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1. 发明专利

JP2014024887A Chemical thermal storage medium, reactor, and thermal storage device 有权
标题翻译：化学热存储介质，反应器和热存储器件
公开(公告)号：JP2014024887A
公开(公告)日：2014-02-06
申请号：JP2012163905
申请日：2012-07-24
申请人： Denso Corp , 株式会社デンソー , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Nihon Univ , 学校法人日本大学
发明人： HAYASE TOMOHIRO , OKAMURA TORU , FUSE TAKUYA , KUWAYAMA KAZUTOSHI , MOCHIZUKI MIYO , SHIMAZU TAKASHI , FUKUSHIMA YOSHIAKI , HASEGAWA YORIKO , KISHIDA YOSHIHIRO , KOJIMA YOSHIYUKI
IPC分类号： C09K5/08 , C09K5/16 , F01N3/24 , F01N5/02 , F28D20/00
CPC分类号： Y02E60/142 , Y02E70/30 , Y02T10/16
摘要： PROBLEM TO BE SOLVED: To secure reversibility between a dehydration reaction and a hydration reaction in a chemical thermal storage medium which is a composite of a hydroxide of an alkali metal or an alkaline earth metal and a water-absorbing substance.SOLUTION: A chemical thermal storage medium is constituted of a plurality of particles 1 including Ca(OH)as a main component and a water-absorbing substance 2 existing on the surface thereof and a skeleton structure 3 forming a continuously shaped skeleton and formed between each of the particles 1. When the skeleton structure is not included in the chemical thermal storage medium, even if the reaction is shifted to a hydration reaction subsequent to a dehydration reaction, the hydration reaction scarcely proceeds because of coagulation of the chemical thermal storage medium in the dehydration reaction. On the other hand, by including the skeleton structure 3, the coagulation of the chemical thermal storage medium in the dehydration reaction is suppressed, and when the reaction is shifted to the hydration reaction subsequent to the dehydration reaction, the hydration reaction can be made to proceed.
摘要翻译：要解决的问题：为了确保作为碱金属或碱土金属的氢氧化物与吸水物质的复合物的化学热存储介质中的脱水反应和水合反应之间的可逆性。解决方案：化学热存储介质由包含Ca（OH）作为主要成分的多个颗粒1和存在于其表面上的吸水物质2和形成连续成形骨架并形成在每个颗粒1之间的骨架结构3构成。当骨架结构不包括在化学热储存介质中时，即使反应转变为脱水反应之后的水合反应，由于脱水反应中的化学热储存介质的凝结，几乎不进行水合反应。另一方面，通过包含骨架构造体3，抑制了脱水反应中的化学热存储介质的凝结，并且当反应转变为脱水反应之后的水合反应时，可以使水合反应继续。

