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1. 发明授权

US08492000B2 Vulcanized rubber laminate 有权
标题翻译：硫化橡胶层压板
公开(公告)号：US08492000B2
公开(公告)日：2013-07-23
申请号：US12864489
申请日：2009-01-28
申请人： Toshiyuki Funayama , Shigeru Shoji , Toyofumi Otaka
发明人： Toshiyuki Funayama , Shigeru Shoji , Toyofumi Otaka
IPC分类号： B32B25/04 , B32B25/14
CPC分类号： F16L11/04 , B32B1/08 , B32B7/10 , B32B25/14 , B32B27/304 , B32B2307/7265 , B32B2597/00 , C08K5/0025 , C08L71/03 , F16L11/045 , F16L11/081 , Y10T428/31511 , Y10T428/31536 , Y10T428/3154
摘要： Disclosed is a vulcanized rubber laminate in which both an unvulcanized epichlorohydrin-based rubber composition layer containing a specific polyfunctional (meth)acrylate compound and a specific vulcanizing agent and an unvulcanized fluororubber composition layer containing a specific vulcanizing agent are heated and bonded, whereby, both rubber layers are firmly bonded. A vulcanized rubber laminate in which (A) an unvulcanized epichlorohydrin-based rubber composition layer and (B) an unvulcanized fluororubber composition layer are heated and bonded, wherein the unvulcanized epichlorohydrin-based rubber composition (A) contains: (1) a polyfunctional (meth)acrylate compound having two or more (meth) acryloyl groups in the molecule, and (2) at least one kind selected from the group consisting of a triazine-based vulcanizing agent, a thiourea-based vulcanizing agent, a quinoxaline-based vulcanizing agent and a bisphenol-based vulcanizing agent, and the unvulcanized fluororubber composition (B) contains an organic peroxide-based vulcanizing agent.
摘要翻译：公开了将含有特定的多官能（甲基）丙烯酸酯化合物和特定硫化剂的未硫化表氯醇类橡胶组合物层和含有特定硫化剂的未硫化氟橡胶组合物层加热粘合的硫化橡胶层叠体，由此两者橡胶层牢固粘合。将（A）未硫化表氯醇类橡胶组合物层和（B）未硫化氟橡胶组合物层加热粘合的硫化橡胶层压体，其中未硫化表氯醇类橡胶组合物（A）含有：（1）多官能（甲基）丙烯酸酯化合物，和（2）选自三嗪系硫化剂，硫脲类硫化剂，喹喔啉类硫化物中的至少一种未硫化氟橡胶组合物（B）含有有机过氧化物类硫化剂。

2. 发明授权

US08283039B2 Vulcanized rubber laminate 有权
标题翻译：硫化橡胶层压板
公开(公告)号：US08283039B2
公开(公告)日：2012-10-09
申请号：US11277434
申请日：2006-03-24
申请人： Toshiyuki Funayama , Shigeru Shoji , Yasushi Hamura , Toyofumi Otaka
发明人： Toshiyuki Funayama , Shigeru Shoji , Yasushi Hamura , Toyofumi Otaka
IPC分类号： B32B27/38 , B32B27/00 , F16L11/00 , F16L9/14
CPC分类号： F16L11/04 , B32B25/042 , B32B25/14 , B32B2250/02 , B32B2250/248 , B32B2307/306 , B32B2307/5825 , B32B2307/712 , B32B2307/714 , B32B2597/00 , Y10T428/31511 , Y10T428/3154
摘要： The invention provides a vulcanized rubber laminate obtained by firmly bonding an unvulcanized epichlorohydrin rubber layer and an organic peroxide-containing fluororubber layer. The laminate is obtained by thermal adhesion a layer of an unvulcanized epichlorohydrin rubber composition to a layer of an unvulcanized fluororubber composition. The epichlorohydrin rubber composition comprises 1) an unvulcanized epichlorohydrin rubber containing 3 to 15 mol % of allyl glycidyl ether unit, 2) quinoxaline-based vulcanizing agents, mercaptotriazine-based vulcanizing agents or bisphenol-based vulcanizing agents, and 3) 1,8-diazabicyclo(5,4,0)undecene-7 salts, 1,5-diazabicyclo(4,3,0)nonene-5 salts, quaternary ammonium salts, quaternary phosphonium salts, basic white carbons or an alkaline metal salt of higher fatty acid the fluororubber composition comprises an fluororubber and an organic peroxide-based vulcanizing agent.
摘要翻译：本发明提供了通过将未硫化的表氯醇橡胶层和含有机过氧化物的氟橡胶层牢固地结合而获得的硫化橡胶层压体。通过将未硫化的表氯醇橡胶组合物的层热粘合到未硫化的氟橡胶组合物的层上来获得层压体。表氯醇橡胶组合物包含1）含有3〜15摩尔％烯丙基缩水甘油醚单元的未硫化表氯醇橡胶，2）喹喔啉类硫化剂，巯基三嗪类硫化剂或双酚系硫化剂，以及3）（5,4,0）十一碳烯-7盐，1,5-二氮杂双环（4,3,0）壬烯-5-盐，季铵盐，季鏻盐，碱性白碳或高级脂肪酸的碱金属盐氟橡胶组合物包含氟橡胶和有机过氧化物基硫化剂。

