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1. 发明授权

US5270379A Amine functional polymers as thickening agents 失效
标题翻译：胺官能聚合物作为增稠剂
公开(公告)号：US5270379A
公开(公告)日：1993-12-14
申请号：US938930
申请日：1992-08-31
申请人： Thomas P. McAndrew , Andrew F. Nordquist , Robert K. Pinschmidt, Jr. , Donald P. Eichelberger
发明人： Thomas P. McAndrew , Andrew F. Nordquist , Robert K. Pinschmidt, Jr. , Donald P. Eichelberger
IPC分类号： A61K8/81 , A61K47/32 , A61Q5/02 , A61Q5/12 , A61Q19/00 , C08F8/28 , C09D7/00 , C08L29/04 , C08L39/02
CPC分类号： A61Q19/00 , A61K47/32 , A61K8/817 , C08F8/28 , C08F8/44 , C09D7/002 , A61Q5/02 , A61Q5/12 , C08L39/02
摘要： Fluid coating materials such as paints, ink pastes, personal care creams and the like having a water-base are thickened with an associative thickener which is a vinylamine polymer having a weight average molecular weight above 10.sup.5 and which has been modified by reaction with at least 0.2 mer percent of a linear monoaldehyde having 8 to 30 carbon atoms. A hydrolyzed polymer of N-vinylformamide which has been hydrophobically modified with an aldehyde such as dodecaldehyde, exhibits associative thickening characteristics and is useful in thickening water-based formulations.
摘要翻译：具有水基的涂料，油墨膏，个人护理霜等流体涂料通过缔合增稠剂增稠，该缔合增稠剂是重均分子量大于105的乙烯基胺聚合物，并且至少与具有8至30个碳原子的直链单醛的0.2个百分比。已经用醛如十二醛疏水改性的N-乙烯基甲酰胺的水解聚合物显示出缔合的增稠特性，并且可用于增稠水性制剂。

2. 发明授权

US5185083A Separation of solids from aqueous suspensions using modified amine functional polymers 失效
标题翻译：使用改性胺官能聚合物从固体悬浮液中分离固体
公开(公告)号：US5185083A
公开(公告)日：1993-02-09
申请号：US803256
申请日：1991-12-05
申请人： John G. Smigo , Thomas P. McAndrew , Robert K. Pinschmidt, Jr. , Andrew F. Nordquist
发明人： John G. Smigo , Thomas P. McAndrew , Robert K. Pinschmidt, Jr. , Andrew F. Nordquist
IPC分类号： B01D21/01 , C02F1/54 , C02F1/56 , C02F11/14 , C08F8/00 , C08F8/28 , G21F9/10
CPC分类号： G21F9/10 , C02F1/54 , C08F8/12 , C08F8/48 , C08F2800/10
摘要： Polyvinylaminals, optionally as the formed copolymer with polyvinylhemiaminals and polyvinylacetals are useful as separating agents and are provided by reacting a poly(vinylamine) or a copolymer containing vinyl alcohol and vinylamine units with a monoaldehyde. The aldehyde, such as butyraldehyde, can be introduced into the polymer aminalization as a liquid or gas, generally in a proportion of about 0.02 to 0.5 mol per mol of alcohol and amine units in the polymer chain. These polymers, especially as the cationic salt, perform very well in the flocculation, settling, clarification and dewatering of wastewater.
摘要翻译：聚乙烯基胺，任选地作为与聚乙烯基缩聚物和聚乙烯醇缩甲醛形成的共聚物可用作分离剂，并且通过使聚（乙烯基胺）或含有乙烯醇和乙烯胺单元的共聚物与单醛反应来提供。醛，如丁醛，可以作为液体或气体引入聚合物中间化，通常在聚合物链中每摩尔醇和胺单元约0.02至0.5摩尔的比例。这些聚合物，特别是作为阳离子盐，在废水的絮凝，沉降，澄清和脱水方面表现非常好。

