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1. 发明申请

US20110287202A1 LAMINATED ARTICLE COMPRISING FLUORINE-CONTAINING RESIN LAYER AND ELASTOMER LAYER 审中-公开
标题翻译：包含含氟树脂层和弹性体层的层压制品
公开(公告)号：US20110287202A1
公开(公告)日：2011-11-24
申请号：US12673374
申请日：2008-08-07
申请人： Toshiki Ichisaka , Michiko Doi , Haruhisa Masuda , Katsuhide Ohtani , Tomihiko Yanagiguchi , Tsuyoshi Ono , Tomohiro Kino , Tadahiro Yabu
发明人： Toshiki Ichisaka , Michiko Doi , Haruhisa Masuda , Katsuhide Ohtani , Tomihiko Yanagiguchi , Tsuyoshi Ono , Tomohiro Kino , Tadahiro Yabu
IPC分类号： B32B25/08 , B32B1/08
CPC分类号： F16L11/04 , B32B1/08 , B32B25/08 , B32B25/14 , B32B27/18 , B32B27/304 , B32B27/322 , B32B27/38 , B32B2250/24 , B32B2270/00 , B32B2307/546 , B32B2307/7265 , B32B2597/00 , B32B2605/08 , F16L2011/047 , Y10T428/1386 , Y10T428/1393 , Y10T428/3154
摘要： The present invention provides a laminated article having improved adhesion of the fluorine-containing resin layer to the elastomer layer. The laminated article comprises a fluorine-containing resin layer (a) formed using a fluorine-containing resin having a carbonyl group, an olefin group or an amino group at an end of a polymer trunk chain or an end of a polymer side chain, and an elastomer layer (b) formed using an elastomer composition.
摘要翻译：本发明提供一种具有改善的含氟树脂层与弹性体层的粘附性的层压制品。层压制品包括使用在聚合物主链或聚合物侧链末端具有羰基，烯基或氨基的含氟树脂形成的含氟树脂层（a），以及使用弹性体组合物形成的弹性体层（b）。

2. 发明申请

US20090226654A1 Thermoplastic polymer composition and process for preparing thermoplastic polymer composition 审中-公开
标题翻译：热塑性聚合物组合物和制备热塑性聚合物组合物的方法
公开(公告)号：US20090226654A1
公开(公告)日：2009-09-10
申请号：US11658807
申请日：2005-11-25
申请人： Tomihiko Yanagiguchi , Toshiki Ichisaka , Haruhisa Masuda , Mitsuhiro Otani
发明人： Tomihiko Yanagiguchi , Toshiki Ichisaka , Haruhisa Masuda , Mitsuhiro Otani
IPC分类号： C08L27/16 , B32B1/08 , B32B27/08
CPC分类号： C08L27/16 , C08K5/136 , C08L27/18 , C08L53/00 , C08L2205/02 , C08L2205/22 , C08L2666/02 , C09J153/00 , Y10T428/1352 , Y10T428/1386 , Y10T428/1397 , Y10T428/3154 , C08L2666/04 , C08L2666/24
摘要： The object of the present invention is to provide a thermoplastic polymer composition which is flexible and capable of melt-molding and has excellent heat resistance, chemical resistance and oil resistance. Another object of the present invention is to provide a molded article, a laminated article, a hose for industrial use, a tube for industrial use, a fuel hose and a fuel tube comprising the thermoplastic polymer composition. Further object of the present invention is to provide a process for preparing a thermoplastic polymer composition. The thermoplastic polymer composition comprises a fluororesin (A) comprising a fluorine-containing ethylenic polymer (a) and a crosslinked fluororubber (B) in which at least a part of at least one kind of fluororubber (b) is crosslinked, and a weight ratio of the fluororesin (A) to the crosslinked fluororubber (B) is 85/15 to 40/60, a fuel permeation coefficient of a molded article obtained from the composition is not more than 40 g·mm/m2·day and a tensile modulus of elasticity of the molded article is not more than 400 MPa.
摘要翻译：本发明的目的是提供一种柔性且能够熔融模塑并且具有优异的耐热性，耐化学性和耐油性的热塑性聚合物组合物。本发明的另一个目的是提供一种模制品，层压制品，工业用软管，工业用管，燃料软管和包含热塑性聚合物组合物的燃料管。本发明的另一个目的是提供一种制备热塑性聚合物组合物的方法。热塑性聚合物组合物包含含有含氟乙烯性聚合物（a）的氟树脂（A）和至少一种氟橡胶（b）的至少一部分交联的交联氟橡胶（B），重量比的氟树脂（A）与交联氟橡胶（B）的摩尔比为85/15〜40/60，由该组合物得到的成型体的燃料透过系数为40g·mm·m·d·以下，拉伸模量成型体的弹性不大于400MPa。

