专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US4239741A Process for producing hydrazine sulfate 失效
标题翻译：硫酸肼生产方法
公开(公告)号：US4239741A
公开(公告)日：1980-12-16
申请号：US955166
申请日：1978-10-27
申请人： Tomiya Isshiki , Tetsuo Tomita , Toshiaki Kozaki , Osamu Aoki , Mitsuo Abe , Norio Takeda , Mitsuo Miura , Yoshiyuki Aoki , Takao Kondo , Kaoru Tsuyuki
发明人： Tomiya Isshiki , Tetsuo Tomita , Toshiaki Kozaki , Osamu Aoki , Mitsuo Abe , Norio Takeda , Mitsuo Miura , Yoshiyuki Aoki , Takao Kondo , Kaoru Tsuyuki
IPC分类号： C01B21/16 , C01B21/54
CPC分类号： C01B21/16
摘要： Hydrazine sulfate having a relatively large particle diameter and a high purity is produced by hydrolysis of benzophenoneazines by sulfuric acid having a concentration of 75% by weight or less in an amount of 1.1 times by mole or more the stoichiometric amount in a very high conversion and a high yield with less operational loss.
摘要翻译：通过以非常高的转化率使化学计量量为1.1倍摩尔以上的浓度为75重量％以下的硫酸水解二苯甲酮酮而产生具有较大粒径且高纯度的硫酸肼，产量高，运营损失少。

2. 发明授权

US4130586A Process for producing imine compounds 失效
标题翻译：亚胺化合物的制备方法
公开(公告)号：US4130586A
公开(公告)日：1978-12-19
申请号：US827791
申请日：1977-08-25
申请人： Tomiya Isshiki , Tetsuo Tomita , Mitsuo Abe , Norio Takeda
发明人： Tomiya Isshiki , Tetsuo Tomita , Mitsuo Abe , Norio Takeda
IPC分类号： C07B61/00 , C07C67/00 , C07C241/00 , C07C251/24 , C07C119/00
摘要： An imine compound is produced by reacting a benzophenone with ammonia in the presence of 0.01 to 10% by weight of a carboxylic acid as a catalyst at a reaction temperature of 50.degree. to 350.degree. C on the basis of benzophenone. Ammonia is fed to the reaction system continuously under a pressure of 2 to 15 atmospheres. A solvent may be used for the reaction. The catalyst carboxylic acid can be readily recovered and reused without any influence of water formed by the reaction and brings about no problem of corrosion to reactor apparatus.
摘要翻译：在二苯甲酮的基础上，在50〜350℃的反应温度下，在0.01〜10重量％的羧酸作为催化剂的存在下，使二苯甲酮与氨反应生成亚胺化合物。在2〜15个大气压的压力下，连续向反应体系供给氨。反应可以使用溶剂。催化剂羧酸可以容易地回收和重复使用而不受反应形成的水的任何影响，并且不会对反应器设备产生腐蚀的问题。

3. 发明授权

US4083869A Process for producing imine compounds 失效
标题翻译：亚胺化合物的制备方法
公开(公告)号：US4083869A
公开(公告)日：1978-04-11
申请号：US831264
申请日：1977-09-07
申请人： Tomiya Isshiki , Tetsuo Tomita , Mitsuo Abe , Norio Takeda , Mitsuo Miura
发明人： Tomiya Isshiki , Tetsuo Tomita , Mitsuo Abe , Norio Takeda , Mitsuo Miura
IPC分类号： C07B61/00 , B01J21/00 , B01J21/02 , B01J21/06 , B01J23/00 , B01J23/14 , B01J23/16 , B01J23/74 , B01J25/00 , C07C67/00 , C07C241/00 , C07C251/24 , C07C119/00
CPC分类号： Y02P20/52
摘要： An imine compound is produced in high yield by reacting a benzophenone with ammonia in the presence of 0.01 to 100% by weight of an oxide of at least one of metals selected from the group consisting of metals of the second to fifth periods of Group III to V of the periodic Table, and iron as a catalyst at a reaction temperature of 150.degree. to 250.degree. C on the basis of benzophenone. Ammonia is fed to the reaction system continuously under a pressure of 2 to 15 atmospheres. A solvent may be used for the reaction. The catalyst metal oxide can be readily recovered and reused without any influence of water formed by the reaction.
摘要翻译：通过使二苯甲酮与氨反应，在0.01至100重量％的至少一种金属的氧化物存在下，以高产率制备亚胺化合物，所述金属选自第III至第5周期的金属组， V，在二苯甲酮的基础上，在150〜250℃的反应温度下使用铁作为催化剂。在2〜15个大气压的压力下，连续向反应体系供给氨。反应可以使用溶剂。催化剂金属氧化物可以容易地回收和再利用，而不受反应形成的水的任何影响。