3. 发明授权

US5324787A Modification of poly (vinylamine) 失效
标题翻译：聚乙烯胺改性
公开(公告)号：US5324787A
公开(公告)日：1994-06-28
申请号：US977973
申请日：1992-11-18
申请人： Robert K. Pinschmidt, Jr. , John G. Smigo , Andrew F. Nordquist
发明人： Robert K. Pinschmidt, Jr. , John G. Smigo , Andrew F. Nordquist
IPC分类号： C08F8/00 , C08F26/00 , C08F126/02 , C08F226/02
CPC分类号： C08F8/00
摘要： Poly(vinylamine) homopolymers and copolymers are hydrophobically modified by reaction of amine units present in the polymer with a saturated aliphatic or aromatic glycidyl ether compound. The resulting polymers are useful as flocculants in separating water from suspended solids and are especially effective in improving fines retention in papermaking. Poly(vinylamine hydrochloride) modified in this manner with butyl glycidyl ether is shown to be very efficient in retaining the paper product fines present in recycle paper pulps.
摘要翻译：通过聚合物中存在的胺单元与饱和脂族或芳族缩水甘油醚化合物的反应，聚（乙烯基胺）均聚物和共聚物被疏水改性。所得聚合物可用作从悬浮固体中分离水中的絮凝剂，并且特别有效地改善造纸中的细粉保留。以这种方式用丁基缩水甘油醚改性的聚（乙烯胺盐酸盐）显示出非常有效地保留存在于回收纸浆中的纸制品细粉。

4. 发明授权

US5569725A N-vinyl-n-acyl urea resins 失效
标题翻译： N-乙烯基-N-酰基脲树脂
公开(公告)号：US5569725A
公开(公告)日：1996-10-29
申请号：US323210
申请日：1994-10-14
申请人： W. Eamon Carroll , Walter L. Renz , Andrew F. Nordquist , Robert K. Pinschmidt, Jr.
发明人： W. Eamon Carroll , Walter L. Renz , Andrew F. Nordquist , Robert K. Pinschmidt, Jr.
IPC分类号： C08F290/06 , C08G18/48 , C08G18/67 , C08G18/75 , C08F283/04 , C08G71/04
CPC分类号： C08G18/4833 , C08F290/06 , C08G18/6705 , C08G18/755
摘要： A class of unsaturated resins which are suitable for use in radiation curable coatings has been developed. The resins comprise N-vinyl-N-acyl oligomers made by reacting a secondary N-vinylamide with a polyisocyanate monomer which is reacted with at least one mono- or polyhydric alcohol to form a urethane linkage.
摘要翻译：已经开发了适用于可辐射固化涂料的一类不饱和树脂。该树脂包括通过使次级N-乙烯基酰胺与多异氰酸酯单体反应制备的N-乙烯基-N-酰基低聚物，其与至少一种一元醇或多元醇反应形成氨基甲酸酯键。

5. 发明授权

US4906777A Synthesis of ethylidene bis-formamide using formic acid 失效
标题翻译：用甲酸合成亚乙基双甲酰胺
公开(公告)号：US4906777A
公开(公告)日：1990-03-06
申请号：US260090
申请日：1988-10-19
申请人： Robert K. Pinschmidt, Jr. , Andrew F. Nordquist
发明人： Robert K. Pinschmidt, Jr. , Andrew F. Nordquist
IPC分类号： C07C231/08
CPC分类号： C07C231/08
摘要： Ethylidene bis-formamide, a precursor for the monomer N-vinylformamide, is made in high yield by heating together formamide and acetaldehyde in a mol ratio of at least 3:1 and in a reaction mixture which is at least 20 weight percent formic acid. In a preferred procedure the acetaldehyde is added after the formamide has been preheated and formic acid is present. Yields of ethylidene bis-formamide of over 50%, based on the acetaldehyde, are obtained in relatively short reaction times, before loss of substantial amounts of recoverable formamide through hydrolysis.
摘要翻译：亚乙基双甲酰胺是单体N-乙烯基甲酰胺的前体，通过以至少3:1的摩尔比和在至少20重量％甲酸的反应混合物中加热甲酰胺和乙醛一起高产率地制备。在优选的方法中，在甲酰胺已被预热并存在甲酸之后加入乙醛。在相对较短的反应时间内，在通过水解失去大量可回收的甲酰胺之前，以乙醛为基础，获得超过50％的亚乙基双甲酰胺的产率。

6. 发明授权

US4959489A Process for making an acrylamide containing a dialkyl acetal group 失效
标题翻译：制备含有二烷基缩醛基团的丙烯酰胺的方法
公开(公告)号：US4959489A
公开(公告)日：1990-09-25
申请号：US416289
申请日：1989-10-02
申请人： Andrew F. Nordquist , Robert K. Pinschmidt, Jr.
发明人： Andrew F. Nordquist , Robert K. Pinschmidt, Jr.
IPC分类号： C07C231/02 , C07C231/14 , C07C233/20 , C07C233/21 , C07C233/22
CPC分类号： C07C231/14 , C07C233/20
摘要： A process is provided for making an N-substituted acrylamide dialkyl acetal, such as acrylamidobutyraldehyde dimethylacetal (ABDA), by blocking the double bond in an acrylic acid ester with a nucleophile, such as methanol, removing excess nucleophile from the blocked ester, aminating the blocked ester with an amino dialkyl acetal in the presence of an aminolysis catalyst but in the absence of any protic solvent, and deblocking the double bond in the product by pyrolysis.

