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1. 发明授权

US5650374A Herbicidal 1-cyclopropyl tetrazolinones 失效
标题翻译：除草1-环丙基四唑啉酮
公开(公告)号：US5650374A
公开(公告)日：1997-07-22
申请号：US553160
申请日：1995-11-07
申请人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo
发明人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo
IPC分类号： C07D401/06 , A01N47/38 , C07D257/04 , C07D403/06 , C07D405/12 , A01N43/713 , A01N43/72
CPC分类号： C07D257/04 , A01N47/38
摘要： Herbicidal 1-cyclopropyl tetrazolinones of the formula ##STR1## wherein X represents C.sub.1-3 alkyl, C.sub.2-4 alkenyl or halogen,n represents 0 to 5,R.sup.1 and R.sup.2 each independently represents C.sub.1-6 alkyl, C.sub.2-6 alkenyl, C.sub.2-6 alkynyl, C.sub.3-7 cycloalkyl which may optionally be substituted by C.sub.1-3 alkyl, epoxy-C.sub.3-5 alkan-1-yl, phenyl which may optionally be substituted, or aralkyl which may optionally be substituted, orR.sup.1 and R.sup.2 together with the N-atom to which they are attached, represent a cyclic ring which may be substituted, and some novel intermediates therefor.
摘要翻译：式（I）的除草1-环丙基四唑啉酮其中X代表C1-3烷基，C2-4烯基或卤素，n代表0-5，R1和R2各自独立地表示C1-6烷基，C2-6烯基 C 2-6炔基，可任选被C 1-3烷基取代的C 3-7环烷基，环烷基-C 3-5烷基-1-基，可任意被取代的苯基或可任意被取代的芳烷基，或R 1和 R2与它们所连接的N-原子一起表示可以被取代的环状环，以及一些新的中间体。

2. 发明授权

US5668087A Herbicidal 1-alkenyltetrazolinones 失效
标题翻译：除草剂1-烯基四唑啉酮
公开(公告)号：US5668087A
公开(公告)日：1997-09-16
申请号：US616674
申请日：1996-03-15
申请人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo , Natsuko Minegishi
发明人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo , Natsuko Minegishi
IPC分类号： C07D401/06 , A01N47/38 , C07D257/04 , C07D403/06 , A01N43/713
CPC分类号： C07D257/04 , A01N47/38
摘要： Herbicidal 1-alkenyltetrazolinones of the formula: ##STR1## wherein R.sup.1 represents the group: ##STR2## or the group: ##STR3## R.sup.2 and R.sup.3, independently of one another, represent C.sub.1-6 alkyl, C.sub.3-7 cycloalkyl which may optionally be substited by methyl, C.sub.2-4 alkenyl, C.sub.2-5 alkynyl, phenyl which may optionally be substituted or aralkyl which may optionally be substituted, orR.sup.2 and R.sup.3 may optionally form, together with the N-atom to which they are bonded, a heterocyclic ring which may optionally be substituted, and novel intermediates therefor.
摘要翻译：下式的除草1-烯基四唑啉酮：彼此独立地表示C 1-6烷基，可以任选地被甲基，C 2-4烯基，C 2-5炔基，可任选被取代的苯基或任选被取代的芳基烷基的C 3-7环烷基可以任选地被取代，或者R 2和R 3可以任选地与它们所键合的N-原子一起形成可以任选被取代的杂环，以及其新颖的中间体。

