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1. 发明授权

US5276201A Process for the production of 3-hydroxyalkanals 失效
标题翻译：生产3-羟基卡那烯的方法
公开(公告)号：US5276201A
公开(公告)日：1994-01-04
申请号：US981324
申请日：1992-11-24
申请人： Thomas Haas , Dietrich Arntz , Reinhold Brand
发明人： Thomas Haas , Dietrich Arntz , Reinhold Brand
IPC分类号： B01J27/16 , B01J21/06 , B01J27/14 , C07B61/00 , C07C45/64 , C07C47/19 , C07C45/61
CPC分类号： B01J21/063 , B01J27/14 , C07C45/64
摘要： A process for the production of 3-hydroxyalkanals, more particularly 3-hydroxypropionaldehyde, by hydration of the basic 2-alkenals, more particularly acrolein, in the presence of a solid catalyst containing acid functional groups. The catalysts are based on an inorganic support containing basic activity centers (which are at least partly occupied by a polybasic acid, of which the first pK.sub.s value is between 0 and 3, in a form in which it cannot be removed by water) enables the hydration to be carried out with high selectivity. At the same time, the disadvantages of known organic fixed-bed catalysts are avoided. Preferred catalyst are based on pyrogenic titanium dioxide with phosphoric acid fixed thereon.
摘要翻译：在含有酸官能团的固体催化剂存在下，通过碱性2-烯烃，更特别是丙烯醛的水合，制备3-羟基卡那烯，更特别是3-羟基丙醛的方法。催化剂基于含有碱性活性中心的无机载体（其至少部分地被多元酸占据，其中第一pK值在0和3之间，其不能被水除去的形式）使得能够水合以高选择性进行。同时，避免了已知有机固定床催化剂的缺点。优选的催化剂基于固定有磷酸的热解二氧化钛。

2. 发明授权

US5734070A Hardening of unsaturated fats, fatty acids or fatty acid esters 失效
标题翻译：不饱和脂肪，脂肪酸或脂肪酸酯的硬化
公开(公告)号：US5734070A
公开(公告)日：1998-03-31
申请号：US689836
申请日：1996-08-14
申请人： Thomas Tacke , Stefan Wieland , Peter Panster , Martin Bankmann , Reinhold Brand , Hendrik Magerlein
发明人： Thomas Tacke , Stefan Wieland , Peter Panster , Martin Bankmann , Reinhold Brand , Hendrik Magerlein
IPC分类号： B01J3/00 , C07C51/36 , C07C67/303 , C11C3/12 , C07C31/56
CPC分类号： C11C3/126 , B01J3/008 , C07C51/36 , C07C67/303 , Y02P20/544
摘要： A process is disclosed for continuously hydrogenating unsaturated fats, fatty acids or fatty acid esters on a shaped catalyst in a solid bed. The reactants flow over the catalyst in the presence of a medium or solvent mixture in supercritical conditions. This leads to considerably improved activity and selectivity of the hydrogenation reaction compared with conventional trickle bed hydrogenation processes.
摘要翻译：公开了用于在固体床中的成形催化剂上连续氢化不饱和脂肪，脂肪酸或脂肪酸酯的方法。反应物在超临界条件下在介质或溶剂混合物存在下流过催化剂。与常规滴流床氢化方法相比，这导致氢化反应的活性和选择性显着提高。

3. 发明授权

US4814146A Device for the containment of monolithic catalysts 失效
标题翻译：用于容纳整体式催化剂的装置
公开(公告)号：US4814146A
公开(公告)日：1989-03-21
申请号：US18247
申请日：1987-02-24
申请人： Reinhold Brand , Bernd Engler , Peter Kleine-Moellhoff , Edgar Koberstein
发明人： Reinhold Brand , Bernd Engler , Peter Kleine-Moellhoff , Edgar Koberstein
IPC分类号： B01J35/04 , B01J33/00 , B01J32/00
CPC分类号： B01J33/00
摘要： A device for the containment of ceramic catalyst monoliths particularly of four cornered cross sectional area as well as for the combination of a plurality thereof into a package. The device includes elastic gaskets arranged on one of the ends of the monoliths and partitions for the form fitting containment of the elements into a cassette.
摘要翻译：用于容纳陶瓷催化剂整料的装置，特别是四个角横截面积的装置，以及用于将其多个组合成包装的装置。该装置包括布置在整料和分隔件的一个端部上的弹性垫片，用于将元件容纳在盒中。

