权

US4550070A Direct positive silver halide photographic light-sensitive materials 失效
标题翻译：直接正卤化银照相感光材料
公开(公告)号：US4550070A
公开(公告)日：1985-10-29
申请号：US604554
申请日：1984-04-27
申请人： Tsutomu Miyasaka , Hidetoshi Kobayashi , Isamu Itoh , Shigeo Hirano
发明人： Tsutomu Miyasaka , Hidetoshi Kobayashi , Isamu Itoh , Shigeo Hirano
IPC分类号： C07C331/28 , C07D257/04 , G03C1/06 , G03C1/485 , G03C5/24
CPC分类号： C07D257/04 , C07C331/28 , G03C1/48561 , Y10S430/141
摘要： Direct positive silver halide photographic light-sensitive materials are described in which at least one layer of light-sensitive silver halide photographic emulsion layers and other hydrophilic colloid layers applied on a base contains a mercapto compound represented by the following general formula (I) or (II) as a nucleating agent: ##STR1## wherein Z, L.sub.1, L.sub.2, L.sub.3, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and m are as defined in the specification. The nucleating agents can also be added to processing solutions.
摘要翻译：描述了直接正性卤化银照相感光材料，其中至少一层感光卤化银照相乳剂层和其它亲水胶体层涂覆在基底上含有由以下通式（I）或（I）表示的巯基化合物， II）作为成核剂：其中Z，L1，L2，L3，R1，R2，R3，R4，R5和m如说明书中所定义。成核剂也可加入到处理溶液中。

2. 发明授权

US4719174A Direct positive silver halide photographic light-sensitive material depress formation of re-reversed negative image 失效
标题翻译：直接正卤化银照相感光材料抑制形成反转负像
公开(公告)号：US4719174A
公开(公告)日：1988-01-12
申请号：US847144
申请日：1986-04-02
申请人： Shigeo Hirano , Tsutomu Miyasaka , Shinsaku Fujita
发明人： Shigeo Hirano , Tsutomu Miyasaka , Shinsaku Fujita
IPC分类号： C07D249/08 , C07D209/88 , C07D219/00 , C07D219/02 , C07D219/10 , C07D231/06 , C07D257/04 , C07D279/24 , C07D403/04 , C07D403/12 , C07D413/12 , C07D417/12 , G03C1/06 , G03C1/485 , G03C1/34
CPC分类号： G03C1/48538
摘要： A direct positive silver halide photographic light-sensitive material is described containing a weak electron donative, adsorptive compound represented by formula (I) or (II) effective for depressing formation of a re-reversed negative image, which is not a spectral sensitizing agent for silver halide or a nucleating agent:D--L--X (I)D--X (II)whereinD represents electron donative atoms comprising an aromatic ring or hereto ring, which is unsubstituted or substituted;L represents a linking group containing at least one of C, N, S and O and an atom or atoms necessary for cutting a .pi.-conjunction system; andX represents a group which is adsorptive with respect to silver halide and contains at least one of C, N, S, O and Se.
摘要翻译：描述了一种直接正性卤化银摄影感光材料，其包含有效抑制形成再反转负像的弱电子给体，由式（I）或（II）表示的吸附化合物，其不是光谱增感剂卤化银或成核剂：DLX（I）DX（II）其中D表示包含芳族环或本文环的给电子原子，其为未取代或取代的; L表示含有C，N，S和O中至少一个的连接基团以及切割π-结合体系所需的原子或原子; X表示相对于卤化银吸附的基团，含有C，N，S，O，Se中的至少一种。

3. 发明授权

US4607006A Silver halide photographic light-sensitive material containing non-spectral sensitizing electron donative silver halide adsorptive compound 失效
标题翻译：含有非光谱敏化电子供体卤化银吸附化合物的卤化银照相感光材料
公开(公告)号：US4607006A
公开(公告)日：1986-08-19
申请号：US658955
申请日：1984-10-09
申请人： Shigeo Hirano , Yasuhisa Sano , Haruo Takei , Tsutomu Miyasaka , Shinsaku Fujita
发明人： Shigeo Hirano , Yasuhisa Sano , Haruo Takei , Tsutomu Miyasaka , Shinsaku Fujita
IPC分类号： G03C1/10 , G03C1/28 , G03C1/02 , G03C1/06 , G03C1/08
CPC分类号： G03C1/28 , G03C1/10
摘要： A silver halide photographic light-sensitive material is described containing at least one electron-donative, silver halide-adsorptive compound represented by the following general formula (A) or (B), which is not a spectral sensitizing agent for silver halide or a nucleating agent:D--L--X (A)D--X (B)wherein D represents an electron donative atomic group comprising an aromatic ring or hetero ring, which may be unsubstituted or substituted with at least one substituent; L represents a linkage group containing at least one of C, N, S or O; and X represents a group which is adsorptive with a silver halide-adsorptive group containing at least one of C, N, S, O or Se, said N being optionally quarternized.
摘要翻译：描述了卤化银摄影感光材料，其含有至少一种由以下通式（A）或（B）表示的给电子，卤化银吸附化合物，其不是用于卤化银的光谱增感剂或成核剂代理：DLX（A）DX（B）其中D表示包含芳族环或杂环的给电子原子团，其可以是未取代的或被至少一个取代基取代; L表示含有C，N，S或O中至少一个的连接基团; X表示与含有C，N，S，O或Se中的至少一种的卤化银吸附基团吸附的基团，所述N任选被季铵化。

