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1. 发明专利

JP2014024887A Chemical thermal storage medium, reactor, and thermal storage device 有权
标题翻译：化学热存储介质，反应器和热存储器件
公开(公告)号：JP2014024887A
公开(公告)日：2014-02-06
申请号：JP2012163905
申请日：2012-07-24
申请人： Denso Corp , 株式会社デンソー , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Nihon Univ , 学校法人日本大学
发明人： HAYASE TOMOHIRO , OKAMURA TORU , FUSE TAKUYA , KUWAYAMA KAZUTOSHI , MOCHIZUKI MIYO , SHIMAZU TAKASHI , FUKUSHIMA YOSHIAKI , HASEGAWA YORIKO , KISHIDA YOSHIHIRO , KOJIMA YOSHIYUKI
IPC分类号： C09K5/08 , C09K5/16 , F01N3/24 , F01N5/02 , F28D20/00
CPC分类号： Y02E60/142 , Y02E70/30 , Y02T10/16
摘要： PROBLEM TO BE SOLVED: To secure reversibility between a dehydration reaction and a hydration reaction in a chemical thermal storage medium which is a composite of a hydroxide of an alkali metal or an alkaline earth metal and a water-absorbing substance.SOLUTION: A chemical thermal storage medium is constituted of a plurality of particles 1 including Ca(OH)as a main component and a water-absorbing substance 2 existing on the surface thereof and a skeleton structure 3 forming a continuously shaped skeleton and formed between each of the particles 1. When the skeleton structure is not included in the chemical thermal storage medium, even if the reaction is shifted to a hydration reaction subsequent to a dehydration reaction, the hydration reaction scarcely proceeds because of coagulation of the chemical thermal storage medium in the dehydration reaction. On the other hand, by including the skeleton structure 3, the coagulation of the chemical thermal storage medium in the dehydration reaction is suppressed, and when the reaction is shifted to the hydration reaction subsequent to the dehydration reaction, the hydration reaction can be made to proceed.
摘要翻译：要解决的问题：为了确保作为碱金属或碱土金属的氢氧化物与吸水物质的复合物的化学热存储介质中的脱水反应和水合反应之间的可逆性。解决方案：化学热存储介质由包含Ca（OH）作为主要成分的多个颗粒1和存在于其表面上的吸水物质2和形成连续成形骨架并形成在每个颗粒1之间的骨架结构3构成。当骨架结构不包括在化学热储存介质中时，即使反应转变为脱水反应之后的水合反应，由于脱水反应中的化学热储存介质的凝结，几乎不进行水合反应。另一方面，通过包含骨架构造体3，抑制了脱水反应中的化学热存储介质的凝结，并且当反应转变为脱水反应之后的水合反应时，可以使水合反应继续。

2. 发明专利

JP2013216763A Chemical heat storage material, and reaction device, heat storage device, and vehicle 有权
标题翻译：化学储热材料和反应装置，储热装置和车辆
公开(公告)号：JP2013216763A
公开(公告)日：2013-10-24
申请号：JP2012087786
申请日：2012-04-06
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー , Nihon Univ , 学校法人日本大学
发明人： SHIMAZU TAKASHI , MOCHIZUKI MIYO , FUKUSHIMA YOSHIAKI , KISHIDA YOSHIHIRO , HASEGAWA YORIKO , OKAMURA TORU , FUSE TAKUYA , KUWAYAMA KAZUTOSHI , KOMAKI KATSUYA , KOJIMA YOSHIYUKI
IPC分类号： C09K5/16 , C01F11/24 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat storage material which has a large heat storage density, and with which heat storage (dehydration) is conducted at lower temperature and more stably compared with a chemically non-composite chemical heat storage material, and to provide a reaction device.SOLUTION: A heat storage device 100 mounted on a vehicle 200 includes a reaction device 10 with a composite heat storage material 14 represented by structural formula (1) including a structure in which an alkaline earth metal hydroxide and an alkali metal chloride are chemically bonded to each other, wherein a ratio of the alkali metal chloride content with respect to the total mass is >0 to ≤6.8 mass% (Mis an alkali metal, Mis an alkaline earth metal, a to d satisfy 2a≥d, b>0, c>0, and d>0), provided therein. The structural formula (1) is represented: MMCl(OH).
摘要翻译：要解决的问题：提供一种具有较大储热密度的化学蓄热材料，与化学非复合化学蓄热材料相比，在较低的温度下更稳定地进行储热（脱水），并且与提供反应装置。解决方案：安装在车辆200上的蓄热装置100包括具有由结构式（1）表示的复合蓄热材料14的反应装置10，其包括其中碱土金属氢氧化物和碱金属氯化物彼此化学键合，其中碱金属氯化物含量相对于总质量的比例> 0〜≤6.8质量％（Mis碱金属，Mis碱土金属，a至d满足2a≥d ，b> 0，c> 0和d> 0）。结构式（1）表示为：MMCl（OH）。