4. 发明授权

US5489563A Platinum alloy catalyst for fuel cells and method of its production 失效
标题翻译：用于燃料电池的铂合金催化剂及其生产方法
公开(公告)号：US5489563A
公开(公告)日：1996-02-06
申请号：US324140
申请日：1994-10-17
申请人： Reinhold Brand , Andreas Freund , Jutta Lang , Thomas Lehmann , Johannes Ohmer , Thomas Tacke , Gerhard Heinz , Robert Schwarz
发明人： Reinhold Brand , Andreas Freund , Jutta Lang , Thomas Lehmann , Johannes Ohmer , Thomas Tacke , Gerhard Heinz , Robert Schwarz
IPC分类号： B01J23/89 , B01J37/03 , H01M4/92 , B01J21/18 , B01J23/26 , B01J23/42
CPC分类号： B01J23/8993 , B01J37/03 , H01M4/92
摘要： A ternary platinum alloy catalyst on a conductive carbon carrier for use in fuel cells is disclosed. For the production of the catalyst, nitrate salts are used as precursors of the alloy components and all alloy components are deposited concurrently on the carbon carrier. This method of procedure yields ageing-stable catalysts with high oxygen mass activity.
摘要翻译：公开了一种用于燃料电池的导电性碳载体上的三元铂合金催化剂。为了生产催化剂，使用硝酸盐作为合金组分的前体，并且所有合金组分同时沉积在碳载体上。这种方法产生具有高氧质量活性的老化稳定催化剂。

5. 发明授权

US5198403A Process for producing a catalyst for selective reduction of nitrous oxides with ammonia 失效
标题翻译：制备用氨选择还原一氧化二氮的催化剂的方法
公开(公告)号：US5198403A
公开(公告)日：1993-03-30
申请号：US787746
申请日：1991-11-05
申请人： Reinhold Brand , Bernd Engler , Wolfgang Honnen , Edgar Koberstein , Johannes Ohmer
发明人： Reinhold Brand , Bernd Engler , Wolfgang Honnen , Edgar Koberstein , Johannes Ohmer
IPC分类号： B01D53/94 , B01J21/06 , B01J23/00 , B01J35/10
CPC分类号： B01J21/066 , B01D53/9418 , B01J21/063 , B01J23/00 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/108 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20776 , B01D2255/9207 , Y02C20/10
摘要： A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of V, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.
摘要翻译：除了氧化钛作为组分（A）之外，用氨选择还原一氧化二氮的催化剂还包含至少一种W，Si，B，Al，P，Zr，Ba，Y，La，Ce和作为组分（B）的至少一种V，Nb，Mo，Fe，Cu的氧化物，其中组分（A）和（B）的元素之间的原子比为1：0.001至1。催化剂可以通过用具有组分（B）或其初级阶段的物质将主要为锐钛矿的高比表面处理的反应性二氧化钛混合，加入加工剂，用均匀的捏合物料卷绕，挤出后者，干燥挤出物并在空气中煅烧300 ℃-800℃

6. 发明授权

US4859428A Apparatus for the containment of monolithic catalysts 失效
标题翻译：用于容纳整体式催化剂的装置
公开(公告)号：US4859428A
公开(公告)日：1989-08-22
申请号：US7884
申请日：1987-01-28
申请人： Reinhold Brand , Bernd Engler , Peter Kleine-Moellhoff , Edgar Koberstein
发明人： Reinhold Brand , Bernd Engler , Peter Kleine-Moellhoff , Edgar Koberstein
IPC分类号： B01D53/86 , F01N3/28
CPC分类号： F01N3/2857 , F01N3/2875 , F01N2350/06
摘要： A device for the support of ceramic catalyst monoliths especially of square cross section as well as for the combination of several of such monoliths into one package. It is formed of an elastic gasket attached on one or both monolith ends and a metal frame attached on the gasket under pressure. The frame has recesses on two adjacent lateral surfaces, and at the two opposite lateral surfaces it has projections which can engage interlockingly into the recesses of adjacent frames.
摘要翻译：用于支撑特别是方形横截面的陶瓷催化剂整料的装置，以及用于将一些这种整料组合成一个包装的装置。它由一个或两个整体端部附接的弹性垫圈和在压力下连接在垫圈上的金属框架形成。框架在两个相邻的侧表面上具有凹槽，并且在两个相对的侧表面处具有突起，该凸起可互锁地接合到相邻框架的凹部中。

