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    • 1. 发明专利
    • 硫化物固体電解質材料
    • 硫化固体电解材料
    • JP2015032462A
    • 2015-02-16
    • JP2013161312
    • 2013-08-02
    • トヨタ自動車株式会社Toyota Motor Corp
    • HAMA SHIGEKIOSADA NAOMISUZUKI TOMOYA
    • H01M10/0562H01B1/06H01B1/10
    • 【課題】本発明は、Liイオン伝導性が高い硫化物固体電解質材料を提供することを主目的とする。【解決手段】本発明は、Li、A(Aは、P、Si、Ge、AlおよびBの少なくとも一種である)、およびSを有するイオン伝導体と、LiX(Xはハロゲンである)と、オルトオキソ酸リチウムとから構成されるガラスセラミックスであり、CuKα線を用いたX線回折測定において、2&thetas;=20.2?、23.6?にピークを有し、上記オルトオキソ酸リチウムの割合が、20mol%未満であることを特徴とする硫化物固体電解質材料を提供することにより、上記課題を解決する。【選択図】図1
    • 要解决的问题:提供具有高Li离子传导性的硫化物固体电解质材料。解决方案:硫化物固体电解质材料由玻璃陶瓷组成,其包括:具有Li,A(其中A表示P,Si ,Ge,Al和B)和S; LiX(其中X表示卤素); 和邻 - 含氧酸锂。 根据CuKα射线的X射线衍射测量,硫化物固体电解质材料在2θ= 20.2°和23.6°处具有峰值。 在硫化固体电解质材料中,邻 - 氧酸锂的含量小于20mol%。
    • 2. 发明专利
    • Method for producing sulfide solid electrolyte material and lithium solid battery
    • 硫酸固体电解质材料和锂离子电池的生产方法
    • JP2014127387A
    • 2014-07-07
    • JP2012284211
    • 2012-12-27
    • Toyota Motor Corpトヨタ自動車株式会社
    • OSADA NAOMIHAMA SHIGEKI
    • H01M10/0562C03C10/02C04B35/547H01B13/00H01M4/62H01M10/052H01M10/0585
    • Y02E60/122Y02P70/54Y02T10/7011
    • PROBLEM TO BE SOLVED: To provide a sulfide solid electrolyte material having high Li ion conductivity.SOLUTION: There are provided a method for producing a sulfide solid electrolyte material, and a lithium solid battery containing a sulfide solid electrolyte material produced by the method for producing a sulfide solid electrolyte material. The method for producing a sulfide solid electrolyte material comprises: an amorphization step of performing the amorphization of a raw material composition containing LiS, a sulfide of A (A represents at least one of P, Si, Ge, Al and B), and LiX (X represents a halogen) to synthesize sulfide glass; and a heat treatment step of heating the sulfide glass at a temperature of a crystallization temperature or above to synthesize glass ceramic. In the heat treatment step, the rate of temperature increase up to the crystallization temperature is 6°C/min or more.