4. 发明授权

US4740453A Silver halide photosensitive material containing a compound capable of releasing a photographically useful group 失效
标题翻译：含有能释放摄影有用基团的化合物的卤化银感光材料
公开(公告)号：US4740453A
公开(公告)日：1988-04-26
申请号：US813308
申请日：1985-12-24
申请人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
发明人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
IPC分类号： G03C1/43 , G03C7/305 , G03C1/40 , G03C5/54
CPC分类号： G03C1/43 , G03C7/305 , G03C2005/168 , Y10S430/156 , Y10S430/158 , Y10S430/16
摘要： A silver halide photosensitive material is described, comprising a support and at least one silver halide emulsion layer, wherein said emulsion layer or another layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group forming a redox center of benzene type having substituents by linking with C.sub.A and C.sub.B, and which does not enable Time-PUG to be released until the redox center is oxidized during development processing; EWG represents an electron withdrawing group having a Hammet's .sigma. para value exceeding 0.3; C.sub.A and C.sub.B each represents a carbon atom; R.sub.1 and R.sub.2 each represents a hydrogen atom or a suitable substituent; Time represents a timing group connecting to C.sub.B through a sulfur, nitrogen, or selenium atom thereof, t is an integer of 0 or 1, and when t=0, Time is a chemical bond; PUG represents a photographically useful group and connects to C.sub.B through a sulfur, nitrogen, or selenium atom thereof when t=0; and n is an integer of 0 or 1.
摘要翻译：描述了卤化银感光材料，其包括载体和至少一种卤化银乳剂层，其中所述乳剂层或另一层含有由式（I）表示的化合物（I），其中X表示形成通过与CA和CB连接而具有取代基的苯类氧化还原中心，并且不能使Time-PUG释放直到氧化还原中心在显影处理期间被氧化; EWG代表Hammet sigma值超过0.3的吸电子基团; CA和CB各自表示碳原子; R1和R2各自表示氢原子或适当的取代基; 时间表示通过其硫，氮或硒原子与CB连接的定时基团，t为0或1的整数，当t = 0时，为化学键; PUG表示当t = 0时，通过其硫，氮或硒原子连接CB; n为0或1的整数。

5. 发明授权

US4508816A Method for bleaching color photosensitive material 失效
标题翻译：彩色感光材料漂白方法
公开(公告)号：US4508816A
公开(公告)日：1985-04-02
申请号：US544155
申请日：1983-10-21
申请人： Kiyohiko Yamamuro , Shigeo Hirano , Isamu Itoh , Yasuo Iwasa
发明人： Kiyohiko Yamamuro , Shigeo Hirano , Isamu Itoh , Yasuo Iwasa
IPC分类号： C07D257/04 , C07D285/12 , C07D285/125 , G03C7/42 , G03C7/00 , G03C5/44
CPC分类号： C07D257/04 , C07D285/125 , G03C7/421
摘要： An improved method for bleaching color photosensitive materials with a persulfate is provided. This method is free of offensive odors, can bleach efficiently color photosensitive materials containing a large amount of silver by using a persulfate, and can effectively bleach color photosensitive materials having colloidal silver layers by using a persulfate. The color photosensitive material used in the present invention contains at least one of the compounds represented by the formula I, salts thereof and precursors thereof: ##STR1## where R.sup.1 and R.sup.2 each independently represents a hydrogen atom, or an aliphatic residue and R.sup.1 and R.sup.2 may form a ring together with the N atom; R.sup.3 represents --R.sup.4 -- or --R.sup.4 --S, said --R.sup.4 -- being a divalent aliphatic residue; and X represents a divalent heterocyclic ring residue containing at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, and a sulfur atom.
摘要翻译：提供了一种用过硫酸盐漂白色彩感光材料的改进方法。该方法没有恶臭，可以通过使用过硫酸盐有效地漂白含有大量银的感光材料，并且可以通过使用过硫酸盐有效地漂白具有胶体银层的彩色感光材料。本发明中使用的着色光敏材料含有至少一种式I表示的化合物及其盐及其前体：其中R 1和R 2各自独立地表示氢原子，或脂族残基和R 1 R2可以与N原子一起形成环; R3表示-R4-或-R4-S，所述-R4-为二价脂族残基; X表示含有至少一个选自氮原子，氧原子和硫原子的原子的二价杂环残基。

