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1. 发明专利

JP2014201545A ２−ヒドロキシメチル−２，３−ジヒドロ−チエノ［３，４−ｂ］［１，４］ジオキシン−５，７−ジカルボン酸ジアルキルエステルの製造方法审中-公开
标题翻译：制备2-羟基甲基-2,3-二氢 - 噻吩并[3,4-b] [1,4]二氧杂-5,7-二羧酸二烷基酯的方法
公开(公告)号：JP2014201545A
公开(公告)日：2014-10-27
申请号：JP2013078338
申请日：2013-04-04
申请人：東ソー株式会社 , Tosoh Corp
发明人： AWANO YUTAKA , NISHIYAMA SHOICHI , YANO YUICHI
IPC分类号： C07D495/04
摘要：【課題】2−ヒドロキシメチル−2,3−ジヒドロ−チエノ[3,4−b][1,4]ジオキシン−5,7−ジカルボン酸ジアルキルエステルを選択的に収率良く製造する方法の提供。【解決手段】3,4−ジヒドロキシチオフェン−2,5−ジカルボン酸エステルと、ジハロゲン化プロパノールとを、ヨウ化物と塩基の存在下で反応させて次式(3)[式中、Rは各々独立して、炭素数1〜4のアルキル基を表す]で示される2−ヒドロキシメチル−2,3−ジヒドロ−チエノ[3,4−b][1,4]ジオキシン−5,7−ジカルボン酸ジアルキルエステルを得る。【選択図】なし
摘要翻译：要解决的问题：提供以选择性和产率良好的2-羟甲基-2,3-二氢 - 噻吩并[3,4-b] [1,4]二恶英-5,7-二羧酸二烷基酯的制备方法。解决方案：在碘化物和碱的存在下，使3,4-二羟基噻吩-2,5-二羧酸酯和二卤代丙醇反应，得到2-羟甲基-2,3-二氢 - 噻吩并[3,4-b] 1,4]二恶英-5,7-二羧酸二烷基酯，R表示各自独立地为具有1〜4个碳原子的烷基。

2. 发明专利

JP2014074007A Thiophene compound, water-soluble conductive polymer and its aqueous solution, and their manufacturing method 有权
标题翻译：噻吩化合物，水溶性导电聚合物及其水溶液及其制造方法
公开(公告)号：JP2014074007A
公开(公告)日：2014-04-24
申请号：JP2013078336
申请日：2013-04-04
申请人： Tosoh Corp , 東ソー株式会社
发明人： YANO YUICHI , NISHIYAMA SHOICHI , AWANO YUTAKA
IPC分类号： C07D495/04 , C08G61/12
摘要： PROBLEM TO BE SOLVED: To provide novel water-soluble thiophene compounds and polythiophenes used for conductive materials.SOLUTION: There are provided thiophene compounds represented by the formula (1) and its polymers. (1), where Rrepresents a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms which may have a substituent, an aryl group having 6 to 20 carbon atoms, or -X-SOM, X represents an alkylene group having 1 to 6 carbon atoms may have a substituent, or an arylene group having 6 to 20 carbon atoms, m represents an integer of 0 to 3, n represents an integer of 0 to 12, and n+m≥1.
摘要翻译：要解决的问题：提供用于导电材料的新型水溶性噻吩化合物和聚噻吩。解决方案：提供由式（1）表示的噻吩化合物及其聚合物。（1）中，R表示氢原子或可具有取代基的碳原子数1〜6的烷基，碳原子数6〜20的芳基或-X-SOM，X表示具有1〜 6个碳原子可以具有取代基，或具有6〜20个碳原子的亚芳基，m表示0〜3的整数，n表示0〜12的整数，n +m≥1。

