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1. 发明授权

US06210657B1 Use of isoindolinone derivatives as stabilizers for organic materials 失效
标题翻译：异吲哚啉酮衍生物作为有机材料的稳定剂的使用
公开(公告)号：US06210657B1
公开(公告)日：2001-04-03
申请号：US09207624
申请日：1998-12-09
申请人： Thorsten Habeck , Sylke Haremza , Hubert Trauth , Volker Schehlmann , Horst Westenfelder
发明人： Thorsten Habeck , Sylke Haremza , Hubert Trauth , Volker Schehlmann , Horst Westenfelder
IPC分类号： A61K742
CPC分类号： A61K31/4035 , C08K5/3417 , C09D7/48 , C09K15/30 , Y10S514/844 , Y10S514/97 , Y10S514/972
摘要： Isoindolinone derivatives of the formula I, in which the variables have the following meanings: R1 is hydrogen, COOR4, COR4, CONR4R5, CN, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, aryl or heteroaryl, substituted or unsubstituted; R1 and R2 together are C7-C10-bicycloalkyl or C7-C10-bicycloalkenyl; R3 is hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl or heteroaryl, substituted or unsubstituted, substituents which confer solubility in water, selected from the group consisting of carboxylate, sulfonate or ammonium radicals; R4 and R5 independently of one another are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl; aryl or heteroaryl, substituted or unsubstituted; are used as stabilizers for organic materials.
摘要翻译：式I的异吲哚啉酮衍生物，其中变量具有以下含义：R1是氢，COOR4，COR4，CONR4R5，CN，C1-C20-烷基，C2-C10-烯基，C3-C10-环烷基，C3-C10- 环烯基，芳基或杂芳基，取代或未取代的; R1和R2一起是C7-C10-双环烷基或C7-C10-双环烯基; R3是氢，C1-C20-烷基，C2-C10-烯基，C3-C10-环烷基，C3 -C 10 - 环烯基，C 1 -C 12 - 烷氧基，C 1 -C 20 - 烷氧基羰基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，芳基或杂芳基，取代或未取代的赋予水溶性的取代基，羧酸酯，磺酸酯或铵基; R 4和R 5彼此独立地是氢，C 1 -C 20 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 3 -C 10 - 环烯基; 芳基或杂芳基，取代或未取代的;被用作有机材料的稳定剂。

2. 发明授权

US06238649B1 Cosmetic and pharmaceutical preparations containing photostable UV filters 有权
标题翻译：含有光稳定紫外线过滤器的化妆品和药物制剂
公开(公告)号：US06238649B1
公开(公告)日：2001-05-29
申请号：US09133173
申请日：1998-08-13
申请人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
发明人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
IPC分类号： A61K742
CPC分类号： C07C235/34 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/42 , A61K31/12 , A61K31/122 , A61K31/216 , A61K31/277 , A61K2800/52 , A61Q1/04 , A61Q17/04 , C07C69/618 , C07C233/11
摘要： 4,4-Diarylbutadienes of the formula I, where the variables have the meanings explained in the description, are used as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：式I中的4,4-二芳基丁二烯，其中变量具有说明书中解释的含义，用作化妆品和药物制剂中的光稳定性UV过滤器，以单独或与化合物一起保护人皮肤或人类头发免受太阳光线其在UV区域中吸收并且本身已知化妆品和药物制剂。

