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1. 发明授权

US07683131B2 Molding material containing a matting agent 有权
标题翻译：含有消光剂的成型材料
公开(公告)号：US07683131B2
公开(公告)日：2010-03-23
申请号：US10579843
申请日：2004-09-15
申请人： Thorsten Goldacker , Andreas Spiess , Reiner Mueller , Klaus Schultes , Uwe Numrich
发明人： Thorsten Goldacker , Andreas Spiess , Reiner Mueller , Klaus Schultes , Uwe Numrich
IPC分类号： C08J5/18 , C08L33/12 , C08L51/00 , C08L101/00 , C08L33/00 , C08F265/04 , C08F265/06
CPC分类号： C08L51/003 , C08F265/04 , C08F265/06 , C08F279/02 , C08L33/12 , C08L35/06 , C08L55/02 , C08L101/00 , C08L2205/22 , C08L2666/02 , C08L2666/04
摘要： The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.
摘要翻译：本发明涉及一种模塑组合物，其包含a）50-99.9重量％的由热塑性聚合物组成的基质和b）0.1至50重量％的分散在（甲基）丙烯酸酯共聚物形式的消光剂在基质中，其特征在于，所述消光剂是已经从下列单体制备的，B1）为50〜95重量％的甲基丙烯酸甲酯b2的）从5至50％（重量）C 1 -C的（甲基）丙烯酸酯共聚物丙烯酸C 6 - 烷基酯b 3）0.01至小于0.5重量％的具有两个或更多个能够进行自由基聚合的烯键式不饱和基团的交联单体和/或接枝交联剂，b4）0至20重量％一种或多种能够进行自由基聚合的其它非交联烯键式不饱和单体，其中b1）和b2）和b3）和/或b4）的总体含量为100％（重量），玻璃消光剂的转变温度Tmg的是至少20 C.

2. 发明申请

US20070066708A1 Molding material containing a matting agent 有权
标题翻译：含有消光剂的成型材料
公开(公告)号：US20070066708A1
公开(公告)日：2007-03-22
申请号：US10579843
申请日：2004-09-15
申请人： Thorsten Goldacker , Andreas Spiess , Reiner Mueller , Klaus Schultes , Uwe Numrich
发明人： Thorsten Goldacker , Andreas Spiess , Reiner Mueller , Klaus Schultes , Uwe Numrich
IPC分类号： C09D11/00
CPC分类号： C08L51/003 , C08F265/04 , C08F265/06 , C08F279/02 , C08L33/12 , C08L35/06 , C08L55/02 , C08L101/00 , C08L2205/22 , C08L2666/02 , C08L2666/04
摘要： The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.
摘要翻译：本发明涉及一种模塑组合物，其包含a）50-99.9重量％的由热塑性聚合物组成的基质和b）0.1至50重量％的分散在（甲基）丙烯酸酯共聚物形式的消光剂在基质中，其特征在于消光剂是由以下单体制备的（甲基）丙烯酸酯共聚物，b1）50-95重量％的甲基丙烯酸甲酯b2）5-50重量％烷基丙烯酸酯b3）0.01至小于0.5重量％的交联单体和/或具有两个或更多个烯属不饱和基团的接枝交联剂的自由基聚合，b4）0至20重量％的一种或多种能够进行自由基聚合的其它非交联烯键式不饱和单体，其中组分b1）和b2的整体），并且在适当的情况下， b3）和/或b4）给出100重量％，玻璃化转变温度T 消光剂至少为20℃