3. 发明专利

JP2009040730A NEW BENZO[c]FLUORENE DERIVATIVE AND ITS USE 有权
标题翻译：新BENZO [c]荧光衍生物及其用途
公开(公告)号：JP2009040730A
公开(公告)日：2009-02-26
申请号：JP2007208332
申请日：2007-08-09
申请人： Tosoh Corp , 東ソー株式会社
发明人： ISHIKAWA SHINICHI , NISHIYAMA SHOICHI , MATSUMOTO NAOKI
IPC分类号： C07C211/61 , C09K11/06 , H01L51/50
摘要： PROBLEM TO BE SOLVED: To provide a new compound which has high hole transport ability and especially exhibits high characteristics for organic EL elements, and to provide an organic EL element using the compound. SOLUTION: Provided is a benzo[c]fluorene derivative represented by general formula (1) (wherein, R 1 and R 2 are each identically or differently H, a 1-18C straight chain, branched or cyclic alkyl group, a 1-18C straight chain, branched or cyclic alkoxy group, a 6-24C aryl group or aryloxy group, or a halogen atom; R 1 and R 2 may be bound to each other to form a ring; Ar 1 groups are each independently a substituted or non-substituted aryl group or heteroaryl group, and may form a nitrogen-containing heterocyclic ring together with nitrogen atoms bound to the groups; Ar 2 groups are each independently a substituted or non-substituted arylene group or heteroarylene group). COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有高空穴传输能力并且特别表现出有机EL元件的高特性的新化合物，并提供使用该化合物的有机EL元件。解决方案：提供由通式（1）表示的苯并[c]芴衍生物（其中R 1和R 2各自为H或H， 1-18C直链，支链或环状烷基，1-18C直链，支链或环状烷氧基，6-24C芳基或芳氧基或卤素原子; R 1 并且R 2可以彼此结合形成环; Ar 1个基团各自独立地为取代或未取代的芳基或杂芳基，并且可以形成含氮杂环和与基团结合的氮原子; Ar 各自独立地为取代或未取代的亚芳基或亚杂芳基）。版权所有（C）2009，JPO＆INPIT