3. 发明专利

JP2014206363A 化学蓄熱装置有权
标题翻译：化学储热装置
公开(公告)号：JP2014206363A
公开(公告)日：2014-10-30
申请号：JP2013231652
申请日：2013-11-08
申请人：株式会社デンソー , Denso Corp , 株式会社豊田中央研究所 , Toyota Central R&D Labs Inc
发明人： OKAMURA TORU , IMAMURA TOMONORI , KOMAKI KATSUYA , FUSE TAKUYA , KUWAYAMA KAZUTOSHI , WAKASUGI TOMOHISA , SHIMAZU TAKASHI , MOCHIZUKI MIYO , MITSUI HIROYUKI
IPC分类号： F28D20/00
CPC分类号： Y02E60/142
摘要：【課題】目標とする反応率を得るための時間を早くすることができ、COPの低下を抑制可能な化学蓄熱装置を提供する。【解決手段】化学蓄熱装置1は、流体状態の反応媒体20が器内に流入、器外に流出可能に構成され、反応媒体20と可逆的な熱化学反応を生じさせる反応物21と、器内外との間で熱を授受可能な熱交換部22とを備えた反応器2を有する。化学蓄熱装置1は、反応器2内に流入した反応媒体20と反応物21との反応により化合物を生成させる発熱反応の反応熱を反応器2外に放出する放熱モードと、反応器2外から供給された熱にて化合物を反応媒体20と反応物21とに分解する吸熱反応による反応媒体20を反応器2外に流出させる蓄熱モードとを動作可能である。化学蓄熱装置1は、放熱モードの発熱反応及び/又は蓄熱モードの吸熱反応の反応速度を制御するよう構成されている。【選択図】図2
摘要翻译：要解决的问题：提供一种能够缩短获得目标反应速度所需时间并抑制COP降解的化学蓄热装置。解决方案：化学蓄热装置1包括构造成能够流动的反应器2 反应器2中的流体状态的反应介质20，其包括反应物21，其与反应性介质20产生可逆的热化学反应，热交换器22向反应器2的外部转移和接收热量化学蓄热装置1可以以放热模式工作，其中通过流入反应器2的反应介质20和反应物21之间的反应产生化合物的放热反应的热反应热到反应器2或储热模式，其中通过用于将化合物分解成反应性介质的吸热反应使反应性介质20从反应器2流出 20和反应物21通过从反应器2的外部供应的热量。化学蓄热装置1被配置为控制放热模式中的放热反应和/或热量中的吸热反应的反应速度存储模式。

