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1. 发明专利

JP2014114196A Composite oxide material and exhaust gas purification catalyst using the same 审中-公开
标题翻译：使用相同的复合氧化物材料和排气净化催化剂
公开(公告)号：JP2014114196A
公开(公告)日：2014-06-26
申请号：JP2012271387
申请日：2012-12-12
申请人： Toyota Motor Corp , トヨタ自動車株式会社 , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： MIURA MASAHIDE , MORIKAWA AKIRA , TANABE TOSHITAKA
IPC分类号： C01G25/00 , B01D53/86 , B01J20/06
CPC分类号： B01J23/10 , B01D53/9445 , B01D2255/2065 , B01D2255/908 , B01J21/066 , B01J35/0006 , B01J35/002 , B01J35/02 , B01J35/023 , B01J37/0236 , B01J37/031 , B01J37/14 , B01J37/16 , C01G25/00 , C01P2002/36 , C01P2004/04 , Y02T10/22
摘要： PROBLEM TO BE SOLVED: To provide an oxygen storage material for an exhaust gas purification catalyst having more excellent stability under high temperatures.SOLUTION: There is provided a composite oxide material which contains crystalline particles having a pyrochlore structure of a ceria-zirconia composite oxide and crystals having a fluorite structure of a ceria-zirconia composite oxide present on the particles surface, wherein crystals having a fluorite structure of the ceria-zirconia composite oxide contain more zirconia than ceria and are integrated with the crystalline particles having a pyrochlore structure of the ceria-zirconia composite oxide. The composite oxide material has high oxygen storage capacity and has characteristics of hardly causing deterioration in oxygen storage capacity even under high temperatures.
摘要翻译：要解决的问题：提供一种在高温下具有更好的稳定性的废气净化催化剂的储氧材料。溶解性：提供一种复合氧化物材料，其含有具有氧化铈 - 氧化锆复合氧化物的烧绿石结构的结晶颗粒，具有存在于颗粒表面上的二氧化铈 - 氧化锆复合氧化物的萤石结构的晶体，其中具有二氧化铈 - 氧化锆复合氧化物的萤石结构的晶体比二氧化铈含有更多的氧化锆，并且与具有二氧化铈烧绿石结构的结晶颗粒一体化氧化锆复合氧化物。复合氧化物材料具有高的储氧能力，并且即使在高温下也具有几乎不引起储氧能力劣化的特征。

2. 发明专利

JP2013204426A Catalyst deterioration diagnostic method 有权
标题翻译：催化检测诊断方法
公开(公告)号：JP2013204426A
公开(公告)日：2013-10-07
申请号：JP2012070749
申请日：2012-03-27
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： SAKAMOTO TOSHIYUKI , SUDA AKIHIKO , MORIKAWA AKIRA
IPC分类号： F01N3/20 , F02D41/22
CPC分类号： F01N11/00 , F01N2550/02 , F01N2560/12 , F01N2900/1624 , F02D41/1475 , F02D2200/0814 , Y02T10/47
摘要： PROBLEM TO BE SOLVED: To provide a catalyst deterioration diagnostic method which allows simple and accurate diagnosis of deterioration of a catalyst based on information directly obtained from an inspected catalyst.SOLUTION: A catalyst deterioration diagnostic method which diagnoses the deterioration of a catalyst for purifying exhaust gas by employing an inspection object catalyst arranged in an exhaust gas flow path where the exhaust gas circulates, includes an exhaust gas control step for inverting an air-fuel ratio of exhaust gas in the flow path from a lean side to a rich side or from the rich side to the lean side, a measuring step for acquiring a change ratio of the inspection object catalyst by measuring temporal change of electric resistance of the inspection object catalyst at air-fuel ratio inversion, and a determination step for determining catalyst deterioration of the inspection object catalyst based on the resistance change ratio.
摘要翻译：要解决的问题：提供一种催化剂劣化诊断方法，其能够基于从被检查催化剂直接获得的信息简单准确地诊断催化剂的劣化。溶解性：用于诊断用于净化排气的催化剂的劣化的催化剂劣化诊断方法通过采用配置在废气循环的废气流路中的检查对象催化剂的气体，包括排气控制步骤，用于使流路中的排气的空燃比从瘦侧变为富侧，富侧为稀侧，通过测定检查对象催化剂在空燃比倒置时的电阻的时间变化来求出检查对象催化剂的变化率的测定步骤，以及确定检测对象催化剂的催化剂劣化的判定步骤检验对象催化剂基于电阻变化率。

