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1. 发明申请

US20100178512A1 CHANGING SURFACE PROPERTIES BY FUNCTIONALIZED NANOPARTICLES 审中-公开
标题翻译：通过功能化纳米粒子改变表面特性
公开(公告)号：US20100178512A1
公开(公告)日：2010-07-15
申请号：US12516890
申请日：2007-11-26
申请人： Thomas Giesenberg , Pascal Hayoz , Thomas Vogel , Andreas Muhlebach , Markus Frey , Stephan Ilg , Rachel Kohli Steck , Laurent Michau , Francois Rime
发明人： Thomas Giesenberg , Pascal Hayoz , Thomas Vogel , Andreas Muhlebach , Markus Frey , Stephan Ilg , Rachel Kohli Steck , Laurent Michau , Francois Rime
IPC分类号： B32B5/16 , B05D3/00 , B05D3/06 , C08G79/00 , C08G79/10 , C08F20/06 , C08F14/06 , C08F12/08
CPC分类号： C08F2/44 , B05D3/065 , B05D3/142 , B05D5/00 , B05D7/04 , B05D2401/32 , B29C70/64 , B82Y30/00 , C01P2004/03 , C01P2004/64 , C08F2/48 , C08F291/00 , C08F292/00 , C08J7/123 , C08J2323/06 , C08J2323/12 , C08K3/18 , C08K9/08 , C08L51/003 , C08L51/10 , C09C1/3081 , C09C3/063 , C09D5/1618 , C09D7/62 , Y10T428/2995 , Y10T428/31663 , Y10T428/31678 , Y10T428/31855 , C08L2666/02
摘要： A process for modifying the surface of an inorganic or organic substrate with strongly adherent nanoparticles is described, providing to the surface modified substrate durable effects like hydrophobicity, hydrophilicity, electrical conductivity, magnetic properties, flame retardance, color, adhesion, roughness, scratch resistance, UV-absorbance, antimicrobial properties, antifouling properties, antiprotein properties, antistatic properties, antifog properties, release properties. In this process, an optional first step a) a low-temperature plasma, ozonization, high energy irradiation, corona discharge or a flame is caused to act on the inorganic or organic substrate, and in a second step b) one or more defined nanoparticles or mixtures of defined nanoparticles with monomers, containing at least one ethylenically unsaturated group, or solutions, suspensions or emulsions of the afore-mentioned substances, are applied, preferably at normal pressure, to the inorganic or organic substrate. In a third step c) suitable methods are applied to dry or cure those afore-mentioned substances and, optionally, in a fourth step d) a further coating is applied on the substrate so pretreated.
摘要翻译：描述了一种用强粘附纳米颗粒改性无机或有机基材的表面的方法，为表面改性的基材提供耐久效果，如疏水性，亲水性，导电性，磁性，阻燃性，颜色，粘合性，粗糙度，耐擦伤性，紫外线吸收，抗菌性，防污性，抗蛋白性，抗静电性，防雾性，脱模性。在该过程中，引入可选的第一步骤a）低温等离子体，臭氧化，高能辐射，电晕放电或火焰作用于无机或有机衬底，并且在第二步骤中b）一个或多个限定的纳米颗粒或含有至少一个烯属不饱和基团的限定的纳米颗粒与单体的混合物，或上述物质的溶液，悬浮液或乳液，优选常压下施用于无机或有机基材。在第三步骤中，c）应用合适的方法来干燥或固化上述物质，并且任选地在第四步骤中d）将另外的涂层施加在基材上以进行预处理。