3. 发明授权

US06262275B1 Herbicidal 1-substituted methyl-tetrazolinones 失效
标题翻译：除草剂1-取代的甲基 - 四唑啉酮
公开(公告)号：US06262275B1
公开(公告)日：2001-07-17
申请号：US09368475
申请日：1999-08-04
申请人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
发明人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
IPC分类号： C07D41306
CPC分类号： C07D257/04 , A01N47/38
摘要： Novel 1-substituted methyltetrazolinones of the formula (I) wherein R1 represents a 5-membered heterocyclic radical which has 1 to 3 heteroatoms selected arbitrarily from the group consisting of N, O and S and which is optionally substituted by halogen and/or C1-4 alkyl, or represents oxiran-2-yl, optionally chloro-substituted pyridyl or C1-4 alkyl-S(O)m— wherein m represents 0, 1 or 2, or represents a C3-6 alicyclic hydrocarbon radical; R2 and R3 represent, independently of one another, C1-6 alkyl, C3-7 cycloalkyl or optionally substituted phenyl, or R2 and R3 may form, together with the N-atom to which they are bonded, an optionally substituted ring; R4 represents a hydrogen atom or methyl; and n represents 0 or 1; as well as for their preparation processes and novel intermediates in their production. The inventive compounds of formula (I) are used as herbicides.
摘要翻译：式（I）的新的1-取代的甲基四唑啉酮，其中R 1表示具有1至3个杂原子的5元杂环基，其任选地由N，O和S组成，并且任选被卤素和/或C 1-4取代烷基，或表示环氧乙烷-2-基，任选氯取代的吡啶基或C 1-4烷基-S（O）m - ，其中m表示0,1或2，或表示C 3-6脂族烃基; R 2和R 3彼此独立地表示C 1-6烷基，C 3-7环烷基或任选取代的苯基，或者R 2和R 3可以与它们所键合的N-原子一起形成任选取代的环; R4表示氢原子或甲基; n表示0或1; 以及它们的制备过程和新型中间体的生产。本发明式（I）化合物用作除草剂。

4. 发明授权

US6017853A Herbicidal 1-substituted methyl-tetrazolinones 失效
标题翻译：除草剂1-取代的甲基 - 四唑啉酮
公开(公告)号：US6017853A
公开(公告)日：2000-01-25
申请号：US890432
申请日：1997-07-09
申请人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
发明人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
IPC分类号： A01N47/38 , C07D257/04 , A01N43/72 , C07D413/12
CPC分类号： C07D257/04 , A01N47/38
摘要： Novel 1-substituted methyltetrazolinones of the formula (I) ##STR1## wherein R.sup.1 represents a 5-membered heterocyclic radical which has 1 to 3 heteroatoms selected arbitrarily from the group consisting of N, O and S and which is optionally substituted by halogen and/or C.sub.1-4 alkyl, or represents oxiran-2-yl, optionally chloro-substituted pyridyl or C.sub.1-4 alkyl-S(O).sub.m --wherein m represents 0, 1 or 2, or represents a C.sub.3-6 alicyclic hydrocarbon radical; R.sup.2 and R.sup.3 represent, independently of one another, C.sub.1-4 alkyl, C.sub.3-7 cycloalkyl or optionally substituted phenyl, or R.sup.2 and R.sup.3 may form, together with the N-atom to which they are bonded, an optionally substituted ring; R.sup.4 represents a hydrogen atom or methyl; and n represents 0 or 1; as well as for their preparation processes and novel intermediates in their production. The inventive compounds of formula (I) are used as herbicides.
摘要翻译：式（I）的新型1-取代的甲基四唑啉酮，其中R 1表示具有1至3个杂原子的5元杂环基，其任选地由N，O和S组成的组中选择，并且其任选被卤素和/或C1- 或烷基，或表示环氧乙烷-2-基，任选氯取代的吡啶基或C 1-4烷基-S（O）m - ，其中m表示0,1或2，或表示C 3-6脂环族烃基; R 2和R 3彼此独立地表示C 1-4烷基，C 3-7环烷基或任选取代的苯基，或者R 2和R 3可以与它们所键合的N-原子一起形成任选取代的环; R4表示氢原子或甲基; n表示0或1; 以及它们的制备过程和新型中间体的生产。本发明式（I）化合物用作除草剂。