4. 发明专利

JP2014180980A Chemical thermal storage air-conditioning system 有权
标题翻译：化学热储存空调系统
公开(公告)号：JP2014180980A
公开(公告)日：2014-09-29
申请号：JP2013057969
申请日：2013-03-21
申请人： Denso Corp , 株式会社デンソー , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： AKITA KENJI , KOMAKI KATSUYA , GOTO YOSUKE , KUWAYAMA KAZUTOSHI , WAKASUGI TOMOHISA , SHIMAZU TAKASHI , MITSUI HIROYUKI , MOCHIZUKI MIYO
IPC分类号： B60H1/08 , C09K5/16 , F25B17/08 , F25B27/02 , F28D20/00
CPC分类号： Y02A30/274 , Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical thermal storage air-conditioning system that enables indoor air-conditioning by an extremely simple configuration using a reactor having a built-in chemical thermal storage medium and evaporation/condensation means.SOLUTION: A chemical thermal storage air-conditioning system 1 comprises: a reactor 3 having a built-in chemical thermal storage medium 31; evaporation/condensation means 4 for evaporating water W used for hydration reaction of the chemical thermal storage medium 31 and condensing water W generated by dehydration reaction of the chemical thermal storage medium 31; and air-conditioning piping 2 through which air A coming into contact with at least one of the reactor 3 and the evaporation/condensation means 4 passes. In the chemical thermal storage air-conditioning system 1, the evaporation/condensation means 4 is made to function as an evaporator 41, and when water W evaporated by the evaporator 41 is supplied to the reactor 3, the air A passing through the air-conditioning piping 2 is heated or cooled by using at least one of heat generated during the hydration reaction of the chemical thermal storage medium 31 and heat deprived of by the evaporation/condensation means 4 during the hydration reaction, so as to perform air-conditioning.
摘要翻译：要解决的问题：提供一种化学热存储空调系统，其使用具有内置化学热存储介质和蒸发/冷凝装置的反应器，通过非常简单的配置实现室内空调。解决方案：化学热存储空调系统1包括：具有内置化学蓄热介质31的反应器3; 用于蒸发水的蒸发/冷凝装置4，用于化学热存储介质31的水合反应和由化学热存储介质31的脱水反应产生的冷凝水W; 空气A与反应器3和蒸发/冷凝装置4中的至少一个接触的空调管路2通过。在化学热存储空调系统1中，使蒸发/冷凝装置4用作蒸发器41，并且当通过蒸发器41蒸发的水W被供应到反应器3时，通过空气 - 通过在水合反应期间使用在化学蓄热介质31的水合反应期间产生的热量和被蒸发/冷凝装置4剥夺的热量中的至少一种来加热或冷却调节管道2，从而进行空气调节。