3. 发明授权

US08088847B2 PMMA film featuring particularly great weather resistance and great UV protection 有权
标题翻译： PMMA薄膜具有特别出色的耐候性和极好的紫外线防护性能
公开(公告)号：US08088847B2
公开(公告)日：2012-01-03
申请号：US12092276
申请日：2006-12-22
申请人： Uwe Numrich , Achim Neuhaeuser , Thorsten Goldacker , Thomas Arndt , Alexander Laschitsch , Guenther Dickhaut-Bayer , Christoph Krohmer
发明人： Uwe Numrich , Achim Neuhaeuser , Thorsten Goldacker , Thomas Arndt , Alexander Laschitsch , Guenther Dickhaut-Bayer , Christoph Krohmer
IPC分类号： C08L33/12 , C08L33/04 , C08K5/23 , B32B37/00 , B05D3/12
CPC分类号： C08J7/047 , C08J2327/06 , C08J2433/00 , C08K5/3475 , Y10T156/10 , C08L33/12
摘要： The invention relates to a novel UV-protective and weather-resistant package for surface protecting films for polyvinyl chloride window profiles made of poly(meth)acrylate. Matrix plastics having great molecular weights are used in order to obtain great weather resistance of the surface protecting films.
摘要翻译：本发明涉及由聚（甲基）丙烯酸酯制成的聚氯乙烯窗型材的表面保护膜的新型紫外线防护和耐候性包装。使用具有大分子量的基质塑料以获得表面保护膜的极好的耐候性。

4. 发明申请

US20080281023A1 Pmma Film Featuring Particularly Great Weather Resistance and Great Uv Protection 有权
标题翻译： Pmma电影具有非常好的耐候性和伟大的Uv保护
公开(公告)号：US20080281023A1
公开(公告)日：2008-11-13
申请号：US12092276
申请日：2006-12-22
申请人： Uwe Numrich , Achim Neuhaeuser , Thorsten Goldacker , Thomas Arndt , Alexander Laschitsch , Guenther Dickhaut-Bayer , Christoph Krohmer
发明人： Uwe Numrich , Achim Neuhaeuser , Thorsten Goldacker , Thomas Arndt , Alexander Laschitsch , Guenther Dickhaut-Bayer , Christoph Krohmer
IPC分类号： C08L33/12 , C08L33/04 , C08K5/23 , B32B37/00 , B05D3/12
CPC分类号： C08J7/047 , C08J2327/06 , C08J2433/00 , C08K5/3475 , Y10T156/10 , C08L33/12
摘要： The invention relates to a novel UV-protective and weather-resistant package for surface protecting films for polyvinyl chloride window profiles made of poly(meth)acrylate. Matrix plastics having great molecular weights are used in order to obtain great weather resistance of the surface protecting films.
摘要翻译：本发明涉及由聚（甲基）丙烯酸酯制成的聚氯乙烯窗型材的表面保护膜的新型紫外线防护和耐候性包装。使用具有大分子量的基质塑料以获得表面保护膜的极好的耐候性。

5. 发明申请

US20130136910A1 PMMA/PVDF FILM WITH PARTICULARLY HIGH WEATHERING STABILITY AND HIGH UV PROTECTIVE ACTION 审中-公开
标题翻译： PMMA / PVDF膜具有特别高的天气稳定性和高紫外线保护作用
公开(公告)号：US20130136910A1
公开(公告)日：2013-05-30
申请号：US13749170
申请日：2013-01-24
申请人： Uwe NUMRICH , Achim Neuhaeuser , Thomas Arndt , Thorsten Goldacker , Alexander Laschitsch , Guenther Dickhaut-Bayer
发明人： Uwe NUMRICH , Achim Neuhaeuser , Thomas Arndt , Thorsten Goldacker , Alexander Laschitsch , Guenther Dickhaut-Bayer
IPC分类号： C08L33/10 , B32B27/08 , C08L27/16
CPC分类号： C08L33/10 , B29C48/022 , B29C48/08 , B29C48/154 , B29C48/17 , B29C48/21 , B29C48/914 , B29K2027/16 , B29K2033/12 , B29K2105/0032 , B29K2105/0044 , B29K2105/005 , B29K2105/256 , B29K2995/0026 , B32B27/08 , B32B27/18 , C08J5/18 , C08J2327/16 , C08J2333/10 , C08K5/005 , C08L27/16 , C09D133/10 , Y10T428/3154 , C08L2666/04 , C08L2666/06
摘要： A transparent plastic foil with improved weathering resistance and increased intrinsic stability is provided. The foil contains a) poly(meth)acrylate and polyvinylidene fluoride in a ratio of from 1:0.01 to 1:0.5 (w/w); and b) a mixture containing a UV stabilizer and a UV absorber. Use of the foil as a protective coating is also included.
摘要翻译：提供了具有改善的耐候性和增加的本征稳定性的透明塑料箔。箔包含a）聚（甲基）丙烯酸酯和比例为1:0.01至1:0.5（w / w）的聚偏二氟乙烯; 和b）含有UV稳定剂和UV吸收剂的混合物。还包括使用箔作为保护涂层。

