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1. 发明专利

JP2013121559A Coproduction catalyst for 1,3-butadiene and methacrolein, and production method of 1,3-butadiene and methacrolein using the same 有权
标题翻译： 1,3-丁二烯和甲基纤维素的共同催化剂及其使用的1,3-丁二烯和甲基纤维素的生产方法
公开(公告)号：JP2013121559A
公开(公告)日：2013-06-20
申请号：JP2011270274
申请日：2011-12-09
申请人： Tosoh Corp , 東ソー株式会社
发明人： DOI TAKAO , OGURI MOTOHIRO
IPC分类号： B01J23/31 , C07B61/00 , C07C5/333 , C07C11/167 , C07C45/28 , C07C47/22
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a coproduction catalyst for 1,3-butadiene and methacrolein in which n-butene and iso-butene are made raw materials, and that can efficiently coproduce 1,3-butadiene industrially useful for a raw material of a synthetic rubber and methacrolein industrially useful for a raw material of methacrylic acid, methyl methacrylate (MMA), and an MMA resin, and to provide a production method for 1,3-butadiene and methacrolein using the same.SOLUTION: The coproduction catalyst for 1,3 butadiene and methacrolein is a multiple element based composite oxide shown by general formula: MoCoFecBiCeTlSbO(wherein b =3-15, c =0.4-5, d =0.01-3, e =0.01-2, f =0.01-2, g =0.01-3, j =40-79, c/b =0.3-1.2).
摘要翻译：待解决的问题：提供一种用于制造正丁烯和异丁烯作为原料的1,3-丁二烯和异丁烯醛的共生产催化剂，并且可以有效地共同生产工业上用于原料的1,3-丁二烯工业上可用于甲基丙烯酸，甲基丙烯酸甲酯（MMA）和MMA树脂的原料的合成橡胶和异丁烯醛的材料，并提供使用该方法的1,3-丁二烯和甲基丙烯醛的制备方法。解决方案：用于1,3-丁二烯和异丁烯醛的共生产催化剂是通式为多元素的复合氧化物：Mo 12 Co b FecBi d Sb （其中b = 3-15，c = 0.4-5，d = 0.01-3，e = 0.01-2），f = 0.01-2，g = 0.01-3，j = 40-79，c / b = 0.3-1.2）。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2012240938A Method for producing epoxy compound 有权
标题翻译：生产环氧化合物的方法
公开(公告)号：JP2012240938A
公开(公告)日：2012-12-10
申请号：JP2011110545
申请日：2011-05-17
申请人： Tosoh Corp , 東ソー株式会社
发明人： DOI TAKAO , FUJITA TAKUMI , OGURI MOTOHIRO , WATABE YOSHIMASA
IPC分类号： C07D301/24 , C07B61/00 , C07D303/04
摘要： PROBLEM TO BE SOLVED: To provide a new method for producing an epoxy compound, capable of producing it in high activity and in high selectivity even if necessarily using no peroxide, and enabling the reaction to be conducted safely as a result of non-use of peroxide.SOLUTION: The new method for producing an epoxy compound comprises: conducting a catalytic reaction between an olefin, a secondary alcohol and molecular oxygen in the presence of a palladium complex and a MWW-type crystalline titanosilicate as catalysts.
摘要翻译：要解决的问题：为了提供一种生产环氧化合物的新方法，即使不需要使用过氧化物也能够以高活性和高选择性生产环氧化合物，并且能够使反应安全地作为非 - - 使用过氧化物。解决方案：制备环氧化合物的新方法包括：在钯络合物和MWW型结晶钛硅酸盐作为催化剂的存在下，在烯烃，仲醇和分子氧之间进行催化反应。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2010264450A New structure containing silica alumina and method of producing the same 有权
标题翻译：含有二氧化硅铝的新结构及其生产方法
公开(公告)号：JP2010264450A
公开(公告)日：2010-11-25
申请号：JP2010166993
申请日：2010-07-26
申请人： Tosoh Corp , 東ソー株式会社
发明人： ASAKAWA TETSUO , DOI TAKAO , OGURI MOTOHIRO
IPC分类号： B01J21/12 , B01J32/00 , B01J37/02 , B01J37/08
摘要： PROBLEM TO BE SOLVED: To provide a new structure containing silica alumina having catalytic activity, which is effective as a catalyst, and a method of producing the same.
SOLUTION: The new structure is provided by supporting a hydroxide and/or oxide, which serves as the raw material of the silica alumina, on the surface layer of a carrier, and then by firing at 200-800°C. In the new structure, the silica alumina having catalytic activity is present in the surface layer of the structure, particularly, the surface layer to the depth of 1-1,000 μm from the outer surface of the structure. The inner layer excluding the surface layer of the structure is composed of the carrier containing substantially no silica alumina having catalytic activity.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题：提供含有作为催化剂有效的具有催化活性的二氧化硅氧化铝的新结构及其制造方法。解决方案：通过在载体的表面层上负载用作二氧化硅氧化铝的原料的氢氧化物和/或氧化物，然后在200-800℃下烧成来提供新的结构。在新结构中，具有催化活性的二氧化硅氧化铝存在于结构的表面层中，特别是从结构的外表面到表面层的深度为1-1000μm。不包括结构表层的内层由基本上不含具有催化活性的二氧化硅氧化铝的载体组成。版权所有（C）2011，JPO＆INPIT

