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1. 发明授权

US6132919A Polymerized toner and production process thereof 有权
标题翻译：聚合调色剂及其制备方法
公开(公告)号：US6132919A
公开(公告)日：2000-10-17
申请号：US305635
申请日：1999-05-05
申请人： Tokudai Ogawa , Noboru Yanagida , Takahiro Takasaki , Kazuhiro Sato
发明人： Tokudai Ogawa , Noboru Yanagida , Takahiro Takasaki , Kazuhiro Sato
IPC分类号： G03G9/093 , G03G9/097 , G03G9/97
CPC分类号： G03G9/09371 , G03G9/09314 , G03G9/097
摘要： A polymerized toner of core-shell structure, comprising core particles composed of colored polymer particles, which comprise a polyfunctional ester compound formed of a trifunctional or still higher polyfunctional polyhydric alcohol and a carboxylic acid, and a colorant, and shell which is formed of a polymer having a glass transition temperature higher than that of a polymer component making up the core particles and covers each of the core particles, a production process thereof, an image forming process comprising using the polymerized toner, and an image forming apparatus containing the polymerized toner.
摘要翻译：核 - 壳结构的聚合调色剂，包含由着色聚合物颗粒组成的核心颗粒，其包含由三官能或更高级多官能多元醇和羧酸形成的多官能酯化合物，以及着色剂和壳，其由聚合物的玻璃化转变温度高于构成核心颗粒的聚合物组分的玻璃化转变温度，并覆盖每个核心颗粒，其制备方法，包括使用聚合调色剂的图像形成方法和包含聚合调色剂的成像设备。

2. 发明授权

US6033822A Process for producing polymerized toner 有权
标题翻译：生产聚合调色剂的方法
公开(公告)号：US6033822A
公开(公告)日：2000-03-07
申请号：US361614
申请日：1999-07-27
申请人： Jun Hasegawa , Tokudai Ogawa , Jun Sakai , Takahiro Takasaki , Noboru Yanagida
发明人： Jun Hasegawa , Tokudai Ogawa , Jun Sakai , Takahiro Takasaki , Noboru Yanagida
IPC分类号： G03G9/093 , G03G9/087
CPC分类号： G03G9/093 , G03G9/09321 , G03G9/09364 , G03G9/09392
摘要： Disclosed herein are a polymerized toner of core-shell structure, comprising core particles composed of colored polymer particles having a volume average particle diameter (dv) of 0.5-20 .mu.m and a ratio (dv/dp) of the volume average particle diameter (dv) to a number average particle diameter (dp) of at most 1.7, and shell which is formed of a polymer layer having an average film thickness of 0.001-0.1 .mu.m and covers each of the core particles, and a production process thereof.
摘要翻译：本文公开了核 - 壳结构的聚合调色剂，其包含由体积平均粒径（dv）为0.5-20μm的有色聚合物颗粒和体积平均粒径（dv / dp）的比（dv / dp） dv）至多为1.7的数均粒径（dp）和由平均膜厚度为0.001-0.1μm并覆盖每个核心颗粒的聚合物层形成的壳及其制备方法。

3. 发明授权

US5958640A Polymerized toner and production process thereof 失效
标题翻译：聚合调色剂及其制备方法
公开(公告)号：US5958640A
公开(公告)日：1999-09-28
申请号：US949432
申请日：1997-10-14
申请人： Jun Hasegawa , Tokudai Ogawa , Jun Sakai , Takahiro Takasaki , Noboru Yanagida
发明人： Jun Hasegawa , Tokudai Ogawa , Jun Sakai , Takahiro Takasaki , Noboru Yanagida
IPC分类号： G03G9/093
CPC分类号： G03G9/093 , G03G9/09321 , G03G9/09364 , G03G9/09392
摘要： Disclosed herein are a polymerized toner of core-shell structure, comprising core particles composed of colored polymer particles having a volume average particle diameter (dv) of 0.5-20 .mu.m and a ratio (dv/dp) of the volume average particle diameter (dv) to a number average particle diameter (dp) of at most 1.7, and shell which is formed of a polymer layer having an average film thickness of 0.001-0.1 .mu.m and covers each of the core particles, and a production process thereof.
摘要翻译：本文公开了核 - 壳结构的聚合调色剂，其包含由体积平均粒径（dv）为0.5-20μm的有色聚合物颗粒和体积平均粒径（dv / dp）的比（dv / dp） dv）至多为1.7的数均粒径（dp）和由平均膜厚度为0.001-0.1μm并覆盖每个核心颗粒的聚合物层形成的壳及其制备方法。

