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1. 发明申请

US20120009234A1 COSMETICS 审中-公开
标题翻译：化妆品
公开(公告)号：US20120009234A1
公开(公告)日：2012-01-12
申请号：US13181852
申请日：2011-07-13
申请人： Toshiki Origuchi , Yoshitaka Nakayama , Takuma Kurahashi , Katsuhiko Yagi , Yuki Murakami
发明人： Toshiki Origuchi , Yoshitaka Nakayama , Takuma Kurahashi , Katsuhiko Yagi , Yuki Murakami
IPC分类号： A61K8/02 , A61Q19/08 , A61K8/87
CPC分类号： A61Q1/02 , A61K8/0241 , A61K8/044 , A61K8/585 , A61K8/87 , A61K2800/412 , A61K2800/61
摘要： It is provided cosmetics to prevent to come off and keep long. The cosmetic comprises specific polyurethane particles with a cosmetic base. The specific polyurethane particle consists of a body of the polyurethane particle and hydrophilic fine silica powders existing on the body. The body is obtained by three-dimensionally polymerizing an isocyanate-terminated urethane prepolymer with trifunctional or more functional amines. The isocyanate-terminated urethane prepolymer is obtained by reacting polyisocyanates and polyols including a poly(tetramethylene ether)glycol. The polyurethane particles are obtained by spray-drying a mixed aqueous dispersion in which the hydrophilic fine silica powders and the polyurethane spheres are dispersed in water.
摘要翻译：提供化妆品防止脱落并保持长时间。化妆品包括具有化妆品基质的特定聚氨酯颗粒。特定的聚氨酯颗粒由聚氨酯颗粒体和身体上存在的亲水性细二氧化硅粉末组成。通过三官能聚合具有三官能或更多官能胺的异氰酸酯封端的氨基甲酸酯预聚物获得体。异氰酸酯封端的氨基甲酸酯预聚物通过聚异氰酸酯和包括聚（四亚甲基醚）二醇的多元醇反应获得。聚氨酯颗粒通过喷雾干燥其中亲水性细二氧化硅粉末和聚氨酯球体分散在水中的混合水性分散体而获得。

2. 发明授权

US07994250B2 Vinyl-urethane copolymers with intermediary linkage segments having silicon-oxygen bonds and production methods thereof 失效
标题翻译：具有硅氧键的中间连接链段的乙烯基 - 氨基甲酸酯共聚物及其制备方法
公开(公告)号：US07994250B2
公开(公告)日：2011-08-09
申请号：US10581446
申请日：2004-12-02
申请人： Toshiki Origuchi , Shintaro Ogawa , Yoshitaka Nakayama
发明人： Toshiki Origuchi , Shintaro Ogawa , Yoshitaka Nakayama
IPC分类号： C08F283/00 , C09G77/06
CPC分类号： C08F283/00 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/3206 , C08G18/6659 , C08G18/6674 , C08G81/00 , C08G81/024 , C08L33/00 , C08L75/04 , C08G18/289 , C08L2666/04
摘要： To provide vinyl-urethane copolymers that can form cured articles having excellent hot-water resistance, water resistance, heat resistance, and weather resistance, and to provide production methods thereof.A vinyl-urethane copolymer contains at least one vinyl polymer chain and at least one urethane polymer chain, in which the vinyl polymer chain is combined with the urethane polymer chain through a linkage segment having a silicon-oxygen bond.A method produces a vinyl-urethane copolymer comprising at least one vinyl polymer chain and at least one urethane polymer chain, in which the vinyl polymer chain is combined with the urethane polymer chain through a linkage segment having a silicon-oxygen bond, by following Steps (X) and (Y): Step (X) of carrying out preparation of an aqueous dispersion or aqueous solution of a urethane polymer (A) having at least one silicon-containing hydrolyzable group; and Step (Y) of, in the aqueous dispersion or aqueous solution of the urethane polymer (A) having at least one silicon-containing hydrolyzable group, carrying out polymerization of an ethylenically unsaturated monomer (B) and carrying out preparation of a vinyl-urethane copolymer using a compound (C) having at least one functional group reactive with a silicon-containing hydrolyzable group and at least one functional group reactive with an ethylenically unsaturated bond-containing group in at least one period selected from before the polymerization reaction, during the polymerization reaction, and after the polymerization reaction.
摘要翻译：为了提供可以形成具有优异的耐热水性，耐水性，耐热性和耐候性的固化物的乙烯基 - 氨基甲酸酯共聚物，并提供其制备方法。乙烯基 - 氨基甲酸酯共聚物包含至少一个乙烯基聚合物链和至少一个聚氨酯聚合物链，其中乙烯基聚合物链通过具有硅 - 氧键的连接链与氨基甲酸酯聚合物链结合。一种方法产生乙烯基 - 氨基甲酸酯共聚物，其包含至少一种乙烯基聚合物链和至少一个氨基甲酸酯聚合物链，其中乙烯基聚合物链通过具有硅 - 氧键的连接链与氨基甲酸酯聚合物链结合，通过以下步骤（X）和（Y）：具有至少一个含硅水解性基团的氨基甲酸酯聚合物（A）的水性分散体或水溶液的制备工序（X）和具有至少一个含硅水解性基团的氨基甲酸酯聚合物（A）的水性分散体或水溶液中进行乙烯性不饱和单体（B）的聚合，进行乙烯基类不饱和单体的制备的工序（Y）使用具有至少一个与含硅可水解基团反应的官能团的化合物（C）的聚氨酯共聚物和至少一种在与聚合反应之前的至少一个时期内与烯属不饱和键基团反应的官能团，在聚合反应，聚合反应后。