4. 发明专利

JP2009215244A Method for producing ethylene 有权
标题翻译：乙烯生产方法
公开(公告)号：JP2009215244A
公开(公告)日：2009-09-24
申请号：JP2008061761
申请日：2008-03-11
申请人： Tosoh Corp , 東ソー株式会社
发明人： DOI TAKAO , ASAKAWA TETSUO , OGURI MOTOHIRO
IPC分类号： C07C1/24 , B01J29/65 , C07B61/00 , C07C11/04
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for producing ethylene in high activity and in high selectivity. SOLUTION: This method for producing ethylene by using the dehydration reaction of ethanol for producing the ethylene is provided by bringing the ethanol in contact with a catalyst using a proton type ferrierite. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供一种以高活性和高选择性生产乙烯的方法。解决方案：通过使用乙醇用于制备乙烯的脱水反应生产乙烯的方法是通过使用质子型镁碱沸石使乙醇与催化剂接触来提供的。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2006255601A Tungsten-zirconia-containing new structure and its manufacturing method 有权
标题翻译： TUNGSTEN-ZIRCONIA包含新结构及其制造方法
公开(公告)号：JP2006255601A
公开(公告)日：2006-09-28
申请号：JP2005077165
申请日：2005-03-17
申请人： Tosoh Corp , 東ソー株式会社
发明人： ASAKAWA TETSUO , DOI TAKAO , OGURI MOTOHIRO
IPC分类号： B01J23/30 , B01J35/08 , B01J37/02
摘要： PROBLEM TO BE SOLVED: To provide a tungsten-zirconia-containing new structure effective as a solid acid catalyst and a method for manufacturing the tungsten-zirconia-containing new structure.
SOLUTION: The tungsten-zirconia-containing new structure is manufactured by depositing zirconium hydroxide and/or zirconium oxide on the surface layer part of an inactive carrier, treating the inactive carrier thus deposited with a tungsten solution and firing the inactive carrier thus treated at 450-1,000°C. Tungsten-zirconia exists in the surface layer part of the structure, particularly, in the surface layer part of the exterior surface to the depth of 1-1,000 μm. The internal layer except the surface layer part of the structure is composed of the inactive carrier in which tungsten-zirconia is not contained.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供作为固体酸催化剂有效的含钨氧化锆的新结构体和含有这种含钨氧化锆的新结构的方法。解决方案：含钨 - 氧化锆的新结构是通过在惰性载体的表面层上沉积氢氧化锆和/或氧化锆来制造的，用钨溶液处理由此沉积的惰性载体，从而烧制非活性载体在450-1,000℃下处理。钨 - 氧化锆存在于结构的表层部分，特别是在外表面的表层部分中，深度为1-1000μm。除了结构的表层部分之外的内层由不含钨氧化锆的无活性载体组成。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2006255599A Silica-alumina-containing new structure and its manufacturing method 有权
标题翻译：含硅铝的新结构及其制造方法
公开(公告)号：JP2006255599A
公开(公告)日：2006-09-28
申请号：JP2005077163
申请日：2005-03-17
申请人： Tosoh Corp , 東ソー株式会社
发明人： ASAKAWA TETSUO , DOI TAKAO , OGURI MOTOHIRO
IPC分类号： B01J21/12 , B01J32/00 , B01J35/08 , B01J37/08 , C04B41/85