6. 发明授权

US4948712A Direct positive photographic materials and a method of forming direct positive images 失效
标题翻译：直接的正性照相材料和形成直接正像的方法
公开(公告)号：US4948712A
公开(公告)日：1990-08-14
申请号：US184552
申请日：1988-06-07
申请人： Noriyuki Inoue , Tatsuo Heki , Hidetoshi Kobayashi , Naoyasu Deguchi , Shigeo Hirano
发明人： Noriyuki Inoue , Tatsuo Heki , Hidetoshi Kobayashi , Naoyasu Deguchi , Shigeo Hirano
IPC分类号： G03C7/30
CPC分类号： G03C7/3022 , G03C2200/20 , G03C7/3029 , Y10S430/156
摘要： The invention provides (1) direct positive photographic photosensitive materials in which at least one type of FR compound which releases fogging agent or development accelerator or a precursor thereof in accordance with the amount of silver developed when the silver halide is being developed is included in a direct positive photographic material comprising at least one layer of non-pre-fogged internal latent image type silver halide emulsion on a support, and (2) a method of forming direct positive images of which the distinguishing features are that in a method for the formation of direct positive images in which a direct positive photographic photosensitive material comprising at least one layer of non-pre-fogged internal latent image forming silver halide emulsion on a support is processed, after image exposure, in a surface developer, at least one type of FR compound which releases fogging agent or development accelerator or precursors thereof is included in the said photographic mateiral, and that the said photosensitive material is subjected to a fogging process and to a development process during and/or after the said fogging process.It is possible by means of this invention to obtain direct positive photographic materials which have excellent stability with respect to the passage of time and especially good stability with respect to the passage of time under conditions of high temperature and high humidity.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images which have a high maximum image density and a high resolving power.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images with which direct positive images which have a satisfactorily high color density can be obtained, even on processing in highly stable developers of low pH.

7. 发明授权

US4518682A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4518682A
公开(公告)日：1985-05-21
申请号：US532631
申请日：1983-09-15
申请人： Hidetoshi Kobayashi , Toshiro Takahashi , Shigeo Hirano , Takeshi Hirose , Keiichi Adachi
发明人： Hidetoshi Kobayashi , Toshiro Takahashi , Shigeo Hirano , Takeshi Hirose , Keiichi Adachi
IPC分类号： G03C7/32 , G03C1/485 , G03C7/26 , G03C7/305
CPC分类号： G03C7/30541 , G03C1/485 , Y10S430/156
摘要： A silver halide photographic light-sensitive material is disclosed. The material has improved sensitivity and granularity as well as an increased gradient. Further, the material can be processed by rapid processing methods. The material is comprised of a support having positioned thereon a light-sensitive silver halide emulsion layer and a compound represented by the general formula (I):A-B (I)wherein A is residue of a compound capable of undergoing a coupling reaction with an oxidized primary amine developer, the residue being derived by eliminating a hydrogen atom from an active position of the compound. B is a group capable of being released through a coupling reaction to exert a fogging effect.
摘要翻译：公开了一种卤化银照相感光材料。该材料具有提高的灵敏度和粒度以及增加的梯度。此外，材料可以通过快速加工方法加工。该材料由其上定位有感光卤化银乳剂层的支持体和由通式（I）表示的化合物组成：AB（I）其中A是能够与氧化的（I）化合物进行偶联反应的化合物的残基伯胺显影剂，残留物是通过从该化合物的活性位置除去氢原子得到的。 B是能够通过偶联反应释放以发挥起雾效果的基团。

8. 发明授权

US4390618A Silver halide photographic light-sensitive materials 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4390618A
公开(公告)日：1983-06-28
申请号：US357930
申请日：1982-03-15
申请人： Hidetoshi Kobayashi , Toshirou Takahashi , Shigeo Hirano , Takeshi Hirosa , Keiichi Adachi
发明人： Hidetoshi Kobayashi , Toshirou Takahashi , Shigeo Hirano , Takeshi Hirosa , Keiichi Adachi
IPC分类号： G03C7/00 , C07C65/24 , C07D231/44 , C07D231/52 , C07D249/10 , C07D249/18 , C07D257/04 , C07D487/04 , C09B29/00 , G03C7/26 , G03C7/305 , G03C7/32 , G03C8/00 , G03C1/40
CPC分类号： C07C243/00 , C07C65/24 , C07D231/52 , C07D249/18 , G03C7/30541 , Y10S430/156
摘要： A silver halide photographic light-sensitive material is described comprising a layer containing a coupler compound represented by formula (I)A--B (I)wherein A represents a residue of a compound capable of undergoing a coupling reaction with an oxidation product of an aromatic primary amine developing agent, by the removal of one hydrogen atom from the active position of said compound, and B represents a group which is released by the coupling reaction and exhibits a development accelerating function.
摘要翻译：描述了一种卤化银照相感光材料，其包含含有式（I）AB（I）表示的成色剂化合物的层，其中A表示能够与芳族伯胺的氧化产物进行偶联反应的化合物的残基显影剂，通过从所述化合物的活性位置除去一个氢原子，B表示通过偶联反应释放并表现显影促进功能的基团。