3. 发明申请

US20100297452A1 VULCANIZED RUBBER LAMINATE 有权
公开(公告)号：US20100297452A1
公开(公告)日：2010-11-25
申请号：US12864489
申请日：2009-01-28
申请人： Toshiyuki Funayama , Shigeru Shoji , Toyofumi Otaka
发明人： Toshiyuki Funayama , Shigeru Shoji , Toyofumi Otaka
IPC分类号： B32B27/38
CPC分类号： F16L11/04 , B32B1/08 , B32B7/10 , B32B25/14 , B32B27/304 , B32B2307/7265 , B32B2597/00 , C08K5/0025 , C08L71/03 , F16L11/045 , F16L11/081 , Y10T428/31511 , Y10T428/31536 , Y10T428/3154
摘要： Disclosed is a vulcanized rubber laminate in which both an unvulcanized epichlorohydrin-based rubber composition layer containing a specific polyfunctional (meth)acrylate compound and a specific vulcanizing agent and an unvulcanized fluororubber composition layer containing a specific vulcanizing agent are heated and bonded, whereby, both rubber layers are firmly bonded. A vulcanized rubber laminate in which (A) an unvulcanized epichlorohydrin-based rubber composition layer and (B) an unvulcanized fluororubber composition layer are heated and bonded, wherein the unvulcanized epichlorohydrin-based rubber composition (A) contains: (1) a polyfunctional (meth)acrylate compound having two or more (meth) acryloyl groups in the molecule, and (2) at least one kind selected from the group consisting of a triazine-based vulcanizing agent, a thiourea-based vulcanizing agent, a quinoxaline-based vulcanizing agent and a bisphenol-based vulcanizing agent, and the unvulcanized fluororubber composition (B) contains an organic peroxide-based vulcanizing agent.
摘要翻译：公开了将含有特定的多官能（甲基）丙烯酸酯化合物和特定硫化剂的未硫化表氯醇类橡胶组合物层和含有特定硫化剂的未硫化氟橡胶组合物层加热粘合的硫化橡胶层叠体，由此两者橡胶层牢固粘合。将（A）未硫化表氯醇类橡胶组合物层和（B）未硫化氟橡胶组合物层加热粘合的硫化橡胶层压体，其中未硫化表氯醇类橡胶组合物（A）含有：（1）多官能（甲基）丙烯酸酯化合物，和（2）选自三嗪系硫化剂，硫脲类硫化剂，喹喔啉类硫化物中的至少一种未硫化氟橡胶组合物（B）含有有机过氧化物类硫化剂。

