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    • 2. 发明专利
    • Production method of catalyst for cleaning emission gas
    • 用于清洁排放气体的催化剂的生产方法
    • JP2006314894A
    • 2006-11-24
    • JP2005138816
    • 2005-05-11
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • TAKAHASHI NAOKIARAYOSHI TAKATOSHI
    • B01J23/63B01D53/94B01J37/00B01J37/02
    • PROBLEM TO BE SOLVED: To provide a production method of a catalyst for cleaning emission gas having a catalyst layer of a double layer structure comprised of the upper layer and the lower layer, wherein enhances the porosity of the upper layer is raised and the grain growth of a noble metal in the upper layer is suppressed. SOLUTION: The upper coat layer with high porosity is formed by using a slurry containing a carrier powder and a burnt-off powder and burning off the burnt-off powder by calcining after wash coating on the surface of the under catalyst layer 2. Then, the upper catalyst layer 3 is formed by carrying the noble metal on the upper coat layer. At the time of calcination of the upper coat layer, the noble metal is not affected even under high temperature due to the heat of combustion of the burnt-off powder because the upper coat does not contain the noble metal. The noble metal chemical liquid used in the impregnation supporting method or absorption supporting method does not cause such a failure that the noble metal is carried to the lower layer because the noble metal chemical liquid has properties to be carried on the surface of the coat layer. COPYRIGHT: (C)2007,JPO&INPIT
    • 解决问题的方案:提供一种用于清洁具有由上层和下层构成的双层结构的催化剂层的排放气体的催化剂的制造方法,其中提高了上层的孔隙率, 上层的贵金属的晶粒生长被抑制。 解决方案:通过使用含有载体​​粉末和烧焦粉末的浆料形成具有高孔隙率的上涂层,并且在催化剂层2的表面上的洗涤涂层之后通过煅烧将烧焦粉末烧掉 然后,通过在上涂层上承载贵金属来形成上催化剂层3。 在上涂层煅烧时,由于上涂层不含有贵金属,所以贵金属即使在高温下也不会受到烧焦粉末的燃烧热的影响。 在浸渍辅助方法或吸收辅助方法中使用的贵金属化学液体不会导致贵金属被运送到下层的故障,因为贵金属化学液体具有在涂层的表面上承载的性质。 版权所有(C)2007,JPO&INPIT
    • 4. 发明专利
    • Inorganic oxide, catalyst carrier for cleaning exhaust gas and catalyst for cleaning exhaust gas
    • 无机氧化物,用于清洁排气的催化剂载体和用于清洁排气的催化剂
    • JP2006035019A
    • 2006-02-09
    • JP2004214939
    • 2004-07-22
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • MORIKAWA AKIRATANABE TOSHITAKAYAMAMURA YOSHIETAKAHASHI NAOKISUZUKI HIROMASAKUNO HISASHISATO AKEMIISHIKIRIYAMA MAMORUKANAZAWA TAKAAKI
    • B01J23/63B01D53/86B01J23/10B01J32/00B01J37/08C01G25/00F01N3/10
    • PROBLEM TO BE SOLVED: To provide an inorganic oxide in which grain growth of carried metals (rhodium, or the like) is sufficiently suppressed, a catalyst carrier for cleaning an exhaust gas comprising the same and a catalyst for cleaning the exhaust gas using the same. SOLUTION: The granular inorganic oxide contains aluminum oxide; a metal oxide not forming a composite oxide with aluminum oxide; and an addition element comprising at least one of a rare-earth element and an alkaline earth element and contains a secondary particle formed by coagulation of a primary particle. In the inorganic oxide, at least a part of the secondary particle is formed by coagulation of a plurality of the first primary particles with a particle diameter of 100 nm or less containing aluminum oxide and the addition element and a plurality of second primary particles with a particle diameter of 100 nm or less containing the metal oxide and the addition element. At least a part of the first and second primary particles has a surface thickening area where a content ratio of the addition element is locally enhanced at the surface layer part. COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供一种无机氧化物,其中承载的金属(铑等)的晶粒生长被充分抑制,用于清洁包含该催化剂的废气的催化剂载体和用于清洁排气的催化剂 使用相同 解决方案:粒状无机氧化物含有氧化铝; 不与氧化铝形成复合氧化物的金属氧化物; 以及包含稀土元素和碱土金属元素中的至少一种的添加元素,并且含有通过一次粒子凝聚而形成的二次粒子。 在无机氧化物中,至少一部分二次粒子是通过使包含氧化铝和添加元素的多个粒径为100nm以下的第一一次粒子和多个第二一次粒子与 含有金属氧化物和添加元素的粒径为100nm以下。 第一和第二初级颗粒的至少一部分具有表面增稠区域,其中添加元素的含量比在表层部分局部增强。 版权所有(C)2006,JPO&NCIPI
    • 6. 发明专利
    • Method for producing metal oxide
    • 生产金属氧化物的方法
    • JP2003313011A
    • 2003-11-06
    • JP2002120941
    • 2002-04-23
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • ISHIBASHI KAZUNOBUITO YUSUKESUDA AKIHIKOSOFUGAWA HIDEOTAKAHASHI NAOKI
    • B01D53/94B01J23/42B01J23/63B01J37/08C01B13/18C01F7/30C01G25/00
    • PROBLEM TO BE SOLVED: To provide a method for producing a metal oxide suitable for use as a catalyst carrier of a catalyst for cleaning of exhaust gas of an internal combustion engine and maintaining a large specific surface area with age and to provide a method for producing a multiple metal oxide having a widely selective composition and a large specific surface area. SOLUTION: In the method for producing a metal oxide, a solution prepared by dissolving at least one metal compound is impregnated into a porous material having pores and reducible to ashes, and after firing in a non-oxidizing atmosphere the porous material is burned and removed. Preferably the pores have 2-40 nm average pore diameter. When the multiple metal oxide is produced, preferably a solution prepared by dissolving at least two metal compounds is impregnated into the above porous material and the porous material is exposed to gaseous ammonia and fired in a non-oxidizing atmosphere. In the case where the metal compound is an aluminum compound, α-alumina is produced. COPYRIGHT: (C)2004,JPO
    • 解决问题的方法:提供适合用作内燃机的排气净化用催化剂的催化剂载体的金属氧化物的制造方法,并且随着时效维持大的比表面积, 具有广泛选择性组成和大比表面积的多金属氧化物的制造方法。 解决方案:在金属氧化物的制造方法中,将通过溶解至少一种金属化合物制备的溶液浸渍到具有孔隙并可还原成灰分的多孔材料中,并且在非氧化性气氛中烧成多孔材料 烧毁 优选孔具有2-40nm平均孔径。 当制备多重金属氧化物时,优选将通过溶解至少两种金属化合物制备的溶液浸渍到上述多孔材料中,并将多孔材料暴露于气态氨并在非氧化性气氛中烧制。 在金属化合物为铝化合物的情况下,制造α-氧化铝。 版权所有(C)2004,JPO