3. 发明专利

JP2013122179A Exhaust emission control device for internal combustion engine 审中-公开
标题翻译：用于内燃机的排气排放控制装置
公开(公告)号：JP2013122179A
公开(公告)日：2013-06-20
申请号：JP2011270325
申请日：2011-12-09
申请人： Toyota Motor Corp , トヨタ自動車株式会社 , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HAYASHI TAKAHIRO , MORIKAWA AKIRA
IPC分类号： F01N3/08 , B01D53/94 , F01N3/24 , F01N3/28 , F02D41/14
CPC分类号： Y02T10/24
摘要： PROBLEM TO BE SOLVED: To improve deterioration in fuel consumption for NOreduction in exhaust gas, in an exhaust emission control device for an internal combustion engine provided with a NOreduction catalyst device carrying a base metal catalyst and having low NOreduction performance.SOLUTION: An exhaust emission control device for an internal combustion engine includes: a first NOreduction catalyst device 40 carrying a base metal catalyst disposed at an exhaust passage 30; a second NOreduction catalyst device 50 disposed at the exhaust passage at a downstream side of the first NOreduction catalyst device and having ammonia storage capability; and a first NOsensor 80 disposed at the exhaust passage at a downstream side of the second NOreduction catalyst device. After a combustion air-fuel ratio of the internal combustion engine is made richer than a theoretical air-fuel ratio, the combustion air-fuel ratio of the internal combustion engine is made leaner than the theoretical air-fuel ratio. When the combustion air-fuel ratio of the internal combustion engine is made leaner than the theoretical air-fuel ratio, if NOis detected by the first NOsensor, the combustion air-fuel ratio of the internal combustion engine is made richer than the theoretical air-fuel ratio.
摘要翻译：要解决的问题：为了提高排气中的NO X 的燃料消耗的劣化，在内燃机的排气排放控制装置中， SB POS =“POST”> X 还原催化剂装置，其具有贱金属催化剂并且具有低NO X 还原性能。解决方案：一种用于内燃机的废气排放控制装置，包括：承载设置在排气通道30处的贱金属催化剂的第一NOS SB POS =“X”SB“还原催化剂装置40; 设置在第一NO SB SB“还原催化剂装置的下游侧的排气通道处的第二NOS SB POS =”X“SB”还原催化剂装置“，以及具有氨储存能力; 以及设置在第二NO ”> X“还原催化剂装置的下游侧的排气通道处的第一NO X 传感器80。在内燃机的燃烧空燃比变得比理论空燃比更浓之后，使内燃机的燃烧空燃比比理论空燃比更稀。当内燃机的燃烧空燃比比理论空燃比更精细时，如果通过第一NO X “> X 传感器，使内燃机的燃烧空燃比变得比理论空燃比更浓。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2013122177A Exhaust emission control device for internal combustion engine 有权
标题翻译：用于内燃机的排气排放控制装置
公开(公告)号：JP2013122177A
公开(公告)日：2013-06-20
申请号：JP2011270311
申请日：2011-12-09
申请人： Toyota Motor Corp , トヨタ自動車株式会社 , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HAYASHI TAKAHIRO , MORIKAWA AKIRA
IPC分类号： F01N3/08 , B01D53/94 , F01N3/10 , F01N3/20 , F01N3/24
CPC分类号： Y02T10/24
摘要： PROBLEM TO BE SOLVED: To improve deterioration in fuel consumption for NOreduction, in an exhaust emission control device for an internal combustion engine with a NOreduction catalyst device carrying a base metal catalyst and having low NOreduction performance.SOLUTION: A NOreduction catalyst device 40 carrying a base metal catalyst is disposed at a third exhaust passage 30 positioned at a downstream side of a confluence part 100 between a first exhaust passage 10 of a first cylinder group and a second exhaust passage 20 of a second cylinder group. A NOstorage device 50 is disposed at the second exhaust passage. A communication passage 60 communicating the second exhaust passage at a downstream side of the NOstorage device with the third exhaust passage at a downstream side of the NOstorage device is provided. When a combustion air-fuel ratio of the first cylinder group is made rich and when a combustion air-fuel ratio of the second cylinder group is made lean, exhaust gas flowing out from the NOstorage device passes through the communication passage. When the combustion air-fuel ratio of the second cylinder group is made rich, the exhaust gas flowing out from the NOstorage device passes through the NOreduction catalyst device.