3. 发明申请

US20090326151A1 HAIR COSMETIC 审中-公开
标题翻译：头发化妆品
公开(公告)号：US20090326151A1
公开(公告)日：2009-12-31
申请号：US12306887
申请日：2007-06-29
申请人： Hideki Shimizu , Tomoko Watanabe , Tomoyuki Kawasoe , Taizo Fujiyama , Toshiki Origuchi , Shintaro Ogawa , Yoshitaka Nakayama
发明人： Hideki Shimizu , Tomoko Watanabe , Tomoyuki Kawasoe , Taizo Fujiyama , Toshiki Origuchi , Shintaro Ogawa , Yoshitaka Nakayama
IPC分类号： C08F8/30
CPC分类号： A61Q5/06 , A61K8/87 , A61K8/898 , A61K8/899 , C08G18/0823 , C08G18/12 , C08G18/6625 , C08G18/3893
摘要： Provided is a hair cosmetic that can exhibit hair styling capability, natural finishing capability, and hair style retentivity respectively at superior levels.The hair cosmetic contains a urethane-modified acrylic polymer having a structure in which a urethane polymer chain is bonded to an acrylic polymer chain through a linkage segment having a silicon-oxygen bond, in which the acrylic polymer chain is a residue of an acrylic polymer derived at least from an acrylic monomer (A) and a compound (B1) and/or a compound (B2), where the compound (B1) has a hydrolyzable silicon-containing group and an ethylenically unsaturated bond-containing group, and the compound (B2) has a hydrolyzable silicon-containing group and a mercapto group, and the urethane polymer chain is a residue of a urethane polymer (C) having a hydrolyzable silicon-containing group. The linkage segment in the urethane-modified acrylic polymer is preferably a silicone polymer chain.
摘要翻译：本发明提供一种能够分别具有发型能力，自然整理能力和发型保持性的头发化妆品。毛发化妆品含有氨基甲酸酯改性的丙烯酸类聚合物，其具有通过具有硅 - 氧键的连接链段将氨基甲酸酯聚合物链与丙烯酸聚合物链结合的结构，其中丙烯酸类聚合物链是丙烯酸聚合物的残基至少从丙烯酸类单体（A）和化合物（B1）和/或化合物（B2）得到的化合物（B1），其中化合物（B1）具有可水解的含硅基团和含烯属不饱和键的基团，化合物（B2）具有可水解的含硅基团和巯基，氨基甲酸酯聚合物链是具有可水解的含硅基团的氨基甲酸酯聚合物（C）的残基。氨基甲酸酯改性丙烯酸类聚合物中的连接段优选为有机硅聚合物链。