9. 发明授权

US06593069B2 Photothermographic material and method for forming images 失效
标题翻译：光热成像材料和形成图像的方法
公开(公告)号：US06593069B2
公开(公告)日：2003-07-15
申请号：US09809024
申请日：2001-03-16
申请人： Toyohisa Oya , Kazunobu Katoh , Shigeo Hirano
发明人： Toyohisa Oya , Kazunobu Katoh , Shigeo Hirano
IPC分类号： G03C134
CPC分类号： G03C1/49845 , G03C1/49827 , G03C7/305 , Y10S430/166
摘要： A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler compound on the same side of a support: wherein, in the formula (1), V1 to V4 each independently represent hydrogen atom or a substituent, and V5 represents a substituted or unsubstituted alkyl group, aryl group or heterocyclic group: Q1—NHNH—V6 (2) wherein, in the formula (2), Q1 represents a 5- to 7-membered unsaturated ring bonding to NHNH—V6 at a carbon atom, and V6 represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group. The photothermographic material of the present invention shows good photographic properties including sensitivity, fog and so forth, and enables control of color tone of the photothermographic material in an arbitrary wavelength region even as a monosheet type photothermographic material.
摘要翻译：一种光热成像材料，其至少包含（a）感光卤化银，（b）可还原的银盐，（c）由下式（1）或（2）表示的还原化合物，（d）粘合剂和（e）其中在式（1）中，V1至V4各自独立地表示氢原子或取代基，V5表示取代或未取代的烷基，芳基或杂环基：其中，在式（2）中，Q1表示在碳原子上与NHNH-V6键合的5至7元不饱和环，V 6表示氨基甲酰基，酰基，烷氧基羰基，芳氧基羰基，磺酰基或氨磺酰基。本发明的光热敏成像材料显示出良好的照相性质，包括灵敏度，雾度等，并且即使作为单片型光热敏成像材料也能够控制光热成像材料在任意波长区域中的色调。

10. 发明授权

US06358677B1 Heat-developable recording material 有权
标题翻译：热显影记录材料
公开(公告)号：US06358677B1
公开(公告)日：2002-03-19
申请号：US09528450
申请日：2000-03-17
申请人： Masahiko Taniguchi , Katsuyuki Watanabe , Shigeo Hirano , Minoru Sakai
发明人： Masahiko Taniguchi , Katsuyuki Watanabe , Shigeo Hirano , Minoru Sakai
IPC分类号： G03C1498
CPC分类号： G03C1/49845
摘要： A heat-developable recording material having, at least on one side and the same side of the support, (a) reducible silver salt, (b) a reducing agent other than a compound represented by the general formula (1) below, (c) a binder, and (d) at least one compound represented by the general formula (1) below; content of the compound represented by the general formula (1) being 0.01 to 100 mol % with respect to the reducing agent: [where in the general formula (1), R1, R2, R3, X1 and X2 independently represent a hydrogen atom; halogen atom; or substituent which is bound to the benzene ring via a carbon atom, oxygen atom, nitrogen atom, sulfur atom or phosphorus atom. At least either X1 or X2 represents a group represented as —NR4R5, where R4 and R5 independently represent a group selected from a hydrogen atom, alkyl group and the like.]
摘要翻译：（a）可还原银盐，（b）除了下述通式（1）表示的化合物以外的还原剂，（c）的可热显影记录材料，至少在一个侧面和同一侧上，（c））粘合剂，和（d）至少一种由下述通式（1）表示的化合物; 通式（1）表示的化合物的含量相对于还原剂为0.01〜100摩尔％[其中，在通式（1）中，R 1，R 2，R 3，X 1和X 2独立地表示氢原子; 卤素原子; 或通过碳原子，氧原子，氮原子，硫原子或磷原子与苯环结合的取代基。 X 1或X 2中至少有一个表示为-NR 4 R 5的基团，其中R 4和R 5独立地表示选自氢原子，烷基等的基团。

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