6. 发明申请

US20100189983A1 PMMA/PVDF FILM WITH PARTICULARLY HIGH WEATHERING STABILITY AND HIGH UV PROTECTIVE ACTION 审中-公开
标题翻译： PMMA / PVDF膜具有特别高的天气稳定性和高紫外线保护作用
公开(公告)号：US20100189983A1
公开(公告)日：2010-07-29
申请号：US12665503
申请日：2008-03-17
申请人： Uwe Numrich , Achim Neuhaeuser , Thomas Arndt , Thorsten Goldacker , Alexander Laschitsch , Guenther Dickhaut-Bayer
发明人： Uwe Numrich , Achim Neuhaeuser , Thomas Arndt , Thorsten Goldacker , Alexander Laschitsch , Guenther Dickhaut-Bayer
IPC分类号： B32B27/08 , C08L27/14 , C08K5/3475 , C08K5/3492
CPC分类号： C08L33/10 , B29C48/022 , B29C48/08 , B29C48/154 , B29C48/17 , B29C48/21 , B29C48/914 , B29K2027/16 , B29K2033/12 , B29K2105/0032 , B29K2105/0044 , B29K2105/005 , B29K2105/256 , B29K2995/0026 , B32B27/08 , B32B27/18 , C08J5/18 , C08J2327/16 , C08J2333/10 , C08K5/005 , C08L27/16 , C09D133/10 , Y10T428/3154 , C08L2666/04 , C08L2666/06
摘要： The invention describes a transparent foil composed of plastic with improved weathering resistance and increased intrinsic stability where the foil encompassesa) poly(meth)acrylate and polyvinylidene fluoride in a ratio of from 1:0.01 to 1:1 (w/w); andb) a mixture composed of UV stabilizers and of UV absorbers.PMMA matrix plastics with high molecular weights and with a certain selected coacrylate proportion are preferably used in order to achieve excellent weathering resistance, and also improved intrinsic stability of the surface-protection foils.
摘要翻译：本发明描述了一种由具有改善的耐候性和增加的固有稳定性的塑料组成的透明箔，其中所述箔包含a）聚（甲基）丙烯酸酯和聚偏二氟乙烯的比例为1:0.01至1:1（w / w）; 和b）由UV稳定剂和UV吸收剂组成的混合物。优选使用具有高分子量和一定选择的丙烯酸酯比例的PMMA基质塑料，以获得优异的耐候性，并且还提高了表面保护箔的本征稳定性。

