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    • 3. 发明申请
    • Polyimide film and process for its production
    • 聚酰亚胺薄膜及其生产工艺
    • US20070100127A1
    • 2007-05-03
    • US10530414
    • 2003-03-31
    • Toyoaki IshiwataTsutomu NakamuraKazunori KojimaToru Sawaki
    • Toyoaki IshiwataTsutomu NakamuraKazunori KojimaToru Sawaki
    • C08G69/08
    • C08J5/18B29C41/003B29D7/01B29K2079/08C08G73/1042C08G73/1082C08J2379/08H05K1/0346
    • An oriented polyimide film with a high Young's modulus, satisfactory moist heat resistance and low moisture absorptivity, and a process for its production. The polyimide film is composed mainly of a pyromellitic acid component, with a p-phenylenediamine component at between 30 mole percent and 99 mole percent and a diamine component represented by the structural unit of the following formula (II) at between 1 mole percent and 70 mole percent: (wherein ArIIa and ArIIb are each independently a C6-20 aromatic group optionally having an non-reactive substituent, and X in structural unit (II) consists of at least one group selected from among —O—, —O—ArIIc—O—, —SO2— and —O—ArIId—O—ArIIe—O—), and the polyimide film is characterized by having two perpendicular directions in which the in-plane Young's modulus is 3 GPa or greater, and having a moisture absorptivity of no greater than 3.3 wt % at 72% RH, 25° C.
    • 具有高杨氏模量,令人满意的耐湿热性和低吸湿性的取向聚酰亚胺膜及其制造方法。 聚酰亚胺膜主要由均苯四酸酸组分组成,对苯二胺组分为30摩尔%至99摩尔%,由下式(II)的结构单元表示的二胺组分的摩尔比为1摩尔%至70摩尔% 摩尔百分数:(其中Ar IIa和Ar IIb各自独立地为任选具有非反应性取代基的C6-20芳族基团,结构单元(II)中的X由 的至少一个选自-O - , - O-Ar II - , - SO 2 - 和-O-Ar IId的基团, 其中,所述聚酰亚胺膜的特征在于,其中所述平面内杨氏模量为3GPa以上,并且具有吸湿性 在72%RH,25℃下不大于3.3重量%
    • 5. 发明申请
    • Process and composition for the production of carbon fiber and mats
    • 用于生产碳纤维和垫子的工艺和组成
    • US20060012061A1
    • 2006-01-19
    • US10529758
    • 2003-09-25
    • Masumi HirataHiroshi SakuraiToru SawakiTetsuo BanSatoru OhmoriShunichi MatsumuraHideaki Nitta
    • Masumi HirataHiroshi SakuraiToru SawakiTetsuo BanSatoru OhmoriShunichi MatsumuraHideaki Nitta
    • D01C5/00D01D5/08D01D5/10C08F8/30
    • D01F9/14
    • A process for manufacturing a carbon fiber having a fiber diameter of 0.001 to 5 μm and a narrow fiber size distribution, and a resin composition suitable for the manufacture of a carbon fiber. A resin composition comprising 100 parts by weight of a thermoplastic resin, 1 to 150 parts by weight of a carbon precursor organic compound (A) and 0.001 to 40 parts by weight of acopolymer of polymer segments (e1) and (e2) which satisfy a specific range of surface tension for the thermoplastic resin and a specific range of surface tension for the carbon precursor organic compound (A) at the same time. A process for manufacturing a carbon fiber, comprising the steps of producing a molded article of a precursor fiber (B) by treating the resin composition, subjecting the carbon precursor organic compound (A) contained in the precursor fiber (B) to a stabilization treatment so as to produce a stabilized precursor fiber (C), removing the thermoplastic resin contained in the stabilized precursor fiber (C), and carbonizing or graphitizing a fibrous carbon precursor (D) obtained by removing the thermoplastic resin.
    • 一种纤维直径为0.001〜5μm,纤维尺寸分布窄的碳纤维的制造方法以及适于制造碳纤维的树脂组合物。 一种树脂组合物,其包含100重量份的热塑性树脂,1至150重量份的碳前体有机化合物(A)和0.001至40重量份的聚合物链段(e1)和(e2)的共聚物,其满足 热塑性树脂的表面张力的特定范围和碳前体有机化合物(A)的同时具有特定的表面张力范围。 一种制造碳纤维的方法,包括以下步骤:通过处理树脂组合物,将前体纤维(B)中所含的碳前体有机化合物(A)进行稳定化处理,制备前体纤维(B)的模制品 以制备稳定的前体纤维(C),除去稳定化的前体纤维(C)中所含的热塑性树脂,并且通过除去热塑性树脂而获得的纤维状碳前体(D)碳化或石墨化。