4. 发明授权

US08835566B2 Rubber composition for vulcanization 有权
标题翻译：用于硫化的橡胶组合物
公开(公告)号：US08835566B2
公开(公告)日：2014-09-16
申请号：US12446506
申请日：2007-10-26
申请人： Shigeru Shoji , Toyofumi Otaka , Toshiyuki Funayama , Yasushi Hamura
发明人： Shigeru Shoji , Toyofumi Otaka , Toshiyuki Funayama , Yasushi Hamura
IPC分类号： C08L71/03 , C08K5/39 , C08K3/26 , C08K5/09 , C08K5/3465
CPC分类号： C08K5/39 , C08L71/03 , C08L2666/22
摘要： The present invention provides a vulcanized rubber material having improved heat resistance while maintaining ozone resistance of an epihalohydrin rubber, and a rubber composition for vulcanization for producing the same. The invention further provides a vulcanized rubber material and a rubber composition for vulcanization, that can achieve the above objects without using an organonickel compound having a concern about toxicity, or if used, using the same as less as possible. The present invention relates to a rubber composition for vulcanization comprising (a) 100 parts by weight of an epihalohydrin rubber, (b) 0.01 to 0.5 part by weight of a copper salt of dithiocarbamic acid, (c) an acid acceptor, and (d) a polythiol type vulcanizing agent or a polyol type vulcanizing agent, a vulcanized rubber material obtained by vulcanizing the composition, and an automotive rubber part comprising the vulcanized rubber material.
摘要翻译：本发明提供一种具有改善的耐热性同时保持表卤代醇橡胶的耐臭氧性的硫化橡胶材料和用于制造硫化橡胶的橡胶组合物。本发明还提供一种硫化橡胶材料和用于硫化的橡胶组合物，其可以在不使用关于毒性的有机镍化合物的情况下实现上述目的，或者如果使用，则尽可能少地使用它们。本发明涉及一种用于硫化的橡胶组合物，其包含（a）100重量份的表卤代醇橡胶，（b）0.01至0.5重量份的二硫代氨基甲酸铜盐，（c）酸受体和（d ）多硫醇型硫化剂或多元醇型硫化剂，通过硫化组合物得到的硫化橡胶材料和包含硫化橡胶材料的汽车橡胶部件。

5. 发明授权

US08258222B2 Composition for vulcanized rubber and vulcanization product 有权
标题翻译：硫化橡胶和硫化产品的组成
公开(公告)号：US08258222B2
公开(公告)日：2012-09-04
申请号：US11285386
申请日：2005-11-23
申请人： Toyofumi Otaka , Shigeru Shoji , Yasushi Hamura , Toshiyuki Funayama
发明人： Toyofumi Otaka , Shigeru Shoji , Yasushi Hamura , Toshiyuki Funayama
IPC分类号： C04B35/634 , C08K5/09 , C08K5/04 , C08K5/05 , D06M15/693 , C08F220/04 , B03D1/016 , C08L27/00
CPC分类号： C08L71/02 , C08K5/3465 , C08L71/03
摘要： A composition for epihalohydrin vulcanized rubber excellent in heat resistance while keeping good vulcanization rate and store stability, comprising (a) an epihalohydrin robber, (b) a metal soap, (c) an acid acceptor, and (d) a vulcanizing agent, the composition further preferably containing (e) a fatty acid for suppressing vulcanization, or preferably containing (f) an alcohol for accelerating vulcanization.
摘要翻译：包含（a）表卤代醇强ber素，（b）金属皂，（c）酸接受体和组合物还优选含有（e）用于抑制硫化的脂肪酸，或优选含有（f）用于加速硫化的醇。

6. 发明申请

US20060216518A1 VULCANIZED RUBBER LAMINATE 有权
公开(公告)号：US20060216518A1
公开(公告)日：2006-09-28
申请号：US11277434
申请日：2006-03-24
申请人： Toshiyuki Funayama , Shigeru Shoji , Yasushi Hamura , Toyofumi Otaka
发明人： Toshiyuki Funayama , Shigeru Shoji , Yasushi Hamura , Toyofumi Otaka
IPC分类号： B32B27/38
CPC分类号： F16L11/04 , B32B25/042 , B32B25/14 , B32B2250/02 , B32B2250/248 , B32B2307/306 , B32B2307/5825 , B32B2307/712 , B32B2307/714 , B32B2597/00 , Y10T428/31511 , Y10T428/3154
摘要： The invention provides a vulcanized rubber laminate obtained by firmly bonding an unvulcanized epichlorohydrin rubber layer and an organic peroxide-containing fluororubber layer. The laminate is obtained by thermal adhesion a layer of an unvulcanized epichlorohydrin rubber composition to a layer of an unvulcanized fluororubber composition. The epichlorohydrin rubber composition comprises 1) an unvulcanized epichlorohydrin rubber containing 3 to 15 mol % of allyl glycidyl ether unit, 2) quinoxaline-based vulcanizing agents, mercaptotriazine-based vulcanizing agents or bisphenol-based vulcanizing agents, and 3) 1,8-diazabicyclo(5,4,0)undecene-7 salts, 1,5-diazabicyclo(4,3,0)nonene-5 salts, quaternary ammonium salts, quaternary phosphonium salts, basic white carbons or an alkaline metal salt of higher fatty acid the fluororubber composition comprises an fluororubber and an organic peroxide-based vulcanizing agent.
摘要翻译：本发明提供了通过将未硫化的表氯醇橡胶层和含有机过氧化物的氟橡胶层牢固地结合而获得的硫化橡胶层压体。通过将未硫化的表氯醇橡胶组合物的层热粘合到未硫化的氟橡胶组合物的层上来获得层压体。表氯醇橡胶组合物包含1）含有3〜15摩尔％烯丙基缩水甘油醚单元的未硫化表氯醇橡胶，2）喹喔啉类硫化剂，巯基三嗪类硫化剂或双酚系硫化剂，以及3）（5,4,0）十一碳烯-7盐，1,5-二氮杂双环（4,3,0）壬烯-5-盐，季铵盐，季鏻盐，碱性白碳或高级脂肪酸的碱金属盐氟橡胶组合物包含氟橡胶和有机过氧化物基硫化剂。