7. 发明申请

US20080132627A1 Impact-Resistant Poly(Meth)Acrylate Moulding Masses With High Thermal Stability 审中-公开
标题翻译：具有高热稳定性的耐冲击聚（甲基）丙烯酸酯成型体
公开(公告)号：US20080132627A1
公开(公告)日：2008-06-05
申请号：US11813946
申请日：2005-12-15
申请人： Klaus Schultes , Klaus Albrecht , Eric Reinheimer , Thorsten Goldacker , Werner Hoss , Michael Wicker , Anton Halblander
发明人： Klaus Schultes , Klaus Albrecht , Eric Reinheimer , Thorsten Goldacker , Werner Hoss , Michael Wicker , Anton Halblander
IPC分类号： C08L33/10 , C08K5/05
CPC分类号： C08L33/04 , C08L2205/02 , C08L2205/025 , C08L2666/04
摘要： The invention relates to a polymer mixture, based on the (meth)acrylate (co)polymer components a.), b.), c.) and/or d.) according to claim 1, where a test specimen produced from the polymer mixture simultaneously has the following properties: a tensile modulus (ISO 527) of at least 2 500 MPa, a Vicat softening point VSP (ISO 306-350) of at least 110° C., an impact resistance (ISO 179-2D, flatwise) of at least 30 kJ/m2, and a melt index MVR (ISO 1133, 230° C./3.8 kg) of at least 1.0 cm3/10 at least The invention further relates to injection mouldings and to the use of the polymer mixture for production of injection mouldings.
摘要翻译：本发明涉及一种基于根据权利要求1的（甲基）丙烯酸酯（共）聚合物组分a。），b。），c。）和/或d。）的聚合物混合物，其中由聚合物混合物同时具有以下特性：至少2500MPa的拉伸模量（ISO 527），至少110℃的维卡软化点VSP（ISO 306-350），耐冲击性（ISO 179-2D，平坦度）至少为30kJ / m 2，熔体指数MVR（ISO 1133,230℃/ 3.8kg）为至少1.0cm 3/10，在本发明还涉及注射成型品和聚合物混合物用于生产注射成型品的用途。

8. 发明授权

US09410043B2 Reactive mixture for coating molded objects by means of reaction injection molding and coated molded object 有权
标题翻译：通过反应注射成型和涂覆成型物体涂覆成型物体的反应性混合物
公开(公告)号：US09410043B2
公开(公告)日：2016-08-09
申请号：US13546051
申请日：2012-07-11
申请人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höβ , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
发明人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höβ , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
IPC分类号： C09D4/00 , C08F4/32 , C08F2/46 , B29C45/16 , B29C45/00
CPC分类号： C09D4/00 , B29C45/0001 , B29C45/1679 , C08F2/46 , C08F4/32 , Y10T428/263 , Y10T428/264 , Y10T428/31721 , Y10T428/31913 , Y10T428/31924 , Y10T428/31928
摘要： A reactive mixture for coating mouldings by means of reaction injection moulding, containing at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture contains at least one photoinitiator and at least one thermal initiator. The present invention furthermore describes a coated moulding including a moulding which is obtainable by injection moulding processes and includes at least one polymer selected from polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer and polymethyl methacrylate copolymers, and a coating which is obtainable by polymerization of (meth)acrylates having at least two double bonds. The coating has an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.
摘要翻译：用于通过反应注射成型涂覆模制品的反应性混合物，其含有至少40重量％的具有至少两个双键的（甲基）丙烯酸酯。反应性混合物含有至少一种光引发剂和至少一种热引发剂。本发明还描述了一种涂覆的模制品，其包括可通过注射成型工艺获得的模制品，并且包括至少一种选自聚甲基丙烯酸甲酯，聚甲基丙烯酸甲酯，苯乙烯 - 丙烯腈共聚物，苯乙烯 - 马来酸共聚物和聚甲基丙烯酸甲酯共聚物的聚合物，可通过具有至少两个双键的（甲基）丙烯酸酯的聚合获得。根据交叉影线试验，涂层的粘合强度等级不超过1，并且根据ASTM 1044（12/05）进行耐擦伤性试验后20°下的光泽度降低（施加重量500g，循环次数= 100）不超过10％。