4. 发明授权

US4347383A Process for producing benzophenone-azines 失效
标题翻译：生产二苯甲酮吖嗪的方法
公开(公告)号：US4347383A
公开(公告)日：1982-08-31
申请号：US147194
申请日：1980-05-06
申请人： Tomiya Isshiki , Tetsuo Tomita , Shuzabu Sakaguchi , Toshiaki Kohzaki , Osamu Aoki , Norio Takeda , Yoshiyuki Aoki
发明人： Tomiya Isshiki , Tetsuo Tomita , Shuzabu Sakaguchi , Toshiaki Kohzaki , Osamu Aoki , Norio Takeda , Yoshiyuki Aoki
IPC分类号： C07C255/67 , C07C109/16
CPC分类号： C07C251/88
摘要： A process for producing a benzophenone-azine which comprises reacting the corresponding benzophenone-imine with molecular oxygen or benzophenone with ammonia and molecular oxygen in the presence of a catalyst selected from the group consisting of metals, metal oxides and alloys of two or more metals, particularly copper or copper alloy-containing catalyst, is disclosed.
摘要翻译：一种二苯甲酮 - 吖嗪的制备方法，其包括使相应的二苯甲酮 - 亚胺与分子氧或二苯甲酮与氨和分子氧在选自金属，金属氧化物和两种或更多种金属的合金的催化剂存在下反应，特别是含铜或含铜合金的催化剂。

5. 发明授权

US4828762A Process for the production of 2,3,5-trimethylbenzoquinone 失效
标题翻译：生产2,3,5-三甲基苯醌的方法
公开(公告)号：US4828762A
公开(公告)日：1989-05-09
申请号：US947503
申请日：1986-12-29
申请人： Tomiya Isshiki , Tomoyuki Yui , Mitsuo Abe , Masahiro Jono , Hideo Uno
发明人： Tomiya Isshiki , Tomoyuki Yui , Mitsuo Abe , Masahiro Jono , Hideo Uno
IPC分类号： B01J27/08 , B01J27/122 , C07C46/08
CPC分类号： B01J27/122 , B01J27/08 , C07C46/08
摘要： A process for the production of 2,3,5-trimethylbenzoquinone (TMBQ) from 2,3,6-trimethylphenol (TMP) is described, comprising contacting TMP with oxygen or an oxygen containing gas in a medium of water and an aliphatic alcohol having from 5 to 10 carbon atoms in the presence of catalyst of a copper halogen complex represented by the formula as shown below or a mixture of the copper halogen complex and an alkali metal halide or a mixture of the copper halogen complex, an alkali metal halide and cupric hydroxide and/or cuprous chlorideM.sub.l [Cu(II).sub.m X.sub.n ].sub.pwherein M is an alkali metal or ammonium, Cu(II) is a divalent copper, X is a halogen atom, l is an integer of 1 to 3, m is 1 or 2, n is an integer or 3 to 8, p is 1 or 2, and l+2mp=np. The process is carried out in a batch system, a semi-batch system or in a continuous flow system. The third mentioned catalyst system is most effectively utilized in the semi-batch system. The present process yields various advantages; for example, TMBQ can be produced with high selectivity, and since the reaction is performed in a specific medium (the medium is heterogeneous because the alcohols are immiscible or only slightly miscible with water) and TMBQ is soluble in the alcohol layer, while the catalyst is soluble in the water layer, the TMBQ can be easily separated and reuse of the catalyst can be accomplished by a simplified procedure. TMBQ is a useful compound as an intermediate for use in the preparation of Vitamin E.
摘要翻译：描述了从2,3,6-三甲基苯酚（TMP）生产2,3,5-三甲基苯醌（TMBQ）的方法，包括将TMP与氧或含氧气体在水和脂族醇的介质中接触，在由下式表示的铜卤素络合物的催化剂存在下的5至10个碳原子或铜卤素络合物和碱金属卤化物的混合物或铜卤素络合物，碱金属卤化物和碱金属卤化物的混合物氢氧化铜和/或氯化亚铜M1 [Cu（II）mXn] p其中M为碱金属或铵，Cu（II）为二价铜，X为卤素原子，l为1〜3的整数，m 为1或2，n为整数或3至8，p为1或2，l + 2mp = np。该方法在分批系统，半分批系统或连续流系统中进行。第三种催化剂体系在半分批系统中最有效地利用。本方法产生各种优点; 例如，可以高选择性地制备TMBQ，并且由于反应在特定介质中进行（介质是异质的，因为醇是不混溶的或仅与水轻微混溶），并且TMBQ可溶于醇层，而催化剂可溶于水层，TMBQ可以容易地分离，催化剂的再利用可以通过简化的程序完成。 TMBQ是一种有用的化合物，作为用于制备维生素E的中间体。