7. 发明授权

US5300472A Catalyst for selective reduction of nitrous oxides with ammonia 失效
标题翻译：用氨选择性还原一氧化二氮的催化剂
公开(公告)号：US5300472A
公开(公告)日：1994-04-05
申请号：US999618
申请日：1992-12-31
申请人： Reinhold Brand , Bernd Engler , Wolfgang Honnen , Edgar Koberstein , Johannes Ohmer
发明人： Reinhold Brand , Bernd Engler , Wolfgang Honnen , Edgar Koberstein , Johannes Ohmer
IPC分类号： B01D53/94 , B01J21/06 , B01J23/00 , B01J35/10 , B01J37/04 , B01J21/02 , B01J21/04
CPC分类号： B01J21/066 , B01D53/9418 , B01J21/063 , B01J23/00 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/108 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20776 , B01D2255/9207 , Y02C20/10
摘要： A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of Y, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.
摘要翻译：除了氧化钛作为组分（A）之外，用氨选择还原一氧化二氮的催化剂还包含至少一种W，Si，B，Al，P，Zr，Ba，Y，La，Ce和作为组分（B）的Y，Nb，Mo，Fe，Cu的至少一种氧化物，由此组分（A）和（B）的元素之间的原子比为1：0.001至1。催化剂可以通过用具有组分（B）或其初级阶段的物质将主要为锐钛矿的高比表面处理的反应性二氧化钛混合，加入加工剂，用均匀的捏合物料卷绕，挤出后者，干燥挤出物并在空气中煅烧300 -800摄氏度

8. 发明授权

US5131260A Device and method for the continuous measurement of the ammonia concentration in gases in the ppm range 失效
标题翻译：在PPM范围内连续测量气体浓度的装置和方法
公开(公告)号：US5131260A
公开(公告)日：1992-07-21
申请号：US676707
申请日：1991-03-29
申请人： Reinhold Brand , Bernd Engler , Wolfgang Honen , Edgar Koberstein
发明人： Reinhold Brand , Bernd Engler , Wolfgang Honen , Edgar Koberstein
IPC分类号： G01N31/00 , G01N1/22 , G01N1/34 , G01N1/40 , G01N33/00
CPC分类号： G01N1/405 , G01N1/2258 , G01N33/0054 , G01N2001/2217 , G01N2001/2282 , G01N2001/4033
摘要： A device for the continuous measurement of the ammonia concentration in gases in the ppm range includes a columnar absorption vessel (1) with a hemispherical bottom (4). The bottom of the column includes an overflow (3) and an outlet (5). The gas introduction pipe (7,8) empties above the bottom (4) and below a sieve bottom (6) arranged in the column (1). A packing material (10) rests on the sieve bottom (6), which packing (10) essentially fills the absorption column (1). A cooling part (11) extends from the absorption column (1). The cooling part (11) includes a cooling zone (15) and a gas collection space (16) above it with a closable connection piece (13). A pipe (14), which may include a serrated crown on each end, runs from the gas collecting space (16) downward in a cooled manner to the packing 10. The liquid absorption agent is introduced through a lateral connection piece (18) into the gas collection space (16). For the measurement of ammonia concentration, a certain volume flow of the gas to be measured is washed in a countercurrent flow with the absorption agent, and the NH.sub.3 content is determined in a part of the ammonia containing absorption agent. The volume flow rate of the absorption agent and of the gas from which NH.sub.3 has been removed is measured (the latter being dried), and the ammonia concentration is thereby calculated.
摘要翻译：在ppm范围内连续测量气体中的氨浓度的装置包括具有半球形底部（4）的柱状吸收容器（1）。塔的底部包括溢流（3）和出口（5）。气体导入管（7,8）在布置在塔（1）中的底部（4）和下方的筛底（6）之上排空。包装材料（10）搁置在筛底（6）上，该填料（10）基本上填充吸收塔（1）。冷却部件（11）从吸收塔（1）延伸。冷却部件（11）在其上方包括一个冷却区（15）和一个气体收集空间（16），并具有可关闭的连接件（13）。可以在每个端部包括锯齿状冠的管道（14）从气体收集空间（16）以冷却的方式向下延伸到填料10.液体吸收剂通过横向连接件（18）引入气体收集空间（16）。为了测量氨浓度，将要测量的气体的一定体积流量与吸收剂以逆流流动洗涤，并且在含氨吸收剂的一部分中测定NH 3含量。测量吸收剂和从其中除去NH 3的气体的体积流量（后者被干燥），由此计算氨浓度。