2. 发明申请

US20090076198A1 Functionalized nanoparticles 审中-公开
标题翻译：官能化纳米粒子
公开(公告)号：US20090076198A1
公开(公告)日：2009-03-19
申请号：US11665627
申请日：2005-10-17
申请人： Thomas Giesenberg , Andreas Muhlebach , Tunja Jung , Francois Rime , Laurent Michau , Martin Muller , Didier Bauer
发明人： Thomas Giesenberg , Andreas Muhlebach , Tunja Jung , Francois Rime , Laurent Michau , Martin Muller , Didier Bauer
IPC分类号： B32B5/16 , C08K5/00 , C08K5/34 , C08K5/45 , C08K5/15 , C08K5/51 , C08K5/53 , B05D3/02
CPC分类号： C09D7/63 , C01P2002/84 , C01P2002/88 , C01P2004/64 , C08K9/06 , C09C1/3081 , C09C1/40 , C09C1/407 , C09D7/48 , Y10T428/2982
摘要： The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of the formula (I) wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, and wherein the general symbols are as defined in claim 1. These functionalized nanoparticles are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations, or as reinforcer of coatings and improver of scratch resistance in coating compositions for surfaces.
摘要翻译：本发明公开了在表面上包含共价结合的式（I）基团的官能化纳米颗粒，其中纳米颗粒是SiO 2，Al 2 O 3或混合SiO 2和Al 2 O 3纳米颗粒，其中通式符号如权利要求1中所定义。这些官能化纳米颗粒是例如在有机材料中用作稳定剂和/或增容剂，或作为预聚物或预交联制剂中的光引发剂，或用作表面涂料组合物中涂料的增强剂和耐划伤性改进剂。

3. 发明申请

US20090099282A1 Functionalized nanoparticles 审中-公开
标题翻译：官能化纳米粒子
公开(公告)号：US20090099282A1
公开(公告)日：2009-04-16
申请号：US11920295
申请日：2006-05-17
申请人： Martin Muller , Andreas Muhlebach , Thomas Giesenberg , Didier Bauer , Thomas Ruch , Francois Rime , Leonhard Feiler , Roman Lenz , Laurent Michau
发明人： Martin Muller , Andreas Muhlebach , Thomas Giesenberg , Didier Bauer , Thomas Ruch , Francois Rime , Leonhard Feiler , Roman Lenz , Laurent Michau
IPC分类号： C08K5/5419 , C04B16/00 , C08K5/00
CPC分类号： C09B69/103 , C09B67/0097 , C09B68/20 , C09B68/443 , C09B69/10
摘要： The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of formula (1), wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, R1 and R2 are independently of each other hydrogen, nanoparticle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, and Y is a radical of formula —B1-D1 (2a), wherein B1 is the direct bond or a bridge member, and D1 is a radical of a cationic dye, a radical of a phthalocyanine dye which carries no water-solubilizing group, or a radical of a fluorescent dye selected from the group consisting of coumarins, benzocoumarins, xanthenes, benzo[a]xanthenes, benzo[b]xanthenes, benzo[c]xanthenes, phenoxazines, benzo[a]phenoxazines, benzo[b]phenoxazines, benzo[c]phenoxazines, napthalimides, naphtholactams, azlactones, methines, oxazines, thiazines, diketopyrrolopyrroles, quinacridones, benzoxanthenes, thio-epindolines, lactamimides, diphenylmaleimides, acetoacetamides, imidazothiazines, benzanthrones, phthalimides, benzotriazoles, pyrimidines, pyrazines and triazines, or Y is a radical of formula —B2D2 (2b), wherein B2 is an organic radical comprising at least one group having a negative charge, and D2 is a cationic dye selected from the group consisting of monoazo, disazo, polyazo, methine, azamethine, diphenylmethane, triphenylmethane, triaminotriaryl methane, azine, oxazine, cyanine and anthraquinone dyes.
摘要翻译：本发明公开了在表面上包含式（1）的共价结合基团的官能化纳米颗粒，其中纳米颗粒是SiO 2，Al 2 O 3或混合的SiO 2和Al 2 O 3纳米颗粒，R 1和R 2彼此独立地是氢，纳米颗粒表面-O-，或取代基，n为1,2,3,4,5,6,7或8，并且Y为式-B1-D1（2a）的基团，其中B1为直接键或桥式构件，D1为是阳离子染料的自由基，不含水溶性基团的酞菁染料的基团，或选自香豆素，苯并香豆素，呫吨，苯并[a]呫吨，苯并[b 苯并[c]呫吨酮，苯并[c]呫吨酮，吩恶嗪，苯并[a]吩恶嗪，苯并[b]吩恶嗪，苯并[c]吩恶嗪，萘酰亚胺，萘并内酰胺，吖内酯，次甲基，恶嗪，噻嗪，二酮吡咯并吡咯，喹吖啶酮，苯并恶庚烯，硫代 - ，内酰胺，二苯基马来酰亚胺，乙酰乙酰胺，咪唑硫基吖嗪，苯并呋喃，邻苯二甲酰亚胺，苯并三唑，嘧啶，吡嗪和三嗪，或Y是式-B2D2（2b）的基团，其中B2是包含至少一个具有负电荷的基团的有机基团，并且D2是选择的阳离子染料来自由单偶氮，双偶氮，多偶氮，次甲基，氮杂酮，二苯基甲烷，三苯甲烷，三氨基三芳基甲烷，吖嗪，恶嗪，花青和蒽醌染料组成的组。

