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    • 6. 发明授权
    • Ni-based alloy product and producing method thereof
    • 镍基合金产品及其制备方法
    • US08801876B2
    • 2014-08-12
    • US13420918
    • 2012-03-15
    • Atsuro IsedaHiroyuki HirataHirokazu OkadaHiroyuki Semba
    • Atsuro IsedaHiroyuki HirataHirokazu OkadaHiroyuki Semba
    • C21D11/00C22C19/05C22C30/00
    • C22F1/10C22C19/05C22F1/00
    • [Problem to be Solved]A Ni-based alloy product consisting of, by mass percent, C: 0.03 to 0.10%, Si: 0.05 to 1.0%, Mn: 0.1 to 1.5%, Sol.Al: 0.0005 to 0.04%, Fe: 20 to 30%, Cr: not less than 21.0% and less than 25.0%, W: exceeding 6.0% and not more than 9.0%, Ti: 0.05 to 0.2%, Nb: 0.05 to 0.35%, and B: 0.0005 to 0.006%, the balance being Ni and impurities, the impurities being P: 0.03% or less, S: 0.01% or less, N: less than 0.010%, Mo: less than 0.5%, and Co: 0.8% or less, wherein a value of effective B (Beff) defined by the formula, Beff (%)=B−(11/14)×N+(11/48)×Ti, is 0.0050 to 0.0300%, and the rupture elongation in a tensile test at 700° C. and at a strain rate of 10−6/sec is 20% or more. This alloy may contain one or more kinds of Cu, Ta, Zr, Mg, Ca, REM, and Pd.
    • [待解决的问题]以质量%计,C:0.03〜0.10%,Si:0.05〜1.0%,Mn:0.1〜1.5%,Sol.Al:0.0005〜0.04%,Fe :20〜30%,Cr:21.0%以上25.0%以下,W:6.0以上9.0%以下,Ti:0.05〜0.2%,Nb:0.05〜0.35%,B:0.0005〜 0.006%,余量为Ni和杂质,杂质为P:0.03%以下,S:0.01%以下,N:小于0.010%,Mo:小于0.5%,Co:0.8%以下,其中, 由公式Beff(%)= B-(11/14)×N +(11/48)×Ti定义的有效B(Beff)的值为0.0050〜0.0300%,拉伸试验中的断裂伸长率为 700℃,应变速率为10-6 /秒为20%以上。 该合金可以含有Cu,Ta,Zr,Mg,Ca,REM和Pd中的一种或多种。
    • 7. 发明申请
    • Ni-BASED HEAT RESISTANT ALLOY
    • 镍基耐热合金
    • US20140234155A1
    • 2014-08-21
    • US14237586
    • 2012-07-31
    • Hiroyuki SembaHirokazu OkadaHiroyuki HirataMitsuru YoshizawaAtsuro Iseda
    • Hiroyuki SembaHirokazu OkadaHiroyuki HirataMitsuru YoshizawaAtsuro Iseda
    • C22C19/05
    • C22C19/056C22C19/05C22C19/051C22C19/055C22F1/10
    • A Ni-based heat resistant alloy as pipe, plate, rod, forgings and the like consists of C≦0.15%, Si≦2%, Mn≦3%, P≦0.03%, S≦0.01%, Cr: 15% or more and less than 28%, Mo: 3 to 15%, Co: more than 5% and not more than 25%, Al: 0.2 to 2%, Ti: 0.2% to 3%, Nd: fn to 0.08%, and O≦0.4Nd, further containing, as necessary, at least one kind of Nb, W, B, Zr, Hf, Mg, Ca, Y, La, Ce, Ta, Re and Fe of specific amounts, the balance being Ni and impurities, wherein, fn=1.7×10−5d+0.05{(Al/26.98)+(Ti/47.88)+(Nb/92.91)}. In the formula, d denotes an average grain size (μm), and each element symbol denotes the content (mass %) of that element. If the alloy contains W, Mo+(W/2)≦15% holds. The alloy has improved ductility after long-term use at high temperatures, and cracking due to welding can be avoided.
