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1. 发明授权

US4980083A Optically active compound and liquid crystal composition containing the same 失效
标题翻译：光学活性化合物和含有它们的液晶组合物
公开(公告)号：US4980083A
公开(公告)日：1990-12-25
申请号：US480168
申请日：1990-02-14
申请人： Toshihiro Shibata , Masaki Kimura
发明人： Toshihiro Shibata , Masaki Kimura
IPC分类号： G02F1/13 , C07D213/30 , C07D239/26 , C09K19/34 , C09K19/54 , G02F1/137
CPC分类号： C07D213/30 , C09K19/3463
摘要： An optically active compound useful as a component of a ferroelectric liquid crystal composition represented by the following general formula (I) and a ferroelectric liquid crystal composition containing the same: ##STR1## wherein R stands for a C.sub.1.about.18 alkyl group; R' stands for a C.sub.1.about.18 alkyl group which may be substituted or an aryl group; X stands for ##STR2## or --O-- and an asterisk refers to an optically active carbon atom.
摘要翻译：用作下述通式（I）表示的铁电液晶组合物的成分的光学活性化合物和含有该铁电液晶组合物的铁电液晶组合物：其中R代表C1差异18 烷基; R'表示可以被取代的C 1 -C 18烷基或芳基; X代表或-O-，星号是指光学活性碳原子。

2. 发明授权

US4956488A Optically active cyanobiphenyl compound 失效
标题翻译：光活性氰基联苯化合物
公开(公告)号：US4956488A
公开(公告)日：1990-09-11
申请号：US177979
申请日：1988-04-05
申请人： Toshihiro Shibata , Masaki Kimura
发明人： Toshihiro Shibata , Masaki Kimura
IPC分类号： C07C255/54 , C07C255/55 , C09K19/12
CPC分类号： C07C255/55 , C07C255/54 , C09K19/126
摘要： The present invention discloses an optically active cyanobiphenyl compound represented by the following general formula: ##STR1## wherein, R is ##STR2## X is hydrogen atom or chlorine atom: when X is hydrogen atom, R.sub.1 is normal alkyl having from 1 to 11 carbon atoms and when X is chlorine atom, R.sub.1 is hydrogen atom or normal alkyl having from 1 to 11 carbon atoms; n is 3 to 5; Y is --CH.sub.2 --or --CO--; and * represents an asymmetric carbon atom.
摘要翻译：本发明公开了以下通式表示的光学活性氰基联苯化合物：其中，R为氢原子或氯原子：当X为氢原子时，R 1为具有 1至11个碳原子，当X为氯原子时，R 1为氢原子或具有1至11个碳原子的正烷基; n为3〜5; Y是-CH 2 - 或-CO-; 和*表示不对称碳原子。

3. 发明授权

US5200111A Optically active compound 失效
标题翻译：光学活性化合物
公开(公告)号：US5200111A
公开(公告)日：1993-04-06
申请号：US326540
申请日：1989-03-20
申请人： Seiichi Takano , Kunio Ogasawara , Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
发明人： Seiichi Takano , Kunio Ogasawara , Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
IPC分类号： C07C41/00 , C07C43/205 , C07C43/225 , C07C43/23 , C07C67/00 , C07C69/035 , C07C69/76 , C07C69/92 , C07C69/94 , C07C253/00 , C07C255/49 , C07C255/54 , C07C255/55 , C07C255/57 , C07D239/26 , C07D239/28 , C07D239/34 , C09K19/02 , C09K19/12 , C09K19/20 , C09K19/34 , C09K19/54 , C09K19/58 , G02F1/13
CPC分类号： C07D239/26 , C07C255/54 , C07C255/55 , C07C69/92 , C07C69/94 , C09K19/0225 , C09K19/126 , C09K19/2021 , C09K19/3463 , C09K19/586 , C09K19/588
摘要： An optically active compound of the formula (I): ##STR1## R is a halogen atom, a cyano group, an alkyl group having 1 to 18 carbon atoms, an alkoxy group having 1 to 18 carbon atoms --R' or --O--R' group; R' is a ##STR2## group, wherein Y is a halogen atom, a hydroxyl group, an alkoxy group having 1 to 18 carbon atoms or an acyloxy group having 1 to 18 carbon atoms; X is a direct bond or a ##STR3## group; m, n and p each are each 0 or 1, provided that at least one of m, n and p is 1; and * represents an asymetric carbon atom. The optically active compound can impart a desired helical pitch to a liquid crystal composition.
摘要翻译：式（I）的光学活性化合物：R是卤素原子，氰基，具有1至18个碳原子的烷基，具有1至18个碳原子的烷氧基碳原子-R'或-OR'基团; R'是基团，其中Y是卤素原子，羟基，具有1至18个碳原子的烷氧基或具有1至18个碳原子的酰氧基; X是直接债券或组; m，n和p各自为0或1，条件是m，n和p中的至少一个为1; 和*表示不对称碳原子。光学活性化合物可以赋予液晶组合物所需的螺距。