4. 发明申请

US20060160940A1 Process for intercalating natural or szynthetic clays with block or comb copolymers 审中-公开
标题翻译：使用嵌段或梳状共聚物插入天然或合成粘土的方法
公开(公告)号：US20060160940A1
公开(公告)日：2006-07-20
申请号：US10547265
申请日：2004-02-23
申请人： Andreas Muhlebach , Francois Rime
发明人： Andreas Muhlebach , Francois Rime
IPC分类号： C08K3/34 , C08L53/00 , B32B27/00
CPC分类号： C09J151/003 , C08F4/00 , C08F291/00 , C08F293/005 , C08K9/08 , C08L51/003 , C08L53/00 , C08L2666/02 , C09D151/003 , C09D153/00 , C09J153/00
摘要： The instant invention relates to a process for manufacturing nanoparticles by intercalating and/or exfoliating natural or synthetic clays using block or comb copolymers having one cationic block and at least one non polar block, which are prepared by controlled free radical polymerization (CFRP). The invention also relates to improved nanocomposite compositions containing nanoparticles produced by this process and to the use of these nanocomposite compositions as, for example in, coatings, sealants, caulks, adhesives and as plastic additives.
摘要翻译：本发明涉及通过使用通过控制自由基聚合（CFRP）制备的具有一个阳离子嵌段和至少一个非极性嵌段的嵌段或梳状共聚物来嵌入和/或剥离天然或合成粘土来制造纳米颗粒的方法。本发明还涉及包含通过该方法生产的纳米颗粒的改进的纳米复合材料组合物以及这些纳米复合材料组合物在例如涂料，密封剂，填缝剂，粘合剂和塑料添加剂中的应用。

5. 发明申请

US20050272617A1 Polymers produced by atom transfer radical polymerisation technique with structurally modified terminal groups 失效
标题翻译：通过原子转移自由基聚合技术制备的结构改性末端基团的聚合物
公开(公告)号：US20050272617A1
公开(公告)日：2005-12-08
申请号：US10513837
申请日：2003-04-29
申请人： Hugo Camenzind , Paul Dubs , Peter Hanggi , Roger Martin , Andreas Muhlebach , Francois Rime
发明人： Hugo Camenzind , Paul Dubs , Peter Hanggi , Roger Martin , Andreas Muhlebach , Francois Rime
IPC分类号： C08F2/38 , C08F8/00 , C08F293/00 , C08K5/00 , C10M145/14
CPC分类号： C08F293/005 , C08F8/26 , C08F8/30 , C08F8/34 , C08F8/40 , C08F2438/01 , C08K5/005 , C08F120/18
摘要： The present invention relates to a block copolymer prepared by ATRP, wherein the polymer chain terminal group is structurally modified with the functionally effective group of a lubricant or polymer additive selected from the group consisting of antioxidants, metal deactivators, antiwear and extreme pressure additives and corrosion inhibitors. The invention also relates to a composition comprising the structurally modified block copolymer and a composition of matter subject to oxidative, thermal or light induced degradation, such as lubricants or polymers.
摘要翻译：本发明涉及通过ATRP制备的嵌段共聚物，其中聚合物链端基在结构上用功能有效的润滑剂或聚合物添加剂基团进行改性，所述润滑剂或聚合物添加剂选自抗氧化剂，金属钝化剂，抗磨和极压添加剂和腐蚀抑制剂。本发明还涉及包含结构改性的嵌段共聚物和经受氧化，热或光诱导降解的物质组合物如润滑剂或聚合物的组合物。