9. 发明申请

US20130001825A1 REACTIVE MIXTURE FOR COATING MOLDED OBJECTS BY MEANS OF REACTION INJECTION MOLDING AND COATED MOLDED OBJECT 审中-公开
标题翻译：通过反应注射成型和涂覆成型对象涂覆模制对象的反应混合物
公开(公告)号：US20130001825A1
公开(公告)日：2013-01-03
申请号：US13546051
申请日：2012-07-11
申请人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höss , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
发明人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höss , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
IPC分类号： B29C45/16
CPC分类号： C09D4/00 , B29C45/0001 , B29C45/1679 , C08F2/46 , C08F4/32 , Y10T428/263 , Y10T428/264 , Y10T428/31721 , Y10T428/31913 , Y10T428/31924 , Y10T428/31928
摘要： A reactive mixture for coating mouldings by means of reaction injection moulding, containing at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture contains at least one photoinitiator and at least one thermal initiator. The present invention furthermore describes a coated moulding including a moulding which is obtainable by injection moulding processes and includes at least one polymer selected from polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer and polymethyl methacrylate copolymers, and a coating which is obtainable by polymerization of (meth)acrylates having at least two double bonds. The coating has an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.
摘要翻译：用于通过反应注射成型涂覆模制品的反应性混合物，其含有至少40重量％的具有至少两个双键的（甲基）丙烯酸酯。反应性混合物含有至少一种光引发剂和至少一种热引发剂。本发明还描述了一种涂覆的模制品，其包括可通过注射成型工艺获得的模制品，并且包括至少一种选自聚甲基丙烯酸甲酯，聚甲基丙烯酸甲酯，苯乙烯 - 丙烯腈共聚物，苯乙烯 - 马来酸共聚物和聚甲基丙烯酸甲酯共聚物的聚合物，可通过具有至少两个双键的（甲基）丙烯酸酯的聚合获得。根据交叉影线试验，涂层的粘合强度等级不超过1，并且根据ASTM 1044（12/05）进行耐擦伤性试验后20°下的光泽度降低（施加重量500g，循环次数= 100）不超过10％。

10. 发明授权

US09062211B2 Reactive mixture for coating molded objects by means of reaction injection molding and coated molded object 有权
标题翻译：通过反应注射成型和涂覆成型物体涂覆成型物体的反应性混合物
公开(公告)号：US09062211B2
公开(公告)日：2015-06-23
申请号：US13546084
申请日：2012-07-11
申请人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Hoess , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
发明人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Hoess , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
IPC分类号： B32B27/08 , B32B27/28 , B32B5/00 , B32B27/30 , B32B27/32 , C09D4/00 , C08F4/32 , C08F2/46 , B29C45/16 , B29C45/00
CPC分类号： C09D4/00 , B29C45/0001 , B29C45/1679 , C08F2/46 , C08F4/32 , Y10T428/263 , Y10T428/264 , Y10T428/31721 , Y10T428/31913 , Y10T428/31924 , Y10T428/31928
摘要： A reactive mixture for coating moldings by reaction injection molding includes at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture also includes at least one photoinitiator and at least one thermal initiator. Furthermore, a coated molding includes a molding obtainable by injection molding processes. The molding includes polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer, polymethyl methacrylate copolymer, or a combination thereof. A coating is obtainable by polymerization of (meth)acrylates having at least two double bonds, the coating having an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.
摘要翻译：用于通过反应注射成型涂覆模制品的反应性混合物包括至少40重量％的具有至少两个双键的（甲基）丙烯酸酯。反应性混合物还包括至少一种光引发剂和至少一种热引发剂。此外，涂覆的模制品包括可通过注射成型工艺获得的模制品。该模塑件包括聚甲基丙烯酸甲酯，聚甲基丙烯酰胺，苯乙烯 - 丙烯腈共聚物，苯乙烯 - 马来酸共聚物，聚甲基丙烯酸甲酯共聚物或其组合。可以通过聚合具有至少两个双键的（甲基）丙烯酸酯来获得涂层，该涂层根据交叉影线试验具有不大于1的粘合强度等级，并且在耐刮擦性试验后在20°下的光泽度降低至ASTM 1044（12/05）（施加重量500g，循环数= 100）不大于10％。

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