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    • 3. 发明申请
    • LAMINATE
    • 层压板
    • US20120107617A1
    • 2012-05-03
    • US13381293
    • 2010-05-19
    • Toshiaki MasuiTomihiko YanagiguchiMayuko TaedaTakeshi Inaba
    • Toshiaki MasuiTomihiko YanagiguchiMayuko TaedaTakeshi Inaba
    • B32B25/08B32B7/04
    • B32B25/08B32B7/10B32B25/14B32B27/304B32B2250/02B32B2250/03B32B2250/24B32B2264/102B32B2264/108B32B2264/12B32B2305/77B32B2307/306B32B2307/51B32B2307/714B32B2307/7265B32B2307/738B32B2605/00F16L11/04F16L2011/047Y10T428/31544
    • The present invention provides a vulcanized laminate in which a rubber layer and a fluororesin layer are firmly adhered to each other without using an adhesive or performing a surface treatment on the rubber layer and the fluororesin layer. The present invention relates to a laminate comprising a rubber layer (A) and a fluororesin layer (B) on the rubber layer (A), wherein the rubber layer (A) is a layer made of a rubber composition for vulcanization, the rubber composition for vulcanization contains an unvulcanized rubber (a1); at least one compound (a2) selected from the group consisting of a 1,8-diazabicyclo(5.4.0)undec-7-ene salt, a 1,5-diazabicyclo(4.3.0)-non-5-ene salt, 1,8-diazabicyclo(5.4.0)undec-7-ene, and 1,5-diazabicyclo(4.3.0)-non-5-ene; magnesium oxide (a3); and silica (a4), the amount of the compound (a2) is larger than 1.0 part by mass and not larger than 5.0 parts by mass, for each 100 parts by mass of the unvulcanized rubber (a1), the fluororesin layer (B) is a layer made of a fluoropolymer composition, and the fluoropolymer composition contains a fluoropolymer (b1) having a copolymer unit derived from chlorotrifluoroethylene.
    • 本发明提供一种硫化层压体,其中橡胶层和氟树脂层彼此牢固地粘合,而不使用粘合剂或对橡胶层和氟树脂层进行表面处理。 本发明涉及一种在橡胶层(A)上包含橡胶层(A)和氟树脂层(B)的层压体,其中橡胶层(A)是由用于硫化的橡胶组合物制成的层,橡胶组合物 用于硫化包含未硫化橡胶(a1); 至少一种选自1,8-二氮杂双环(5.4.0)十一碳-7-烯盐,1,5-二氮杂双环(4.3.0) - 壬-5-烯盐的化合物(a2) 1,8-二氮杂双环(5.4.0)十一碳-7-烯和1,5-二氮杂双环(4.3.0) - 壬-5-烯; 氧化镁(a3); 和二氧化硅(a4)中,相对于100质量份未硫化橡胶(a1),氟树脂层(B),化合物(a2)的含量相对于1.0质量份以上且5.0质量份以下, 是含氟聚合物组合物的层,含氟聚合物组合物含有具有来源于三氟氯乙烯的共聚物单元的含氟聚合物(b1)。