3. 发明申请

US20090202769A1 Thermoplastic Polymer Composition 审中-公开
标题翻译：热塑性聚合物组合物
公开(公告)号：US20090202769A1
公开(公告)日：2009-08-13
申请号：US11658867
申请日：2005-11-25
申请人： Haruhisa Masuda , Mitsuhiro Otani , Tomihiko Yanagiguchi , Toshiki Ichisaka
发明人： Haruhisa Masuda , Mitsuhiro Otani , Tomihiko Yanagiguchi , Toshiki Ichisaka
IPC分类号： B32B1/00 , C08L27/12 , C08J3/24
CPC分类号： F16J15/102 , B60K15/03177 , C08L23/08 , C08L27/16 , C08L27/18 , C08L53/00 , C08L2205/02 , C09K3/1009 , F16L11/04 , F16L2011/047 , Y10T428/1352 , Y10T428/1393 , Y10T428/1397 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： An object of the present invention is to provide a thermoplastic polymer composition which is flexible and capable of melt-molding and has excellent heat resistance and chemical resistance. Further object of the present invention is to provide a molded article, a sealing material, peripheral parts of fuel system, a fuel hose and a fuel container comprising the thermoplastic polymer composition. The present invention relates to a thermoplastic polymer composition comprising a fluororesin (A) containing a fluorine-containing ethylenic polymer (a), a crosslinked fluororubber (B) in which at least a part of at least one kind of fluororubber (b) is crosslinked, and a fluorine-containing thermoplastic elastomer (C).
摘要翻译：本发明的目的是提供一种柔性且能够熔融模塑并且具有优异的耐热性和耐化学性的热塑性聚合物组合物。本发明的另一个目的是提供一种模制品，密封材料，燃料系统的周边部分，燃料软管和包含热塑性聚合物组合物的燃料容器。本发明涉及含有含氟乙烯性聚合物（a）的氟树脂（A），交联氟橡胶（B），其中至少一种至少一种氟橡胶（b）交联的热塑性聚合物组合物，和含氟热塑性弹性体（C）。

4. 发明申请

US20090011164A1 Thermoplastic Polymer Composition 审中-公开
标题翻译：热塑性聚合物组合物
公开(公告)号：US20090011164A1
公开(公告)日：2009-01-08
申请号：US11658866
申请日：2005-11-25
申请人： Haruhisa Masuda , Mitsuhiro Otani , Tomihiko Yanagiguchi , Toshiki Ichisaka
发明人： Haruhisa Masuda , Mitsuhiro Otani , Tomihiko Yanagiguchi , Toshiki Ichisaka
IPC分类号： C08L15/02 , B32B1/08
CPC分类号： C08L27/16 , C08K5/136 , C08L27/18 , C08L53/00 , C08L2205/02 , C08L2205/22 , C08L2666/02 , C09J153/00 , Y10T428/1352 , Y10T428/1386 , Y10T428/1397 , Y10T428/3154 , C08L2666/04 , C08L2666/24
摘要： An object of the present invention is to provide a thermoplastic polymer composition which is flexible and capable of melt-molding and has excellent heat resistance, chemical resistance and oil resistance. The thermoplastic polymer composition comprises 10 to 95% by weight of a fluororesin (A) and 90 to 5% by weight of a crosslinked fluororubber (B), in which the fluororubber (A) comprises a fluorine-containing ethylenic polymer (a) having a melting point of 120° to 330° C. and the crosslinked fluororubber (B) is obtained by cross-linking dynamically at least one kind of fluororubber (b-1) or a fluorine-containing thermoplastic elastomer (b-2) in the presence of the fluororubber (A) and a crosslinking agent (C) under melting condition.
摘要翻译：本发明的目的是提供一种柔性且能够熔融模塑并且具有优异的耐热性，耐化学性和耐油性的热塑性聚合物组合物。热塑性聚合物组合物包含10至95重量％的氟树脂（A）和90至5重量％的交联氟橡胶（B），其中氟橡胶（A）包含含氟乙烯性聚合物（a），其含有熔点为120〜330℃，交联氟橡胶（B）通过动态交联至少一种氟橡胶（b-1）或含氟热塑性弹性体（b-2）氟橡胶（A）和交联剂（C）在熔融条件下的存在。