3. 发明授权

US6090374A Cosmetic and pharmaceutical preparations comprising photostable UV filters 失效
标题翻译：包含光稳定型紫外线过滤器的化妆品和药物制剂
公开(公告)号：US6090374A
公开(公告)日：2000-07-18
申请号：US172672
申请日：1998-10-15
申请人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wunsch
发明人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wunsch
IPC分类号： A61K8/00 , A61K8/40 , A61K31/00 , A61P17/00 , A61P17/16 , A61Q1/04 , A61Q17/04 , A61K7/42 , A61K7/00 , A61K7/44
CPC分类号： A61Q17/04 , A61K8/40 , A61Q1/04 , A61K2800/52
摘要： The use of substituted .alpha.-methylstyrene derivatives of the formula I, ##STR1## where the variables have the following meanings: R.sup.1 C.sub.4 -C.sub.10 -alkoxy, C.sub.1 -C.sub.12 -alkylamino, C.sub.1 -C.sub.12 -dialkylamino, substituents which confer solubility in water and which are selected from the group consisting of carboxylate, sulfonate or ammonium residues;R.sup.2 hydrogen, C.sub.2 -C.sub.10 -alkyl, C.sub.1 -C.sub.12 -alkoxy;R.sup.3 COOR.sup.5, COR.sup.5, CONR.sup.5 R.sup.6, CN;R.sup.4 COOR.sup.5, COR.sup.5, CONR.sup.5 R.sup.6, CN; where the substituents R.sup.3 and R.sup.4 are identical in each case;R.sup.5 andR.sup.6 independently of one another hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.10 -alkenyl, C.sub.3 -C.sub.10 -cycloalkyl, C.sub.3 -C.sub.10 -cycloalkenyl, aryl, hetaryl, unsubstituted or substituted;as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays, alone or together with UV-absorbing compounds known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用式I的取代的α-甲基苯乙烯衍生物，其中变量具有以下含义：R 1 C 4 -C 10 - 烷氧基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，赋予在水中溶解度并且被选择的取代基由羧酸盐，磺酸盐或铵残基组成的组; R2氢，C2-C10-烷基，C1-C12-烷氧基; R3 COOR5，COR5，CONR5R6，CN; R4 COOR5，COR5，CONR5R6，CN; 其中取代基R 3和R 4在每种情况下相同; R 5和R 6彼此独立地为氢，C 1 -C 12 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 3 -C 10 - 环烯基，芳基，杂芳基，未取代或取代的; 作为化妆品和药物制剂中的光稳定紫外线过滤器，用于保护人体皮肤或人体毛发免受太阳光线的照射，或者与本身已知的用于化妆品和药物制剂的紫外线吸收化合物一起使用。

4. 发明授权

US06545174B2 Cosmetic and pharmaceutical preparations containing photostable UV filters 有权
标题翻译：含有光稳定紫外线过滤器的化妆品和药物制剂
公开(公告)号：US06545174B2
公开(公告)日：2003-04-08
申请号：US09765624
申请日：2001-01-22
申请人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
发明人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
IPC分类号： C07C6976
CPC分类号： C07C235/34 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/42 , A61K31/12 , A61K31/122 , A61K31/216 , A61K31/277 , A61K2800/52 , A61Q1/04 , A61Q17/04 , C07C69/618 , C07C233/11
摘要： 4,4-Diarylbutadienes of the formula I, where the diene system has the Z,Z; Z,E; E,Z or E,E configuration or a mixture thereof, and where the variables independently of one another have the following meanings: R1 and R2 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl, hetaryl, unsubstituted or substituted, substituents which confer solubility in water and are selected from the group consisting of carboxylate, sulfonate, or ammonium residues; R3 is COOR5, CONR5R6; R4 is COOR6, CONR5R6; R5 and R6 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C7-C10-bicycloalkyl, C3-C10-cycloalkenyl, C7-C10-bicycloalkenyl, aryl, hetaryl, unsubstituted or substituted; n is 1 to 3; and R3 and R4 are not COOCH3 when R1 and R2 are hydrogen, are used as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：式I的4,4-二芳基丁二烯，其中二烯体系具有Z，Z; Z，E; E，Z或E，E构型或其混合物，其中彼此独立的变量具有以下含义：R 1和R 2为氢，C 1 -C 20 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基， C 3 -C 10 - 环烯基，C 1 -C 12 - 烷氧基，C 1 -C 20烷氧基羰基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，芳基，杂芳基，未取代或取代的取代基，其赋予在水中的溶解性并且选自由羧酸盐，磺酸盐或铵残基组成; R3为COOR5，CONR5R6; R4是COOR6，CONR5R6; R 5和R 6是氢，C 1 -C 20烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 7 -C 10 - 双环烷基，C 3 -C 10 - 环烯基，C 7 -C 10 - 双环烯基，芳基，杂芳基，未取代或取代的; n为1〜3; 当R 1和R 2为氢时，R 3和R 4不是COOCH 3，用作化妆品和药物制剂中的光稳定性UV过滤剂，以保护人皮肤或人类头发免受太阳光线的影响，单独或与在UV区域吸收的化合物一起，本身就是化妆品和药物制剂。