2. 发明专利

JP2013113552A Chemical heat storage device 有权
标题翻译：化学储热装置
公开(公告)号：JP2013113552A
公开(公告)日：2013-06-10
申请号：JP2011262350
申请日：2011-11-30
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー
发明人： WAKASUGI TOMOHISA , SHIMAZU TAKASHI , KOMAKI KATSUYA , KUWAYAMA KAZUTOSHI , FUSE TAKUYA , NAKAGAWA TADAHIRO , SAEGUSA HIROSHI
IPC分类号： F25B17/08
摘要： PROBLEM TO BE SOLVED: To improve an energy utilization rate by recovering sensible heat remaining in a reaction vessel in which the regeneration of a chemical heat storage material is completed.SOLUTION: The chemical heat storage device includes: a first heat exchange part 11 and first reaction vessels 12 (a plurality of reaction vessels) heated by a chemical reaction with a reaction material 16 and having a chemical heat storage material 18 from which the reaction material 16 is desorbed by heating; an evaporative condenser 14 storing the reaction material 16, and supplying the reaction material 16 to the reaction vessels while recovering the reaction material 16 desorbed from the chemical heat storage material 18; and the first heat exchange part 11 allowing heat exchange between the first heat exchange part 11 and the first reaction vessels 12 ( the plurality of reaction vessels).
摘要翻译：解决的问题：通过回收在化学蓄热材料的再生完成的反应容器中残存的显热来提高能量利用率。解决方案：化学蓄热装置包括：通过与反应材料16的化学反应加热并具有化学蓄热材料18的第一热交换部分11和第一反应容器12（多个反应容器）反应物料16通过加热解吸; 储存反应材料16的蒸发冷凝器14，并且在回收从化学蓄热材料18脱附的反应材料16的同时将反应材料16供给到反应容器中; 以及允许第一热交换部11和第一反应容器12（多个反应容器）之间进行热交换的第一热交换部11。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2013113565A Chemical heat pump 有权
标题翻译：化学热泵
公开(公告)号：JP2013113565A
公开(公告)日：2013-06-10
申请号：JP2011262849
申请日：2011-11-30
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー
发明人： WAKASUGI TOMOHISA , SHIMAZU TAKASHI , SAEGUSA HIROSHI , KUWAYAMA KAZUTOSHI , FUSE TAKUYA , NAKAGAWA TADAHIRO , KOMAKI KATSUYA
IPC分类号： F25B17/08
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat pump allowing the progress of a chemical reaction even if no supply of heat from the outside and reducing a loss of reaction heat generated by the chemical reaction.SOLUTION: The chemical heat pump 10 includes a reactor 12 storing a chemical reaction material, and including a heat recovery apparatus 26 recovering reaction heat generated by the chemical reaction of the chemical reaction material, and a regenerating heat source 16 for returning the chemical reaction material after the chemical reaction into its original state; a medium storage container 14 storing a reaction medium for reacting on the chemical reaction material; and a communicating pipe 20 connecting the medium storage container 14 to the heat recovery apparatus 26 through a medium transporting means 22 for transporting the reaction medium in the medium storage container 14 to the reactor 12, and a flow regulating means 24 for regulating the flow of the reaction medium transported from the medium storage container 14 to the reactor 12, and connecting the heat recovery apparatus 26 to the reactor 12 through an external heat exchanger 28 supplying heat recovered by the heat recovery apparatus 26, to the outside.