    • 作为管,板,棒,锻件等的Ni基耐热合金由C< Ll; 0.15%,Si&NlE; 2%,Mn&NlE; 3%,P&NlE; 0.03%,S< 0.01%,Cr:15% 多于28%,Mo:3〜15%,Co:5%以上25%以下,Al:0.2〜2%,Ti:0.2%〜3%,Nd:fn〜0.08% O,nNE,0.4Nd,根据需要还含有特定量的Nb,W,B,Zr,Hf,Mg,Ca,Y,La,Ce,Ta,Re和Fe中的至少一种,其余为Ni和 杂质,其中,fn = 1.7×10-5d + 0.05 {(Al / 26.98)+(Ti / 47.88)+(Nb / 92.91)}。 式中,d表示平均粒径(μm),各元素符号表示该元素的含量(质量%)。 如果合金含有W,则Mo +(W / 2)≦̸ 15%成立。 该合金在长期使用高温下具有改善的延展性,并且可以避免由于焊接引起的开裂。
    • 8. 发明申请
    • AUSTENITIC HEAT RESISTANT ALLOY
    • 奥氏体耐热合金
    • US20100166594A1
    • 2010-07-01
    • US12647028
    • 2009-12-24
    • Hiroyuki HirataAtsuro IsedaHirokazu OkadaHiroyuki SembaKaori KawanoOsamu Miyahara
    • Hiroyuki HirataAtsuro IsedaHirokazu OkadaHiroyuki SembaKaori KawanoOsamu Miyahara
    • C22C19/05C22C30/04C22C30/00C22C30/06
    • C22C38/44C21D6/001C21D6/002C21D6/004C22C38/001C22C38/002C22C38/008C22C38/02C22C38/04C22C38/06C22C38/50C22C38/52C22C38/54F22B37/04
    • An austenitic heat resistant alloy, which comprises, by mass percent, C≦0.15%, Si≦2%, Mn≦3%, Ni: 40 to 80%, Cr: 15 to 40%, W and Mo: 1 to 15% in total content, Ti≦3%, Al≦3%, N≦0.03%, O≦0.03%, with the balance being Fe and impurities, and among the impurities P≦0.04%, S≦0.03%, Sn≦0.1%, As≦0.01%, Zn≦0.01%, Pb≦0.01% and Sb≦0.01%, and satisfies the conditions [P1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5}≦0.050], [0.2≦P2=Ti+2Al≦7.5−10×P1], [P2≦9.0−100×O] and [N≦0.002×P2+0.019] can prevent both the liquation crack in the HAZ and the brittle crack in the HAZ and also can prevent defects due to welding fabricability, which occur during welding fabrication, and moreover has excellent creep strength at high temperatures. Therefore, the alloy can be used suitably as a material for constructing high temperature machines and equipment, such as power generating boilers, plants for the chemical industry and so on. The ally may contain a specific amount or amounts of one or more elements selected from Co, B, Ta, Hf, Nb, Zr, Ca, Mg, Y, La, Ce and Nd.
    • 一种奥氏体系耐热合金,以质量%计含有0.15%,Si&NlE; 2%,Mn&NlE; 3%,Ni:40〜80%,Cr:15〜40%,W:1〜15% 在总含量中,Ti&NlE; 3%,Al&NlE; 3%,N& NlE; 0.03%,O&NlE; 0.03%,余量为Fe和杂质,杂质P< L; 0.04%,S&NlE; 0.03%,Sn& ,As / nlE; 0.01%,Zn和nlE; 0.01%,Pb和nlE; 0.01%和Sb≦̸ 0.01%,满足条件[P1 = S + {(P + Sn)/ 2} + {(As + Zn + Pb + Sb)/ 5}≦̸ 0.050],[0.2≦̸ P2 = Ti + 2Al≦̸ 7.5-10×P1],[P2≦̸ 9.0-100×O]和[N< lE; 0.002×P2 + 0.019]可以防止液化裂纹 HAZ和HAZ中的脆性裂纹,并且还可以防止在焊接制造期间发生的焊接可制造性的缺陷,并且还在高温下具有优异的蠕变强度。 因此,该合金可以适当地用作构成发电锅炉,化工工业用等的高温机器和设备的材料。 盟友可以含有一定量或数量的选自Co,B,Ta,Hf,Nb,Zr,Ca,Mg,Y,La,Ce和Nd中的一种或多种元素。
    • 9. 发明授权
    • Austenitic heat resistant alloy
    • 奥氏体耐热合金
    • US08313591B2
    • 2012-11-20
    • US12647028
    • 2009-12-24
    • Hiroyuki HirataAtsuro IsedaHirokazu OkadaHiroyuki SembaKaori KawanoOsamu Miyahara
    • Hiroyuki HirataAtsuro IsedaHirokazu OkadaHiroyuki SembaKaori KawanoOsamu Miyahara
    • C22C30/00C22C19/05
    • C22C38/44C21D6/001C21D6/002C21D6/004C22C38/001C22C38/002C22C38/008C22C38/02C22C38/04C22C38/06C22C38/50C22C38/52C22C38/54F22B37/04
    • An austenitic heat resistant alloy, which contains, by mass percent, C≦0.15%, Si≦2%, Mn≦3%, Ni: 40 to 80%, Cr: 15 to 40%, W and Mo: 1 to 15% in total content, Ti≦3%, Al≦3%, N≦0.03%, O≦0.03%, with the balance being Fe and impurities, and among the impurities P≦0.04%, S≦0.03%, Sn≦0.1%, As≦0.01%, Zn≦0.01%, Pb≦0.01% and Sb≦0.01%, and satisfies the conditions [P1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5}≦0.050], [0.2≦P2=Ti+2Al≦7.5−10×P1], [P2≦9.0−100×O] and [N≦0.002×P2+0.019] can prevent both the liquation crack in the HAZ and the brittle crack in the HAZ and also can prevent defects due to welding fabricability, which occur during welding fabrication, and moreover has excellent creep strength at high temperatures. Therefore, the alloy can be used suitably as a material for constructing high temperature machines and equipment, such as power generating boilers, plants for the chemical industry and so on. The ally may contain a specific amount or amounts of one or more elements selected from Co, B, Ta, Hf, Nb, Zr, Ca, Mg, Y, La, Ce and Nd.
