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1. 发明申请

US20180127653A1 Alignment Polymers 审中-公开
公开(公告)号：US20180127653A1
公开(公告)日：2018-05-10
申请号：US15573174
申请日：2015-06-12
申请人： Transitions Optical, Inc.
发明人： Anil Kumar , Meng He , Ryan Stayshich , Gobinda Saha
IPC分类号： C09K19/38 , C08F220/30 , C08F220/36 , C09K19/34
摘要： The present invention relates to polymers that include residues of at least one monomer represented by the following Formula (I). With reference to Formula (I), at least one of E1 and E2 independently is, or is independently substituted with, at least one reactive group, such as a (meth)acryloyl group. Monomers represented by Formula (I) and monomer residues thereof have alignment properties, such as photoalignment properties. The present invention also relates to alignment layers that include such polymers, and articles of manufacture, such as optical elements, that include one or more such alignment layers.

2. 发明授权

US09487499B2 Methods of making fused ring compounds 有权
标题翻译：稠环化合物的制备方法
公开(公告)号：US09487499B2
公开(公告)日：2016-11-08
申请号：US14822938
申请日：2015-08-11
申请人： Transitions Optical, Inc.
发明人： Meng He , Anil Kumar
IPC分类号： C07D405/04 , C07D407/04 , C07D311/94 , C07C37/11 , C07C41/01 , C07C51/353
CPC分类号： C07C39/17 , C07C37/11 , C07C41/01 , C07C51/353 , C07C2602/08 , C07C2603/40 , C07D307/33 , C07D311/94 , C07D405/04 , C07D407/04
摘要： The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C1-C6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R3 and R16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C1-C8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R16 is hydrogen, or an optionally substituted hydrocarbyl group).
摘要翻译：关于式II的不饱和化合物：环-A可以选自任选取代的芳基（例如苯基）; m可以是例如0至4; 每个m的R 1可以选自任选被至少一个连接基团（例如-O-）中断的任选取代的烃基（例如C 1 -C 6烷基）; 并且R 3和R 16各自独立地选自例如氢或任选取代的烃基，例如C 1 -C 8烷基。当环A是苯基时，由式II表示的不饱和化合物可以称为不饱和茚酮酸/酯化合物或茚酮酸/酯化合物（取决于R 16是氢还是任选取代的烃基）。

3. 发明授权

US09206151B2 Method of preparing fused ring indeno compounds 有权
标题翻译：稠环茚并吡啶化合物的制备方法
公开(公告)号：US09206151B2
公开(公告)日：2015-12-08
申请号：US14084739
申请日：2013-11-20
申请人： Transitions Optical, Inc.
发明人： Meng He , Massimiliano Tomasulo , Allison Greene , Anil Kumar
IPC分类号： C07D307/02 , C07D307/89 , C07D209/70 , C07C69/017 , C07C67/00 , C07D311/78 , C07C65/17 , C07C51/09 , C07C65/26 , C07D209/58 , C07D307/77 , C07C63/44
CPC分类号： C07C65/26 , C07C51/09 , C07C51/38 , C07C63/44 , C07C63/72 , C07C65/17 , C07C67/00 , C07C69/017 , C07C2602/08 , C07C2603/40 , C07D209/58 , C07D209/70 , C07D307/77 , C07D307/89 , C07D311/78
摘要： The present invention relates to methods of preparing fused ring indeno compounds that involves reacting together a dienophile and a lactone compound, in the presence of a catalyst, and a carboxylic acid anhydride. With some embodiments, the fused ring indeno compound is represented by the following Formula (I-A), the dienophile is represented by the following Formula (II-A), and the lactone compound is represented by the following Formula (III-A):
摘要翻译：本发明涉及制备稠环茚并化合物的方法，该方法包括在催化剂和羧酸酐的存在下使亲双酯和内酯化合物反应。在一些实施方案中，稠环茚并化合物由下式（I-A）表示，亲双烯体由下式（II-A）表示，内酯化合物由下式（III-A）表示：