摘要： PROBLEM TO BE SOLVED: To provide a silica-alumina-containing new structure having catalytic activity effective as a catalyst and a method for manufacturing the silica-alumina-containing new structure.
SOLUTION: The silica-alumina-containing new structure is manufactured by depositing a hydroxide and/or oxide being a raw material of silica-alumina on the surface layer part of a carrier and firing the carrier thus deposited at 200-800°C. Silica-alumina having catalytic activity exists in the surface layer part of the structure, particularly, the surface layer part of the exterior surface to the depth of 1-1,000 μm. The internal layer except the surface layer part of the structure is composed of the carrier in which silica-alumina having catalytic activity is not contained substantially.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供具有催化活性作为催化剂的具有二氧化硅 - 氧化铝的新结构和制备含二氧化硅 - 氧化铝的新结构的方法。解决方案：含二氧化硅 - 氧化铝的新结构是通过在载体的表面层上沉积作为二氧化硅 - 氧化铝的原料的氢氧化物和/或氧化物制造的，并将如此沉积的载体烧制在200-800° C。具有催化活性的二氧化硅 - 氧化铝存在于结构的表层部分，特别是外表面的表层部分，深度为1-1000μm。除了结构的表层部分之外的内层由其中基本不含有具有催化活性的二氧化硅 - 氧化铝的载体组成。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2014001171A Process of producing 1,3-butadiene 有权
标题翻译： 1,3-丁二烯生产工艺
公开(公告)号：JP2014001171A
公开(公告)日：2014-01-09
申请号：JP2012137931
申请日：2012-06-19
申请人： Tosoh Corp , 東ソー株式会社
发明人： DOI TAKAO , OGURI MOTOHIRO
IPC分类号： C07C5/48 , B01J23/28 , B01J23/30 , B01J29/035 , C07B61/00 , C07C6/04 , C07C11/08 , C07C11/167
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a process of producing 1,3-butadiene that can efficiently produce 1,3-butadiene, which is industrially useful as a raw material of synthetic rubber, using propylene as a raw material.SOLUTION: A process of producing 1,3-butadiene includes at least the steps of: (A) disproportionating a gas containing at least gaseous propylene in the presence of a disproportionation reaction catalyst to convert the gas into a product gas containing n-butene and ethylene; (B) subjecting the reaction product gas obtained in the step (A) to a separation operation to separate and recover a fraction containing n-butene as a main component; and (C) dehydrogenating the fraction obtained in the step (B) in the presence of a dehydrogenation catalyst to produce a reaction product gas containing 1,3-butadiene.
摘要翻译：要解决的问题：提供一种生产1,3-丁二烯的方法，其可以有效地生产工业上可用作合成橡胶原料的1,3-丁二烯，使用丙烯作为原料。方法：生产1,3-丁二烯至少包括以下步骤：（A）在歧化反应催化剂存在下歧化至少含有气态丙烯的气体，将气体转化为含有正丁烯和乙烯的产物气体; （B）使步骤（A）中获得的反应产物气体进行分离操作，分离并回收含有正丁烯作为主要成分的馏分; 和（C）在脱氢催化剂的存在下使步骤（B）中获得的馏分脱氢以产生含有1,3-丁二烯的反应产物气体。