    • 一种奥氏体耐热合金,以质量%计含有0.15%,Si&NlE; 2%,Mn&NlE; 3%,Ni:40〜80%,Cr:15〜40%,W和Mo:1〜15% 在总含量中,Ti&NlE; 3%,Al&NlE; 3%,N& NlE; 0.03%,O&NlE; 0.03%,余量为Fe和杂质,杂质P< L; 0.04%,S&NlE; 0.03%,Sn& ,As / nlE; 0.01%,Zn和nlE; 0.01%,Pb和nlE; 0.01%和Sb≦̸ 0.01%,满足条件[P1 = S + {(P + Sn)/ 2} + {(As + Zn + Pb + Sb)/ 5}≦̸ 0.050],[0.2≦̸ P2 = Ti + 2Al≦̸ 7.5-10×P1],[P2≦̸ 9.0-100×O]和[N< lE; 0.002×P2 + 0.019]可以防止液化裂纹 HAZ和HAZ中的脆性裂纹,并且还可以防止在焊接制造期间发生的焊接可制造性的缺陷,并且还在高温下具有优异的蠕变强度。 因此,该合金可以适当地用作构成发电锅炉,化工工业用等的高温机器和设备的材料。 盟友可以含有一定量或数量的选自Co,B,Ta,Hf,Nb,Zr,Ca,Mg,Y,La,Ce和Nd中的一种或多种元素。
    • 10. 发明授权
    • Ni-based heat resistant alloy
    • 镍基耐热合金
    • US09328403B2
    • 2016-05-03
    • US14237586
    • 2012-07-31
    • Hiroyuki SembaHirokazu OkadaHiroyuki HirataMitsuru YoshizawaAtsuro Iseda
    • Hiroyuki SembaHirokazu OkadaHiroyuki HirataMitsuru YoshizawaAtsuro Iseda
    • C22C19/05C22F1/10
    • C22C19/056C22C19/05C22C19/051C22C19/055C22F1/10
    • A Ni-based heat resistant alloy as pipe, plate, rod, forgings and the like consists of C≦0.15%, Si≦2%, Mn≦3%, P≦0.03%, S≦0.01%, Cr: 15% or more and less than 28%, Mo: 3 to 15%, Co: more than 5% and not more than 25%, Al: 0.2 to 2%, Ti: 0.2% to 3%, Nd: fn to 0.08%, and O≦0.4Nd, further containing, as necessary, at least one kind of Nb, W, B, Zr, Hf, Mg, Ca, Y, La, Ce, Ta, Re and Fe of specific amounts, the balance being Ni and impurities, wherein, fn=1.7×10−5d+0.05{(Al/26.98)+(Ti/47.88)+(Nb/92.91)}. In the formula, d denotes an average grain size (μm), and each element symbol denotes the content (mass %) of that element. If the alloy contains W, Mo+(W/2)≦15% holds. The alloy has improved ductility after long-term use at high temperatures, and cracking due to welding can be avoided.
    • 作为管,板,棒,锻件等的Ni基耐热合金由C< Ll; 0.15%,Si&NlE; 2%,Mn&NlE; 3%,P&NlE; 0.03%,S< 0.01%,Cr:15% 多于28%,Mo:3〜15%,Co:5%以上25%以下,Al:0.2〜2%,Ti:0.2%〜3%,Nd:fn〜0.08% O,nNE,0.4Nd,根据需要还含有特定量的Nb,W,B,Zr,Hf,Mg,Ca,Y,La,Ce,Ta,Re和Fe中的至少一种,其余为Ni和 杂质,其中,fn = 1.7×10-5d + 0.05 {(Al / 26.98)+(Ti / 47.88)+(Nb / 92.91)}。 式中,d表示平均粒径(μm),各元素符号表示该元素的含量(质量%)。 如果合金含有W,则Mo +(W / 2)≦̸ 15%成立。 该合金在长期使用高温下具有改善的延展性,并且可以避免由于焊接引起的开裂。