7. 发明申请

US20110160344A1 RUBBER COMPOSITION FOR VULCANIZATION 有权
标题翻译：用于VULCANIZATION的橡胶组合物
公开(公告)号：US20110160344A1
公开(公告)日：2011-06-30
申请号：US12446506
申请日：2007-10-26
申请人： Shigeru Shoji , Toyofumi Otaka , Toshiyuki Funayama , Yasushi Hamura
发明人： Shigeru Shoji , Toyofumi Otaka , Toshiyuki Funayama , Yasushi Hamura
IPC分类号： C08K5/40
CPC分类号： C08K5/39 , C08L71/03 , C08L2666/22
摘要： The present invention provides a vulcanized rubber material having improved heat resistance while maintaining ozone resistance of an epihalohydrin rubber, and a rubber composition for vulcanization for producing the same. The invention further provides a vulcanized rubber material and a rubber composition for vulcanization, that can achieve the above objects without using an organonickel compound having a concern about toxicity, or if used, using the same as less as possible. The present invention relates to a rubber composition for vulcanization comprising (a) 100 parts by weight of an epihalohydrin rubber, (b) 0.01 to 0.5 part by weight of a copper salt of dithiocarbamic acid, (c) an acid acceptor, and (d) a polythiol type vulcanizing agent or a polyol type vulcanizing agent, a vulcanized rubber material obtained by vulcanizing the composition, and an automotive rubber part comprising the vulcanized rubber material.
摘要翻译：本发明提供一种具有改善的耐热性同时保持表卤代醇橡胶的耐臭氧性的硫化橡胶材料和用于制造硫化橡胶的橡胶组合物。本发明还提供一种硫化橡胶材料和用于硫化的橡胶组合物，其可以在不使用关于毒性的有机镍化合物的情况下实现上述目的，或者如果使用，则尽可能少地使用它们。本发明涉及一种用于硫化的橡胶组合物，其包含（a）100重量份的表卤代醇橡胶，（b）0.01至0.5重量份的二硫代氨基甲酸铜盐，（c）酸受体和（d ）多硫醇型硫化剂或多元醇型硫化剂，通过硫化组合物得到的硫化橡胶材料和包含硫化橡胶材料的汽车橡胶部件。

8. 发明申请

US20060128857A1 Composition for vulcanized rubber and vulcanization product 有权
标题翻译：硫化橡胶和硫化产品的组成
公开(公告)号：US20060128857A1
公开(公告)日：2006-06-15
申请号：US11285386
申请日：2005-11-23
申请人： Toyofumi Otaka , Shigeru Shoji , Yasushi Hamura , Toshiyuki Funayama
发明人： Toyofumi Otaka , Shigeru Shoji , Yasushi Hamura , Toshiyuki Funayama
IPC分类号： C08K5/09
CPC分类号： C08L71/02 , C08K5/3465 , C08L71/03
摘要： A composition for epihalohydrin vulcanized rubber excellent in heat resistance while keeping good vulcanization rate and store stability, comprising (a) an epihalohydrin robber, (b) a metal soap, (c) an acid acceptor, and (d) a vulcanizing agent, the composition further preferably containing (e) a fatty acid for suppressing vulcanization, or preferably containing (f) an alcohol for accelerating vulcanization.
摘要翻译：包含（a）表卤代醇强ber素，（b）金属皂，（c）酸接受体和组合物还优选含有（e）用于抑制硫化的脂肪酸，或优选含有（f）用于加速硫化的醇。