    • 要解决的问题:提供具有高Li离子传导性的硫化物固体电解质材料。提供一种硫化物固体电解质材料的制造方法,以及含有通过该制造方法制造的硫化物固体电解质材料的锂固体电池 硫化物固体电解质材料。 硫化物固体电解质材料的制造方法包括:使含有LiS的原料组合物,A(A表示P,Si,Ge,Al和B中的至少一种)的硫化物和LiX的硫化物进行非晶化的非晶化工序 (X代表卤素)合成硫化物玻璃; 以及在结晶温度以上的温度下加热硫化玻璃以合成玻璃陶瓷的热处理工序。 在热处理步骤中,升温至结晶温度的速度为6℃/分钟以上。
    • 6. 发明专利
    • Battery system
    • 电池系统
    • JP2013041749A
    • 2013-02-28
    • JP2011177919
    • 2011-08-16
    • Toyota Motor Corpトヨタ自動車株式会社
    • HAMA SHIGEKIKATO YUKIOTOMO TAKATADAYAMAZAKI HISATSUGU
    • H01M16/00H01M2/10H01M10/0562H01M10/60H01M10/615H01M10/625H01M10/633H01M10/6571
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a battery system comprising a liquid electrolyte battery and capable of starting under low temperatures of -30°C or lower.SOLUTION: The battery system comprises a solid state battery comprising a solid electrolyte containing a sulfide solid electrolyte which has a composition represented by the formula: LiMPS, where M represents an element selected from Ge, Sb, Si, C, Sn, B, Al, Ga, In, Ti, Zr, V, and Nb, and x, y, and z represent the atomic ratio and satisfy x+my+5z=8, where m represents the valence of M, shows a peak at 2θ=29.58°±0.50° in an X-ray diffraction measurement with CuKα radiation, and satisfies the requirement that I/Iis less than 0.50, where Irepresents the diffraction intensity of the peak at 2θ=29.58°±0.50°, and Irepresents the diffraction intensity of a peak at 2θ=27.33°±0.50°; and a liquid electrolyte battery containing an electrolytic solution as an electrolyte.
    • 要解决的问题:提供一种包括液体电池并且能够在-30℃或更低的低温下起动的电池系统。 解决方案:电池系统包括固体电池,其包含含有硫化物固体电解质的固体电解质,所述固体电解质具有由下式表示的组成: y P z S 4 ,其中M表示选自Ge,Sb,Si ,C,Sn,B,Al,Ga,In,Ti,Zr,V和Nb,x,y和z表示原子比,满足x + my + 5z = 8,其中m表示M 在CuKα辐射的X射线衍射测定中,在2θ= 29.58°±0.50°处显示出峰值,满足I B / I A 小于0.50,其中I A 表示在2θ= 29.58°±0.50°处的峰的衍射强度,I B 表示在2θ= 27.33°±0.50°的峰的衍射强度; 以及含有电解液作为电解液的液体电解质电池。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Method of manufacturing all-solid lithium-ion secondary battery
    • 制造全固态锂离子二次电池的方法
    • JP2010205536A
    • 2010-09-16
    • JP2009049169
    • 2009-03-03
    • Toyota Motor Corpトヨタ自動車株式会社
    • UENO YUKIYOSHITSUCHIDA YASUSHIHAMA SHIGEKIKAMIYA MASATONAGASE HIROSHI
    • H01M10/0562H01M10/052H01M10/0585
    • Y02E60/122Y02P70/54
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing an all-solid lithium-ion secondary battery with enhanced energy density and improved durability. SOLUTION: The method of manufacturing the all-solid lithium-ion secondary battery comprises: an electrolyte layer-making step of mixing and molding a solid electrolyte to make up an electrolyte layer; a cathode layer-making step of mixing and molding a cathode material and the solid electrolyte to make up a cathode layer; an anode layer-making step of mixing and molding an anode material and the solid electrolyte to make up an anode layer; a laminate making step of laminating the cathode layer, the electrolyte layer, and the anode layer thus made in that order to make up a laminate; a battery making step of compressing the laminate made to make up a battery; and a charge and discharge treatment step of repeating charge and discharge of the battery for 10 hours or more and 40 hours or less. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种具有增强的能量密度和改进的耐久性的全固态锂离子二次电池的制造方法。 解决方案:制造全固体锂离子二次电池的方法包括:电解质层制备步骤,将固体电解质混合和模塑以构成电解质层; 阴极层制造步骤,将阴极材料和固体电解质混合并成型以构成阴极层; 负极层制造步骤,将负极材料和所述固体电解质混合并成型以构成阳极层; 层压制造步骤,其层叠由此制成的阴极层,电解质层和阳极层以构成层压体; 电池制造步骤,压缩构成电池的层压体; 以及将电池重复充放电10小时以上40小时以下的充放电处理工序。 版权所有(C)2010,JPO&INPIT