5. 发明授权

US5605920A Tetrazolinones 失效
标题翻译：四唑啉酮
公开(公告)号：US5605920A
公开(公告)日：1997-02-25
申请号：US618954
申请日：1996-03-20
申请人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
发明人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
IPC分类号： C07D401/06 , A01N47/38 , C07D257/04 , C07D401/12 , C07D403/06 , C07D403/12 , A01N43/713 , A61K31/41
CPC分类号： C07D257/04 , A01N47/38 , C07D401/12 , C07D403/12
摘要： Disclosed are herbicidal tetrazolinone derivatives, selective in paddy fields of the formula ##STR1## wherein X represents C.sub.1-4 alkyl,n represents 1, 2, 3 or 4,R.sup.1 and R.sup.2 each independently represents C.sub.1-6 alkyl, C.sub.2-4 alkenyl, C.sub.2-6 alkynyl, C.sub.3-8 cycloalkyl, aryl which may optionally be substituted (wherein the substituent is at least one radical selected from the group consisting of halogen, C.sub.1-4 alkyl, C.sub.1-2 haloalkyl, C.sub.1-2 haloalkoxy, C.sub.1-2 haloalkylthio, acyl, nitro and cyano) or aralkyl optionally substituted by halogen orR.sup.1 and R.sup.2 form, together with the N-atom to which they are bonded, a cyclic ring which may be substituted. Also, disclosed are novel intermediates useful in the preparation of the compounds of formula (I).
摘要翻译：公开了除草性四唑啉酮衍生物，其在式（I）的水田中是选择性的，其中X表示C1-4烷基，n表示1,2,3或4，R1和R2各自独立地表示C1-6烷基，C2- 4链烯基，C 2-6炔基，C 3-8环烷基，可任选取代的芳基（其中取代基是至少一个选自卤素，C 1-4烷基，C 1-2卤代烷基，C 1-2卤代烷氧基，C 1-2卤代烷硫基，酰基，硝基和氰基）或任选被卤素或R 1和R 2形式取代的芳烷基与它们所键合的N-原子一起可以被取代的环状基团。还公开了可用于制备式（I）化合物的新型中间体。

6. 发明授权

US5654257A 1-cycloalkenyltetrazolinones 失效
标题翻译： 1-环烯基四唑啉酮
公开(公告)号：US5654257A
公开(公告)日：1997-08-05
申请号：US601748
申请日：1996-02-15
申请人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
发明人： Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
IPC分类号： C07D401/06 , A01N47/38 , C07D257/04 , C07D403/06 , A01N43/713
CPC分类号： C07D257/04 , A01N47/38
摘要： 1-cycloalkenyltetrazolinone derivatives of the following herbicidal formula ##STR1## R.sup.1 is cycloalkenyl which may optionally be substituted by halogen C.sub.1-4 alkyl, or bicycloalkenyl which may optionally be substituted by halogen or C.sub.1-4 alkyl, andR.sup.2 and R.sup.3 each independently is alkyl, cycloalkyl, phenyl (optionally substituted by a member selected from the group consisting of nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy and alkylthio), alkenyl and alkynyl,orR.sup.2 and R.sup.3 together with the N-atom to which they are bonded form, a 5- or 6-membered heterocyclic ring which may optionally contain a further hetero atom, said heterocyclic ring optionally being benzo-condensed, or a C-.sub.1-4 alkyl,and intermediates therefore of the formula ##STR2##
摘要翻译：以下除草式R 1的1-环烯基四唑啉酮衍生物是可任选被卤素C 1-4烷基取代的环烯基，或可任意被卤素或C 1-4烷基取代的双环烯基，R 2和R 3各自独立地为烷基，环烷基，苯基（任选被选自硝基，氰基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基和烷硫基的成员取代），烯基和炔基，或者R 2和R 3与它们的N-原子一起键合形式，可任选地含有另外的杂原子的所述5或6元杂环，所述杂环任选地被苯并稠合，或C 1-4烷基，因此具有下式的中间体：