4. 发明授权

US4981967A Pyrimidine compounds and their use as liquid crystals 失效
标题翻译：嘧啶化合物及其作为液晶的用途
公开(公告)号：US4981967A
公开(公告)日：1991-01-01
申请号：US216367
申请日：1988-07-07
申请人： Toshihiro Shibata , Masaki Kimura
发明人： Toshihiro Shibata , Masaki Kimura
IPC分类号： C07D239/26 , C09K19/34
CPC分类号： C07D239/26 , C09K19/3463
摘要： The present invention discloses an optically active pyrimidine compound represented by the following general formula: ##STR1## wherein, n is 3 to 5; X is hydrogen atom or chlorine atom; when X is hydrogen atom, R.sub.1 is normal alkyl having from 1 to 12 carbon atoms and when X is chlorine atom, R.sub.1 is hydrogen atom or normal alkyl having from 1 to 12 carbon atoms; R.sub.2 is normal alkyl having from 1 to 18 carbon atoms; and C* represents an asymmetric carbon atom.
摘要翻译：本发明公开了由以下通式表示的光学活性嘧啶化合物：其中n为3至5; X是氢原子或氯原子; 当X是氢原子时，R 1是具有1至12个碳原子的正烷基，当X是氯原子时，R 1是氢原子或具有1至12个碳原子的正烷基; R2是具有1至18个碳原子的正烷基; C *表示不对称碳原子。

5. 发明授权

US4831143A Pyrimidine compound 失效
标题翻译：嘧啶化合物
公开(公告)号：US4831143A
公开(公告)日：1989-05-16
申请号：US136649
申请日：1987-12-22
申请人： Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
发明人： Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
IPC分类号： C07D239/26 , C09K19/34
CPC分类号： C07D239/26 , C09K19/3463
摘要： The present invention discloses an optically active pyrimidine compound represented by the following general formula: ##STR1## wherein m is 3 to 14n is 4 to 18; p is 3 to 5; and*C represents an asymmetric carbon atom.The pyrimidine compound of the present invention is a liquid crystal compound useful as an electrooptic element wherein the response of the ferroelectric liquid crystal to an electric field is utilized.
摘要翻译：本发明公开了由以下通式表示的光学活性嘧啶化合物：其中m为3至14 n为4至18; p为3〜5; 和* C表示不对称碳原子。本发明的嘧啶化合物是用作电光元件的液晶化合物，其中利用铁电液晶对电场的响应。

