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    • 5. 发明申请
    • PRODUCTION PROCESS FOR LITHIUM-SILICATE-SYSTEM COMPOUND
    • 硅酸盐体系化合物的生产工艺
    • US20110291055A1
    • 2011-12-01
    • US13147747
    • 2009-11-20
    • Toshikatsu KojimaTetsuo SakaiTakuhiro MiyukiYasue OkumuraAkira KojimaJunichi NiwaHitotoshi Murase
    • Toshikatsu KojimaTetsuo SakaiTakuhiro MiyukiYasue OkumuraAkira KojimaJunichi NiwaHitotoshi Murase
    • H01M4/58H01B1/18
    • H01M4/5825C01B33/32H01M10/052Y02E60/122Y02P70/54
    • The present invention is one which provides a production process for lithium-silicate-system compound, the production process being characterized in that: a lithium-silicate compound being expressed by Li2SiO3 is reacted with a substance including at least one member of transition-metal elements that is selected from the group consisting of iron and manganese at 400-650° C. in a molten salt of a carbonate mixture comprising lithium carbonate and at least one member of alkali-metal carbonates that is selected from the group consisting of potassium carbonate, sodium carbonate, rubidium carbonate and cesium carbonate in a mixed-gas atmosphere including carbon dioxide and a reducing gas; and a positive-electrode active material for lithium-ion secondary battery that comprises a lithium-silicate-system compound being obtained by the aforesaid process.In accordance with the present invention, it becomes feasible to produce lithium-silicate-system materials, which are useful as positive-electrode active materials for lithium-ion secondary battery, and the like, by means of relatively simple and easy means.
    • 本发明是提供一种硅酸锂系化合物的制造方法,其制造方法的特征在于:将由Li 2 SiO 3表示的硅酸锂化合物与包含至少一种过渡金属元素的物质 选自铁和锰在400-650℃的碳酸盐混合物的熔融盐中的碳酸盐混合物,所述碳酸盐混合物包含碳酸锂和至少一种碱金属碳酸盐成员,所述碱金属碳酸盐选自碳酸钾, 碳酸钠,碳酸铷和碳酸铯在包括二氧化碳和还原气体的混合气体气氛中; 以及锂离子二次电池用正极活性物质,其包含通过上述方法得到的硅酸锂系化合物。 根据本发明,通过相对简单且容易的手段,可以生产用作锂离子二次电池的正极活性物质等的硅酸锂系材料。