摘要翻译：要解决的问题：即使没有从外部供应热量并且减少由化学反应产生的反应热的损失，提供允许化学反应进行的化学热泵。解决方案：化学热泵10包括存储化学反应材料的反应器12，并且包括回收由化学反应材料的化学反应产生的反应热的热回收装置26和再生热源16 化学反应物质化学反应进入其原始状态; 存储用于对化学反应材料发生反应的反应介质的介质储存容器14; 以及连通管20，其通过用于将介质储存容器14中的反应介质输送到反应器12的介质输送装置22将介质储存容器14连接到热回收装置26;以及流量调节装置24，反应介质从介质储存容器14输送到反应器12，并且通过供给由热回收装置26回收的热量的外部热交换器28将热回收装置26连接到反应器12到外部。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2013113564A Reactor for chemical heat storage 有权
标题翻译：化学储热反应器
公开(公告)号：JP2013113564A
公开(公告)日：2013-06-10
申请号：JP2011262847
申请日：2011-11-30
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー
发明人： WAKASUGI TOMOHISA , SHIMAZU TAKASHI , KOMAKI KATSUYA , KUWAYAMA KAZUTOSHI , FUSE TAKUYA , NAKAGAWA TADAHIRO , SAEGUSA HIROSHI
IPC分类号： F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To improve heat conduction/cutoff performance between a heater layer and a heat storage layer during hydration reaction, and a heat transfer promotion function between the heater layer and the heat storage layer during dehydration reaction.SOLUTION: A reactor 100 for chemical heat storage includes: a heat storage layer 110 filled with a chemical heat storage material storing heat through dehydration reaction by heating and radiating heat through hydration reaction; a heater layer 150 converting electric energy into thermal energy and heating the heat storage layer 110 during the dehydration reaction; and a heat transmission partition wall 104 making a partition between the heater layer 150 and heat storage layer 110, having a smaller coefficient of linear expansion than that of the heater layer 150, having a gap formed with the heater layer 150 during the hydration reaction, and coming into contact by thermal expansion of the heater layer 150 during the dehydration reaction, and thereby transmitting the heat of the heater layer 150 to the heat storage layer 110.
摘要翻译：要解决的问题：提高水合反应期间加热器层和储热层之间的热传导/截止性能，以及脱水反应期间加热器层和储热层之间的传热促进功能。解决方案：用于化学蓄热的反应器100包括：储热层110，填充有通过加热和通过水合反应辐射热而通过脱水反应储存热量的化学蓄热材料; 在脱水反应期间将电能转换为热能并加热蓄热层110的加热器层150; 以及在水合反应期间具有与加热层150形成的间隙的在加热器层150和蓄热层110之间形成隔板的传热分隔壁104，其具有比加热器层150更小的线性膨胀系数，并且在脱水反应期间通过加热层150的热膨胀而接触，从而将加热器层150的热量传递到储热层110.版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2014206363A 化学蓄熱装置有权
标题翻译：化学储热装置
公开(公告)号：JP2014206363A
公开(公告)日：2014-10-30
申请号：JP2013231652
申请日：2013-11-08
申请人：株式会社デンソー , Denso Corp , 株式会社豊田中央研究所 , Toyota Central R&D Labs Inc
发明人： OKAMURA TORU , IMAMURA TOMONORI , KOMAKI KATSUYA , FUSE TAKUYA , KUWAYAMA KAZUTOSHI , WAKASUGI TOMOHISA , SHIMAZU TAKASHI , MOCHIZUKI MIYO , MITSUI HIROYUKI
IPC分类号： F28D20/00
CPC分类号： Y02E60/142
摘要：【課題】目標とする反応率を得るための時間を早くすることができ、COPの低下を抑制可能な化学蓄熱装置を提供する。【解決手段】化学蓄熱装置1は、流体状態の反応媒体20が器内に流入、器外に流出可能に構成され、反応媒体20と可逆的な熱化学反応を生じさせる反応物21と、器内外との間で熱を授受可能な熱交換部22とを備えた反応器2を有する。化学蓄熱装置1は、反応器2内に流入した反応媒体20と反応物21との反応により化合物を生成させる発熱反応の反応熱を反応器2外に放出する放熱モードと、反応器2外から供給された熱にて化合物を反応媒体20と反応物21とに分解する吸熱反応による反応媒体20を反応器2外に流出させる蓄熱モードとを動作可能である。化学蓄熱装置1は、放熱モードの発熱反応及び/又は蓄熱モードの吸熱反応の反応速度を制御するよう構成されている。【選択図】図2
摘要翻译：要解决的问题：提供一种能够缩短获得目标反应速度所需时间并抑制COP降解的化学蓄热装置。解决方案：化学蓄热装置1包括构造成能够流动的反应器2 反应器2中的流体状态的反应介质20，其包括反应物21，其与反应性介质20产生可逆的热化学反应，热交换器22向反应器2的外部转移和接收热量化学蓄热装置1可以以放热模式工作，其中通过流入反应器2的反应介质20和反应物21之间的反应产生化合物的放热反应的热反应热到反应器2或储热模式，其中通过用于将化合物分解成反应性介质的吸热反应使反应性介质20从反应器2流出 20和反应物21通过从反应器2的外部供应的热量。化学蓄热装置1被配置为控制放热模式中的放热反应和/或热量中的吸热反应的反应速度存储模式。