4. 发明申请

US20120208950A1 HYDROGENATED NORBORNENE-BASED RING-OPENING POLYMERIZATION POLYMER, RESIN COMPOSITION, AND MOLDED OBJECT 有权
公开(公告)号：US20120208950A1
公开(公告)日：2012-08-16
申请号：US13336522
申请日：2011-12-23
申请人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
发明人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
IPC分类号： C08F132/08 , C08L55/00
CPC分类号： C08G61/08 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/286 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2307/7242 , B32B2439/70 , B32B2439/80 , C08G2261/3324 , C08G2261/724 , Y10T428/1345 , Y10T428/1352 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.

5. 发明授权

US08481166B2 Hydrogenated norbornene-based ring-opening polymerization polymer, resin composition, and molded object 有权
标题翻译：氢化降冰片烯类开环聚合物，树脂组合物和成型体
公开(公告)号：US08481166B2
公开(公告)日：2013-07-09
申请号：US13336522
申请日：2011-12-23
申请人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
发明人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
IPC分类号： B32B27/32 , C08F32/08
CPC分类号： C08G61/08 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/286 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2307/7242 , B32B2439/70 , B32B2439/80 , C08G2261/3324 , C08G2261/724 , Y10T428/1345 , Y10T428/1352 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
摘要翻译：通过2-取代的降冰片烯的开环聚合得到的开环聚合物的80％以上的主链碳 - 碳双键进行氢化而得到的氢化降冰片烯开环聚合物。氢化降冰片烯开环聚合物的重均分子量通过凝胶渗透色谱法（GPC）测定为50,000〜200,000，分子量分布为1.5〜10.0，熔点为110〜145℃。氢化降冰片烯环通过将通过2-降冰片烯与含取代基的降冰片烯单体的开环共聚而得到的开环聚合物的碳 - 碳双键的80％以上氢化得到的开环聚合物，其中，重复单元（A）衍生自所有重复单元的2-降冰片烯的比例为90〜99重量％，相对于所有重复单元衍生自含取代基的降冰片烯单体的重复单元（B）的比例为1〜10重量％。树脂组合物和成型材料。

6. 发明授权

US5741618A Process for producing polymer toner 失效
标题翻译：生产聚合物调色剂的方法
公开(公告)号：US5741618A
公开(公告)日：1998-04-21
申请号：US728475
申请日：1996-10-10
申请人： Kazunori Shigemori , Tokudai Ogawa
发明人： Kazunori Shigemori , Tokudai Ogawa
IPC分类号： G03G9/08 , G03G9/087 , G03G5/00
CPC分类号： G03G9/0806 , G03G9/08702 , G03G9/08711
摘要： A process for producing a polymer toner comprises the steps of pouring a polymerizable monomer composition containing at least a polymerizable monomer and a colorant, but containing no oil-soluble polymerization initiator into an aqueous dispersion medium containing a dispersing agent; adding an oil-soluble polymerization initiator to the polymerizable monomer composition while stirring the composition to form primary droplets thereof, thereby bringing the droplets of the polymerizable monomer composition into contact with droplets of the oil-soluble polymerization initiator to form droplets of a polymerizable monomer composition containing the oil-soluble polymerization initiator; further continuing the stirring to form secondary droplets having desired droplet sizes; and then conducting suspension polymerization of the polymerizable monomer composition.
摘要翻译：制备聚合物调色剂的方法包括将含有至少可聚合单体和着色剂但不含油溶性聚合引发剂的可聚合单体组合物倒入含有分散剂的水性分散介质中的步骤; 在搅拌组合物的同时，将可溶性聚合引发剂加入到可聚合单体组合物中以形成其初级液滴，从而使可聚合单体组合物的液滴与油溶性聚合引发剂的液滴接触，形成可聚合单体组合物含有油溶性聚合引发剂; 进一步继续搅拌以形成具有所需液滴尺寸的二次液滴; 然后进行可聚合单体组合物的悬浮聚合。