5. 发明专利

JP2013112310A Chemical heat accumulation system for vehicle and air conditioning system provided with the same 有权
标题翻译：用于车辆和空调系统的化学热量累积系统
公开(公告)号：JP2013112310A
公开(公告)日：2013-06-10
申请号：JP2011262848
申请日：2011-11-30
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Denso Corp , 株式会社デンソー
发明人： WAKASUGI TOMOHISA , SHIMAZU TAKASHI , KOMAKI KATSUYA , KUWAYAMA KAZUTOSHI , FUSE TAKUYA , NAKAGAWA TADAHIRO , SAEGUSA HIROSHI
IPC分类号： B60H1/08 , B60H1/20 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat accumulation system for vehicle which can be used as a heat source of an air conditioning system for vehicle and an air conditioning system for vehicle provided with the same.SOLUTION: A chemical heat accumulation system 60 for vehicle includes a reactor 62, a condenser 80, an evaporator 90, and a water tank 100. In a container 64 of the reactor 62, there is provided a reaction flow passage 64A in which a chemical thermal storage medium 66 is charged. Further, in the container 64 of the reactor 62, there is provided a refrigerant flow passage 64C. A heat emission line 72 is connected to the refrigerant flow passage 64C, and heat exchange is performed between engine cooling water flowing through the heat emission line 72 and the reactor 62. As a result, heat generated along with hydration reaction of the chemical thermal storage medium 66 is emitted into the engine cooling water, so that the engine cooling water is heated. The heated engine cooling water is supplied to a heater core 22, and the heater core 22 performs heat exchange with an air conditioning air flowing through an air conditioning case 32, so that air for air conditioning is heated.
摘要翻译：要解决的问题：提供一种可用作车辆空调系统的热源的车辆用化学蓄热系统和具备该车辆的车辆用空调系统。解决方案：用于车辆的化学热积聚系统60包括反应器62，冷凝器80，蒸发器90和水箱100.在反应器62的容器64中，设置有反应流路64A，化学热存储介质66被充电。此外，在反应器62的容器64中设置有制冷剂流路64C。发热管线72与制冷剂流路64C连接，并且在流过发热管线72的发动机冷却水和反应器62之间进行热交换。结果，与化学热存储器的水合反应一起产生的热量介质66被排放到发动机冷却水中，使得发动机冷却水被加热。加热的发动机冷却水被供给到加热器芯22，并且加热器芯22与流过空调壳体32的空调空气进行热交换，从而加热用于空调的空气。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2012215324A Chemical heat accumulator 有权
标题翻译：化学热收缩剂
公开(公告)号：JP2012215324A
公开(公告)日：2012-11-08
申请号：JP2011079727
申请日：2011-03-31
申请人： Toyota Central R&D Labs Inc , Denso Corp , 株式会社デンソー , 株式会社豊田中央研究所
发明人： SHIMAZU TAKASHI , WAKASUGI TOMOHISA , MITSUI HIROYUKI , SOFUGAWA HIDEO , KOMAKI KATSUYA , SAEGUSA HIROSHI , NAKAGAWA TADAHIRO
IPC分类号： F28D20/00 , C09K5/16 , F01N3/20 , F01N3/24 , F01N3/28
CPC分类号： F28D20/003 , Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat accumulator can not only generate high temperatures but also suppress the internal pressure of a sealing system low and be downsized.SOLUTION: A chemical heat accumulator 10 includes: a receptacle 12 which pools water; a first reaction vessel 14 integrating a chemical heat accumulation material 34 connected to the receptacle 12 in a sealed state to not only supply water from the receptacle 12 but also react with the water supplied from the receptacle 12 to generate steam by the heat of reaction and generate a dehydration reaction by heating; a second reaction vessel 16 integrating a chemical heat storage material 44 connected to the first reaction vessel 14 under the sealed status to not only supply steam from the first reaction vessel 14 but also generate heat by generating a hydration reaction by the steam supplied from first reaction vessel 14, store the heat by generating a dehydration reaction by heating, and thermally contact with a catalyst 46; and a condenser 18 connected to the second reaction vessel 16 in the sealed state not only to supply the steam generated from the second reaction vessel 16 in association with the dehydration reaction to condense the steam supplied from the second reaction vessel 16.
摘要翻译：要解决的问题：提供化学蓄热器不仅可以产生高温，而且可以抑制密封系统的内部压力低并且被小型化。解决方案：化学蓄热器10包括：容器12，其收集水; 第一反应容器14将密封状态下连接到容器12的化学蓄热材料34整合，不仅从容器12供给水，而且与从容器12供应的水反应，以通过反应热产生蒸汽，通过加热产生脱水反应; 在密封状态下将与第一反应容器14连接的化学蓄热材料44整合在一起的第二反应容器16不仅能够从第一反应容器14供给蒸汽，而且还通过由第一反应供给的蒸汽产生水化反应而产生热量容器14通过加热产生脱水反应并与催化剂46热接触来储存热量; 以及在密封状态下连接到第二反应容器16的冷凝器18，不仅能够提供与脱水反应相关联的从第二反应容器16产生的蒸汽，以冷凝从第二反应容器16供应的蒸汽。（C）2013，JPO＆INPIT

