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1. 发明授权

US06193943B1 Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 失效
标题翻译：介孔金属硅酸盐分子筛的催化应用及其制备方法
公开(公告)号：US06193943B1
公开(公告)日：2001-02-27
申请号：US08797718
申请日：1997-02-11
申请人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
发明人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
IPC分类号： C01B3338
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 Å, small elementary particle size (≦400 Å), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S+X·I+ templating pathway (Pathway 3) and mild reaction conditions. These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 Å) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.
摘要翻译：已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅金属中心。该模板方法允许制备具有至少约17埃的大框架壁厚度，小的基本粒度（<= 400）的六边形或六边形样介孔氧化催化剂，以及框架约束的中孔和结构中孔的独特组合同时通过简单的溶剂萃取提供中性模板的简便回收。中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。此外，已经使用介导的S + X.I +模板途径（途径3）和温和的反应条件制备了类似于MCM-41的六方晶过渡金属取代的催化剂。这些新的介孔金属硅酸盐分子筛显示出极好的催化活性苯的过氧化羟基化和具有太大（大于6）的动力学直径的取代芳族化合物的氧化，以进入常规的微孔过渡金属取代的分子筛如钛和钒硅酸盐的孔结构。

2. 发明授权

US06391278B1 Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 失效
标题翻译：介孔金属硅酸盐分子筛的催化应用及其制备方法
公开(公告)号：US06391278B1
公开(公告)日：2002-05-21
申请号：US09246739
申请日：1999-02-08
申请人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
发明人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
IPC分类号： C01B3344
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 Å, small elementary particle size (≦400 Å), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S+X−I+ templating pathway (Pathway 3) and mild reaction conditions.
摘要翻译：已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅金属中心。该模板方法允许制备具有至少约17埃的大框架壁厚度，小的基本粒度（<= 400）的六边形或六边形样介孔氧化催化剂，以及框架约束的中孔和结构中孔的独特组合同时通过简单的溶剂萃取提供中性模板的简便回收。中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。此外，使用介导的S + X-I +模板途径（途径3）和温和的反应条件，已经制备了类似于MCM-41的六方晶过渡金属取代的催化剂。

3. 发明授权

US5855864A Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 失效
标题翻译：介孔金属硅酸盐分子筛的催化应用及其制备方法
公开(公告)号：US5855864A
公开(公告)日：1999-01-05
申请号：US798066
申请日：1997-02-11
申请人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
发明人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/20 , C01B33/38 , C01B33/44 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06 , C07C46/08 , C07C50/02 , C01B33/26
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S.degree.) and neutral inorganic precursors (I.degree.) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 .ANG., small elementary particle size (.ltoreq.400 .ANG.), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I.degree.) with neutral diamine surfactants (S.degree.-S.degree.) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S.sup.+ X.sup.- I.sup.+ templating pathway (Pathway 3) and mild reaction conditions.These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 .ANG.) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.
摘要翻译：已经使用了基于中性伯胺或二胺表面活性剂（S DEG）和中性无机前体（I DEG）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅金属中心。这种模板方法允许制备六角形或六边形状的介孔氧化催化剂，其具有至少约17安培，小的基本粒度（

4. 发明授权

US5712402A Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 失效
标题翻译：介孔金属硅酸盐分子筛的催化应用及其制备方法
公开(公告)号：US5712402A
公开(公告)日：1998-01-27
申请号：US409173
申请日：1995-03-23
申请人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
发明人： Thomas J. Pinnavaia , Peter T. Tanev , Wenzhong Zhang , Jialiang Wang , Malama Chibwe
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/20 , C01B33/38 , C01B33/44 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06 , C07C46/08 , C07C50/02
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S.degree.) and neutral inorganic precursors (I.degree.) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 .ANG., small elementary particle size (.ltoreq.400 .ANG.), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 .ANG.) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.
摘要翻译：已经使用了基于中性伯胺或二胺表面活性剂（S DEG）和中性无机前体（I DEG）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅金属中心。这种模板方法允许制备六角形或六边形状的介孔氧化催化剂，其具有至少约17安培，小的基本粒度（