4. 发明申请

US20070117902A1 Vinyl-urethane copolymers and production methods thereof 失效
标题翻译：乙烯基 - 氨基甲酸酯共聚物及其制备方法
公开(公告)号：US20070117902A1
公开(公告)日：2007-05-24
申请号：US10581446
申请日：2004-12-02
申请人： Toshiki Origuchi , Shintaro Ogawa , Yoshitaka Nakayama
发明人： Toshiki Origuchi , Shintaro Ogawa , Yoshitaka Nakayama
IPC分类号： C08F283/00 , C08G77/06
CPC分类号： C08F283/00 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/3206 , C08G18/6659 , C08G18/6674 , C08G81/00 , C08G81/024 , C08L33/00 , C08L75/04 , C08G18/289 , C08L2666/04
摘要： To provide vinyl-urethane copolymers that can form cured articles having excellent hot-water resistance, water resistance, heat resistance, and weather resistance, and to provide production methods thereof. A vinyl-urethane copolymer contains at least one vinyl polymer chain and at least one urethane polymer chain, in which the vinyl polymer chain is combined with the urethane polymer chain through a linkage segment having a silicon-oxygen bond. A method produces a vinyl-urethane copolymer comprising at least one vinyl polymer chain and at least one urethane polymer chain, in which the vinyl polymer chain is combined with the urethane polymer chain through a linkage segment having a silicon-oxygen bond, by following Steps (X) and (Y): Step (X) of carrying out preparation of an aqueous dispersion or aqueous solution of a urethane polymer (A) having at least one silicon-containing hydrolyzable group; and Step (Y) of, in the aqueous dispersion or aqueous solution of the urethane polymer (A) having at least one silicon-containing hydrolyzable group, carrying out polymerization of an ethylenically unsaturated monomer (B) and carrying out preparation of a vinyl-urethane copolymer using a compound (C) having at least one functional group reactive with a silicon-containing hydrolyzable group and at least one functional group reactive with an ethylenically unsaturated bond-containing group in at least one period selected from before the polymerization reaction, during the polymerization reaction, and after the polymerization reaction.
摘要翻译：为了提供可以形成具有优异的耐热水性，耐水性，耐热性和耐候性的固化物的乙烯基 - 氨基甲酸酯共聚物，并提供其制备方法。乙烯基 - 氨基甲酸酯共聚物包含至少一个乙烯基聚合物链和至少一个聚氨酯聚合物链，其中乙烯基聚合物链通过具有硅 - 氧键的连接链与氨基甲酸酯聚合物链结合。一种方法产生乙烯基 - 氨基甲酸酯共聚物，其包含至少一种乙烯基聚合物链和至少一个氨基甲酸酯聚合物链，其中乙烯基聚合物链通过具有硅 - 氧键的连接链与氨基甲酸酯聚合物链结合，通过以下步骤（X）和（Y）：具有至少一个含硅水解性基团的氨基甲酸酯聚合物（A）的水性分散体或水溶液的制备工序（X）和具有至少一个含硅水解性基团的氨基甲酸酯聚合物（A）的水性分散体或水溶液中进行乙烯性不饱和单体（B）的聚合，进行乙烯基类不饱和单体的制备的工序（Y）使用具有至少一个与含硅可水解基团反应的官能团的化合物（C）和至少一种与含烯属不饱和键的基团反应的官能团的聚氨酯共聚物在至少一个选自聚合反应之前的期间内，在聚合反应，聚合反应后。