7. 发明专利

JP2011196661A Heat accumulator 有权
标题翻译：热量累加器
公开(公告)号：JP2011196661A
公开(公告)日：2011-10-06
申请号：JP2010066888
申请日：2010-03-23
申请人： Denso Corp , Toyota Central R&D Labs Inc , 株式会社デンソー , 株式会社豊田中央研究所
发明人： SHIMAZU TAKASHI , MITSUI HIROYUKI , FUKUSHIMA YOSHIAKI , WAKAYAMA HIROAKI , FUSE TAKUYA , SAEGUSA HIROSHI
IPC分类号： F28D20/00 , C09K5/16
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a heat accumulator capable of improving the durability as a chemical thermal storage medium complex or chemical thermal storage medium molding, and capable of securing a heat transfer route to the chemical heat storage material complex or chemical heat storage material molding.SOLUTION: A heat exchange heat storing and radiating device 10 as the heat accumulator includes: a chemical heat storage material composite molding 11 obtained by mixing a powder chemical heat storage material 12 and copper powder 32 at a predetermined ratio and sintering; a metallic heat exchanger body 18 that accommodates the chemical heat storage material composite molding 11; and a copper foil film 30 provided on a surface of chemical heat storage material composite molding 11 to form a contact surface with an inner face of heat exchanger body 18.
摘要翻译：要解决的问题：提供一种能够提高作为化学储热介质复合体或化学蓄热介质成型的耐久性的蓄热器，并且能够确保向化学储热材料配合物或化学蓄热材料成型的热传递路线解决方案：作为蓄热器的热交换蓄热和散热装置10包括：通过以预定比例混合粉末化学蓄热材料12和铜粉32并烧结而获得的化学蓄热材料复合模制件11; 容纳化学蓄热材料复合成型体11的金属制热交换器体18; 以及设置在化学蓄热材料复合模塑件11的表面上以与热交换器主体18的内表面形成接触表面的铜箔膜30。

8. 发明专利

JP2011027311A Chemical heat storage device 有权
标题翻译：化学储热装置
公开(公告)号：JP2011027311A
公开(公告)日：2011-02-10
申请号：JP2009172953
申请日：2009-07-24
申请人： Denso Corp , Toyota Central R&D Labs Inc , 株式会社デンソー , 株式会社豊田中央研究所
发明人： WAKAYAMA HIROAKI , FUKUSHIMA YOSHIAKI , SHIMAZU TAKASHI , MITSUI HIROYUKI , SOFUGAWA HIDEO , SAEGUSA HIROSHI , INOUE SATORU
IPC分类号： F28D20/00 , F28F19/02
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat storage device capable of preventing decline in a reaction rate of a chemical thermal storage medium when used repeatedly. SOLUTION: The chemical heat storage device is constituted so that (1) the chemical heat storage device includes a heat storage body having the chemical thermal storage medium absorbing/generating heat by dehydration-hydration reaction and a heat transfer body made of a heat transfer material to give/receive heat to/from the chemical thermal storage medium and (2) the heat transfer body includes a hydroxyl group or oxide film on a face coming into contact with the chemical thermal storage medium. The heat storage body is a formed body or porous sintered body including the chemical thermal storage medium, and the heat transfer body may be a heat transfer wall coming into contact with the periphery of the formed body or sintered body. The heat storage body may be a composite body including powder of the chemical thermal storage medium and the heat transfer body interposed in the powder of the chemical thermal storage medium. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供能够防止化学蓄热介质反复使用时的反应速度下降的化学蓄热装置。解决方案：化学蓄热装置构成为：（1）化学蓄热装置包括具有通过脱水 - 水合反应吸收/产生热量的化学热储存介质的蓄热体和由用于向/从化学热存储介质供给/接收热量的传热材料和（2）传热体在与化学热存储介质接触的面上包括羟基或氧化物膜。蓄热体是包含化学热存储介质的成形体或多孔烧结体，传热体也可以是与成形体或烧结体的周边接触的传热壁。蓄热体可以是包括化学热存储介质的粉末和介于化学热存储介质的粉末中的传热体的复合体。版权所有（C）2011，JPO＆INPIT