7. 发明授权

US5451653A Curable crosslinking system with monobenzaldimine as crosslinker 失效
标题翻译：可变交联体系，以单苯甲醛亚胺为交联剂
公开(公告)号：US5451653A
公开(公告)日：1995-09-19
申请号：US365723
申请日：1994-12-28
申请人： Ning Chen , Chao-Fong Tien , Thomas M. Santosusso , Larry A. Wasowski , Robert K. Pinschmidt, Jr.
发明人： Ning Chen , Chao-Fong Tien , Thomas M. Santosusso , Larry A. Wasowski , Robert K. Pinschmidt, Jr.
IPC分类号： C08F8/30 , C08G18/83
CPC分类号： C08F8/30 , C08G18/833
摘要： This invention relates to improved crosslinking systems for polymeric dispersions and solutions having suitability for coatings, adhesives and use in many other applications. These systems are based upon crosslinkable polymers having a plurality of activated keto methylene groups, e.g., a beta diketone such as an acetoacetate or a keto cyano methylene functional groups and a crosslinkable component comprising an aldimine. A sufficient amount of the aldimine curing agent is used to effect reaction with the polymer containing the activated keto methylene groups and cure thereof. The improvement in the crosslinking system resides in the utilization of a monoaldimine having only one aldimine group and no other methylene reactive group as a crosslinking agent. Another improvement variation to that previously suggested comprises a redispersible polymer(s) containing activated methylene functionality and combined with the monoaldimine and the use of heterocyclic aldimine.
摘要翻译：本发明涉及用于聚合物分散体的改进的交联体系和具有适用于涂料，粘合剂和在许多其它应用中使用的溶液。这些体系基于具有多个活化的酮亚甲基的可交联聚合物，例如β-二酮如乙酰乙酸酯或酮基氰基亚甲基官能团，以及可交联组分，其包含醛亚胺。使用足够量的醛亚胺固化剂来与含有活化酮亚甲基的聚合物进行反应并固化。交联体系的改进在于利用仅具有一个醛亚胺基并且没有其它亚甲基反应性基团的单醛亚胺作为交联剂。与之前提出的另一改进的变化包括含有活化的亚甲基官能团的可再分散的聚合物并与单醛亚胺和使用杂环醛亚胺组合。

8. 发明授权

US5397436A Paper wet-strength improvement with cellulose reactive size and amine functional poly(vinyl alcohol) 失效
标题翻译：纤维素反应性大小和胺官能聚（乙烯醇）纸张湿强度改善
公开(公告)号：US5397436A
公开(公告)日：1995-03-14
申请号：US207460
申请日：1994-03-07
申请人： Lloyd M. Robeson , George Davidowich , Robert K. Pinschmidt, Jr.
发明人： Lloyd M. Robeson , George Davidowich , Robert K. Pinschmidt, Jr.
IPC分类号： D21H17/14 , D21H17/15 , D21H17/17 , D21H17/34 , D21H17/36 , D21H21/20
CPC分类号： D21H17/17 , D21H17/15 , D21H17/34 , D21H21/20
摘要： The wet strength of cellulosic paper is improved by adding the combination of an amine-functional poly(vinyl alcohol) and a cellulose reactive size which is a 4 or 5 membered cyclic ester or anhydride having alkyl or alkenyl substituents of 4 or more carbon atoms. The amine-functional polymer is preferably a hydrolyzed copolymer of vinyl acetate and N-vinylformamide in which about 1-25 mole % of the monomer units are incorporated N-vinylformamide, and the cellulose reactive size is preferably an alkyl ketene dimer or an alkenyl succinic anhydride. A paper product is provided having improved wet-strength and containing normally 0.05 to 4.0 wt % based on the dry pulp of the additive amine-functional polymer and cellulose reactive size. The particular compounds which represent the polymer and the size cooperate to provide improvements in wet-tensile strength for paper which could not have been foreseen from the effects of either material acting alone.
摘要翻译：纤维素纸的湿强度通过加入胺官能聚（乙烯醇）和纤维素反应性大小的组合来改善，该组合是具有4个或更多个碳原子的烷基或链烯基取代基的4或5元环状酯或酸酐。胺官能聚合物优选为乙酸乙烯酯和N-乙烯基甲酰胺的水解共聚物，其中约1-25摩尔％的单体单元加入N-乙烯基甲酰胺，纤维素反应性大小优选为烷基烯酮二聚体或链烯基琥珀酸酐。提供了具有改进的湿强度并且基于添加剂胺官能聚合物的干纸浆和纤维素反应尺寸通常含有0.05至4.0重量％的纸产品。表示聚合物和尺寸的特定化合物相互配合以提供纸张的湿拉伸强度的改进，这不仅是单独使用任一种材料的作用所预见的。

