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1. 发明授权

US4668397A Novel cyclic octapeptide, method for production of said octapeptide, and ion extracting/separating agent using said octapeptide as principal component 失效
标题翻译：新的环状八肽，所述八肽的制造方法以及使用所述八肽作为主成分的离子提取分离剂
公开(公告)号：US4668397A
公开(公告)日：1987-05-26
申请号：US767846
申请日：1985-08-21
申请人： Toshimi Shimizu , Yoshio Tanaka
发明人： Toshimi Shimizu , Yoshio Tanaka
IPC分类号： B01D11/04 , B01J20/281 , C07K1/02 , C07K5/12 , C07K7/64 , C09K3/00 , C22B3/26 , C22B26/00 , G01N30/88 , B01D11/00
CPC分类号： C22B26/00 , C07K5/126 , C22B3/0005 , Y02P10/234 , Y10S930/27
摘要： Cyclic octapeptide represented by the general formula: ##STR1## (wherein A denotes an iminoalkylene group of 3 or 4 carbon atoms or an alkylene group of 1 or 2 carbon atoms) are novel substances. They are produced by cyclo-dimerizing specific tetrapeptide esters. They are possessed of excellent properties as an agent for the extraction of ions, particularly alkaline earth metal ions.
摘要翻译：由以下通式表示的环状八肽：其中A表示3或4个碳原子的亚氨基亚烷基或1或2个碳原子的亚烷基，是新物质。它们通过环二聚特异性四肽酯产生。它们具有优异的性能，作为提取离子，特别是碱土金属离子的试剂。

2. 发明授权

US08652269B2 Flux composition and soldering paste composition 有权
标题翻译：助焊剂组成和焊膏组成
公开(公告)号：US08652269B2
公开(公告)日：2014-02-18
申请号：US13121734
申请日：2009-09-25
申请人： Tetsuro Nishimura , Mitsuhiro Kawahara , Masuml Asakawa , Toshimi Shimizu
发明人： Tetsuro Nishimura , Mitsuhiro Kawahara , Masuml Asakawa , Toshimi Shimizu
IPC分类号： B23K35/36 , B23K35/363
CPC分类号： C22C13/00 , B23K35/262 , B23K35/3613 , B23K35/362 , H05K3/3484 , H05K3/3489
摘要： Disclosed herein are a flux and a soldering paste based on the flux. The flux is free from a change in viscosity with age, “skinned surface,” and “rough and crumbling,” and is excellent in printability and solderability. The flux contains, as elements, a resin, a thixo agent, an activator, a solvent and glucopyranosylamine type nanotube. The soldering paste further contains a solder powder. Preferably, the solder powder is free from lead.
摘要翻译：本文公开了基于助焊剂的焊剂和焊膏。助焊剂随着年龄，“皮肤表面”和“粗糙和破碎”而没有粘度变化，并且具有优异的可印刷性和可焊性。助熔剂含有树脂，触变剂，活化剂，溶剂和吡喃葡萄糖胺型纳米管。焊膏还含有焊料粉末。优选地，焊料粉末不含铅。

3. 发明授权

US08551916B2 Method for preparation of aqueous emulsion using interfacially active organic compound as emulsifying agent 失效
标题翻译：使用界面活性有机化合物作为乳化剂制备水性乳液的方法
公开(公告)号：US08551916B2
公开(公告)日：2013-10-08
申请号：US12918943
申请日：2009-02-25
申请人： Masumi Asakawa , Masaki Kogiso , Toshimi Shimizu , Atsushi Kisuno
发明人： Masumi Asakawa , Masaki Kogiso , Toshimi Shimizu , Atsushi Kisuno
IPC分类号： A01N63/00 , A01N37/00 , A01N37/18 , A01N47/10 , A61K38/00 , A61K31/27
CPC分类号： A61K8/062 , A61Q19/00 , G03G9/0804 , G03G9/08755
摘要： The present invention provides a method for obtaining O/W emulsions by emulsifying various to-be-emulsified material without the use of any organic solvent, and drying and making into powder the O/W emulsion. The invention relates to a method for producing an O/W emulsion including after preliminarily dispersing a to-be-emulsified material and an interfacially active organic compound in water, heating the preliminary dispersion to a temperature equal to or higher than the melting point of the to-be-emulsified material and equal to or higher than the phase transition temperature of a self-assembled product of the interfacially active organic compound in the absence of an organic solvent, and performing emulsification under a pressure.
摘要翻译：本发明提供一种通过在不使用任何有机溶剂的情况下乳化各种待乳化材料并干燥并制成O / W乳液粉末来获得O / W乳液的方法。本发明涉及一种生产O / W乳液的方法，其包括将预乳化物和界面活性有机化合物预先分散在水中，将预分散体加热至等于或高于待乳化的材料，并且在不存在有机溶剂的情况下等于或高于界面活性有机化合物的自组装产物的相转变温度，并且在压力下进行乳化。