5. 发明申请

US20110262514A1 POLYURETHANE PARTICLE AND METHOD FOR PRODUCING POLYURETHANE PARTICLES 审中-公开
标题翻译：聚氨酯颗粒和生产聚氨酯颗粒的方法
公开(公告)号：US20110262514A1
公开(公告)日：2011-10-27
申请号：US13152659
申请日：2011-06-03
申请人： Toshiki Origuchi , Yoshitaka Nakayama
发明人： Toshiki Origuchi , Yoshitaka Nakayama
IPC分类号： B01J20/26 , B01J20/32 , B05D7/02 , A01P17/00 , A01P19/00 , A61K8/87 , B01J20/28 , A01N25/26
CPC分类号： B05D1/12 , A61K8/11 , A61K8/25 , A61K8/87 , A61K2800/412 , A61Q19/00 , B01J20/103 , B01J20/262 , B01J20/28026 , B01J20/3212 , B01J20/3234 , B01J20/3295 , C08G18/0866 , C08G18/10 , C08G18/4854 , C08G18/755 , C08J3/12 , C08J2375/04 , C08G18/3228
摘要： It is provided smooth polyurethane particles for oil absorption under producing, treating, keeping and transporting. A polyurethane particle consists of a body of the polyurethane particle and hydrophilic fine silica powders existing on the body. The body is obtained by three-dimensionally polymerizing an isocyanate-terminated urethane prepolymer with trifunctional or more functional amines. The isocyanate-terminated urethane prepolymer is obtained by reacting polyisocyanates and polyols including a poly(tetramethylene ether)glycol. The polyurethane particles are obtained by spray-drying a mixed aqueous dispersion in which the hydrophilic fine silica powders and the polyurethane spheres are dispersed in water.
摘要翻译：在生产，处理，保存和运输中提供用于吸油的光滑聚氨酯颗粒。聚氨酯颗粒由聚氨酯颗粒体和身体上存在的亲水性细二氧化硅粉末组成。通过三官能聚合具有三官能或更多官能胺的异氰酸酯封端的氨基甲酸酯预聚物获得体。异氰酸酯封端的氨基甲酸酯预聚物通过聚异氰酸酯和包括聚（四亚甲基醚）二醇的多元醇反应获得。聚氨酯颗粒通过喷雾干燥其中亲水性细二氧化硅粉末和聚氨酯球体分散在水中的混合水性分散体而获得。

6. 发明授权

US06495628B1 Process for producing vinyl acetate resin emulsion and water-based adhesive 失效
标题翻译：生产乙酸乙烯酯树脂乳液和水性粘合剂的方法
公开(公告)号：US06495628B1
公开(公告)日：2002-12-17
申请号：US09647591
申请日：2000-10-03
申请人： Toshiki Origuchi , Shintaro Ogawa
发明人： Toshiki Origuchi , Shintaro Ogawa
IPC分类号： C08L2904
CPC分类号： C09D151/003 , C08F255/026 , C08F263/04 , C08F285/00 , C08L51/003 , C08L2666/02 , C09J151/003 , C08F218/08
摘要： A process of the invention produces a vinyl acetate polymer based emulsion by seed polymerization of vinyl acetate in an ethylene-vinyl acetate copolymer based emulsion. This process includes a step of performing seed polymerization while adding vinyl acetate to a system, and, prior to or subsequent to the step, a step of adding a polymerizable unsaturated monomer other than vinyl acetate to the system. The amount of the polymerizable unsaturated monomer other than vinyl acetate is, for example, about 0.05 to 10 parts by weight relative to 100 parts by weight of vinyl acetate. At least one monomer selected from acrylic esters, methacrylic esters, vinyl esters, and vinyl ethers can be used as the polymerizable unsaturated monomer other than vinyl acetate. The invented process can produce a vinyl acetate polymer based emulsion which has satisfactory low-temperature film-forming property and adhesive strength, even containing no plasticizer, and which can exhibit a high adhesive strength even when cured at low temperatures.
摘要翻译：本发明的方法通过乙酸乙烯酯在乙烯 - 乙酸乙烯酯共聚物基乳液中的种子聚合产生基于乙酸乙烯酯聚合物的乳液。该方法包括在向系统中加入乙酸乙烯酯的同时进行种子聚合的步骤，并且在步骤之前或之后，向系统中加入除乙酸乙烯酯之外的可聚合不饱和单体的步骤。乙酸乙烯酯以外的聚合性不饱和单体的量相对于100重量份乙酸乙烯酯为例如约0.05〜10重量份。可以使用选自丙烯酸酯，甲基丙烯酸酯，乙烯基酯和乙烯基醚中的至少一种单体作为除乙酸乙烯酯以外的可聚合不饱和单体。本发明的方法可以生产具有令人满意的低温成膜性和粘合强度的乙酸乙烯酯聚合物基乳液，甚至不含增塑剂，并且即使在低温下固化也能表现出高的粘合强度。