6. 发明专利

JP2014180980A Chemical thermal storage air-conditioning system 有权
标题翻译：化学热储存空调系统
公开(公告)号：JP2014180980A
公开(公告)日：2014-09-29
申请号：JP2013057969
申请日：2013-03-21
申请人： Denso Corp , 株式会社デンソー , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： AKITA KENJI , KOMAKI KATSUYA , GOTO YOSUKE , KUWAYAMA KAZUTOSHI , WAKASUGI TOMOHISA , SHIMAZU TAKASHI , MITSUI HIROYUKI , MOCHIZUKI MIYO
IPC分类号： B60H1/08 , C09K5/16 , F25B17/08 , F25B27/02 , F28D20/00
CPC分类号： Y02A30/274 , Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical thermal storage air-conditioning system that enables indoor air-conditioning by an extremely simple configuration using a reactor having a built-in chemical thermal storage medium and evaporation/condensation means.SOLUTION: A chemical thermal storage air-conditioning system 1 comprises: a reactor 3 having a built-in chemical thermal storage medium 31; evaporation/condensation means 4 for evaporating water W used for hydration reaction of the chemical thermal storage medium 31 and condensing water W generated by dehydration reaction of the chemical thermal storage medium 31; and air-conditioning piping 2 through which air A coming into contact with at least one of the reactor 3 and the evaporation/condensation means 4 passes. In the chemical thermal storage air-conditioning system 1, the evaporation/condensation means 4 is made to function as an evaporator 41, and when water W evaporated by the evaporator 41 is supplied to the reactor 3, the air A passing through the air-conditioning piping 2 is heated or cooled by using at least one of heat generated during the hydration reaction of the chemical thermal storage medium 31 and heat deprived of by the evaporation/condensation means 4 during the hydration reaction, so as to perform air-conditioning.
摘要翻译：要解决的问题：提供一种化学热存储空调系统，其使用具有内置化学热存储介质和蒸发/冷凝装置的反应器，通过非常简单的配置实现室内空调。解决方案：化学热存储空调系统1包括：具有内置化学蓄热介质31的反应器3; 用于蒸发水的蒸发/冷凝装置4，用于化学热存储介质31的水合反应和由化学热存储介质31的脱水反应产生的冷凝水W; 空气A与反应器3和蒸发/冷凝装置4中的至少一个接触的空调管路2通过。在化学热存储空调系统1中，使蒸发/冷凝装置4用作蒸发器41，并且当通过蒸发器41蒸发的水W被供应到反应器3时，通过空气 - 通过在水合反应期间使用在化学蓄热介质31的水合反应期间产生的热量和被蒸发/冷凝装置4剥夺的热量中的至少一种来加热或冷却调节管道2，从而进行空气调节。

7. 发明专利

JP2013112310A Chemical heat accumulation system for vehicle and air conditioning system provided with the same 有权
标题翻译：用于车辆和空调系统的化学热量累积系统
公开(公告)号：JP2013112310A
公开(公告)日：2013-06-10
申请号：JP2011262848
申请日：2011-11-30
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー
发明人： WAKASUGI TOMOHISA , SHIMAZU TAKASHI , KOMAKI KATSUYA , KUWAYAMA KAZUTOSHI , FUSE TAKUYA , NAKAGAWA TADAHIRO , SAEGUSA HIROSHI
IPC分类号： B60H1/08 , B60H1/20 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat accumulation system for vehicle which can be used as a heat source of an air conditioning system for vehicle and an air conditioning system for vehicle provided with the same.SOLUTION: A chemical heat accumulation system 60 for vehicle includes a reactor 62, a condenser 80, an evaporator 90, and a water tank 100. In a container 64 of the reactor 62, there is provided a reaction flow passage 64A in which a chemical thermal storage medium 66 is charged. Further, in the container 64 of the reactor 62, there is provided a refrigerant flow passage 64C. A heat emission line 72 is connected to the refrigerant flow passage 64C, and heat exchange is performed between engine cooling water flowing through the heat emission line 72 and the reactor 62. As a result, heat generated along with hydration reaction of the chemical thermal storage medium 66 is emitted into the engine cooling water, so that the engine cooling water is heated. The heated engine cooling water is supplied to a heater core 22, and the heater core 22 performs heat exchange with an air conditioning air flowing through an air conditioning case 32, so that air for air conditioning is heated.
摘要翻译：要解决的问题：提供一种可用作车辆空调系统的热源的车辆用化学蓄热系统和具备该车辆的车辆用空调系统。解决方案：用于车辆的化学热积聚系统60包括反应器62，冷凝器80，蒸发器90和水箱100.在反应器62的容器64中，设置有反应流路64A，化学热存储介质66被充电。此外，在反应器62的容器64中设置有制冷剂流路64C。发热管线72与制冷剂流路64C连接，并且在流过发热管线72的发动机冷却水和反应器62之间进行热交换。结果，与化学热存储器的水合反应一起产生的热量介质66被排放到发动机冷却水中，使得发动机冷却水被加热。加热的发动机冷却水被供给到加热器芯22，并且加热器芯22与流过空调壳体32的空调空气进行热交换，从而加热用于空调的空气。版权所有（C）2013，JPO＆INPIT

