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    • 4. 发明授权
    • Organosilicon compound, liquid crystal composition, and liquid-crystal
display element
    • 有机硅化合物,液晶组合物和液晶显示元件
    • US5993690A
    • 1999-11-30
    • US000409
    • 1998-01-26
    • Tomoyuki KondoShuichi MatsuiNorihisa HachiyaEtsuo Nakagawa
    • Tomoyuki KondoShuichi MatsuiNorihisa HachiyaEtsuo Nakagawa
    • C07F7/08C09K19/40C09K19/42C09K19/54C07F7/04C09K19/52
    • C07F7/0896C09K19/40C09K19/406C09K19/42
    • An object of the present invention is to provide organosilicon compounds having an excellent miscibility with other liquid crystal materials, low viscosity, and improved threshold voltage; to provide liquid crystal compositions comprising the organosilicon compound; and to provide liquid crystal display devices comprising the liquid crystal composition. The organosilicon compounds are expressed by the general formula (1)Ra--A.paren open-st.Z.sub.1 --A.sub.1 .paren close-st..sub.m .paren open-st.Z.sub.2 --A.sub.2 .paren close-st..sub.n .paren open-st.Z.sub.3 --A.sub.3 .paren close-st..sub.o Rb (1)wherein at least one of Ra, Rb, Z.sub.1, Z.sub.2, and Z.sub.3 has --SiH.sub.2 --; Ra represents hydrogen atom or an alkyl group having 1 to 20 carbon atoms; at least one --CH.sub.2 -- in the alkyl group may be replaced by --SiH.sub.2 --, --O--, --S--, --CO--, --CH.dbd.CH--, --C.tbd.C--, or 1,3 -cyclobutylene; Rb represents a group selected from Ra, a halogen atom, or CN; each of A, A.sub.1, A.sub.2, and A.sub.3 represents a divalent cyclic group; Z.sub.1, Z.sub.2 and Z.sub.3 independently represent a covalent bond or --(CH.sub.2).sub.p --; at least one --CH.sub.2 -- in the --(CH.sub.2).sub.p -- may be replaced by --SiH.sub.2 --, --O--, --S--, --CO--, --CH.dbd.CH--, or --C.tbd.C--; p is an integer of 1 to 4; and m, n, and o are independently 0 or 1.
    • PCT No.PCT / JP96 / 02103 Sec。 371日期1998年1月26日 102(e)1998年1月26日PCT PCT 1996年7月26日PCT公布。 公开号WO97 / 05144 日期1997年2月13日本发明的目的是提供与其它液晶材料混合性优异的有机硅化合物,粘度低,阈值电压提高; 提供包含有机硅化合物的液晶组合物; 并提供包括液晶组合物的液晶显示装置。 有机硅化合物由通式(1)表示:Ra-A + 545 Z1-A1 + 546m + 545Z2-A2 + 546n + 545Z3-A3 + 546 oRb(1)其中Ra,Rb中的至少一个 ,Z1,Z2和Z3具有-SiH2-; Ra表示氢原子或碳原子数1〜20的烷基。 烷基中的至少一个-CH 2可以被-SiH 2 - , - O - , - S - , - CO - , - CH = CH - , - C 3 CF 3 - 或1,3-亚环丁基代替; Rb表示选自Ra,卤素原子或CN的基团; A,A1,A2和A3各自表示二价环状基团; Z 1,Z 2和Z 3独立地表示共价键或 - (CH 2)p - ; - (CH 2)p - 中的至少一个-CH 2可以被-SiH 2 - , - O - , - S - , - CO - , - CH = CH-或-C p为1〜4的整数, 且m,n和o独立地为0或1。
    • 10. 发明授权
    • Vinylene compounds and liquid-crystal composition
    • 维尼尼亚化合物和液晶组成
    • US06337034B1
    • 2002-01-08
    • US09125685
    • 1998-08-24
    • Tomoyuki KondoShuichi MatsuiKazutoshi MiyazawaYasuko SekiguchiEtsuo Nakagawa
    • Tomoyuki KondoShuichi MatsuiKazutoshi MiyazawaYasuko SekiguchiEtsuo Nakagawa
    • C09K1930
    • C07D213/79C07C69/75C07C69/753C07C69/76C07D213/80C07D239/28C07D239/34C07D319/06C09K19/04C09K19/3001C09K19/3068
    • Liquid crystalline compounds which have a wide temperature range of liquid crystal phase, low viscosity, and improved threshold voltage; liquid crystal compositions; and liquid crystal display devices comprising the composition can be provided; and the liquid crystalline compounds are expressed by the general formula (1) Ra—A1—Z1—A2—Z2—A3—(Z3—A4)m—Rb  (1) wherein Ra represents an alkyl group having 1 to 20 carbon atoms one or more —CH2— in which alkyl group may be replaced by —O— or the like, and one or more hydrogen atoms in which alkyl group may be replaced by a halogen atom; Rb represents Ra, a halogen atom, or cyano group; A1, A2, A3, and A4 independently represent a divalent ring group; Z1, Z2, and Z3 independently represent an alkenylene group having 2 to 4 carbon atoms, —COO—, a covalent bond, or the like provided that at least one of Z1 to Z3 represents an alkenylene group having 2 to 4 carbon atoms, and at least one of Z1 to Z3 represents —COO— or —OCO—; and m is 0 or 1.
    • 具有液晶相温度范围宽,粘度低,阈值电压提高的液晶化合物; 液晶组合物; 并且可以提供包含该组合物的液晶显示装置; 并且液晶化合物由通式(1)表示,其中R a表示具有1至20个碳原子的烷基,一个或多个-CH 2 - ,其中烷基可以被-O-取代,以及一个或 更多的氢原子,其中烷基可被卤素原子取代; Rb表示Ra,卤素原子或氰基; A1,A2,A3和A4独立地表示二价环基团; Z 1,Z 2和Z 3独立地表示具有2〜4个碳原子的亚烯基,-COO-,共价键等,条件是Z1至Z3中的至少一个表示具有2至4个碳原子的亚烯基, Z1至Z3中的至少一个表示-COO-或-OCO-; m为0或1。