9. 发明专利

JP2010248374A Heat storage agent-metal structure and manufacturing method for the same 有权
标题翻译：热存储代理 - 金属结构及其制造方法
公开(公告)号：JP2010248374A
公开(公告)日：2010-11-04
申请号：JP2009099301
申请日：2009-04-15
申请人： Denso Corp , Toyota Central R&D Labs Inc , 株式会社デンソー , 株式会社豊田中央研究所
发明人： FUSE TAKUYA , INOUE SATORU , SAEGUSA HIROSHI , KOMAKI KATSUYA , SHIMAZU TAKASHI , FUKUSHIMA YOSHIAKI , WAKAYAMA HIROAKI
IPC分类号： C09K5/16 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a heat storage agent-metal structure which can suppresses mechanical decomposition and lowering of thermal output of the heat storage agent, and to provide a method of manufacturing the same.
SOLUTION: The heat storage agent-metal structure has a structure wherein a nucleus 20 formed of solid chemical heat storage agent particles, which changes exothermic/endothermic reactions at the boundary of a specific temperature or pressure with a gas as a reaction medium, is bonded with metal particles 31 by sintering. Further, the structure has a shell 30 enclosing the nucleus 20, and a gap 40 which is formed on the shell 30 and allows a reaction medium flowing out and into the inside of the shell 30.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供能够抑制蓄热剂的机械分解和热输出降低的蓄热剂 - 金属结构体，并提供其制造方法。解决方案：储热剂 - 金属结构具有这样的结构，其中由固体化学储热剂颗粒形成的核20，其在气体作为反应介质的特定温度或压力的边界处改变放热/吸热反应通过烧结与金属粒子31结合。此外，该结构具有包围核20的壳体30和形成在壳体30上并允许反应介质流出并进入壳体30的内部的间隙40.版权所有（C）2011， JPO＆INPIT

10. 发明专利

JP2014180979A Chemical thermal storage air-conditioning system 有权
标题翻译：化学热储存空调系统
公开(公告)号：JP2014180979A
公开(公告)日：2014-09-29
申请号：JP2013057968
申请日：2013-03-21
申请人： Denso Corp , 株式会社デンソー , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HAYASE TOMOHIRO , FUSE TAKUYA , KOMAKI KATSUYA , MITSUI HIROYUKI , SHIMAZU TAKASHI , WAKASUGI TOMOHISA , MOCHIZUKI MIYO
IPC分类号： B60H1/20 , B60H1/03 , B60H1/14 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical thermal storage air-conditioning system capable of flexibly responding to both of the case where heat is stored in a chemical thermal storage medium of a reactor by dehydration reaction and the case where heat is released from the chemical thermal storage medium of the reactor by hydration reaction.SOLUTION: A chemical thermal storage air-conditioning system 4 is used in an energy operation device 1 including energy conversion means 2 and energy storage means 3. The chemical thermal storage air-conditioning system 4 includes: a reactor 6 in which a chemical thermal storage medium 61 is incorporated: and air-conditioning piping 5 that accommodates the reactor 6 therein for passing air A. The reactor 6 includes: a first reaction unit 6A enabling dehydration reaction of the chemical thermal storage medium 61 by using exhaust energy X by the energy conversion means 2; and a second reaction unit 6B enabling dehydration reaction of the chemical thermal storage medium 61 by using either of the exhaust energy X or stored energy by the energy storage means 3.
摘要翻译：要解决的问题：提供一种能够灵敏地响应于通过脱水反应将热量存储在反应器的化学热存储介质中的情况和从化学品释放热量的情况的化学热存储空调系统反应器的热存储介质通过水合反应。解决方案：化学热存储空调系统4用于包括能量转换装置2和储能装置3的能量操作装置1中。化学热存储空调系统4包括：组装有化学蓄热介质61的反应器6和容纳反应器6的空气调节配管5，使空气A通过。反应器6包括：第一反应单元6A，其能够进行化学热存储器的脱水反应介质61通过能量转换装置2使用废气能量X; 以及第二反应单元6B，其能够通过利用能量存储装置3中的任一种排放能量X或存储的能量来实现化学热存储介质61的脱水反应。

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