8. 发明专利

JP2014180981A Chemical thermal storage air-conditioning system 有权
标题翻译：化学热储存空调系统
公开(公告)号：JP2014180981A
公开(公告)日：2014-09-29
申请号：JP2013057970
申请日：2013-03-21
申请人： Denso Corp , 株式会社デンソー , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： AKITA KENJI , KUWAYAMA KAZUTOSHI , KOMAKI KATSUYA , GOTO YOSUKE , WAKASUGI TOMOHISA , SHIMAZU TAKASHI , MITSUI HIROYUKI , MOCHIZUKI MIYO
IPC分类号： B60H1/20 , B60H1/32 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical thermal storage air-conditioning system that can effectively store sensible heat remaining in a reactor after dehydration reaction of a chemical thermal storage medium and can appropriately control a temperature of air during hydration reaction of the chemical thermal storage medium.SOLUTION: In a chemical thermal storage air-conditioning system 1, during dehydration reaction of a chemical thermal storage medium 21, water W is recovered to a heat exchange type water tank 4 via a condenser 32, and immediately after completion of the dehydration reaction of the chemical thermal storage medium 21 or during hydration reaction, heat generated by the dehydration reaction of the chemical thermal storage medium 21 is stored in the heat exchange type water tank 4 via a heat exchanger 25. In the chemical thermal storage air-conditioning system 1, during hydration reaction of the chemical thermal storage medium 21, when the water W recovered to the heat exchange type water tank 4 is supplied to a reactor 2 via an evaporator 31, heat stored in the heat exchange type water tank 4 is used as a heat source of the evaporator 31, and by using heat generated by the hydration reaction of the chemical thermal storage medium 21, a temperature of air A passing through air-conditioning piping 6 and coming into contact with the reactor 2 and the heat exchanger 25 is controlled.
摘要翻译：要解决的问题：提供一种化学热存储空调系统，其可以有效地存储化学热存储介质的脱水反应之后残留在反应器中的显热，并且可以适当地控制化学热存储器的水合反应期间的空气温度介质：在化学热存储空调系统1中，在化学储热介质21的脱水反应期间，水W通过冷凝器32回收到热交换型水箱4中，并且在脱水完成后立即化学热存储介质21的反应或水合反应期间，化学热存储介质21的脱水反应产生的热量经由热交换器25储存在热交换型水箱4中。在化学热存储空调系统1在化学蓄热介质21的水合反应期间，当水W回收到热量时交换型水箱4通过蒸发器31供给到反应器2，将存储在热交换型水箱4中的热量用作蒸发器31的热源，并且通过化学热的水合反应产生的热量存储介质21，控制通过空调管路6并与反应器2和热交换器25接触的空气A的温度。