9. 发明授权

US07909604B2 Root apex position detection apparatus 有权
标题翻译：根顶位置检测仪
公开(公告)号：US07909604B2
公开(公告)日：2011-03-22
申请号：US11297993
申请日：2005-12-09
申请人： Shigeru Shoji , Masahiro Otsuka
发明人： Shigeru Shoji , Masahiro Otsuka
IPC分类号： A61C19/04 , A61B5/05 , A61B5/103
CPC分类号： A61C19/04 , A61C19/042
摘要： Root apex position model data associated with electrical characteristic values between a measurement electrode and a mouth electrode in a state in which the distal end of the measurement electrode is located at a root apex position of a root canal is stored in a storage unit. A power supply applies measurement signals of 500 Hz and 2 kHz between the measurement electrode and the mouth electrode. Two different current values flowing between the measurement electrode and the mouth electrode are detected. These current values are compared with the root apex position mode data stored in the storage unit. If the root apex position data includes any data which coincides with the current values, it is detected that the distal end of the measurement electrode is located at the root apex position.
摘要翻译：在测量电极的远端位于根管的根尖位置的状态下，与测量电极和口电极之间的电特性值相关联的根顶位置模型数据被存储在存储单元中。电源在测量电极和嘴电极之间施加500 Hz和2 kHz的测量信号。检测在测量电极和嘴电极之间流动的两个不同的电流值。将这些当前值与存储在存储单元中的根顶点位置模式数据进行比较。如果根顶位置数据包括与当前值一致的任何数据，则检测到测量电极的远端位于根顶位置。

10. 发明授权

US07645685B2 Method for producing a thin IC chip using negative pressure 失效
标题翻译：使用负压制造薄IC芯片的方法
公开(公告)号：US07645685B2
公开(公告)日：2010-01-12
申请号：US11377273
申请日：2006-03-17
申请人： Masaharu Ishizuka , Shigeru Shoji
发明人： Masaharu Ishizuka , Shigeru Shoji
IPC分类号： H01L21/00
CPC分类号： H01L21/78 , B32B37/12 , B32B38/1833 , B32B38/1858 , B32B2309/68 , B32B2457/14 , H01L21/6836 , H01L2221/68327
摘要： The present invention relates to a method for bonding a first thin plate having a first adhesion surface and a first back surface and a second thin plate having a second adhesion surface and a second back surface by an adhesive, the adhesive being sandwiched between said first adhesion surface and said second adhesion surface. The method comprises the steps of: applying said adhesive to said second adhesion surface of said second thin plate; holding said first thin plate by applying negative pressure to said first back surface, wherein said first thin plate is held at said first back surface, and said first adhesion surface faces downward; holding said second thin plate by applying negative pressure to said second back surface, wherein said second thin plate is held at said second back surface, and said second adhesion surface faces upward; temporarily bonding said first thin plate and said second thin plate by putting said first and second adhesion surfaces into contact with each other, wherein said first thin plate and said second thin plate are held by negative pressure; and bonding said first thin plate and said second thin plate by curing said adhesive, wherein said first thin plate and said second thin plate are temporarily bonded.
摘要翻译：本发明涉及一种通过粘合剂粘合具有第一粘合表面和第一后表面的第一薄板和具有第二粘合表面和第二后表面的第二薄板的方法，所述粘合剂夹在所述第一粘合剂表面和所述第二粘附表面。该方法包括以下步骤：将所述粘合剂施加到所述第二薄板的所述第二粘附表面; 通过对所述第一后表面施加负压来保持所述第一薄板，其中所述第一薄板保持在所述第一后表面，并且所述第一粘合表面面向下; 通过对所述第二后表面施加负压来保持所述第二薄板，其中所述第二薄板保持在所述第二后表面，并且所述第二粘合表面面向上; 通过使所述第一和第二粘合表面彼此接触来临时粘合所述第一薄板和所述第二薄板，其中所述第一薄板和所述第二薄板由负压保持; 以及通过固化所述粘合剂来粘合所述第一薄板和所述第二薄板，其中所述第一薄板和所述第二薄板暂时粘合。

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