5. 发明申请

US20080032080A1 Thermoplastic, moldable polymer composition and dynamic vulcanizates thereof 审中-公开
标题翻译：热塑性塑料，可成型聚合物组合物及其动态硫化胶
公开(公告)号：US20080032080A1
公开(公告)日：2008-02-07
申请号：US11712433
申请日：2007-03-01
申请人： Roger Faulkner , James Reilly , Haruhisa Masuda , Mitsuhiro Otani , Tomihiko Yanagiguchi , Toshiki Ichisaka
发明人： Roger Faulkner , James Reilly , Haruhisa Masuda , Mitsuhiro Otani , Tomihiko Yanagiguchi , Toshiki Ichisaka
IPC分类号： F16L11/04 , C08L53/00
CPC分类号： F16J15/102 , B60K15/03177 , C08L23/08 , C08L27/16 , C08L27/18 , C08L53/00 , C08L2205/02 , C09K3/1009 , F16L11/04 , F16L2011/047 , Y10T428/1352 , Y10T428/1393 , Y10T428/1397 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： A thermoplastic, moldable, millable, extrudable composition of matter involving at least three polymeric components: a fluoroelastomer, an ETFE (ethylene/tetrafluoroethylene alternating copolymer, which may optionally contain one or more comonomers in minor amounts to alter crystallinity and melting temperature) fluoroplastic, and a block fluoropolymer containing at least one fluoroelastomer block and at least one ETFE block. The fluoroelastomer component and optionally the fluoroelastomer portion of the block fluoropolymer are crosslinked in a dynamic vulcanization process. Also disclosed are multilayer articles in which the aforesaid fluoro-TPV is adhered to an ETFE plastic layer. These bonded multilayer objects may include injection-molded parts that are either co-injected with both ETFE and fluoro-TPV layers, or insert molding jobs in which a previously molded ETFE insert is placed into a mold and surrounded by fluoro-TPV; and also multilayer co-extruded products such as hoses in which a fluoro-TPV layer is extruded against an ETFE layer.
摘要翻译：氟塑料，ETFE（乙烯/四氟乙烯交替共聚物，其可以任选地含有少量以改变结晶度和熔融温度的一种或多种共聚单体）的氟塑料，可模塑，可研磨，可挤出的物质组合物，包括至少三种聚合物组分：氟弹性体，和含有至少一个含氟弹性体嵌段和至少一个ETFE嵌段的嵌段含氟聚合物。嵌段含氟聚合物的含氟弹性体组分和任选的含氟弹性体部分在动态硫化过程中交联。还公开了其中将上述氟-TPV粘附到ETFE塑料层的多层制品。这些粘合的多层物体可以包括与ETFE和氟-TPV层共同注射的注射成型部件，或嵌入成型工件，其中先前模制的ETFE插入物被放置在模具中并被氟-TPV包围; 以及多层共挤出产品，例如其中氟-TPV层被挤压成ETFE层的软管。