9. 发明授权

US4963332A Method for the catalytic removal of nitrogen oxides from exhaust gases by means of a reducing agent 失效
标题翻译：通过还原剂从废气中催化除去氮氧化物的方法
公开(公告)号：US4963332A
公开(公告)日：1990-10-16
申请号：US384754
申请日：1989-07-25
申请人： Reinhold Brand , Bernd Engler , Peter Kleine-Moellhoff , Edgar Koberstein
发明人： Reinhold Brand , Bernd Engler , Peter Kleine-Moellhoff , Edgar Koberstein
IPC分类号： B01D53/86 , B01D53/94 , F01N3/20 , F01N9/00
CPC分类号： F01N3/208 , B01D53/8625 , B01D53/8696 , B01D53/9409 , B01D53/9495 , F01N2560/026 , F01N2560/14 , F01N2570/18 , F01N2610/02 , F01N2610/146 , F01N2900/0422 , Y02T10/24
摘要： A method for the removal of nitrogen oxides contained in exhaust gases of an optionally fluctuating composition with a temperature of 0.degree.-600.degree. C. by means of catalytic reduction at a preselected stoichiometric ratio between the concentration of reducing agent and the concentration of nitrogen oxide in which the reducing agent is dosed in a pulsed manner.
摘要翻译：通过以预选的化学计量比在还原剂的浓度与氮氧化物的浓度之间通过催化还原来除去包含在任选波动的组合物的废气中的氮氧化物的温度为0℃-600℃的方法其中还原剂以脉冲方式配制。

10. 发明授权

US5912394A Catalyst for the dehydrogenation of C.sub.6 -C.sub.15 paraffins and to a process for making such catalysts 失效
标题翻译：用于C6-C15烷烃脱氢的催化剂和制备这种催化剂的方法
公开(公告)号：US5912394A
公开(公告)日：1999-06-15
申请号：US169011
申请日：1998-10-09
申请人： Hans Lansink Rotgerink , Thomas Tacke , Reinhold Brand , Peter Panster
发明人： Hans Lansink Rotgerink , Thomas Tacke , Reinhold Brand , Peter Panster
IPC分类号： B01J23/60 , B01J23/62 , C07B61/00 , C07C5/32 , C07C5/333 , C07C11/02 , C07C5/327
CPC分类号： C07C5/325 , B01J23/60 , B01J23/62 , B01J23/622 , B01J23/626 , C07C5/3337 , C07C2523/14 , C07C2523/42 , C07C2523/62
摘要： A catalyst for the dehydrogenation of C.sub.6 -C.sub.15 paraffins is disclosed. The catalyst contains, on support, at least one platinum group component, at least one promoter component from the group tin, germanium and lead, and at least one additional modifier. The additional modifier contains at least one alkaline earth metal. The stability of the catalyst is essentially higher than that achieved by conventional use of an alkali metal.
摘要翻译：公开了用于C6-C15烷烃脱氢的催化剂。所述催化剂在载体上含有至少一种铂族组分，至少一种来自锡，锡和铅的助催化剂组分和至少一种另外的改性剂。附加改性剂含有至少一种碱土金属。催化剂的稳定性基本上高于常规使用碱金属所达到的稳定性。

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