摘要翻译：要解决的问题为了改善NO X 的燃料消耗的劣化，在具有NO X 还原性能的“X”SB“还原催化剂装置”。
解决方案：承载贱金属催化剂的NOS SB POS =“POST”> X“还原催化剂装置40设置在位于汇合部100的下游侧的第三排气通道30之间，位于第一第一气缸组的排气通道10和第二气缸组的第二排气通道20。存储装置50设置在第二排气通道中。否则，将 X 存储装置50。在NO X 存储装置的下游侧将第二排气通道与NO X 存储设备。当第一气缸组的燃烧空燃比变浓时，当第二气缸组的燃烧空燃比变稀时，从NO X < SB>存储装置通过通信通道。当第二气缸组的燃烧空燃比变浓时，从NO X 储存装置流出的废气通过NO X 还原催化剂装置。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2013022507A Exhaust gas purification catalyst and method of producing the same 审中-公开
标题翻译：排气净化催化剂及其生产方法
公开(公告)号：JP2013022507A
公开(公告)日：2013-02-04
申请号：JP2011159102
申请日：2011-07-20
申请人： Toyota Motor Corp , トヨタ自動車株式会社 , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： TAKAGI SHIGEJI , WATABE GAO , MORIKAWA AKIRA , HIROSE TAKUTO , NAGAI YASUTAKA
IPC分类号： B01J23/76 , B01D53/94 , B01J37/04 , B01J37/08 , F01N3/10
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas purification catalyst having excellent exhaust gas purification performance under a relatively low temperature condition and excellent heat endurance, and to provide a method of producing the exhaust gas purification catalyst.SOLUTION: The exhaust gas purification catalyst includes: at least one Group-XIII element oxide; at least either one of at least one lanthanoid oxide and at least one Group-IV element oxide; and particles including at least one base metal selected from a group comprising copper etc. An average particle size of the particles including the base metal is 1-1,000 nm. An average distance between the particles including the base metal and the Group-XIII element oxide nearest to the particles is 60 nm or less, and an average distance between the particles including the base metal and the lanthanoid oxide and/or the Group-IV element oxide nearest to the particles is 60 nm or less.
摘要翻译：解决的问题：提供一种在相对低的温度条件下具有优异的废气净化性能和优异的耐热性的废气净化催化剂，并提供一种生产废气净化催化剂的方法。废气净化催化剂包括：至少一种第ⅩⅢ族元素氧化物; 至少一种镧系元素氧化物和至少一种IV族元素氧化物中的至少一种; 以及包含选自铜等的至少一种母体金属的粒子。包含母体金属的粒子的平均粒径为1-1000nm。包括贱金属和最接近粒子的第ⅩⅢ族元素氧化物的粒子之间的平均距离为60nm以下，包含贱金属和镧系元素氧化物的粒子和/或IV族元素之间的平均距离最接近粒子的氧化物为60nm以下。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2012024701A Catalyst for purifying exhaust gas 有权
标题翻译：用于净化排气的催化剂
公开(公告)号：JP2012024701A
公开(公告)日：2012-02-09
申请号：JP2010166101
申请日：2010-07-23
申请人： Toyota Central R&D Labs Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： NOBUKAWA KEN , KUNO HISASHI , MORIKAWA AKIRA , YAMAMURA YOSHIE , TAKAHASHI NAOKI , SUDA AKIHIKO
IPC分类号： B01J23/63 , B01D53/94 , F01N3/10
CPC分类号： B01J35/04 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2065 , B01D2255/20715 , B01D2255/407 , B01D2255/908 , B01J23/63 , B01J37/0244 , Y02T10/22
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for purifying exhaust gas, having high NOpurifying performance after endurance.SOLUTION: The catalyst for purifying exhaust gas includes: a first oxygen absorption/emission material that does not support a noble metal and has a regulatory formation structure of a pyrochlore phase type; and a second oxygen absorption/emission material that has higher oxygen absorption/emission speed and lower oxygen absorption/emission capacity than the first oxygen absorption/emission material, wherein the second oxygen absorption/emission material supports the platinum group noble metal.