6. 发明授权

US5401436A Optically active compound 失效
标题翻译：光学活性化合物
公开(公告)号：US5401436A
公开(公告)日：1995-03-28
申请号：US989222
申请日：1992-12-11
申请人： Seiichi Takano , Kunio Ogasawara , Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
发明人： Seiichi Takano , Kunio Ogasawara , Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
IPC分类号： C07C41/00 , C07C43/205 , C07C43/225 , C07C43/23 , C07C67/00 , C07C69/035 , C07C69/76 , C07C69/92 , C07C69/94 , C07C253/00 , C07C255/49 , C07C255/54 , C07C255/55 , C07C255/57 , C07D239/26 , C07D239/28 , C07D239/34 , C09K19/02 , C09K19/12 , C09K19/20 , C09K19/34 , C09K19/54 , C09K19/58 , G02F1/13 , C09K19/52 , C07C43/00 , C07D239/02
CPC分类号： C07D239/26 , C07C255/54 , C07C255/55 , C07C69/92 , C07C69/94 , C09K19/0225 , C09K19/126 , C09K19/2021 , C09K19/3463 , C09K19/586 , C09K19/588
摘要： An optically active compound of the formula (I): ##STR1## R is a halogen atom, a cyano group, an alkyl group having 1 to 18 carbon atoms, an alkoxy group having 1 to 18 carbon atoms, --R' or --O--R' group; R' is a ##STR2## group, wherein Y is a halogen atom, a hydroxyl group, an alkoxy group having 1 to 18 carbon atoms or an acyloxy group having 1 to 18 carbon atoms; X is a direct bond or a ##STR3## group; m, n and p each are each 0 or 1, provided that at least one of m, n and p is 1; and , represents an asymetric carbon atom. The optically active compound can impart a desired helical pitch to a liquid crystal composition
摘要翻译：式（I）的光学活性化合物：R 1是卤素原子，氰基，具有1至18个碳原子的烷基，具有1至18个碳原子的烷氧基碳原子，-R'或-OR'基团; R'是基团，其中Y是卤素原子，羟基，具有1至18个碳原子的烷氧基或具有1至18个碳原子的酰氧基; X是直接债券或组; m，n和p各自为0或1，条件是m，n和p中的至少一个为1; 并且表示不对称碳原子。光学活性化合物可以赋予液晶组合物所需的螺距

7. 发明授权

US5342544A Liquid crystal composition 失效
标题翻译：液晶组成
公开(公告)号：US5342544A
公开(公告)日：1994-08-30
申请号：US968152
申请日：1992-10-26
申请人： Tomijiro Naito , Yumiko Sato , Toshiro Yukinari , Toshihiro Shibata , Masaki Kimura , Yukari Shinada
发明人： Tomijiro Naito , Yumiko Sato , Toshiro Yukinari , Toshihiro Shibata , Masaki Kimura , Yukari Shinada
IPC分类号： C09K19/06 , C09K19/42 , C09K19/44 , C09K19/46 , C09K19/12 , C09K19/30
CPC分类号： C09K19/46 , C09K19/06 , C09K19/42 , C09K19/44
摘要： A nematic liquid crystal composition comprising at least one member selected from 4-alkyl- or 4-alkoxy-benzoic acids represented by the following general formula (I) , particularly a nematic liquid crystal composition comprising a carboxylic acid mixture composed of at least one member selected from 4-alkyl- or 4-alkoxy-benzoic acids represented by the following general formula (I) and at least one member selected from 4-alkylcyclohexanecarboxylic acids represented by the following general formula (IV): ##STR1## wherein R.sub.1 stands for an alkyl or alkoxy group having 1 to 12 carbon atoms and R.sub.4 stands for an alkyl group having 1 to 12 carbon atoms.
摘要翻译：一种向列型液晶组合物，其包含至少一种选自下列通式（I）表示的4-烷基 - 或4-烷氧基 - 苯甲酸的成分，特别是包含由至少一种成分选自由以下通式（I）表示的4-烷基 - 或4-烷氧基 - 苯甲酸和选自以下通式（IV）表示的4-烷基环己烷羧酸中的至少一种：（IV）其中R1代表具有1至12个碳原子的烷基或烷氧基，R4代表具有1至12个碳原子的烷基。