7. 发明申请

US20100076396A1 HYDROGENATED NORBORNENE-BASED RING-OPENING POLYMERIZATION POLYMER, RESIN COMPOSITION, AND MOLDED OBJECT 审中-公开
标题翻译：基于NORBORNENE的开环聚合聚合物，树脂组合物和模塑对象
公开(公告)号：US20100076396A1
公开(公告)日：2010-03-25
申请号：US12439360
申请日：2007-08-31
申请人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
发明人： Haruhiko Takahashi , Teiji Kohara , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
IPC分类号： A61J1/10 , C08F132/08 , C08L55/00 , B32B27/08 , B32B1/00
CPC分类号： C08G61/08 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/286 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2307/7242 , B32B2439/70 , B32B2439/80 , C08G2261/3324 , C08G2261/724 , Y10T428/1345 , Y10T428/1352 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening polymerization of 2-norbornene is disclosed. The hydrogenated norbornene ring-open polymer has a weight average molecular weight (Mw) determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution (Mw/Mn) of 1.5 to 10.0, and a melting point of 110 to 145° C. Also disclosed is a hydrogenated norbornene ring-open polymer (hydrogenated polymer) obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. The hydrogenated ring-open polymer has a melting point of 110 to 145° C. A resin composition and a molding material containing these hydrogenated polymers, a molded article, a resin film, a resin sheet, a multilayer laminate, a packing material, a molded article for medical supplies, a blister molding sheet, a blister molded article, and a multilayer blow-molded container made of these hydrogenated polymers are also disclosed.
摘要翻译：公开了通过2-取代降冰片烯的开环聚合获得的开环聚合物的80％以上的主链碳 - 碳双键氢化得到的氢化降冰片烯开环聚合物。氢化降冰片烯开环聚合物通过凝胶渗透色谱法（GPC）测定的重均分子量（Mw）为50,000〜200,000，分子量分布（Mw / Mn）为1.5〜10.0，熔点为110〜 145℃。还公开了通过将通过2-降冰片烯的开环共聚获得的开环聚合物的80％以上的碳 - 碳双键氢化得到的氢化降冰片烯开环聚合物（氢化聚合物）和含有取代基的降冰片烯单体，其中，来自2-降冰片烯的重复单元（A）相对于所有重复单元的比例为90〜99重量％，衍生自取代基的降冰片烯的重复单元（B）含有降冰片烯单体相对于所有重复单元为1〜10重量％。氢化开环聚合物的熔点为110〜145℃。树脂组合物和含有这些氢化聚合物的成型材料，模塑制品，树脂膜，树脂片，多层压板，包装材料，还公开了用于医疗用品的模制品，泡罩成型片，泡罩模制品和由这些氢化聚合物制成的多层吹塑容器。

8. 发明授权

US06720122B1 Toner for developing static charge image and method for preparation thereof 有权
标题翻译：用于开发静电荷图像的调色剂及其制备方法
公开(公告)号：US06720122B1
公开(公告)日：2004-04-13
申请号：US09926829
申请日：2002-04-01
申请人： Tokudai Ogawa
发明人： Tokudai Ogawa
IPC分类号： G03G9097
CPC分类号： G03G9/08791 , G03G9/08 , G03G9/08755 , G03G9/08782 , G03G9/09733
摘要： A toner for development of electrostatic images, comprising colored particles containing at least a binder resin, a colorant and a softening agent, wherein the softening agent is an organic compound having a molecular weight of at least 1,000, a solubility of at least 5 g in 100 g of styrene as measured at 25° C., and an acid value of at most 10 mg KOH/g. The toner is excellent in fixing ability, shelf stability and flowability and permits forming images having high image quality. A production process thereof is also provided.
摘要翻译：用于显影静电图像的调色剂，包含至少含有粘合剂树脂，着色剂和软化剂的着色颗粒，其中所述软化剂是分子量至少为1,000的有机化合物，至少5g的溶解度在25℃下测量的苯乙烯100g，酸值至多10mg KOH / g。调色剂的定影能力，保存稳定性和流动性优异，并且可以形成具有高图像质量的图像。还提供了其生产方法。