6. 发明授权

US6162883A Catalyst mixture and polymerizable composition 失效
标题翻译：催化剂混合物和可聚合组合物
公开(公告)号：US6162883A
公开(公告)日：2000-12-19
申请号：US155561
申请日：1998-09-30
申请人： Andreas Muhlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
发明人： Andreas Muhlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
IPC分类号： B01J31/24 , C08G61/08 , C08G61/12 , C09D145/00
CPC分类号： C08G61/12 , C08G61/08 , Y10T428/2991 , Y10T428/2993 , Y10T428/31678
摘要： A mixture of at least one thermal carbene-free ruthenium catalyst A and at least one thermal ruthenium carbene catalyst B, both of which initiate the ring-opening metathesis polymerization on their own, said catalysts being present in a weight ratio of A to B from 10:1 to 1:10. By adding this mixture even in small amounts, the ring-opening metathesis polymerization of strained cycloolefins can be effectively catalyzed.
摘要翻译： PCT No.PCT / EP97 / 01579 Sec。 371日期：1998年9月30日 102（e）1998年9月30日PCT PCT 1997年3月27日PCT公布。公开号WO97 / 38036 日期1997年10月16日将至少一种不含热不卡宾的钌催化剂A和至少一种热钌卡宾催化剂B的混合物二者自身引发开环易位聚合，所述催化剂以重量比存在的A到B从10：1到1:10。通过少量加入该混合物，可以有效催化应变环烯烃的开环易位聚合。

7. 发明授权

US6100323A Curable composition comprising a diels-alder-adduct of cyclopentadiene and a filler 失效
标题翻译：包含环戊二烯的二醇 - al - 加合物和填料的可固化组合物
公开(公告)号：US6100323A
公开(公告)日：2000-08-08
申请号：US812231
申请日：1997-03-06
申请人： Frans Setiabudi , Andreas Muhlebach , Yoshiaki Naganuma
发明人： Frans Setiabudi , Andreas Muhlebach , Yoshiaki Naganuma
IPC分类号： C07C2/50 , C08G61/08 , C08L65/00 , H01B3/30 , C08J3/28
CPC分类号： H01B3/30 , C08G61/08
摘要： A composition, comprising(a) a Diels-Alder-adduct of cyclopentadiene,(b) a catalyst for the ring-opening metathesis polymerisation, and(c) 2-95% by weight of a filler, based on the entire composition,the filler containing at least 0.5% by weight of a basic adsorbent, based on the entire composition,gives cured products having excellent mechanical and electrical properties and is particularly suitable as coating material for electrical and electronic components.
摘要翻译：一种组合物，其包含（a）环戊二烯的狄尔斯 - 阿尔德加合物，（b）用于开环易位聚合的催化剂，和（c）基于整个组合物的2-95重量％的填料，含有至少0.5重量％碱性吸附剂的填料基于整个组合物，得到具有优异的机械和电学性能的固化产物，并且特别适合作为电气和电子部件的涂料。