8. 发明授权

US4959173A Optically active ester compound 失效
标题翻译：光活性酯化合物
公开(公告)号：US4959173A
公开(公告)日：1990-09-25
申请号：US242177
申请日：1988-09-08
申请人： Toshihiro Shibata , Norio Kurosawa , Masaki Kimura
发明人： Toshihiro Shibata , Norio Kurosawa , Masaki Kimura
IPC分类号： C07C69/92 , C07C69/94 , C09K19/20
CPC分类号： C09K19/2021 , C07C69/92 , C07C69/94
摘要： An optically active ester of the formula ##STR1## wherein p is 0 or 1, q is 1 or 2, r is 1 or 2, q+r is 3, and s is 0 or 1. R.sub.1 and R.sub.2 in the above formula are each independently selected from the group consisting of C.sub.6-18 straight chain alkyl and an optically active group of the formula ##STR2## and in which m is 2 to 5, n is 1 or 2, X is hydrogen or chlorine, R.sub.3 is hydrogen or C.sub.1-11 straight chain alkyl, and C.sup.* represents a chiral carbon atom, with the proviso that when n is 1 and X is hydrogen, R.sub.3 is C.sub.1-11 straight chain alkyl. When q is 2 and r is 1 and R.sub.1 is C.sub.6-18 straight chain alkyl, p is 1; on the other hand, when q is 1 and r is 2 and R.sub.2 is an optically active group of the above formula, s is 1. One of R.sub.1 and R.sub.2 is an optically active group of the above formula, and the other of R.sub.1 and R.sub.2 is C.sub.6-18 straight chain alkyl.
摘要翻译：式IMA的光学活性酯，其中p为0或1，q为1或2，r为1或2，q + r为3，s为0或1.上式中的R 1和R 2为各自独立地选自C6-18直链烷基和式IMAMA的光学活性基团，其中m为2至5，n为1或2，X为氢或氯，R3为氢或 C1-11直链烷基，C *表示手性碳原子，条件是当n为1且X为氢时，R 3为C 1-12直链烷基。当q为2且r为1且R 1为C 6-18直链烷基时，p为1; 另一方面，当q为1且r为2，R2为上式的光学活性基团时，s为1.其中R1和R2为上式的光学活性基团，R1和 R2是C6-18直链烷基。

9. 发明授权

US5013475A Optically active ester compound and liquid crystal composition containing the same 失效
标题翻译：光学活性酯化合物和含有它们的液晶组合物
公开(公告)号：US5013475A
公开(公告)日：1991-05-07
申请号：US427603
申请日：1989-10-27
申请人： Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
发明人： Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
IPC分类号： C07D237/08 , C07C69/007 , C07C69/02 , C07C69/18 , C07C69/28 , C07C69/63 , C07D213/30 , C07D213/63 , C07D239/26 , C07D239/34 , C07D241/12 , C09K19/12 , C09K19/34 , C09K19/46 , G02F1/13
CPC分类号： C07D239/26 , C07C69/007 , C07D239/34 , C09K19/126 , C09K19/3463
摘要： An optically active ester compound useful as a component of a ferroelectric liquid crystal composition is represented by the following formula: ##STR1## wherein R is C.sub.1-18 alkyl or C.sub.1-18 alkoxyl; R' is C.sub.1-18 alkyl or C.sub.1-18 haloalkyl; and ##STR2##
摘要翻译：用作铁电液晶组合物组分的光学活性酯化合物由下式表示：其中R为C 1-18烷基或C 1-18烷氧基; R'是C 1-18烷基或C 1-18卤代烷基; 和

10. 发明授权

US4866199A Optically active ester compound 失效
标题翻译：光活性酯化合物
公开(公告)号：US4866199A
公开(公告)日：1989-09-12
申请号：US164878
申请日：1988-03-08
申请人： Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
发明人： Toshihiro Shibata , Masaki Kimura , Norio Kurosawa
IPC分类号： C09K19/20
CPC分类号： C09K19/2021
摘要： An optically active ester compound is provided represented by the following general formula: ##STR1## wherein R.sub.1 is a normal alkyl group having from 6 to 18 carbon atoms; m is zero or one, n is zero or one, and m+n is one or two; X is --CO--O-- or --O--CO--; p is 3 to 6; Y is a hydrogen atom or chlorine atom; R.sub.2 is hydrogen or a normal alkyl group having from 1 to 11 carbon atoms but may be a hydrogen atom only when Y is a chlorine atom; and *C represents an asymmetric carbon atom. The ester compound of the present invention is useful as a ferroelectric liquid crystal compound.
摘要翻译：提供由以下通式表示的光学活性酯化合物：其中R 1是具有6至18个碳原子的正烷基; m为0或1，n为0或1，m + n为1或2; X是-CO-O-或-O-CO-; p为3〜6; Y是氢原子或氯原子; R2是氢或具有1至11个碳原子的正烷基，但只有当Y是氯原子时可以是氢原子; 和* C表示不对称碳原子。本发明的酯化合物可用作铁电液晶化合物。

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