6. 发明授权

US5344972A Process for producing acetic acid 失效
标题翻译：生产乙酸的方法
公开(公告)号：US5344972A
公开(公告)日：1994-09-06
申请号：US400106
申请日：1982-07-20
申请人： Tomiya Isshiki , Yasuhiko Kijima , Takayuki Watanabe
发明人： Tomiya Isshiki , Yasuhiko Kijima , Takayuki Watanabe
IPC分类号： B01J27/00 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/12 , C07C51/353 , C07C53/08 , C07C67/00
CPC分类号： C07C51/353
摘要： There is disclosed a process for producing acetic acid in which methyl formate is isomerized into acetic acid with a catalyst containing at least one of Pd, Ru and Ir, at least one compound of said metals or a mixture thereof, and a promoter of a halide compound in the presence of carbon monoxide. This process can be carried out under mild reaction conditions and acetic acid is obtained in high yield.
摘要翻译：公开了一种生产乙酸的方法，其中甲酸甲酯与含有Pd，Ru和Ir中至少一种的催化剂异构化成乙酸，至少一种所述金属或其混合物的化合物和卤化物的助催化剂化合物在一氧化碳存在下。该方法可以在温和的反应条件下进行，并以高产率获得乙酸。

7. 发明授权

US4517377A Process for producing vinyl acetate 失效
标题翻译：乙酸乙烯酯的制造方法
公开(公告)号：US4517377A
公开(公告)日：1985-05-14
申请号：US390074
申请日：1982-06-18
申请人： Tomiya Isshiki , Takanari Nawata , Yasuhiko Kijima , Akira Ito , Takayuki Watanabe
发明人： Tomiya Isshiki , Takanari Nawata , Yasuhiko Kijima , Akira Ito , Takayuki Watanabe
IPC分类号： B01J27/00 , B01J27/06 , B01J31/00 , B01J31/02 , C07B61/00 , C07C67/297 , C07C69/15
CPC分类号： C07C67/297
摘要： A process for producing vinyl acetate which comprises decomposing ethylidene diacetate in the presence of at least one compound selected from fluorides, bromides, chlorides, iodides, halogens and mixtures thereof is disclosed. According to this invention decomposition rate of ethylidene diacetate is high and selectivity to vinyl acetate is also high.
摘要翻译：公开了一种制备乙酸乙烯酯的方法，其包括在至少一种选自氟化物，溴化物，氯化物，碘化物，卤素及其混合物的化合物存在下分解亚乙基二乙酸酯。根据本发明，亚乙基二乙酸酯的分解速率高，对乙酸乙烯酯的选择性也高。

8. 发明授权

US4659865A Process for producing ethylidenediacetate 失效
标题翻译：乙二乙酸乙酯的制备方法
公开(公告)号：US4659865A
公开(公告)日：1987-04-21
申请号：US636067
申请日：1984-07-30
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takayuki Yasunaga
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takayuki Yasunaga
IPC分类号： C07C67/37 , B01J27/00 , C07B61/00 , C07C27/00 , C07C67/00 , C07C67/36 , C07C69/16 , C07C67/38
CPC分类号： C07C67/36 , C07C67/37
摘要： A process for producing ethylidenediacetate which comprises reacting methyl acetate or dimethyl ether, carbon monoxide and hydrogen in the presence of catalyst comprising as a secondary-component at least one material selected from the group consisting of, iodides and bromides and as a main component combination of (1) at least one material selected from the group consisting of nickel and nickel compounds, at least one material selected from the group consisting of cobalt and cobalt compounds under substantially anhydrous conditions is disclosed. According to the present invention synthesis of ethylidenediacetate is achieved by using a cheaper catalyst than the prior catalyst.
摘要翻译：制备亚乙基二乙酸酯的方法，其包括在催化剂存在下使乙酸甲酯或二甲醚，一氧化碳和氢气反应，所述催化剂包含作为次要组分的至少一种选自碘化物和溴化物的材料，并且作为主要组分（1）公开了在基本无水条件下选自镍和镍化合物，至少一种选自钴和钴化合物的材料中的至少一种材料。根据本发明，通过使用比现有催化剂更便宜的催化剂来实现亚乙基二乙酸酯的合成。