摘要翻译：要解决的问题：提供耐久性高的NO X 净化性能的排气净化催化剂。解决方案：用于净化废气的催化剂包括：不支持贵金属并具有烧绿石相类型的调节形成结构的第一氧吸收/发射材料; 以及第二氧吸收/发射材料，其具有比第一氧吸收/发射材料更高的氧吸收/发射速度和更低的氧吸收/释放能力，其中第二氧吸收/发射材料支撑铂族贵金属。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2011144421A Precious-metal-based colloidal solution and method for producing the same 有权
标题翻译：基于金属的金属溶液及其生产方法
公开(公告)号：JP2011144421A
公开(公告)日：2011-07-28
申请号：JP2010005620
申请日：2010-01-14
申请人： Toyota Central R&D Labs Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： SATO KIMITOSHI , YAMAMURA YOSHIE , MORIKAWA AKIRA , SUDA AKIHIKO , NAGAO SATOSHI , HIRATA HIROTO
IPC分类号： B22F9/24 , B01F17/52 , B01J13/00
摘要： PROBLEM TO BE SOLVED: To provide a precious-metal-based colloidal solution that has precious-metal-based fine particles uniformly dispersed therein which have a small particle size and are uniform, and is superior in storability, and to provide a method for producing the same.
SOLUTION: The precious-metal-based colloidal solution includes at least one precious-metal-based fine particle selected from the group consisting of a precious-metal fine particle, a precious-metal-alloy fine particle, a precious-metal-compound fine particle and a precious-metal-alloyed compound fine particle, and a polymeric dispersing agent. As for a particle size of the precious-metal-based fine particles, a particle size D
50 at which the accumulated mass in the particle size distribution reaches 50% is 0.8-5.0 nm, and a particle size D
90 at which the accumulated mass reaches 90% is 2.5 times of the particle size D
50 or smaller.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：解决问题：提供一种贵金属系的胶体溶液，其具有均匀分散在其中的具有小颗粒尺寸并且均匀且具有优异的储存性的贵金属微细颗粒，并提供一种其制造方法解决方案：贵金属基胶体溶液包括至少一种选自贵金属微粒，贵金属合金微粒，贵金属微细的贵金属微细颗粒复合微粒和贵金属合金化合物微粒，以及聚合物分散剂。对于贵金属类微粒的粒径，粒径分布达到50％时的累积质量为0.8〜5.0nm的粒径D 50 ，粒径累积质量达到90％的D 90 是粒径D 50 以下的2.5倍。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2010260046A Catalyst for cleaning exhaust gas 有权
标题翻译：催化剂用于清洁排气
公开(公告)号：JP2010260046A
公开(公告)日：2010-11-18
申请号：JP2010088012
申请日：2010-04-06
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： MORIKAWA AKIRA , YAMAMURA YOSHIE , SUDA AKIHIKO , HATANAKA YOSHIO , TANABE TOSHITAKA , TAKAHASHI NAOKI
IPC分类号： B01J23/63 , B01D53/94 , B01J23/56 , F01N3/10
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for cleaning exhaust gas, which is used for removing nitrogen oxides (NOx) and hydrocarbons (HC) on satisfactorily high levels even when a small amount of a noble metal is used in the catalyst. SOLUTION: The catalyst for cleaning exhaust gas comprises a carrier and rhodium deposited on the carrier. The carrier is a mixture of a first oxide particle, which contains alumina and zirconia but does not contain ceria substantially, with a second oxide particle containing ceria. Rhodium of ≥70 at% are deposited on the first oxide particle and the second oxide particle has ≤35 m 2 /g specific surface area. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于清洁废气的催化剂，其用于以令人满意的高水平除去氮氧化物（NOx）和烃（HC），即使在催化剂中使用少量贵金属时。解决方案：用于清洁废气的催化剂包括沉积在载体上的载体和铑。载体是含有氧化铝和氧化锆但不含二氧化铈的第一氧化物颗粒与含有二氧化铈的第二氧化物颗粒的混合物。 ≥70at％的铑沉积在第一氧化物颗粒上，第二氧化物颗粒的比表面积≤35m2 / SP / g。版权所有（C）2011，JPO＆INPIT

