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    • 3. 发明授权
    • Sheet-like material
    • US11441033B2
    • 2022-09-13
    • US16488293
    • 2018-02-06
    • Toray Industries, Inc.
    • Ryuji ShikuriMakoto NishimuraYukihiro MatsuzakiSatoshi Yanagisawa
    • C08L75/04C08J5/04C08J5/18D06M15/564D06M101/32
    • The present invention provides a sheet-like material having soft texture, durability capable of withstanding practical use, and abrasion resistance. The sheet-like material of the present invention is a sheet-like material containing a nonwoven fabric composed of an ultrafine fiber having an average single fiber diameter 0.3 to 7 μm; and an elastic resin, wherein the elastic resin is a polyurethane resin (D) which contains: as essential constituent monomers, a copolymerized polycarbonate diol (A1) which contains a structural unit derived from C3-5 alkane diol (a1) and a structural unit derived from C8-12 alkane diol (a2), the molar ratio of the alkanediol (a2) with respect to the total number of moles of the alkanediol (a1) and the alkanediol (a2) being 50 to 95 mole %; a polycarbonate diol (A2) containing a structural unit derived from a C4-6 alkane diol (a3); an organic diisocyanate (B); and a chain extender (C), and the polyurethane resin (D) satisfies the following conditions (1) to (3): (1) The copolymerized polycarbonate diol (A1) has a heat quantity of fusion (ΔH) o 40 to 100 J/g, the heat quantity of fusion (ΔH) being determined according to a melting point measuring method provided in JIS K7121-1987; (2) The polycarbonate diol (A2) has a heat quantity of fusion (ΔH) of 0 J/g; (3) A difference (ΔTm) in a melting point (Tm) between a mixture (A12) of the copolymerized polycarbonate diol (A1) with the polycarbonate diol (A2) and the copolymerized polycarbonate diol (A1) is 1.5° C. or lower, the melting point (Tm) being determined by a melting point measuring method provided in JIS K7121-1987.
    • 6. 发明申请
    • SHEET MATERIAL AND METHOD FOR PRODUCING SAME
    • US20220380976A1
    • 2022-12-01
    • US17773915
    • 2020-12-10
    • Toray Industries, Inc.
    • Takuya ShibanoRyuji ShikuriKoki Ishii
    • D06N3/00D06N3/14
    • The purpose of the present invention is to provide: a sheet-like article which has a good balance between soft texture and excellent light resistance; and a method for producing this sheet-like article. In order to achieve this purpose, a sheet-like article according to the present invention has the following configuration. Specifically, a sheet-like article which contains a polymer elastic body in a fibrous base material, wherein: the fibrous base material is composed of ultrafine fibers that have an average single fiber diameter of from 0.1 μm to 10 μm; the polymer elastic body has a hydrophilic group, while containing a polyether diol as a constituent; the polymer elastic body internally has an N-acylurea bond and/or an isourea bond; and the condition 1 and the condition 2 described below are satisfied. Condition 1: The bending resistance in the lengthwise direction as determined in accordance with specific standards is from 40 mm to 140 mm. Condition 2: The abrasion weight loss after 20,000 cycles of a Martindale abrasion test set forth in JIS L 1096 (2005) after a light resistance test as performed under the conditions defined in accordance with specific standards is 25 mg or less.