9. 发明授权

US4556519A Process for producing acetic anhydride 失效
标题翻译：生产乙酸酐的方法
公开(公告)号：US4556519A
公开(公告)日：1985-12-03
申请号：US568526
申请日：1984-01-06
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takao Kondo
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takao Kondo
IPC分类号： C07C51/54 , C07C51/56
CPC分类号： C07C51/54 , C07C51/56
摘要： A process for producing acetic anhydride which comprises reacting methyl acetate or dimethyl ether with carbon monoxide in the presence of a catalyst comprising (a) nickel or a nickel compound and (b) at least one halide selected from the group consisting of bromides, iodides and mixtures thereof, and together with a specific co-catalyst which is disclosed. According to this invention acetic anhydride is produced by using highly active non-expensive catalyst and co-catalyst.
摘要翻译：一种生产乙酸酐的方法，其包括使乙酸甲酯或二甲醚与一氧化碳在催化剂存在下反应，所述催化剂包含（a）镍或镍化合物和（b）至少一种选自溴化物，碘化物和并且与所公开的特定助催化剂一起。根据本发明，通过使用高活性非昂贵的催化剂和助催化剂制备乙酸酐。

10. 发明授权

US4239698A Process for preparing carboxylic acid anhydrides 失效
标题翻译：制备羧酸酐的方法
公开(公告)号：US4239698A
公开(公告)日：1980-12-16
申请号：US949853
申请日：1978-10-10
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
IPC分类号： C07C53/00 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/10 , C07C51/56 , C07C67/00 , C07C51/54
CPC分类号： C07C51/10
摘要： A process for preparing a carboxylic acid anhydride by reacting an aliphatic carboxylic acid ester or an ether with carbon monoxide in the presence of elemental nickel or a nickel compound, iodine or an iodine compound and an organic compound of a trivalent nitrogen-group element; wherein said iodine or iodine compound is selected from the following formulae (I) to (IV),RX.sub.n (I)wherein R represents a hydrogen atom or an alkyl or alkylene group, X represents an iodine or bromine atom, n represents an integer of 1 to 3, and at least one of n X's is an iodine atom,I.sub.2 or I.sub.3.sup.- (II)RCOI (III)wherein R represents an alkyl group, andMI.sub.2 (IV)wherein M represents an alkaline earth metal, and is used in an amount such that the free iodine or iodine compound not chemically combined with said nickel or nickel compound or with said organic compound of a nitrogen-group element is present in an amount of at least 0.2 mole, as elemental iodine, per mole of each of said nitrogen-group element compound and said nickel or nickel compound, and wherein the reaction is carried out in the presence of an aliphatic carboxylic acid solvent.
摘要翻译：在元素镍或镍化合物，碘或碘化合物和三价氮基元素的有机化合物存在下，使脂族羧酸酯或醚与一氧化碳反应制备羧酸酐的方法; 其中所述碘或碘化合物选自下式（I）至（IV），RXn（I）其中R表示氢原子或烷基或亚烷基，X表示碘或溴原子，n表示整数 1至3，并且n X中的至少一个为碘原子，I 2或I 3 - （II）R COI（III）其中R表示烷基，MI 2（IV）其中M表示碱土金属，并且使用其量使得不与所述镍或镍化合物或所述有机化合物与氮基元素化学结合的游离碘或碘化合物以每摩尔每摩尔至少0.2摩尔的元素碘的量存在，作为元素碘的所述氮族元素化合物和所述镍或镍化合物，并且其中所述反应在脂族羧酸溶剂的存在下进行。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式