5. 发明授权

US06409995B1 Use of amino-substituted hydroxybenzophenones as photostable UV filters in cosmetic and pharmaceutical preparations 有权
标题翻译：在化妆品和药物制剂中使用氨基取代的羟基二苯甲酮作为光稳定的紫外线过滤器
公开(公告)号：US06409995B1
公开(公告)日：2002-06-25
申请号：US09553897
申请日：2000-04-20
申请人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder , Sylke Haremza , Thorsten Bach , Anja Spiegel
发明人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder , Sylke Haremza , Thorsten Bach , Anja Spiegel
IPC分类号： C07D49310
CPC分类号： C07D295/112 , A61K8/411 , A61K8/445 , A61K8/4913 , A61K2800/52 , A61Q1/04 , A61Q17/04 , C07C225/22 , C07C229/52 , C07C2601/14
摘要： Use of amino-substituted hydroxybenzophenones of the formula I in which the variables have the meanings explained in the description, as photostable UV filters in cosmetic and pharmaceutical preparations for protecting human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用式Iin的氨基取代的羟基二苯甲酮，其变量具有在说明书中解释的含义，作为用于保护人类皮肤或人类头发免受太阳光线的化妆品和药物制剂中的光稳定性UV过滤器，单独或与吸收的化合物一起使用 UV区域，并且本身已知化妆品和药物制剂。

6. 发明授权

US06060042A Use of cholesteric, liquid-crystalline compositions as UV filters in cosmetic and pharmaceutical preparations 失效
标题翻译：在化妆品和药物制剂中使用胆固醇，液晶组合物作为UV过滤器
公开(公告)号：US06060042A
公开(公告)日：2000-05-09
申请号：US324712
申请日：1999-06-03
申请人： Peter Schuhmacher , Norbert Schneider , Horst Westenfelder , Sylke Haremza , Thorsten Habeck , Frank Meyer
发明人： Peter Schuhmacher , Norbert Schneider , Horst Westenfelder , Sylke Haremza , Thorsten Habeck , Frank Meyer
IPC分类号： A61K8/00 , A61K8/02 , A61K8/23 , A61K8/25 , A61K8/29 , A61K8/31 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/37 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/73 , A61K8/86 , A61K8/89 , A61K8/97 , A61K8/98 , A61K31/255 , A61K31/34 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q1/10 , A61Q5/00 , A61Q17/04 , A61Q19/00 , C09B67/20 , C09C3/08 , C09K3/00 , A61K7/42 , A61K7/00 , A61K7/44
CPC分类号： A61K8/0295 , A61K8/4973 , A61Q17/04 , A61Q19/00 , A61K2800/52 , A61Q19/001
摘要： The use of cholesteric, liquid-crystalline compositions comprisinga) at least one chiral, liquid-crystalline, polymerizable monomer of the formula I,[Z.sup.1 -Y.sup.1 -(A.sup.1).sub.m -Y.sup.2 -M.sup.1 -Y.sup.3 -].sub.n -XI by means of which a cholesteric, liquid-crystalline phase with a pitch of less than 450 nm can be obtained, orb) a mixture ofb.sub.1) at least one achiral, liquid-crystalline, polymerizable monomer of the formula IIZ.sup.2 -Y.sup.4 -(A.sup.2)-.sub.o -Y.sup.5 -M.sup.2 -Y.sup.6 -(A.sup.3).sub.p -Y.sup.7 -Z.sup.3 lI andb.sub.2) at least one chiral additive by means of which a cholesteric, liquid-crystalline phase with a pitch of less than 450 nm can be obtained,where the variables are as defined in the description, as UV filters in cosmetic and pharmaceutical preparations for protecting the human skin or human hair against sunlight, alone or together with UV-absorbent compounds which are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用胆甾型液晶组合物，其包含a）至少一种式I的手性，液晶可聚合单体[Z1-Y1-（A1）m-Y2-M1-Y3-] n-XI，通过方法其中可以获得具有小于450nm的间距的胆甾型液晶相，或b）b1）至少一种式IIZ2-Y4-（A2）的非手性，液晶的可聚合单体的混合物， -o-Y5-M2-Y6-（A3）p-Y7-Z3I1和b2）至少一种手性添加剂，借此可以获得具有小于450nm的间距的胆甾醇型液晶相，其中变量如说明书中所定义的，作为用于保护人类皮肤或人类头发免受阳光照射的化妆品和药物制剂中的紫外线过滤器，单独或与化妆品和药物制剂本身已知的紫外线吸收剂化合物一起使用。

