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    • 10. 发明授权
    • Method for recovering scraps of multi-layer plastic sheet or film
    • 回收多层塑料片或薄膜废料的方法
    • US5194109A
    • 1993-03-16
    • US890358
    • 1992-05-22
    • Toyokazu Yamada
    • Toyokazu Yamada
    • B29B17/02
    • B29B17/02B29B2017/0203B29B2017/0255B29K2009/06B29K2023/083B29K2023/086B29K2023/12B29K2031/04B29K2033/12B29K2067/00B29L2007/008B29L2009/00Y02W30/622Y10S156/919Y10T156/11
    • A method for recovering and reusing a scrap multilayer plastic sheet or film comprising at least a base material layer and laminated with an adhesive resin comprising at least one of an ethylene-vinyl acetate copolymer, a styrene-isoprene copolymer, a styrene-butadiene copolymer, a styrene-methyl methacrylate copolymer and an ethylene-acrylic acid ester-maleic anhydride copolymer. The method comprises heating the scrap multilayer sheet or film to a temperature lower than the softening point of the base material layer to make the interlaminar peeling strength of the adhesive resin lower than the strength at break of a layer having the lowest strength at break, except for the adhesive layer, and separating the multilayer scrap into at least two scrap layers and recovering at least one scrap layer in sheet or film form. The present invention provides effective reuse of scrap with almost no reduction in physical properties. Furthermore the cost of the production or molding of the sheet can be reduced. Still further, it is not necessary to add an additive, a white pigment and the like for preventing thermal deterioration. When polypropylene is used as a base material in the present method, it is not necessary to use low viscosity polypropylene as is conventionally required. That is, since high viscosity polypropylene can be used, vacuum molding becomes easy and furthermore a multilayer sheet or film having desirable physical properties can be produced very economically.
    • 一种用于回收和重复使用废片多层塑料片或薄膜的方法,所述废层多层塑料片或薄膜至少包括基材层并与粘合剂树脂层压,所述粘合剂树脂包括乙烯 - 乙酸乙烯酯共聚物,苯乙烯 - 异戊二烯共聚物,苯乙烯 - 丁二烯共聚物, 苯乙烯 - 甲基丙烯酸甲酯共​​聚物和乙烯 - 丙烯酸酯 - 马来酸酐共聚物。 该方法包括将废料多层片材或膜加热到低于基材层的软化点的温度,使得粘合剂树脂的层间剥离强度低于断裂强度的断裂强度,除了 用于粘合剂层,并将多层废料分离成至少两个废料层,并以片状或薄膜形式回收至少一个废料层。 本发明提供了几乎不降低物理性质的废料的有效再利用。 此外,可以降低片材的生产或模制成本。 此外,不需要添加用于防止热劣化的添加剂,白色颜料等。 在本方法中使用聚丙烯作为基材时,不需要像以往那样使用低粘度聚丙烯。 也就是说,由于可以使用高粘度聚丙烯,因此真空成型变得容易,而且可以非常经济地制造具有理想物理性质的多层片材或膜。