7. 发明授权

US5710278A Herbicidal 1-pyridyltetrazolinones 失效
标题翻译：除草剂1-吡啶基四唑啉酮
公开(公告)号：US5710278A
公开(公告)日：1998-01-20
申请号：US802152
申请日：1997-02-19
申请人： Toshio Goto , Koichi Moriya , Fritz Maurer , Seishi Ito , Katsuaki Wada , Kazuhiro Ukawa , Ryo Watanabe , Asami Ito
发明人： Toshio Goto , Koichi Moriya , Fritz Maurer , Seishi Ito , Katsuaki Wada , Kazuhiro Ukawa , Ryo Watanabe , Asami Ito
IPC分类号： A01N47/38 , C07D401/04 , C07D401/14
CPC分类号： C07D401/04 , A01N47/38
摘要： Herbicidal tetrazolinone derivatives of the formula: ##STR1## in which R.sup.1 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, and R.sup.2 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, or R.sup.1 and R.sup.2 together with the nitrogen atom to which they are bonded form an optionally benzofused heterocyclic ring, which is optionally substituted by C.sub.1-4 alkyl, n is 0, 1, 2 or 3, and R.sup.3 each independently is nitro, halogen, alkyl, haloalkyl, alkylthio or phenoxy.
摘要翻译：式中：R 1为烷基，卤代烷基，环烷基，烯基，卤代烯基，炔基或苯基，R 2为烷基，卤代烷基，环烷基，链烯基，卤代烯基，炔基或苯基，或R 1和R 2一起形成的除草四氢唑酮衍生物与其键合的氮原子形成任选的苯并稠合的杂环，其任选被C 1-4烷基取代，n是0,1,2或3，并且R 3各自独立地是硝基，卤素，烷基，卤代烷基，烷硫基或苯氧基。

8. 发明授权

US5641727A Herbicidal 1-pyridyltetrazolinones 失效
标题翻译：除草剂1-吡啶基四唑啉酮
公开(公告)号：US5641727A
公开(公告)日：1997-06-24
申请号：US498736
申请日：1995-07-06
申请人： Toshio Goto , Koichi Moriya , Fritz Maurer , Seishi Ito , Katsuaki Wada , Kazuhiro Ukawa , Ryo Watanabe , Asami Ito
发明人： Toshio Goto , Koichi Moriya , Fritz Maurer , Seishi Ito , Katsuaki Wada , Kazuhiro Ukawa , Ryo Watanabe , Asami Ito
IPC分类号： A01N47/38 , C07D401/04 , C07D401/14 , A01N43/40
CPC分类号： C07D401/04 , A01N47/38
摘要： Herbicidal tetrazolinone derivatives of the formula: ##STR1## in which R.sup.1 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, andR.sup.2 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, orR.sup.1 and R.sup.2 together with the nitrogen atom to which they are bonded form an optionally benzofused heterocyclic ring, which is optionally substituted by C.sub.1-4 alkyl,n is 0, 1, 2 or 3, andR.sup.3 each independently is nitro, halogen, alkyl, haloalkyl, alkylthio or phenoxy.
摘要翻译：式中：R 1为烷基，卤代烷基，环烷基，烯基，卤代烯基，炔基或苯基，R 2为烷基，卤代烷基，环烷基，链烯基，卤代烯基，炔基或苯基，或R 1和R 2一起形成的除草四氢唑酮衍生物与其键合的氮原子形成任选的苯并稠合的杂环，其任选被C 1-4烷基取代，n是0,1,2或3，并且R 3各自独立地是硝基，卤素，烷基，卤代烷基，烷硫基或苯氧基。