4. 发明专利

JP2008214271A NOVEL BENZO[c]FLUORENE DERIVATIVE AND ITS APPLICATION 有权
标题翻译：新颖的BENZO [c]荧光衍生物及其应用
公开(公告)号：JP2008214271A
公开(公告)日：2008-09-18
申请号：JP2007053980
申请日：2007-03-05
申请人： Tosoh Corp , 東ソー株式会社
发明人： ISHIKAWA SHINICHI , NISHIYAMA SHOICHI , MATSUMOTO NAOKI , TENMA HIROAKI
IPC分类号： C07C211/60 , C09K11/06 , H01L51/50
摘要： PROBLEM TO BE SOLVED: To provide a novel compound that has high positive hole-transportability and exhibits high performances particularly on an organic EL element, and an organic EL element using the compound.
SOLUTION: The benzo[c]fluorene compound represented by general formula (1) is used. In the formula, R
1 and R
2 are each hydrogen atom, an alkyl group, an aryl group or the like, and may be linked together to form a ring; Ar
1 is an aryl group or a heteroaryl group, and may form a nitrogen-containing heterocyclic ring together with nitrogen atom bonded thereto; and Ar
2 is an arylene group or a heteroarylene group.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种具有高空穴传输性和具有高性能的新型化合物，特别是在有机EL元件上，以及使用该化合物的有机EL元件。解决方案：使用由通式（1）表示的苯并[c]芴化合物。在该式中，R“SP”1和R“SP”2各自为氢原子，烷基，芳基等，并且可以连接在一起形成环; Ar 1 是芳基或杂芳基，并且可以与与其结合的氮原子一起形成含氮杂环; 且Ar 2 是亚芳基或亚杂亚芳基。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2008050337A Benzofluorene compound and use thereof 有权
标题翻译：苯并噻唑化合物及其用途
公开(公告)号：JP2008050337A
公开(公告)日：2008-03-06
申请号：JP2007010813
申请日：2007-01-19
申请人： Tosoh Corp , 東ソー株式会社
发明人： NISHIYAMA SHOICHI , MATSUMOTO NAOKI , MIYAZAKI TAKANORI , KANBARA TAKESHI
IPC分类号： C07C211/54 , C09K11/06 , H01L51/50
CPC分类号： C09B57/00 , C09B57/008 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , H01L51/0054 , H01L51/006 , H01L51/5012 , H01L51/5056 , H05B33/10
摘要： PROBLEM TO BE SOLVED: To provide a new material having high hole transporting ability, high glass transition temperature and long-term durability.
SOLUTION: The invention relates to the benzofluorene compound represented by general formula (1). In the formula, M represents a (substituted) aryl group having 6-40 carbon atoms or a (substituted) heteroaryl group having 5-40 carbon atoms; Ar
1 -Ar
4 are each independently a (substituted) aryl group having 6-40 carbon atoms or a (substituted) heteroaryl group having 5-40 carbon atoms, provided that at least one of Ar
1 -Ar
4 represents a substituent having a fluorene skeleton. And p is an integer of 0-2.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供具有高空穴传输能力，高玻璃化转变温度和长期耐久性的新材料。解决方案：本发明涉及由通式（1）表示的苯并芴化合物。在该式中，M表示具有6-40个碳原子的（取代的）芳基或具有5-40个碳原子的（取代的）杂芳基; Ar 1 -Ar 4 各自独立地为具有6-40个碳原子的（取代的）芳基或具有5-40个碳原子的（取代的）杂芳基，条件是 Ar 1 -Ar 4 中的至少一个表示具有芴骨架的取代基。 p是0-2的整数。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2005035919A New arylvinyl compound having fluorene skeleton, and method for producing the same and organic el element 有权
标题翻译：具有氟橡胶的新型芳香族化合物及其生产方法和有机EL元件
公开(公告)号：JP2005035919A
公开(公告)日：2005-02-10
申请号：JP2003199204
申请日：2003-07-18
申请人： Tosoh Corp , 東ソー株式会社
发明人： NISHIYAMA SHOICHI , MATSUMOTO NAOKI , TENMA HIROAKI , EGUCHI HISAO
IPC分类号： H01L51/50 , C07C13/567 , C07C13/66 , C09K11/06 , H05B33/14
摘要： PROBLEM TO BE SOLVED: To provide an arylvinyl compound which has a fluorene skeleton and can be used as a light-emitting material for organic electroluminescent (EL) elements and the like which are used for planar light sources and displays, to provide a method for producing the arylvinyl compound, and to provide the organic EL elements.
SOLUTION: The arylvinyl compound represented by general formula (1) (R
1 to R
4 are each independently H, a straight chain, branched or cyclic alkyl or alkoxy, an aryl, an aryloxy, a halogen, amino, a specific vinyl or a specific aryl; Ar
1 is a substituted or non-substituted arylene; Ar
2 is a substituted or non-substituted aryl; Z is H or a substituted or non-substituted aryl).
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供具有芴骨架的芳族乙烯基化合物，可以用作用于平面光源和显示器的有机电致发光（EL）元件等的发光材料，以提供制备芳基乙烯基化合物的方法和提供有机EL元件。解决方案：由通式（1）表示的芳基乙烯基化合物（R 1 SP＆gt;至R SP 3）各自独立地为H，直链，支链或环状的烷基或烷氧基芳基，芳氧基，卤素，氨基，特定的乙烯基或特定芳基; Ar 1是取代或未取代的亚芳基; Ar 是取代的或未取代的芳基; Z是H或取代或未取代的芳基）。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2014065898A Polythiophene, aqueous solution thereof, and thiophene monomer thereof 有权
标题翻译：聚氧乙烯，其水溶液及其单体
公开(公告)号：JP2014065898A
公开(公告)日：2014-04-17
申请号：JP2013176920
申请日：2013-08-28
申请人： Tosoh Corp , 東ソー株式会社
发明人： NISHIYAMA SHOICHI , YANO YUICHI
IPC分类号： C08G61/12 , C09D5/00 , C09D5/24 , C09D181/00
摘要： PROBLEM TO BE SOLVED: To provide a novel water-soluble polythiophene having high conductivity, and a novel thiophene monomer that is a material of the polythiophene.SOLUTION: The polythiophene is obtained by polymerizing a thiophene monomer represented by the following formula in water or an alcohol solvent in the presence of an oxidant, wherein R represents a 1-6C open-chain or branched alkyl group, or a fluorine atom, and M represents a hydrogen atom, an alkali metal selected from the group consisting of Li, Na and K, NH(R)or HNCH.
摘要翻译：要解决的问题：提供具有高导电性的新型水溶性聚噻吩和作为聚噻吩的材料的新型噻吩单体。溶液：聚噻吩通过将下式所示的噻吩单体在水中或醇溶剂，其中R表示1-6C开链或支链烷基或氟原子，M表示氢原子，选自Li，Na和K的碱金属，NH（R）或HNCH。