4. 发明申请

US20060140847A1 Method for introducing functional material into organic nanotube 审中-公开
标题翻译：将功能材料引入有机纳米管的方法
公开(公告)号：US20060140847A1
公开(公告)日：2006-06-29
申请号：US10544800
申请日：2004-02-12
申请人： Bo Yang , Toshimi Shimizu , Shoko Kamiya
发明人： Bo Yang , Toshimi Shimizu , Shoko Kamiya
IPC分类号： D01F9/12
CPC分类号： B82Y30/00 , C01B32/15
摘要： The objective is to easily introduce a desired functional substance into organic nanotubes under milder conditions such as ambient temperature and ambient pressure. The method comprises the steps of allowing a surface active organic compound comprising hydrophobic hydrocarbon groups and hydrophilic groups to self aggregate in liquid phase to form organic nanotubes having an internal cavity size of at least 5 nm (step 1), freeze drying the organic nanotubes (step 2), dissolving or dispersing a desired functional substance in a solvent (step 3) and dispersing said freeze dried organic nanotubes in the solvent or the dispersion at or below the gel-liquid crystal phase transition temperature of said surface active organic compound (step 4). The organic nanotubes formed can be used in a variety of applications depending on the properties of the functional substance.
摘要翻译：目的是在较温和的条件（如环境温度和环境压力）下，容易地将所需的功能物质引入有机纳米管。该方法包括以下步骤：使包含疏水性烃基和亲水基团的表面活性有机化合物在液相中自聚集形成内部空腔尺寸至少为5nm的有机纳米管（步骤1），冷冻干燥有机纳米管步骤2），将期望的功能性物质溶解或分散在溶剂（步骤3）中，并将所述冷冻干燥的有机纳米管分散在所述表面活性有机化合物的凝胶 - 液晶相转变温度以下或低于所述表面活性有机化合物的凝胶 - 液晶相转变温度的步骤 4）。形成的有机纳米管可以根据功能物质的性质而用于各种应用中。

5. 发明申请

US20090211907A1 Separation Medium for Biochemical Analysis 审中-公开
标题翻译：分离培养基用于生物化学分析
公开(公告)号：US20090211907A1
公开(公告)日：2009-08-27
申请号：US11884993
申请日：2006-02-24
申请人： Mitsutoshi Masuda , Kazuko Matsumoto , Rika Iwaura , Yoshinori Yamaguchi , Toshimi Shimizu
发明人： Mitsutoshi Masuda , Kazuko Matsumoto , Rika Iwaura , Yoshinori Yamaguchi , Toshimi Shimizu
IPC分类号： B01D57/02 , G01N27/26
CPC分类号： B01D57/02 , C07K1/26 , C07K1/28 , G01N27/44747
摘要： The invention provides a novel packing composition for separation and/or analysis which permits easy capillary replacement; a process for the production of the packing composition; a method for filling a capillary with the packing composition; and electrophoretic methods (such as capillary electrophoresis) with the same. The invention relates to a packing composition for electrophoretic separation and/or analysis which contains a long self-assembly produced by dissolving a low-molecular-weight amphiphilic compound having a hydrophobic moiety and a hydrophilic moiety in water under heating and then cooling the resulting solution; a process for the production of the packing composition; a method of separation and/or analysis with the composition; and so on.
摘要翻译：本发明提供了用于分离和/或分析的新型包装组合物，其允许容易的毛细管置换; 一种生产包装组合物的方法; 用填充组合物填充毛细管的方法; 和电泳方法（如毛细管电泳）相同。本发明涉及一种用于电泳分离和/或分析的包装组合物，其包含通过在加热下将具有疏水部分和亲水部分的低分子量两亲性化合物溶解在水中，然后冷却所得溶液而产生的长自组装 ; 一种生产包装组合物的方法; 用该组合物分离和/或分析的方法; 等等。