7. 发明授权

US06214929B1 Stabilized polymer dispersions or polymer solutions, and prepared polymers obtainable therefrom 失效
标题翻译：稳定的聚合物分散体或聚合物溶液，以及由其获得的制备的聚合物
公开(公告)号：US06214929B1
公开(公告)日：2001-04-10
申请号：US09265704
申请日：1999-03-10
申请人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Joachim Pakusch , Heinrich Sack
发明人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Joachim Pakusch , Heinrich Sack
IPC分类号： C08K500
CPC分类号： C08K5/005 , C09D7/48 , C09J11/06
摘要： A polymer is obtained by removing the medium from a polymer dispersion or polymer solution containing at least one polymeric phase and at least one stabilizer suitable to protect against the damaging effect of light, heat and/or oxidation.
摘要翻译：通过从包含至少一个聚合物相和至少一种适于防止光，热和/或氧化的破坏作用的至少一种稳定剂的聚合物分散体或聚合物溶液中除去介质来获得聚合物。

8. 发明授权

US06908956B2 Stabilizer composition 失效
标题翻译：稳定剂组成
公开(公告)号：US06908956B2
公开(公告)日：2005-06-21
申请号：US10181439
申请日：2001-01-31
申请人： Heinz Friedrich Sutoris , Sylke Haremza , Hubert Trauth , Erik Hofmann , Manfred Appel
发明人： Heinz Friedrich Sutoris , Sylke Haremza , Hubert Trauth , Erik Hofmann , Manfred Appel
IPC分类号： C08K5/00 , C08K5/34 , C08K5/3435 , C08K5/56 , C08L23/00 , C08L25/04 , C08L101/00 , C09K15/20 , C09K15/22 , C09K15/30 , C09K15/32 , C08K5/357 , C08K5/3415 , C08K5/3462 , C08K5/3477 , C08K5/3492
CPC分类号： C08K5/0091 , C08K5/34 , C08K5/3435 , C09K15/30 , C09K15/326
摘要： A description is given of a stabilizer composition comprising A) at least one nitrogen compound having a molecular weight of at least 150, selected from a secondary amine in which all substituents positioned α to the amine nitrogen atom are different than hydrogen, or, derived from the secondary amine, a tertiary amine, hydroxylamine, alkoxyamine or amide; and B) at least one iron compound. The stabilizer composition optionally comprises nitroxyl radicals. It is suitable for stabilizing nonliving organic material, especially polyolefins or homopolymers or copolymers of styrene, against the effects of light, heat or oxygen.
摘要翻译：给出了一种稳定剂组合物的描述，其包括A）至少一种分子量至少为150的氮化合物，其选自仲胺，其中所有位于胺氮原子的α-取代基不同于氢，或衍生自仲胺，叔胺，羟胺，烷氧基胺或酰胺; 和B）至少一种铁化合物。稳定剂组合物任选地包含硝酰基。适用于稳定非活性有机材料，尤其是聚苯乙烯的聚烯烃或苯乙烯的均聚物或共聚物与光，热或氧的作用。