9. 发明专利

JP2013216763A Chemical heat storage material, and reaction device, heat storage device, and vehicle 有权
标题翻译：化学储热材料和反应装置，储热装置和车辆
公开(公告)号：JP2013216763A
公开(公告)日：2013-10-24
申请号：JP2012087786
申请日：2012-04-06
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー , Nihon Univ , 学校法人日本大学
发明人： SHIMAZU TAKASHI , MOCHIZUKI MIYO , FUKUSHIMA YOSHIAKI , KISHIDA YOSHIHIRO , HASEGAWA YORIKO , OKAMURA TORU , FUSE TAKUYA , KUWAYAMA KAZUTOSHI , KOMAKI KATSUYA , KOJIMA YOSHIYUKI
IPC分类号： C09K5/16 , C01F11/24 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat storage material which has a large heat storage density, and with which heat storage (dehydration) is conducted at lower temperature and more stably compared with a chemically non-composite chemical heat storage material, and to provide a reaction device.SOLUTION: A heat storage device 100 mounted on a vehicle 200 includes a reaction device 10 with a composite heat storage material 14 represented by structural formula (1) including a structure in which an alkaline earth metal hydroxide and an alkali metal chloride are chemically bonded to each other, wherein a ratio of the alkali metal chloride content with respect to the total mass is >0 to ≤6.8 mass% (Mis an alkali metal, Mis an alkaline earth metal, a to d satisfy 2a≥d, b>0, c>0, and d>0), provided therein. The structural formula (1) is represented: MMCl(OH).
摘要翻译：要解决的问题：提供一种具有较大储热密度的化学蓄热材料，与化学非复合化学蓄热材料相比，在较低的温度下更稳定地进行储热（脱水），并且与提供反应装置。解决方案：安装在车辆200上的蓄热装置100包括具有由结构式（1）表示的复合蓄热材料14的反应装置10，其包括其中碱土金属氢氧化物和碱金属氯化物彼此化学键合，其中碱金属氯化物含量相对于总质量的比例> 0〜≤6.8质量％（Mis碱金属，Mis碱土金属，a至d满足2a≥d ，b> 0，c> 0和d> 0）。结构式（1）表示为：MMCl（OH）。

10. 发明专利

JP2013115996A Energy storing unit 有权
标题翻译：能源储存单位
公开(公告)号：JP2013115996A
公开(公告)日：2013-06-10
申请号：JP2011262351
申请日：2011-11-30
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー
发明人： WAKASUGI TOMOHISA , SHIMAZU TAKASHI , SAEGUSA HIROSHI , KUWAYAMA KAZUTOSHI , FUSE TAKUYA , NAKAGAWA TADAHIRO , KOMAKI KATSUYA
IPC分类号： H02J15/00 , H01M10/48
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To cope with a large amount of heat demand, and compatibly realize the miniaturization and cost reduction of a system.SOLUTION: There is provided an energy storing unit comprising: power generation means 12; a secondary battery 14 that is electrically connected to the power generation means 12 and storing electric power generated by the power generation means 12 as chemical energy, while the secondary battery 14 can convert the chemical energy to electric power and discharge the electric power; and a chemical heat storage device 16 including an electric heater electrically connected to the power generation means 12, the electric heater converting electric power to heat energy, and also including a chemical heat storage material that can be reversibly bonded to a reaction material. The heat storage device 16 is capable of storing heat by separating the chemical heat storage material and the reaction material by the heat energy, while capable of discharging the heat energy by reacting the chemical heat storage material and the reaction material.
摘要翻译：要解决的问题：为了应对大量的热需求，兼容地实现了系统的小型化和降低成本。解决方案：提供一种能量存储单元，包括：发电装置12; 与发电装置12电连接并蓄积由发电装置12产生的电力作为化学能的二次电池14，二次电池14可以将化学能转换成电力并放电; 以及具有与发电装置12电连接的电加热器，电加热器将电力转换成热能的化学蓄热装置16，还包括能够可逆地结合到反应材料上的化学蓄热材料。蓄热装置16能够通过利用热能分离化学蓄热材料和反应材料来储存热量，同时能够通过使化学蓄热材料和反应材料反应来排出热能。版权所有（C）2013，JPO＆INPIT

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