8. 发明专利

JP2007325982A Catalyst for producing arylamines and method for producing arylamines by using the same 有权
标题翻译：用于生产芳族聚酰胺的催化剂和使用它们生产亚胺的方法
公开(公告)号：JP2007325982A
公开(公告)日：2007-12-20
申请号：JP2006156919
申请日：2006-06-06
申请人： Tosoh Corp , 東ソー株式会社
发明人： MIYAZAKI TAKANORI , NISHIYAMA SHOICHI , MATSUMOTO NAOKI
IPC分类号： B01J31/24 , C07B61/00 , C07C209/10 , C07C211/54 , C07D209/82
CPC分类号： B01J31/24 , B01J2231/4283 , B01J2531/824 , C07C209/10 , C07C209/66 , C07C211/54
摘要： PROBLEM TO BE SOLVED: To provide a method for producing arylamines with high selectivity, in high efficiency and at industrial advantage without concern about a side reaction when a strong base is used. SOLUTION: Arylamines are produced by reacting aryl compounds each having an active group such as triflate and halogen with amine compounds in the presence of the base by using a catalyst for producing arylamines, which is composed of a palladium compound having a group of tertiary phosphine such as tri-tert-butyl phosphine and an interphase transfer catalyst such as crown ether. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种以高选择性，高效率和工业优势生产芳基胺的方法，而不考虑使用强碱时的副反应。解决方案：芳基胺是通过在碱存在下使各自具有活性基团的芳基化合物如三氟甲磺酸酯和卤素与胺化合物反应而制备的，该方法是使用由具有下述基团的钯化合物叔膦如三叔丁基膦和相间转移催化剂如冠醚。版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2007137795A Fluorene compound and organic el element by using the same 有权
标题翻译：氟化合物和有机EL元素使用它
公开(公告)号：JP2007137795A
公开(公告)日：2007-06-07
申请号：JP2005331326
申请日：2005-11-16
申请人： Tosoh Corp , 東ソー株式会社
发明人： MATSUMOTO NAOKI , NISHIYAMA SHOICHI , EGUCHI HISAO
IPC分类号： C07C211/16 , C07B61/00 , C07C209/16 , C09K11/06 , H01L51/50
CPC分类号： C09B57/008 , C07C211/61 , C07C2603/18 , C09B57/00 , H01L51/006
摘要： PROBLEM TO BE SOLVED: To provide a new fluorene compound capable of being used as a positive hole-transporting layer and a method for producing the same. SOLUTION: This fluorene compound expressed by general formula (1) [wherein, R is H, a halogen atom, an alkyl or an alkoxy; Ar 1 , Ar 2 are each independently a substituted or non-substituted phenyl, 1-naphthyl, 2-naphthyl or 4-biphenyl (provided that a case that the Ar 1 , Ar 2 are both the substituted or non-substituted 4-biphenyl, is excluded)] is used. COPYRIGHT: (C)2007,JPO&INPIT

10. 发明专利

JP2002371034A Method for producing para-acetoxystyrene 审中-公开
标题翻译：生产对羟基苯乙烯的方法
公开(公告)号：JP2002371034A
公开(公告)日：2002-12-26
申请号：JP2001181390
申请日：2001-06-15
申请人： Tosoh Corp , 東ソー株式会社
发明人： NISHIYAMA SHOICHI , EGUCHI HISAO
IPC分类号： C07C67/24 , C07B61/00 , C07C69/157
摘要： PROBLEM TO BE SOLVED: To solve problems of conventional technology and provide a method for economically and safely producing para-acetoxystyrene in good yield.
SOLUTION: Para-Tertiary butoxystyrene is reacted with acetic anhydride in the presence of a mixture of sulfuric acid with an organic sulfonic acid as a catalyst to produce para-acetoxystyrene.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：解决常规技术的问题，并提供一种经济，安全地以良好的产率生产对 - 乙酰氧基苯乙烯的方法。解决方案：在硫酸与有机磺酸的混合物作催化剂的存在下，将副仲丁基苯乙烯与乙酸酐反应，生成对 - 乙酰氧基苯乙烯。

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