6. 发明授权

US07196178B2 Sugar-derived gellant for hydrogel formation 失效
标题翻译：用于水凝胶形成的糖衍生胶凝剂
公开(公告)号：US07196178B2
公开(公告)日：2007-03-27
申请号：US10415729
申请日：2002-03-15
申请人： Jong Hwa Jung , George John , Toshimi Shimizu
发明人： Jong Hwa Jung , George John , Toshimi Shimizu
IPC分类号： C07H17/00 , C07H1/00 , C07H1/06
CPC分类号： C07H15/203 , C09K3/00 , C40B40/00
摘要： A gelatinizer having gel-forming capability in both organic solvents and water, is provided. The hydrogelatinizer is represented by: (where, A is a sugar residue, and R is an alkyl group).
摘要翻译：提供了在有机溶剂和水中都具有凝胶形成能力的胶凝剂。表示水凝胶化剂

7. 发明授权

US06897326B2 Asymmetrical bicipital lipid and tubular aggregate formed by using the same 失效
标题翻译：通过使用相同的形式形成不对称的脂质和管状聚集体
公开(公告)号：US06897326B2
公开(公告)日：2005-05-24
申请号：US10475700
申请日：2002-02-01
申请人： Mitsutoshi Masuda , Toshimi Shimizu
发明人： Mitsutoshi Masuda , Toshimi Shimizu
IPC分类号： C07H5/04 , C07H13/06 , C07C231/00
CPC分类号： C07H5/04
摘要： The present invention is a stable, nanometer scale micro-tubular aggregated material of an asymmetric double-headed lipid represented by the general formula R—NHCO—(CH2)n—COOH (I) (in the formula, R represents an aldopyranose radical from which the terminal reducing hydroxyl group is excluded and n is from six to twenty). The external diameter of the micro-tubular aggregated material is 10-300 nm, and the length is 0.3-10 μm. The micro-tubular aggregated material can be manufactured by dispersing the asymmetric double-headed lipid described above in water at pH of two to eight, next heating to 80-100° C. to dissolve it and then gradually cooling the aqueous solution obtained.
摘要翻译：本发明是由通式<？in-line-formula description =“In-Line Formulas”end =“lead”→> R-（式2）所示的不对称双头脂质的稳定的纳米级微管聚集物， NHCO-（CH 2 CH 2）n -COOH（I）<βin-line-formula description =“In-line Formulas”end =“tail”？>（in 式中，R表示不具有末端还原羟基的醛吡喃基，n为6〜20）。微管聚集材料的外径为10-300nm，长度为0.3-10μm。微管状聚集体可以通过将上述不对称双头脂质分散在pH为2〜8的水中，接着加热至80-100℃，使其溶解，然后逐渐冷却所得水溶液。

8. 发明申请

US20070292338A1 Transition Metal Oxide Nano-Tube 审中-公开
标题翻译：过渡金属氧化物纳米管
公开(公告)号：US20070292338A1
公开(公告)日：2007-12-20
申请号：US11667880
申请日：2005-09-12
申请人： Masaki Kogiso , Toshimi Shimizu
发明人： Masaki Kogiso , Toshimi Shimizu
IPC分类号： C01G3/02 , B82B1/00 , C01B13/32 , C01G45/02 , C01G1/02
CPC分类号： C01G1/00 , B82Y30/00 , C01B13/32 , C01G1/02 , C01P2004/13 , C01P2004/60
摘要： To provide nano-tubes consisting of transition metal oxide and a production method thereof. The nano-tubes consisting of a transition metal oxide with an average diameter of about 10 to 1,000 nm and an average length of about 1 to 100 μm can be obtained by coexisting a peptide lipid represented by the general formula RCO(NHCH2CO)mOH, wherein R represents a hydrocarbon group with six to eighteen carbon atoms and m represents an integer one to three, and a transition metal ion in water and sintering at 300 to 600° C. the fibrous substance formed.
摘要翻译：提供由过渡金属氧化物组成的纳米管及其制造方法。由平均直径约10〜1000nm，平均长度约1〜100μm的过渡金属氧化物组成的纳米管可以通过共存由通式RCO（NHCH 2） CO）m OH，其中R表示具有6至18个碳原子且m表示1至3的整数的烃基和在水中的过渡金属离子并在300至600℃下烧结 ℃形成纤维状物质。