9. 发明授权

US5589439A Tetrazolinone derivatives 失效
标题翻译：四唑啉酮衍生物
公开(公告)号：US5589439A
公开(公告)日：1996-12-31
申请号：US508776
申请日：1995-07-28
申请人： Toshio Goto , Koichi Moriya , Fritz Maurer , Seishi Ito , Katsuaki Wada , Kazuhiro Ukawa , Ryo Watanabe , Asami Ito , Natsuko Minegishi
发明人： Toshio Goto , Koichi Moriya , Fritz Maurer , Seishi Ito , Katsuaki Wada , Kazuhiro Ukawa , Ryo Watanabe , Asami Ito , Natsuko Minegishi
IPC分类号： A01N47/38 , C07D401/14 , C07D403/04 , C07D403/14 , C07D405/04 , C07D409/04 , C07D413/04 , C07D417/04 , A01N43/82 , A01N43/713 , A01N43/824 , A01N43/828 , A01N43/832 , A01N43/836 , C07D407/04
CPC分类号： C07D401/14 , A01N47/38 , C07D403/04 , C07D403/14 , C07D405/04 , C07D409/04 , C07D413/04 , C07D417/04
摘要： Herbicidal novel tetrazolinone derivatives of the formula: ##STR1## wherein R.sup.1 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl, alkoxy or phenyl which is optionally substituted, andR.sup.2 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl, alkoxy or phenyl which is optionally substituted, orR.sup.1 and R.sup.2 form, together with the nitrogen atom to which R.sup.1 and R.sup.2 are bonded, a 5- or 6-membered heterocyclic ring, optionally fused to a carbocyclic ring optionally and independently substituted by C.sub.1-4 alkyl, andR.sup.3 is a 5-membered heterocyclic radical containing at least one hereto atom selected from the group consisting of nitrogen, oxygen, and sulfur, optionally substituted by at least one substitutent selected from the group consisting of halogen, benzyl, phenyl, halogen-substituted phenyl, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 haloalkyl, C.sub.1-4 haloalkoxy, C.sub.1-4 alkylthio, C.sub.1-4 alkyl-sulfonyl and C.sub.3-8 cycloalkyl, processes for their preparation and novel intermediates therefor.
摘要翻译：除草新型四唑啉酮衍生物，其分子式如下：其中R1是烷基，卤代烷基，环烷基，烯基，卤代烯基，炔基，烷氧基或任选取代的苯基，R 2是烷基，卤代烷基，环烷基，烯基，卤代烯基，炔基，烷氧基或任选被取代的苯基，或R 1和R 2与R 1和R 2键合的氮原子一起形成5-或6-元杂环，任选地与任选和独立地被 C 1-4烷基，R 3是含有至少一个选自氮，氧和硫的至少一个选自氮，氧和硫的5元杂环基团，任选被至少一个选自卤素，苄基，苯基，卤素取代的苯基，C 1-4烷基，C 1-4烷氧基，C 1-4卤代烷基，C 1-4卤代烷氧基，C 1-4烷硫基，C 1-4烷基磺酰基和C 3-8环烷基，其制备方法和新型中间体那里 r。

10. 发明授权

US5641725A Sulphonylaminophenyluracil herbicides for paddy field 失效
标题翻译：用于稻田的磺酰基氨基苯基尿嘧啶除草剂
公开(公告)号：US5641725A
公开(公告)日：1997-06-24
申请号：US562923
申请日：1995-11-27
申请人： Toshio Goto , Seishi Ito , Chieko Ueno , Tatsuya Yamaoka , Kazuhiro Ukawa , Natsuko Minegishi
发明人： Toshio Goto , Seishi Ito , Chieko Ueno , Tatsuya Yamaoka , Kazuhiro Ukawa , Natsuko Minegishi
IPC分类号： A01N43/54
CPC分类号： A01N43/54
摘要： A herbicide for paddy field comprising sulphonylaminophenyluracil derivative as an active ingredient which is represented by the formula (I): ##STR1## wherein R.sup.1 represents hydrogen or methyl,R.sup.2 represents C.sub.1-5 alkyl, fluro-substituted C.sub.1-2 alkyl or C.sup.3-6 cycloalkyl,optionally applied in combination with another herbicide.
摘要翻译：一种稻田除草剂，其包含由式（I）表示的磺酰氨基苯基尿嘧啶衍生物作为活性成分：其中R1表示氢或甲基，R2表示C1-5烷基，氟取代的C1-2烷基或C3- 6环烷基，任选地与另一种除草剂组合施用。

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