9. 发明申请

US20120165461A1 HYDROGENATED NORBORNENE-BASED RING-OPENING POLYMERIZATION POLYMER, RESIN COMPOSITION, AND MOLDED OBJECT 有权
标题翻译：基于NORBORNENE的开环聚合聚合物，树脂组合物和模塑对象
公开(公告)号：US20120165461A1
公开(公告)日：2012-06-28
申请号：US13336494
申请日：2011-12-23
申请人： Haruhiko TAKAHASHI , Teiji KOHARA , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
发明人： Haruhiko TAKAHASHI , Teiji KOHARA , Nobuhiro Kudo , Koichi Ikeda , Tokudai Ogawa , Takeshi Hirata
IPC分类号： C08L55/00 , C08F132/08
CPC分类号： C08G61/08 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/286 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/558 , B32B2307/714 , B32B2307/7242 , B32B2439/70 , B32B2439/80 , C08G2261/3324 , C08G2261/724 , Y10T428/1345 , Y10T428/1352 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
摘要翻译：通过2-取代的降冰片烯的开环聚合得到的开环聚合物的80％以上的主链碳 - 碳双键进行氢化而得到的氢化降冰片烯开环聚合物。氢化降冰片烯开环聚合物的重均分子量通过凝胶渗透色谱法（GPC）测定为50,000〜200,000，分子量分布为1.5〜10.0，熔点为110〜145℃。氢化降冰片烯环通过将通过2-降冰片烯与含取代基的降冰片烯单体的开环共聚而得到的开环聚合物的碳 - 碳双键的80％以上氢化得到的开环聚合物，其中，重复单元（A）衍生自所有重复单元的2-降冰片烯的比例为90〜99重量％，相对于所有重复单元衍生自含取代基的降冰片烯单体的重复单元（B）的比例为1〜10重量％。树脂组合物和成型材料。

10. 发明申请

US20100092712A1 POLYMER COMPOSITION AND USE THEREOF 失效
标题翻译：聚合物组合物及其用途
公开(公告)号：US20100092712A1
公开(公告)日：2010-04-15
申请号：US12570185
申请日：2009-09-30
申请人： Tokudai Ogawa , Hiroaki Matsuda
发明人： Tokudai Ogawa , Hiroaki Matsuda
IPC分类号： C08L45/00 , B32B1/00
CPC分类号： C08G61/08 , A61J1/10 , C08G2261/3324 , C08G2261/3325 , C08G2261/612 , C08L45/00 , C08L65/00 , C08L2205/02 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/139 , Y10T428/1397 , C08L2666/04
摘要： A polymer composition includes (1) a crystalline norbornene-based polymer and (2) an amorphous alicyclic structure-containing polymer in a weight ratio of 90:10 to 50:50, the crystalline norbornene-based polymer (1) having a melting point of 110 to 145° C., an Mw measured by gel permeation chromatography of 50,000 to 200,000, and a ratio Mw/Mn of 1.5 to 10.0, and obtained by ring-opening polymerization of a polymerizable monomer mixture (1) containing 90 to 100 wt % of 2-norbornene and 0 to 10 wt % of a substituent-containing norbornene monomer, and hydrogenating the resulting polymer, and the amorphous alicyclic structure-containing polymer (2) having a Tg of 50° C. or more and not having a melting point, and obtained by polymerization of a polymerizable monomer mixture (2) containing a 2-norbornene compound and a dicyclopentadiene compound in an amount of 50 wt % or more and less than 90 wt % in total. A film obtained by molding the polymer composition has a steam permeability of 0.40 g/m2·day or less and a haze value of 20% or less when the film has a thickness of 100 μm. A medical container is obtained by molding the polymer composition.
摘要翻译：聚合物组合物包括（1）结晶降冰片烯系聚合物和（2）重量比为90:10〜50:50的无定形脂环结构聚合物，结晶性降冰片烯系聚合物（1）的熔点为110〜145℃，通过凝胶渗透色谱法测定的Mw为50,000〜200,000，Mw / Mn为1.5〜10.0的Mw，通过含有90〜100的聚合性单体混合物（1）的开环聚合得到重量％的2-降冰片烯和0〜10重量％的含取代基的降冰片烯单体，和氢化所得聚合物，以及Tg为50℃以上且不具有的无定形脂环式结构的聚合物（2）熔点，通过聚合含有总计为50重量％以上且小于90重量％的2-降冰片烯化合物和二环戊二烯化合物的聚合性单体混合物（2）而获得。通过模塑聚合物组合物获得的薄膜的厚度为100μm时，透水度为0.40g / m 2·天以下，雾度值为20％以下。通过模制聚合物组合物获得医疗容器。

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