7. 发明申请

US20070225421A1 Poly (Vinyl Acetate) Emulsions and Production Methods Thereof 审中-公开
标题翻译：聚（乙酸乙烯酯）乳液及其制备方法
公开(公告)号：US20070225421A1
公开(公告)日：2007-09-27
申请号：US11587375
申请日：2005-08-11
申请人： Toshiki Origuchi , Yuji Ikemura , Hideki Maki
发明人： Toshiki Origuchi , Yuji Ikemura , Hideki Maki
IPC分类号： C08F2/22 , C08F18/08 , C09J131/04 , C09J151/06
CPC分类号： C08F2/22 , C08F218/08 , C09D123/0853
摘要： A poly(vinyl acetate) emulsion that is free from VOC components and can form a cured article having satisfactory transparency even though being free from plasticizers is provided. The poly(vinyl acetate) emulsion is a seed polymerization product of a monomer component comprising at least vinyl acetate, the seed polymerization is carried out in an ethylene-vinyl acetate copolymer emulsion, in which the ethylene-vinyl acetate copolymer emulsion has been prepared by using a dispersing agent in an amount less than 3 parts by mass to 100 parts by mass of a dispersoid, and the dispersing agent comprises a vinyl alcohol polymer comprising 1.9 percent by mole or more of a unit represented by following Formula (1) relative to the total of vinyl alcohol units in a polymer chain after saponification to a degree of saponification of 99 percent by mole or more.
摘要翻译：提供了不含VOC组分并且可以形成具有令人满意的透明度的固化制品的聚（乙酸乙烯酯）乳液，即使没有增塑剂。聚（乙酸乙烯酯）乳液是至少包含乙酸乙烯酯的单体组分的种子聚合产物，种子聚合在乙烯 - 乙酸乙烯酯共聚物乳液中进行，其中乙烯 - 乙酸乙烯酯共聚物乳液已经由使用相对于100质量份的分散质量小于3质量份的分散剂，并且所述分散剂包含相对于下述通式（1）表示的单位为1.9摩尔％以上的乙烯醇系聚合物皂化后的聚合物链中的乙烯醇单元的总量达到99摩尔％以上。

8. 发明授权

US5977242A Two-part emulsion adhesive 失效
标题翻译：两部分乳胶粘合剂
公开(公告)号：US5977242A
公开(公告)日：1999-11-02
申请号：US757847
申请日：1996-11-27
申请人： Toshiki Origuchi , Yukiharu Hayashi
发明人： Toshiki Origuchi , Yukiharu Hayashi
IPC分类号： C09J133/06 , C08L33/08
CPC分类号： C09J133/062 , C09J133/064
摘要： Disclosed is a two-part adhesive comprising: (A) an aqueous emulsion liquid having a polymer component and an emulsifier component, in which at least one of the polymer component and the emulsifier component contains an anion radical; and (B) a solution having an amino-radical-containing acrylic copolymer. The amount of the polymer component in the aqueous emulsion liquid is within a range of from about 20% to about 80% by weight. When the aqueous emulsion liquid (A) contacts the solution (B) on an adherend surface, they form sticky gel adhesive.
摘要翻译：公开了两部分粘合剂，其包含：（A）具有聚合物组分和乳化剂组分的水性乳液，其中至少一种聚合物组分和乳化剂组分含有阴离子基团; 和（B）具有含氨基自由基的丙烯酸共聚物的溶液。水乳液中的聚合物组分的量在约20％至约80％重量的范围内。当水性乳液液体（A）与被粘物表面上的溶液（B）接触时，它们形成粘性凝胶粘合剂。

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