9. 发明授权

US06737527B2 4-formylamino-N-methylpiperidine derivatives, the use thereof as stabilizers and organic material stabilized therewith 有权
标题翻译： 4-甲酰氨基-N-甲基哌啶衍生物，其作为稳定剂的用途和用其稳定的有机物质
公开(公告)号：US06737527B2
公开(公告)日：2004-05-18
申请号：US10239213
申请日：2002-09-27
申请人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Alexander Aumüller
发明人： Sylke Haremza , Jürgen Krockenberger , Manfred Appel , Hubert Trauth , Alexander Aumüller
IPC分类号： C07D21158
CPC分类号： C07D211/58 , C08K5/3435 , C09D7/48
摘要： The present invention relates to 4-formylamino-N-methylpiperidine derivatives of the formula (I) where the variables are as defined in the Description, to a process for preparing these piperidine derivatives, to the use of these piperidine derivatives of the invention, or prepared according to the invention, for stabilizing organic material, in particular for stabilizing plastics or coating materials, and also to the use of these piperidine derivatives of the invention, or prepared according to the invention, as light stabilizers or stabilizers for wood surfaces. The present invention further relates to stabilized organic material which comprises these piperidine derivatives of the invention or prepared according to the invention.
摘要翻译：本发明涉及式（I）的4-甲酰基氨基-N-甲基哌啶衍生物，其中变量如说明书中所定义，涉及制备这些哌啶衍生物的方法，使用本发明的这些哌啶衍生物，或根据本发明制备的，用于稳定有机材料，特别是用于稳定塑料或涂层材料，以及本发明的这些哌啶衍生物或根据本发明制备的用作木材表面的光稳定剂或稳定剂的用途。本发明还涉及包含本发明的或根据本发明制备的这些哌啶衍生物的稳定的有机材料。

10. 发明申请

US20100160502A1 STABILIZER MIXTURE 审中-公开
标题翻译：稳定剂混合物
公开(公告)号：US20100160502A1
公开(公告)日：2010-06-24
申请号：US12160724
申请日：2007-01-12
申请人： Simon Schambony , Alban Glaser , Hubert Trauth , Manfred Appel , Sylke Haremza
发明人： Simon Schambony , Alban Glaser , Hubert Trauth , Manfred Appel , Sylke Haremza
IPC分类号： C08K5/3435
CPC分类号： C08K5/3435 , C07B63/04 , C07D211/58 , C08K5/34 , C08K2201/014 , C08L23/12 , C08L2201/08 , C09D7/48 , C09K15/20 , C09K15/30
摘要： Suitable stabilizers for organic material are a mixture comprising A. at least one oligomeric compound, comprising repeat units of the formula (I), in which the meanings of the symbols are as follows: R1 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5-C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula —CR′═CH—CO—OR″, where R′ is hydrogen, C1-C6-alkyl or a radical of the formula —CO—OR″, and R″ is C1-C18-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl, or tolyl; R2 is a mixture composed of C14-C28-alkyl groups, where two of these alkyl groups whose number of carbon atoms is not permitted to differ by more than two respectively make up at least 30% of this mixture; R3 and R4, independently of one another, are C1-C6-alkyl; and B. at least one compound of the formula (II) or (III) where the meanings of the symbols and indices are as follows: n and m, independently of one another, are a natural number from 2 to 22, and R1, R3 and R4, independently of one another, have the meanings given in formula (I).
摘要翻译：用于有机材料的合适的稳定剂是包含A.至少一种低聚化合物的混合物，其包含式（I）的重复单元，其中符号的含义如下：R 1是氢，C 1 -C 6 - 烷基，甲酰基， C 2 -C 6 - 烷酰基，C 1 -C 12 - 烷氧基，C 5 -C 6 - 环烷氧基，氰基甲基，2-羟基乙基，苄基或式-CR'≡CH-CO-OR的基团，其中R'是氢，C1- C6烷基或式-CO-OR基团，R“为C1-C18-烷基，C5-C8-环烷基，C7-C18-芳烷基，苯基或甲苯基; R2是由C14-C28-烷基组成的混合物，其中不允许两个以上碳原子数不同的这些烷基中的两个分别构成该混合物的至少30％ R 3和R 4彼此独立地为C 1 -C 6 - 烷基; 和B.至少一种式（II）或（III）的化合物，其中符号和指数的含义如下：n和m彼此独立地是2至22的自然数，并且R 1， R 3和R 4彼此独立地具有式（I）中给出的含义。

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