9. 发明授权

US5194492A Two-phase process for preparing poly(vinyl alcohol)-co-poly(vinylamine) 失效
标题翻译：制备聚（乙烯醇） - 共聚（乙烯基胺）的两相工艺
公开(公告)号：US5194492A
公开(公告)日：1993-03-16
申请号：US816196
申请日：1992-01-02
申请人： Robert K. Pinschmidt, Jr. , Ta-Wang Lai
发明人： Robert K. Pinschmidt, Jr. , Ta-Wang Lai
IPC分类号： C08F8/12
CPC分类号： C08F8/12
摘要： Vinyl acetate and an N-vinyl formamide are copolymerized to yield poly(vinyl acetate)-co-poly(N-vinyl formamide) which is base hydrolyzed to poly(vinyl alcohol)-co-poly(N-vinyl formamide). Two phase hydrolysis of particles of poly(vinyl alcohol)-co-poly(N-vinyl formamide) as a slurry in methanol yields particles of poly(vinyl alcohol)-co-poly(vinylamine).Provided is a copolymer of the following general formula ##STR1## where m is 0 to 15 mole %,n is 50 to 99 mole %, x is 0 to 30 mole %, and y is 1 to 50 mole %.
摘要翻译：将乙酸乙烯酯和N-乙烯基甲酰胺共聚合得到基础水解成聚（乙烯醇） - 共 - （N-乙烯基甲酰胺）的聚乙酸乙烯酯 - 共 - （N-乙烯基甲酰胺）。在甲醇中作为浆料的聚（乙烯醇） - 共聚（N-乙烯基甲酰胺）颗粒的两相水解产生聚（乙烯醇） - 共 - （乙烯胺）的颗粒。本发明提供下述通式[IMAGE]的共聚物，其中m为0〜15摩尔％，n为50〜99摩尔％，x为0〜30摩尔％，y为1〜50摩尔％。

10. 发明授权

US5300566A Method for preparing poly(vinyl alcohol)-co-poly(vinylamine) via a two-phase process 失效
标题翻译：通过两相工艺制备聚（乙烯醇） - 共聚（乙烯基胺）的方法
公开(公告)号：US5300566A
公开(公告)日：1994-04-05
申请号：US181887
申请日：1988-04-15
申请人： Robert K. Pinschmidt, Jr. , Ta-Wang Lai
发明人： Robert K. Pinschmidt, Jr. , Ta-Wang Lai
IPC分类号： C08F8/12 , C08F16/06
CPC分类号： C08F8/12
摘要： Vinyl acetate and an N-vinyl formamide are copolymerized to yield poly(vinyl acetate)-co-poly(N-vinyl formamide) which is base hydrolyzed to poly(vinyl alcohol)-co-poly(N-vinyl formamide). Two phase hydrolysis of particles of poly(vinyl alcohol)-co-poly(N-vinyl formamide) as a slurry in methanol yields particles of poly(vinyl alcohol)-co-poly(vinylamine).provided is a copolymer of the following general formula ##STR1## where m is 0 to 15 mole %. n is 50 to 99 mole %.x is 0 to 30 mole %. andy is 1 to 50 mole % .
摘要翻译：将乙酸乙烯酯和N-乙烯基甲酰胺共聚合得到基础水解成聚（乙烯醇） - 共 - （N-乙烯基甲酰胺）的聚乙酸乙烯酯 - 共 - （N-乙烯基甲酰胺）。在甲醇中作为浆料的聚（乙烯醇） - 共聚（N-乙烯基甲酰胺）颗粒的两相水解产生聚（乙烯醇） - 共 - （乙烯胺）的颗粒。提供了以下通式（*化学结构*）的共聚物，其中m为0至15摩尔％。 n为50〜99摩尔％。 x为0〜30摩尔％。 y为1〜50摩尔％。

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