6. 发明授权

US09322477B2 Vehicle transmission oil seal 有权
标题翻译：车辆传动油封
公开(公告)号：US09322477B2
公开(公告)日：2016-04-26
申请号：US13575216
申请日：2011-03-04
申请人： Hidetaka Ogishi , Tetsuya Mizone , Kouhei Takemura , Tomihiko Yanagiguchi
发明人： Hidetaka Ogishi , Tetsuya Mizone , Kouhei Takemura , Tomihiko Yanagiguchi
IPC分类号： F16J15/32 , C09K3/10
CPC分类号： F16J15/3284 , C09K3/1009
摘要： The present invention provides a vehicle transmission having excellent sliding properties over the entire speed range of engines from a low speed range to a high speed range. The present invention is a vehicle transmission oil seal comprising: an elastic member with a seal lip portion having at least a main lip portion, wherein the elastic member is formed of a composition containing a fluororubber and a fluororesin and has projecting portions at least on a surface of the main lip portion, the projecting portions being substantially formed of the fluororesin contained in the composition, the fluororesin is a copolymer including a polymerization unit derived from ethylene and a polymerization unit derived from tetrafluoroethylene, and the fluororubber is a polymer including a polymerization unit derived from vinylidene fluoride.
摘要翻译：本发明提供一种在低速范围至高速范围的发动机的整个速度范围内具有优异的滑动特性的车辆传动装置。本发明是一种车辆用传动油封，其特征在于，具备：弹性部件，具有至少具有主唇部的密封唇部，所述弹性部件由含有氟橡胶和氟树脂的组合物形成，主唇部的表面，突出部分基本上由组合物中所含的氟树脂形成，氟树脂是包含衍生自乙烯的聚合单元和衍生自四氟乙烯的聚合单元的共聚物，氟橡胶是包含聚合物的聚合物衍生自偏氟乙烯的单元。

7. 发明授权

US06930142B2 Seal ring 有权
标题翻译：密封环
公开(公告)号：US06930142B2
公开(公告)日：2005-08-16
申请号：US10239500
申请日：2001-03-21
申请人： Tomihiko Yanagiguchi , Masamichi Sukegawa , Michio Asano
发明人： Tomihiko Yanagiguchi , Masamichi Sukegawa , Michio Asano
IPC分类号： B29C43/00 , C08J5/00 , F16J15/16 , C08F3/00
CPC分类号： C08J5/00 , B29C43/006 , B29K2027/18 , B29L2031/26 , C08J2327/18
摘要： A seal ring with a sliding surface, which is obtained by molding a molding powder or granulated powder of non-melt-moldable modified polytetrafluoroethylene containing 0.01 to 1% by weight of a perfluorovinylether unit represented by the formula (I): —CF2—CF(—O—X)— (I) wherein X represents a perfluoroalkyl group having 1 to 6 carbon atoms or a perfluoroalkoxyalkyl group having 2 to 9 carbon atoms, the modified polytetrafluoroethylene having a heat of crystallization of 18 to 25J/g measured by a differential scanning calorimeter.
摘要翻译：一种具有滑动表面的密封环，其通过模制含有0.01至1重量％的由式（I）表示的全氟乙烯基醚单元的不可熔融模塑的改性聚四氟乙烯的模制粉末或造粒粉末获得： line-formula description =“In-line Formulas”end =“lead”？ - CF <2> -CF（-OX） - （I）<？in-line-formula description =“In- 其中X表示碳原子数为1〜6的全氟烷基或碳原子数为2〜9的全氟烷氧基烷基，其结晶度为18〜25J / g的改性聚四氟乙烯通过差示扫描量热仪

8. 发明授权

US07718247B2 Sliding member, sliding member manufacturing method, and coating for sliding member 失效
标题翻译：滑动构件，滑动构件制造方法和滑动构件用涂层
公开(公告)号：US07718247B2
公开(公告)日：2010-05-18
申请号：US10548883
申请日：2005-01-12
申请人： Nobuaki Takeda , Tomihiko Yanagiguchi
发明人： Nobuaki Takeda , Tomihiko Yanagiguchi
IPC分类号： D06N7/04
CPC分类号： C09D127/18 , C08L27/18 , C08L79/08 , F16C17/04 , F16C33/201 , F16C33/208 , F16C2208/32 , F16C2208/42 , F16C2240/54 , F16C2360/42 , Y10T428/24355 , Y10T428/254 , Y10T428/3154 , Y10T428/31721 , C08L2666/20
摘要： A coating film (43) in which a plurality of fluoric resin particles (45) are dispersed in a matrix resin (44) is formed on the surface of a base material (41). Each exposed part (45a) of the fluoric resin particles (45) which is exposed at the surface of the coating film (43) is crushed to expand therearound to increase the area of the exposed part, increasing the amount of a fluorine element existing in a sliding face portion.
摘要翻译：在基材（41）的表面上形成有多个氟树脂颗粒（45）分散在基体树脂（44）中的涂膜（43）。在涂膜表面暴露的氟树脂颗粒（45）的每个暴露部分（45a）被破碎以在其周围扩张以增加暴露部分的面积，增加存在于滑动面部。