4. 发明授权

US09051332B1 Photochromic indeno-fused ring pyran compounds 有权
标题翻译：光致变色茚并稠环吡喃化合物
公开(公告)号：US09051332B1
公开(公告)日：2015-06-09
申请号：US14084891
申请日：2013-11-20
申请人： Transitions Optical, Inc.
发明人： Meng He , Massimiliano Tomasulo , Anil Kumar
IPC分类号： C07D491/052 , C07D493/04
CPC分类号： C07D493/04 , C07D311/94 , C07D491/052 , C09K9/02 , C09K19/32 , C09K19/3488 , C09K19/3491 , C09K19/36 , C09K19/60 , C09K2019/3408 , C09K2211/1007 , C09K2211/1033 , C09K2211/1088 , G02B1/043 , G02B5/23
摘要： The present invention relates to photochromic indeno-fused ring pyran compounds represented by the following Formula (I-A): The present invention also relates to photochromic dichroic compounds, such as represented by Formula (I-A), in which (i) Z2 is a group N—R13 in which R13 is a group L, and (ii) optionally at least one R1 independently for each n is selected from a group L, in which the group L independently in each case is a lengthening group that provides the photochromic compound with dichroic properties, in accordance with some embodiments. The present invention also relates to photochromic articles, such as photochromic ophthalmic articles, that include one or more photochromic compounds according to the present invention, such as represented by Formula (I-A).
摘要翻译：本发明涉及由下式（IA）表示的光致变色茚并稠环吡喃化合物：本发明还涉及由式（IA）表示的光致变色二色性化合物，其中（i）Z2是基团N -R13，其中R13为基团L，和（ii）每个n独立地选自至少一个R 1，其中基团L在每种情况下独立地为提供具有二色性的光致变色化合物的延长基团属性，根据一些实施例。本发明还涉及包含一种或多种根据本发明的光致变色化合物的光致变色制品，例如光致变色眼用制品，如式（I-A）所示。

5. 发明申请

US20150141663A1 Fused Ring Indeno Compounds For Preparation Of Photochromic Compounds 有权
标题翻译：用于制备光致变色化合物的稠环烯茚化合物
公开(公告)号：US20150141663A1
公开(公告)日：2015-05-21
申请号：US14084830
申请日：2013-11-20
申请人： Transitions Optical, Inc.
发明人： Meng He , Massimiliano Tomasulo , Anil Kumar
IPC分类号： C07D307/93 , C07D209/94
CPC分类号： C07D307/93 , C07C49/507 , C07C49/747 , C07C50/36 , C07C2603/52 , C07C2603/54 , C07D209/70 , C07D209/94 , C07D307/77 , C07D307/88 , C07D307/89 , C07D311/78 , C07D311/94 , C09K9/02 , C09K19/32 , C09K19/3488 , C09K19/3491 , C09K19/36 , C09K19/60 , C09K2019/3408 , G02B5/23
摘要： The present invention relates to intermediate compounds represented by the following Formula (I-A), The intermediate compounds of the present invention, such as represented by Formula (I-A), can be used to prepare photochromic compounds, such as photochromic fused ring indenopyran compounds, including but not limited to photochromic fused ring indeno-naphtho-pyran compounds.
摘要翻译：本发明涉及由下式（IA）表示的中间体化合物。本发明的中间体化合物（如式（IA）所示）可用于制备光致变色化合物，如光致变色稠环茚并吡喃化合物，包括但不限于光致变色稠环茚并萘并吡喃化合物。

6. 发明申请

US20140272468A1 PHOTOCHROMIC ARTICLES THAT INCLUDE PHOTOCHROMIC-DICHROIC MATERIALS 有权
标题翻译：包含光致变色材料的光电制品
公开(公告)号：US20140272468A1
公开(公告)日：2014-09-18
申请号：US13835413
申请日：2013-03-15
申请人： Transitions Optical, Inc.
发明人： Rachael L. DeMeio , Anil Kumar , Meng He , Darrin R. Dabideen , Sujit Mondal
IPC分类号： G02B1/04
CPC分类号： G02B5/23 , B60J3/007 , C09K9/02 , C09K2211/1029 , C09K2211/1033 , C09K2211/1088 , G02B1/043 , G02B1/10 , G02B5/208 , G02B5/223 , G02C7/102 , G03C1/685 , G03C1/695 , G03C1/73 , C08L33/10 , C08L83/04
摘要： The present invention relates to photochromic articles that include a substrate and at least one photochromic material that is adapted to change from an unactivated form to an activated form by exposure to radiation substantially in the wavelength range from 380 to 450 nanometers when measured over a range of from 380 to 700 nanometers. The photochromic article is also adapted to retain at least 12 percent of the delta OD measured in the Outdoor Test when tested in the Behind the Windshield Test. The photochromic material can be selected from certain compounds including, for example, fluoranthenoxazines, naphthopyrans, phenanthropyrans, fluoranthenopyrans, and indenonaphthopyrans, which each have bonded thereto at least one chiral or achiral lengthening group that provides the photochromic compound with dichroic properties. The present invention also relates to methods of forming a photochromic article.
摘要翻译：本发明涉及光致变色制品，其包括基材和至少一种光致变色材料，其适于通过暴露于基本上在380至450纳米的波长范围内的辐射而从未活化形式转变为活化形式从380到700纳米。当在挡风玻璃测试后面进行测试时，光致变色制品也适用于保留户外测试中测量的ΔOD的至少12％。光致变色材料可以选自某些化合物，包括例如荧蒽酮，萘并吡喃，菲并吡喃，荧蒽吡喃和茚并萘并吡喃，它们各自具有至少一个提供具有二色性的光致变色化合物的手性或非手性延长基。本发明还涉及形成光致变色制品的方法。