9. 发明专利

JP2010216839A Method of detecting existence of chemiluminescence deriving from solid surface reaction, method of identifying chemical substance species deriving from solid surface reaction, and device used in these methods for detecting chemiluminescence deriving from solid surface reaction 审中-公开
标题翻译：检测从固体表面反应得到的薄膜存在的方法，识别从固体表面反应得到的化学物质物种的方法，以及用于检测从固体表面反应衍生的亮度的方法中使用的装置
公开(公告)号：JP2010216839A
公开(公告)日：2010-09-30
申请号：JP2009060896
申请日：2009-03-13
申请人： Tohoku Denshi Sangyo Kk , Toyota Central R&D Labs Inc , 東北電子産業株式会社 , 株式会社豊田中央研究所
发明人： KATO SATORU , ITO YOSHIHIKO , SUDA AKIHIKO , MORIKAWA AKIRA , YAMADA RIE , MORI TOSHIKATSU
IPC分类号： G01N21/76
摘要： PROBLEM TO BE SOLVED: To provide a method of detecting the existence of chemiluminescence for detecting chemiluminescence deriving from a chemical reaction that progresses on a solid surface out of light emitted from the surface of a solid under high temperature conditions.
SOLUTION: According to this method of detection, light emission deriving from heat dissipation and chemiluminescence deriving from a chemical reaction on the surface of a solid are separated from light emitted from the surface of a solid under high temperature conditions to detect the existence of the chemiluminescence.
COPYRIGHT: (C)2010,JPO&INPIT

10. 发明专利

JP2010110720A Colloidal solution of metallic compound, and method of producing the same 有权
标题翻译：金属化合物的胶体溶液及其制造方法
公开(公告)号：JP2010110720A
公开(公告)日：2010-05-20
申请号：JP2008287007
申请日：2008-11-07
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： SATO KIMITOSHI , SUDA AKIHIKO , YAMAMURA YOSHIE , MORIKAWA AKIRA
IPC分类号： B01J13/00 , B01F17/52
摘要： PROBLEM TO BE SOLVED: To provide a colloidal solution of a metallic compound having excellent preservability wherein uniform crystallites of a metallic compound having small crystallite diameters are dispersed in a state of uniform aggregates having small diameters. SOLUTION: The colloidal solution of a metallic compound including aggregates of crystallites of a metallic compound having a crystallite diameter d 50 of 0.8 to 3 nm whereat the cumulative number of the crystallite particles in the particle size distribution reaches 50% and having a crystallite diameter d 90 1.5 times or lower the crystallite diameter d 50 whereat the cumulative number reaches 90%, and a polymeric dispersant, is characterized in that the aggregates have an aggregate particle diameter D 50 of 4 to 70 nm whereat the cumulative mass in the particle size distribution reaches 50% and having an aggregate particle diameter D 90 2.5 times or lower the aggregate particle diameter D 50 whereat the cumulative mass reaches 90%. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的保存性的金属化合物的胶体溶液，其中具有小晶粒直径的金属化合物的均匀微晶在具有小直径的均匀聚集体的状态下分散。解决方案：金属化合物的胶体溶液，其包含具有0.8-3nm的微晶直径d 50 的金属化合物的微晶聚集体，其中粒径的微晶颗粒的累积数分布达到50％，并且具有微晶直径d 90 1.5倍或更低的微晶直径d 50 ，其中累积数达到90％，聚合物分散剂的特征在于聚集体的聚集体粒径D 50 4〜70nm，粒度分布的累积质量达到50％，聚集体粒径D 90 <2.5> 时间或降低聚集粒径D 50 ，其中累积质量达到90％。版权所有（C）2010，JPO＆INPIT

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