9. 发明授权

US07172747B2 Metal oxide nanotube and process for production thereof 有权
标题翻译：金属氧化物纳米管及其制造方法
公开(公告)号：US07172747B2
公开(公告)日：2007-02-06
申请号：US10502562
申请日：2003-03-26
申请人： Toshimi Shimizu , John Hwa Jung
发明人： Toshimi Shimizu , John Hwa Jung
IPC分类号： C01B33/113 , C01G1/00 , C01G23/00 , C01G25/00
CPC分类号： B82Y30/00 , B01J20/06 , B01J20/28007 , B01J20/28023 , B01J20/28092 , B01J20/30 , C01B3/001 , C01B13/14 , C01B13/32 , C01B33/12 , C01G1/02 , C01G23/047 , C01G25/02 , C01P2004/04 , C01P2004/13 , C01P2006/12 , C01P2006/17 , C01P2006/80 , Y02E60/327 , Y02E60/328 , Y10S977/811 , Y10S977/963
摘要： Spiral shaped fibers were utilized to prepare completely novel metal oxide nanotubes comprising solely metal oxides. The metal oxide nanotubes comprise solely a hollow cylinder shaped metal oxide which may contain hydroxyl groups constituting a double helix and having hole diameter distributions containing two peak hole diameters ranging from 1 to 2 nm and from 3 to 7 nm. The tubes may be obtained by forming spiral shaped fibers from a solution of compound 1 and compound 2 and using the fibers as a template for making the nanotubes. The hydrogen adsorption and storage capacity of the metal oxide nanotubes are extremely good.
摘要翻译：使用螺旋形纤维来制备完全新型金属氧化物纳米管，其仅包含金属氧化物。金属氧化物纳米管仅包含中空圆柱形金属氧化物，其可以含有构成双螺旋的羟基并且具有包含2至2nm和3至7nm的2个峰值孔径的孔直径分布。可以通过从化合物1和化合物2的溶液中形成螺旋形纤维并使用纤维作为制备纳米管的模板来获得管。金属氧化物纳米管的氢吸附和储存能力非常好。

10. 发明申请

US20060160248A1 N-glycoside type glycolipids and hollow fiber type organic nanotubes made of the same 失效
标题翻译： N-糖苷型糖脂和由其制成的中空纤维型有机纳米管
公开(公告)号：US20060160248A1
公开(公告)日：2006-07-20
申请号：US10543865
申请日：2003-12-25
申请人： Shoko Kamiya , Toshimi Shimizu , Jong Jung
发明人： Shoko Kamiya , Toshimi Shimizu , Jong Jung
IPC分类号： H01L21/00 , C08B37/00
CPC分类号： C07H13/06 , B82Y10/00 , B82Y30/00 , C07H5/06 , C07K9/001 , Y10S977/706 , Y10S977/742
摘要： Presents novel hollow fiber shaped organic nanotubes that can be easily produced in a short time span and also have a broad range of utility. An N-glycoside type glycolipid represented by the general formula (1) shown below. G-NHCO—R (1)(In the formula, G represents a saccharide radical other than a hemiacetal hydroxyl group bonded to the anomer carbon atom of the saccharide, and R represents an unsaturated hydrocarbon group containing ten to 39 carbon atoms.) This molecule self-aggregates and forms hollow fiber shaped organic nanotubes in water when this N-glycoside type glycolipid is dissolved, allowed to cool gradually and allowed to stand undisturbed at room temperature. The average external diameter of the nanotubes is from 70 nm to 500 nm and the average internal diameter (average diameter of the cavity) is from 40 nm to 300 nm.
摘要翻译：呈现新颖的中空纤维状有机纳米管，可以在短时间内容易地生产，也具有广泛的应用。由下述通式（1）表示的N-糖苷型糖脂。 <？in-line-formula description =“In-line Formulas”end =“lead”？> G-NHCO-R（1）<？in-line-formula description =“In-line Formulas”end =“tail” （式中，G表示除了与糖的端基碳原子键合的半缩醛羟基以外的糖基，R表示含有10〜39个碳原子的不饱和烃基。）该分子自聚集形成当N-糖苷型糖脂溶解时，将水中的中空纤维状有机纳米管置于水中，使其逐渐冷却，并在室温下静置。纳米管的平均外径为70nm〜500nm，平均内径（空腔的平均直径）为40nm〜300nm。

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