5. 发明授权

US06410473B1 Quasi crystalline inorganic oxide compositions prepared by neutral templating route 有权
标题翻译：通过中性模板法制备的准晶体无机氧化物组合物
公开(公告)号：US06410473B1
公开(公告)日：2002-06-25
申请号：US09541728
申请日：2000-04-03
申请人： Thomas J. Pinnavaia , Wenzhong Zhang , Thomas R. Pauly , Peter T. Tanev
发明人： Thomas J. Pinnavaia , Wenzhong Zhang , Thomas R. Pauly , Peter T. Tanev
IPC分类号： C01B3338
CPC分类号： B01J29/041 , B01J29/0308 , B01J29/89 , B01J37/036 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06
摘要： Crystalline inorganic oxide compositions having regular wormhole-like channels are described. The formation of the mesoporous composition is accomplished by hydrogen bonding between a neutral amine template in water and a water miscible organic solvent and a neutral inorganic oxide precursor, wherein there is an excess of an alkanol or water used to dissolve the template. The template can be removed and recycled.
摘要翻译：描述了具有规则虫洞状通道的结晶无机氧化物组合物。中孔组合物的形成通过在水中的中性胺模板与水混溶性有机溶剂和中性无机氧化物前体之间的氢键结合来实现，其中存在用于溶解模板的过量的链烷醇或水。模板可以被删除和回收。

6. 发明授权

US6162414A Quasi crystalline inorganic oxide compositions prepared by neutral templating route 有权
公开(公告)号：US6162414A
公开(公告)日：2000-12-19
申请号：US192172
申请日：1998-11-13
申请人： Thomas J. Pinnavaia , Wenzhong Zhang , Thomas R. Pauly , Peter T. Tanev
发明人： Thomas J. Pinnavaia , Wenzhong Zhang , Thomas R. Pauly , Peter T. Tanev
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/38 , C01B37/00 , C01B37/02 , C07C46/06 , C01B33/26
CPC分类号： B01J29/041 , B01J29/0308 , B01J29/89 , B01J37/036 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06
摘要： Crystalline inorganic oxide compositions having regular wormhole-like channels are described. The formation of the mesoporous composition is accomplished by hydrogen bonding between a neutral amine template in water and a water miscible organic solvent and a neutral inorganic oxide precursor, wherein there is an excess of an alkanol or water used to dissolve the template. The template can be removed and recycled.

7. 发明授权

US5672556A Crystalline silicate compositions and method of preparation 失效
标题翻译：结晶硅酸盐组合物及其制备方法
公开(公告)号：US5672556A
公开(公告)日：1997-09-30
申请号：US527504
申请日：1995-09-13
申请人： Thomas J. Pinnavaia , Peter T. Tanev
发明人： Thomas J. Pinnavaia , Peter T. Tanev
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/20 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06
CPC分类号： B01J29/041 , B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/89 , B01J35/1061 , B01J37/036 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06
摘要： Crystalline silicate compositions having unique combinations of framework-confined uniform mesopores and textural mesopores and to a method for their preparation. The compositions typically possess a small particle size of .ltoreq.400 .ANG., a ratio of textural to framework-confined mesoporosity of 0.2 or greater, and a novel ability to discriminate, to adsorb, and with a metal element in the mesopores, to catalytically transform large organic molecules. The method for the formation of the mesoporous structure is accomplished by hydrogen bonding between a non-ionic amine template and a non-ionic inorganic oxide precursor followed by hydrolysis and crosslinking under mild reaction conditions. The templated products of this invention are preferably obtained using water as a hydrolyzing reagent and an alcohol as a co-solvent. The framework-confined uniform mesopore size can be expanded without the use of an auxiliary organic (pore expanding agent). The template can be easily recovered and recycled, preferably, by ethanol extraction.
摘要翻译：结晶硅酸盐组合物具有框架限制的均匀介孔和结构中孔的独特组合及其制备方法。组合物通常具有小颗粒尺寸