9. 发明授权

US07563510B2 Fluid machinery 有权
标题翻译：流体机械
公开(公告)号：US07563510B2
公开(公告)日：2009-07-21
申请号：US10557888
申请日：2005-01-12
申请人： Tomoko Nogawa , Keiji Yoshimura , Tomihiko Yanagiguchi , Takeyoshi Okawa
发明人： Tomoko Nogawa , Keiji Yoshimura , Tomihiko Yanagiguchi , Takeyoshi Okawa
IPC分类号： B32B27/00 , B32B27/06 , B32B27/34
CPC分类号： F04C29/0021 , F04C18/0215 , F04C2230/91 , F05C2225/04 , F05C2225/10 , F16C17/04 , F16C33/201 , F16C2360/42 , Y10T428/3154 , Y10T428/31721 , Y10T428/31725
摘要： In a scroll compressor, a thrust ring is mounted between a movable-side flat plate part of a movable scroll and a housing. An upper surface of the thrust ring slides relative to a lower surface of the movable-side flat plate part and supports a thrust load from the movable scroll. A resinous coating is formed on the upper surface of the thrust ring which slides relative to the movable-side flat plate part. The resinous coating is composed primarily of fluorocarbon resin and polyamide-imide resin. The component percentage of the polyamide-imide resin in the primary component of the resinous coating is set, such that it is not less than 65% by mass nor more than 85% by mass.
摘要翻译：在涡旋压缩机中，止推环安装在动涡旋盘的可动侧平板部分和壳体之间。推力环的上表面相对于可动侧平板部分的下表面滑动并且支撑来自动涡旋盘的推力载荷。在推力环的上表面上形成树脂涂层，其相对于可动侧平板部分滑动。树脂涂料主要由氟碳树脂和聚酰胺 - 酰亚胺树脂组成。树脂涂料的一次成分中的聚酰胺酰亚胺树脂的成分百分比为65质量％以上85质量％以下。

10. 发明申请

US20070031275A1 Fluid machine 有权
标题翻译：流体机
公开(公告)号：US20070031275A1
公开(公告)日：2007-02-08
申请号：US10557888
申请日：2005-01-12
申请人： Tomoko Nogawa , Keiji Yoshimura , Tomihiko Yanagiguchi , Takeyoshi Okawa
发明人： Tomoko Nogawa , Keiji Yoshimura , Tomihiko Yanagiguchi , Takeyoshi Okawa
IPC分类号： F04C2/00 , F01C1/02 , F04C18/00 , F01C1/063 , F03C4/00
CPC分类号： F04C29/0021 , F04C18/0215 , F04C2230/91 , F05C2225/04 , F05C2225/10 , F16C17/04 , F16C33/201 , F16C2360/42 , Y10T428/3154 , Y10T428/31721 , Y10T428/31725
摘要： In a scroll compressor, a thrust ring is mounted between a movable-side flat plate part of a movable scroll and a housing. An upper surface of the thrust ring slides relative to a lower surface of the movable-side flat plate part and supports a thrust load from the movable scroll. A resinous coating is formed on the upper surface of the thrust ring which slides relative to the movable-side flat plate part. The resinous coating is composed primarily of fluorocarbon resin and polyamide-imide resin. The component percentage of the polyamide-imide resin in the primary component of the resinous coating is set, such that it is not less than 65% by mass nor more than 85% by mass.
摘要翻译：在涡旋压缩机中，止推环安装在动涡旋盘的可动侧平板部分和壳体之间。推力环的上表面相对于可动侧平板部分的下表面滑动并且支撑来自动涡旋盘的推力载荷。在推力环的上表面上形成树脂涂层，其相对于可动侧平板部分滑动。树脂涂料主要由氟碳树脂和聚酰胺 - 酰亚胺树脂组成。树脂涂料的一次成分中的聚酰胺酰亚胺树脂的成分百分比为65质量％以上85质量％以下。

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