7. 发明申请

US20140256935A1 5,6-RING-SUBSTITUTED NAPHTHOPYRAN COMPOUNDS 有权
标题翻译： 5,6环取代的萘普生化合物
公开(公告)号：US20140256935A1
公开(公告)日：2014-09-11
申请号：US13792345
申请日：2013-03-11
申请人： TRANSITIONS OPTICAL, INC.
发明人： Darrin R. Dabideen , Meng He , Anil Kumar
IPC分类号： G02B1/04
CPC分类号： G02B1/04 , C07D493/04 , C09K9/02 , C09K2211/1029 , C09K2211/1088 , G03C1/73
摘要： The present invention relates to naphthopyran compounds that include at least one compound represented by the following Formulas (I), (II), and (III): With reference to Formulas (I), (II), and (III), there is the proviso that: (i) at least one R1 is a group L; and/or (ii) B and/or B′ is substituted with at least one group L. The group L can be described as a lengthening group. The present invention also relates to photochromic-dichroic naphthopyran compounds and photochromic-dichroic articles containing such compounds.
摘要翻译：本发明涉及包含由下式（I），（II）和（III）表示的至少一种化合物的萘并吡喃化合物：参考式（I），（II）和（III）条件是：（i）至少一个R1是基团L; 和/或（ii）B和/或B'被至少一个基团L取代。基团L可以被描述为延长基团。本发明还涉及含有这些化合物的光致变色二色萘并吡喃化合物和光致变色二色性物品。

8. 发明授权

US10689317B2 Methods of making fused ring compounds 有权
公开(公告)号：US10689317B2
公开(公告)日：2020-06-23
申请号：US15881196
申请日：2018-01-26
申请人： Transitions Optical, Inc.
发明人： Meng He , Anil Kumar
IPC分类号： C07D405/04 , C07D407/04 , C07D311/94 , C07C51/353 , C07C37/11 , C07C41/01 , C07C39/17 , C07D307/33
摘要： The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C1-C6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R3 and R16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C1-C8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R16 is hydrogen, or an optionally substituted hydrocarbyl group).

9. 发明授权

US10532998B2 Photochromic compounds 有权
公开(公告)号：US10532998B2
公开(公告)日：2020-01-14
申请号：US16009254
申请日：2018-06-15
申请人： Transitions Optical, Inc.
发明人： Meng He , Darrin R. Dabideen , Terry A. Kellar, II , Anil Kumar
IPC分类号： C07D405/10 , G02C7/10 , G02B1/04 , G03C1/73 , G03C1/685 , G02B5/30 , G02B5/23 , C09K9/02 , C07D311/92 , G02B5/22 , C07D311/94
摘要： A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N3, —CN, —COOR′, —CCR′, —C(R′)C(R′)R′, —OCOR′, —OCOOR′, —SR′, —OSO2R″′, and/or —CON(R′)R′, wherein each R′ is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R″′ is —CF3 or a perfluorinated alkyl group having from 2 to 18 carbon atoms The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound.

10. 发明授权

US10145996B2 Photochromic articles that include photochromic-dichroic materials 有权
公开(公告)号：US10145996B2
公开(公告)日：2018-12-04
申请号：US15050500
申请日：2016-02-23
申请人： Transitions Optical, Inc.
发明人： Rachael L. DeMeio , Darrin R. Dabideen , Meng He , Anil Kumar , Sujit Mondal
IPC分类号： G02B5/23 , G02C7/02 , G02C7/10 , G03C1/685 , G03C1/695 , G03C1/73 , B60J3/00 , C09K9/02 , G02B1/04 , G02B5/20 , G02B5/22 , G02B1/10
摘要： The present invention relates to photochromic articles that include a substrate and at least one photochromic material that is adapted to change from an unactivated form to an activated form by exposure to radiation substantially in the wavelength range from 380 to 450 nanometers when measured over a range of from 380 to 700 nanometers. The photochromic article is also adapted to retain at least 12 percent of the delta OD measured in the Outdoor Test when tested in the Behind the Windshield Test. The photochromic material can be selected from certain compounds including, for example, fluoranthenoxazines, naphthopyrans, phenanthropyrans, fluoranthenopyrans, and indenonaphthopyrans, which each have bonded thereto at least one chiral or achiral lengthening group that provides the photochromic compound with dichroic properties. The present invention also relates to methods of forming a photochromic article.

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