8. 发明授权

US5861443A Polymerizable composition and process for polymerizing cyclical olefins 失效
标题翻译：用于聚合循环烯烃的可聚合组合物和方法
公开(公告)号：US5861443A
公开(公告)日：1999-01-19
申请号：US836422
申请日：1997-05-14
申请人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Muhlebach
发明人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Muhlebach
IPC分类号： B05D7/24 , B32B27/32 , C08F2/48 , C08G61/00 , C08G61/08 , C08G61/12 , C09D165/00 , C08F32/00 , C08F34/00
CPC分类号： C08G61/12 , C08G61/08
摘要： Process for the photocatalytic polymerization of a cyclical olefin or at least two different cyclical olefins in the presence of a metal compound as the catalyst, which is characterized in that a photochemical ring-opening metathesis polymerization is carried out in the presence of a catalytic amount of at least one carbene-free, bivalent-cationic ruthenium or osmium compound which contains at least one phosphine group, at least one photolabile ligand, and optionally neutral ligands bonded to the metal atom, a total of 2 or 3 ligands being bonded, and which contains acid ions for balancing the charge. The process can also be carried out by first carrying out the irradiation and ending the polymerization by heating. The process is suitable, for example, for the preparation of thermoplastics shaping compounds and the production of coatings and images in relief.
摘要翻译： PCT No.PCT / EP95 / 04362 Sec。 371日期1997年5月14日 102（e）日期1997年5月14日PCT提交1995年11月6日PCT公布。 WO96 / 16103 PCT出版物日期1996年5月30日在金属化合物作为催化剂存在下，循环烯烃或至少两种不同的环状烯烃的光催化聚合方法，其特征在于光化学开环易位聚合在催化量的至少一种不含有碳原子的二价阳离子钌或锇化合物，其含有至少一个膦基，至少一个光不稳定配体和任选的与该金属原子结合的中性配体，总共有2或3个配体是并且含有用于平衡电荷的酸性离子。该方法也可以首先进行照射并通过加热结束聚合。该方法适用于例如制备热塑性塑料成型化合物以及缓解涂料和图像的生产。

9. 发明授权

US5391681A Curable compositions based on epoxy resins or mixtures of epoxy resins and polyisocyanates containing trisimidazolyl triazines 失效
标题翻译：基于环氧树脂的固化组合物或含有三咪唑基三嗪的环氧树脂和多异氰酸酯的混合物
公开(公告)号：US5391681A
公开(公告)日：1995-02-21
申请号：US68376
申请日：1993-05-27
申请人： Andreas Muhlebach , Peter Flury
发明人： Andreas Muhlebach , Peter Flury
IPC分类号： C07D403/14 , C07D521/00 , C08G18/00 , C08G18/20 , C08G18/58 , C08G18/65 , C08G59/40 , C08G59/50 , C08G59/68 , C08L63/00 , C08G59/00 , C08K5/29 , C08K5/3445 , C08K5/3492 , C08L75/00
CPC分类号： C07D403/14 , C07D231/12 , C07D233/56 , C07D249/08 , C08G18/003 , C08G18/2081 , C08G18/58 , C08G59/4028 , C08G59/686 , C08G2270/00
摘要： Curable compositions based on epoxy resins or a mixture of epoxy resins and polyisocyanates and containing at least one compound of formula I: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each independently of one another hydrogen, alkyl, aryl, arylalkyl or halogen, and R.sub.2 together with R.sub.3 and R.sub.5 together with R.sub.6 and R.sub.8 together with R.sub.9 may each also represent a fused benzene ring.The compositions have high reactivity and at the same time good storage stability.
摘要翻译：含有至少一种式I化合物的环氧树脂或环氧树脂和多异氰酸酯的混合物的固化组合物：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8和R 9各自为独立地是氢，烷基，芳基，芳基烷基或卤素，并且R 2与R 3和R 5以及R 6和R 8与R 9一起可以各自表示稠合苯环。该组合物具有高反应性，同时具有良好的储存稳定性。

10. 发明申请

US20060160950A1 Pigment compositions with modified ATRP copolymer dispersants 有权
标题翻译：具有改性ATRP共聚物分散剂的颜料组合物
公开(公告)号：US20060160950A1
公开(公告)日：2006-07-20
申请号：US11387020
申请日：2006-03-21
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
IPC分类号： C08L53/00 , C08K5/07 , C08K5/16
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/01 , C08K5/0041 , C08L53/00 , C09D11/03 , C09D153/00
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigments. The block copolymers are prepared by atom transfer radical polymerisation (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物通过原子转移自由基聚合（ATRP）制备并用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

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