8. 发明专利

JP2013129628A Method of manufacturing 1,3-butadiene and methacrolein 有权
标题翻译：制备1,3丁二烯和甲基纤维素的方法
公开(公告)号：JP2013129628A
公开(公告)日：2013-07-04
申请号：JP2011280390
申请日：2011-12-21
申请人： Tosoh Corp , 東ソー株式会社
发明人： DOI TAKAO , OGURI MOTOHIRO
IPC分类号： C07C5/48 , B01J23/88 , C07B61/00 , C07C11/167 , C07C45/35 , C07C47/22
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for substantially and efficiently manufacturing 1,3-butadiene and methacrolein by going through a specific process, in the manufacture of the 1,3-butadiene and the methacrolein from C4 hydrocarbons, as a raw material, containing n-butene and iso-butene.SOLUTION: A method of manufacturing 1,3-butadiene and methacrolein comprises at least a step (A): a step of causing at least n-butene and iso-butene to react with molecular oxygen at 300-500°C in the presence of an oxidation reaction catalyst thereby to manufacture the 1,3-butadiene and the methacrolein as a reaction product gas, a step (B): a step of bringing the obtained reaction product gas into direct contact with an aqueous medium to separate the gas into a methacrolein aqueous solution and a gas component containing the 1,3-butadiene, a step (C): a step of separating and recovering the methacrolein from the methacrolein aqueous solution obtained in the step (B), and a step (D): a step of separating and recovering the 1,3-butadiene from the gas component obtained in the step (B).
摘要翻译：要解决的问题：为了提供通过特定方法实质上有效地制造1,3-丁二烯和甲基丙烯醛的方法，在以C4烃为原料制造1,3-丁二烯和甲基丙烯醛时，含有正丁烯和异丁烯的方法。解决方案：制备1,3-丁二烯和甲基丙烯醛的方法至少包括步骤（A）：使至少正丁烯和异丁烯与分子氧反应的步骤在氧化反应催化剂的存在下反应300-500℃，由此制造作为反应产物气体的1,3-丁二烯和甲基丙烯醛，步骤（B）：使得到的反应产物气体与将气体分离为甲基丙烯醛水溶液的水性介质和含有1,3-丁二烯的气体成分，工序（C）：从步骤（B）得到的甲基丙烯醛水溶液中分离回收异丁烯醛的工序，，和步骤（D）：步骤从步骤（B）中获得的气体组分中脱乙酰并回收1,3-丁二烯。

9. 发明专利

JP2011111431A Process for simultaneously producing epoxy compound and ketone compound 有权
标题翻译：同时生产环氧化合物和酮酮化合物的方法
公开(公告)号：JP2011111431A
公开(公告)日：2011-06-09
申请号：JP2009271536
申请日：2009-11-30
申请人： Tosoh Corp , 東ソー株式会社
发明人： DOI TAKAO , MORI YOSHIHIKO , OGURI MOTOHIRO
IPC分类号： C07D301/06 , B01J31/38 , C07B61/00 , C07C45/39 , C07C49/08 , C07D303/04
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a novel process for simultaneously producing an epoxy compound and a ketone compound which can produce an epoxy compound with a high selectivity and high activity even without using a peroxide and can produce a ketone compound as well with a high selectivity and high activity at the same time, and moreover can safely carry out the reaction due to no use of a peroxide.
SOLUTION: The process for simultaneously producing an epoxy compound and a ketone compound comprises bringing an olefin, a secondary alcohol, and molecular oxygen into contact with one another with the use of a divalent palladium complex and a crystalline titanosilicate as catalysts.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种同时生产环氧化合物和酮化合物的新方法，其可以生产环氧化合物，即使不使用过氧化物也可以生产具有高选择性和高活性的环氧化合物，并且还可以制备酮化合物同时具有高选择性和高活性，而且由于不使用过氧化物，可以安全地进行反应。解决方案：同时制备环氧化合物和酮化合物的方法包括使用二价钯络合物和结晶钛硅酸盐作为催化剂使烯烃，仲醇和分子氧彼此接触。版权所有（C）2011，JPO＆INPIT

10. 发明专利

JP2010024185A Method for producing 1,2-dichloroethane 有权
标题翻译： 1,2-二氯乙烷的制备方法
公开(公告)号：JP2010024185A
公开(公告)日：2010-02-04
申请号：JP2008188058
申请日：2008-07-22
申请人： Tosoh Corp , 東ソー株式会社
发明人： ASAKAWA TETSUO , DOI TAKAO , OGURI MOTOHIRO
IPC分类号： C07C17/15 , B01J27/122 , B01J29/24 , B01J29/46 , B01J29/68 , C07B61/00 , C07C17/158 , C07C19/045
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for producing 1,2-dichloroethane from ethanol and/or chloroethane with hydrogen chloride and molecular oxygen in a good efficiency. SOLUTION: The method for producing 1,2-dichloroethane by reacting the ethanol and/or chloroethane with hydrogen chloride and molecular oxygen in the presence of a catalyst is characterized by bringing the ethanol and/or chloroethane with hydrogen chloride and molecular oxygen in contact with the catalyst obtained by mixing a solid acid catalyst and an oxychlorination catalyst loaded with copper chloride. COPYRIGHT: (C)2010,JPO&INPIT

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