8. 发明授权

US06413902B1 Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 有权
标题翻译：介孔金属硅酸盐分子筛的催化应用及其制备方法
公开(公告)号：US06413902B1
公开(公告)日：2002-07-02
申请号：US09661023
申请日：2000-09-13
申请人： Thomas J. Pinnavaia , Peter T. Tanev , Ying Liang
发明人： Thomas J. Pinnavaia , Peter T. Tanev , Ying Liang
IPC分类号： C01B3338
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 Å) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.
摘要翻译：已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅金属中心。中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。这些新的介孔金属硅酸盐分子筛对于苯的过氧化羟基化和对具有太大（大于6埃）的动力学直径的取代芳族化合物的氧化具有优异的催化活性，以进入常规的微孔过渡金属取代的分子筛的孔结构，例如钛和钒硅酸盐。

9. 发明授权

US5800800A Crystalline inorganic oxide compositions prepared by neutral templating route 失效
标题翻译：通过中性模板法制备的结晶无机氧化物组合物
公开(公告)号：US5800800A
公开(公告)日：1998-09-01
申请号：US706552
申请日：1996-09-05
申请人： Thomas J. Pinnavaia , Peter T. Tanev
发明人： Thomas J. Pinnavaia , Peter T. Tanev
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/20 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/89 , B01J35/1061 , B01J37/036 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , Y10S502/509
摘要： This invention relates to new crystalline organic compositions having unique combinations of framework-confined uniform mesopores and textural mesopores and to a method for their preparation. The compositions typically possess a framework wall thickness of at least about 17 .ANG., small elementary particle size of less than about 400 .ANG., and ratio of textural to framework-confined mesoporosity of greater than about 0.2. The formation of the mesoporous structure is accomplished by a novel self-assembly mechanism involving hydrogen bonding between neutral amine surfactant (S.degree.) and neutral inorganic oxide precursor (I.degree.). This S.degree.I.degree. templating approach allows for facile and environmentally benign recycling of the cost-intensive template by simple solvent extraction methods.
摘要翻译：本发明涉及具有框架限制的均匀介孔和质构介孔的独特组合的新型结晶有机组合物及其制备方法。所述组合物通常具有至少约17安培的小的基本粒子尺寸，小于约400安培的小的基本粒度，以及大于约0.2的结构与框架约束的中孔隙比。中孔结构的形成是通过一种新型的自组装机理实现的，该机制涉及中性胺表面活性剂（S DEG）和中性无机氧化物前体（I DEG）之间的氢键合。这种S DEG I DEG模板方法允许通过简单的溶剂萃取方法轻松和环境友好地回收成本密集型模板。

10. 发明授权

US5785946A Crystalline inorganic oxide compositions prepared by neutral templating route 失效
公开(公告)号：US5785946A
公开(公告)日：1998-07-28
申请号：US808190
申请日：1997-02-28
申请人： Thomas J. Pinnavaia , Peter T. Tanev
发明人： Thomas J. Pinnavaia , Peter T. Tanev
IPC分类号： B01J29/03 , B01J29/89 , B01J37/03 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06
CPC分类号： C07C46/06 , B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/89 , B01J35/1061 , B01J37/036 , C01B37/00 , C01B37/005 , C01B37/02 , Y10S502/509
摘要： This invention relates to new crystalline organic compositions having unique combinations of framework-confined uniform mesopores and textural mesopores and to a method for their preparation. The compositions typically possess a framework wall thickness of at least about 17.ANG., small elementary particle size of less than about 400.ANG., and ratio of textural to framework-confined mesoporosity of greater than about 0.2. The formation of the mesoporous structure is accomplished by a novel self-assembly mechanism involving hydrogen bonding between neutral amine surfactant (S.degree.) and neutral inorganic oxide precursor (I.degree.). This S.degree.I.degree. templating approach allows for facile and environmentally benign recycling of the cost-intensive template by simple solvent extraction methods.

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