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    • 4. 发明申请
    • LAMINATED CERAMIC ELECTRONIC COMPONENT AND MANUFACTURING METHOD THEREFOR
    • 层压陶瓷电子元件及其制造方法
    • US20100328843A1
    • 2010-12-30
    • US12821305
    • 2010-06-23
    • Masahito SARUBANMakoto OGAWAToshiyuki IWANAGASeiichi MATSUMOTOAkihiro MOTOKIShunsuke TAKEUCHISeiichi NISHIHARAKenichi KAWASAKI
    • Masahito SARUBANMakoto OGAWAToshiyuki IWANAGASeiichi MATSUMOTOAkihiro MOTOKIShunsuke TAKEUCHISeiichi NISHIHARAKenichi KAWASAKI
    • H01G4/008B05D5/12
    • H01G4/2325H01G4/30H01L41/083H01L41/293
    • In a method for manufacturing a laminated ceramic electronic component, after a plating layer for an external terminal electrode is formed by applying copper plating to an end surface of a component main body at which respective ends of a plurality of internal electrodes primarily including nickel are exposed, when a heat treatment at a temperature of about 800° C. or more is applied in order to improve adhesion strength and resistance to moisture of the external terminal electrode, voids may occur in the plating layer. The step of applying a heat treatment at a temperature of about 800° C. or more to a component main body with plating layers formed thereon includes not only a step of maintaining a top temperature of about 1000° C. or more but also a step of maintaining a temperature of about 600° C. to 900° C. at least once before the step of maintaining the top temperature. These steps preliminarily diffuse copper included in the plating layers, which has a relatively high diffusion velocity, into the internal electrodes primarily including nickel, thereby reducing a difference in diffusion velocity between copper and nickel at the top temperature, which causes the occurrence of voids.
    • 在层叠陶瓷电子部件的制造方法中,在将外部端子电极的镀覆层通过在主体的主体的多个内部电极的各端露出的部件主体的端面上进行镀铜而形成后, 为了提高外部端子电极的附着强度和耐潮湿性而在800℃以上的温度下进行热处理时,可能会在镀层中产生空隙。 在其上形成有镀层的组件主体上,在约800℃以上的温度下进行热处理的步骤不仅包括保持顶部温度为约1000℃以上的步骤,还包括步骤 在保持顶部温度的步骤之前至少保持约600℃至900℃的温度。 这些步骤将包含在具有较高扩散速度的镀层中的铜初步扩散到主要包括镍的内部电极中,从而减少了在最高温度下铜和镍之间扩散速度的差异,这导致空隙的发生。