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    • 6. 发明申请
    • Black ink for inkjet recording and inkjet recording method
    • 黑色墨水用于喷墨记录和喷墨记录方法
    • US20060044375A1
    • 2006-03-02
    • US10528772
    • 2003-07-01
    • Toshiki TaguchiTakashi OzawaToshiaki AonoYoshiharu YabukiTomohiro Chino
    • Toshiki TaguchiTakashi OzawaToshiaki AonoYoshiharu YabukiTomohiro Chino
    • G01D11/00
    • C09D11/328
    • An object of the present invention is to provide an inkjet recording ink ensuring excellent discharge stability even after aging of the ink and also exhibiting excellent weather resistance. This object of the present invention can be attained by a black ink for inkjet recording, comprising an aqueous medium containing a dye in which λmax of the absorption spectrum in an aqueous solution is in the region from 500 and 700 nm and the standardized half-value width thereof is 100 nm or more. The aqueous ink of the present invention is more enhanced in the discharge stability and weather resistance when the dye contained in the ink, particularly, the dye having the above-described spectral characteristics, is a dye having an oxidation potential of 1.0 V vs SCE or more, 2) a dye having a discoloration rate constant of 5.0×10−2 Hr−1 or less, 3) a dye where the maximum value/minimum value ratio of discoloration rate constants of three colors is 1.2 or less, 4) a dye represented by formula (1), 4) a dye containing a compound of formula (A), 5) a dye containing a high boiling point water-miscible organic solvent, 6) particularly a dye containing 20 mass % or more of a water-miscible organic solvent having a boiling point of 100° C. or more and 2 mass % or less of a compound of formula (A), and 7) a dye containing a high boiling point water-miscible solvent and a low boiling point water-miscible solvent. The inkjet recording ink of the present invention is an ink capable of ensuring pictorial quality with no loosening in the gradation of neutral gray even by visual evaluation.
    • 本发明的目的是提供即使在油墨老化之后也确保优异的喷射稳定性并且还具有优异的耐候性的喷墨记录油墨。 本发明的目的可以通过一种用于喷墨记录的黑色油墨来实现,该黑色油墨包括含有一种染料的水性介质,其中在水溶液中的吸收光谱的lambdamax在500和700nm的范围内,标准化的半值 其宽度为100nm以上。 当包含在油墨中的染料,特别是具有上述光谱特性的染料是具有1.0V的氧化电位的染料与SCE相比时,本发明的水性油墨的放电稳定性和耐候性更强, 更多,2)染色速率常数为5.0×10 -2 H -1以下的染料,3)染料,其中最大值/最小值比值变色 三种颜色的速率常数为1.2以下,4)由式(1)表示的染料,4)含有式(A)化合物的染料,5)含有高沸点水混溶性有机溶剂的染料6 )特别是含有20质量%以上的沸点为100℃以上且2质量%以下的水溶性有机溶剂的式(A)化合物的染料,以及7)含有 高沸点水溶性溶剂和低沸点水溶性溶剂。 本发明的喷墨记录油墨是即使通过目视评价也能够确保中性灰色的灰度等级而不会松动的画质。
    • 9. 发明授权
    • Black ink and ink set for inkjet recording
    • 黑色油墨和墨水设置用于喷墨记录
    • US07491266B2
    • 2009-02-17
    • US10578229
    • 2004-11-04
    • Toshiki TaguchiNaotaka WachiManabu Ogawa
    • Toshiki TaguchiNaotaka WachiManabu Ogawa
    • C09D11/02
    • C09D11/40
    • To provide an inkjet black ink having excellent image durability and ink discharge properties and an ink set, the inkjet black ink, which contains a dye having a λmax of from 500 nm to 700 nm and a half-band width of 100 nm or more in an absorption spectrum of a diluted solution standardized at an absorbance of 1.0 at the λmax, has the change ratio of absorbance at the λmax in the visible region, specified in the specification; and the inkjet ink set containing at least two black inks having different densities has the relationship among the at least two black inks, specified in the specification.
    • 为了提供具有优异的图像耐久性和油墨排出性能的喷墨黑色油墨和油墨组,该喷墨黑色油墨包含具有500nm至700nm的拉姆达姆的染料和100nm以上的半带宽度 在lambdamax的吸光度为1.0时标准化的稀释溶液的吸收光谱具有说明书中规定的可见区域中的lambdamax的吸光度变化率; 并且包含至少两种具有不同密度的黑色油墨的喷墨油墨组在本说明书中指定的至少两种黑色油墨之间具有关系。