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1. 发明授权

US6133482A Method for producing carbonyl compounds 失效
标题翻译：生产羰基化合物的方法
公开(公告)号：US6133482A
公开(公告)日：2000-10-17
申请号：US331063
申请日：1999-06-16
申请人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
发明人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
IPC分类号： B01J23/72 , C07C45/38 , C07C45/39 , C07C47/127 , C07C45/29
CPC分类号： C07C45/39 , C07C45/38
摘要： In a process for preparing carbonyl compounds of the formula ##STR1## where R.sup.1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R.sup.2 is a hydrogen atom or a radical of the formula ##STR2## where R.sup.3 is a hydrogen atom or together with R.sup.4 is an oxygen atom, R.sup.4 is the radical OR.sup.6 or together with R.sup.3 is an oxygen atom, R.sup.5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical and R.sup.6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula --CH.sub.2 --CHO or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CHO, by gas-phase oxidation of methanol or alcohols of the formula ##STR3## where R.sup.1 and R.sup.5 are as defined above and R.sup.7 is a hydrogen atom or a radical OR.sup.8 and R.sup.8 is a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical for the formula --CH.sub.2 --CH.sub.2 --OH or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --OH, using an oxygen-containing gas in the presence of copper- and/or silver-containing catalysts and an amount of a phosphorus compound which is volatile under the reaction conditions which is such that the amount of phosphorus (calculated as P) is up to 20 ppm, based on the weight of alcohol used, the phosphorus is introduced within the catalyst bed.
摘要翻译： PCT No.PCT / EP97 / 06856 Sec。 371日期1999年6月16日第 102（e）日期1999年6月16日PCT 1997年12月23日PCT公布。公开号WO98 / 28251 日期1998年7月2日在制备下式的羰基化合物的方法中，其中R 1是氢原子或具有1至3个碳原子的烷基，R 2是氢原子或下式的基团，其中R 3是氢原子或与R4一起为氧原子，R4为基团OR6或与R3为氧原子一起，R5为氢原子，具有1至8个碳原子的烷基或环己基或环戊基，R6为烷基具有1至4个碳原子的基团，环己基或环戊基或式-CH2-CHO或-CH2-CH2-O-CH2-CHO的基团，通过下式的甲醇或醇的气相氧化其中R1 R 5为氢原子或OR 8，R 8为氢原子，碳原子数为1〜4的烷基，环己基或环戊基或式-CH 2 -CH 2 - 的基团， OH或-CH 2 -CH 2 -O-CH 2 -CH 2 -OH，使用含铜气体在铜和/或银-co 在催化剂和一定量的磷化合物中，在反应条件下挥发的量为磷（根据P计算）高达20ppm，基于所使用的醇的重量，磷被引入催化剂床。

2. 发明授权

US6072087A Method for producing carbonyl compounds 失效
标题翻译：生产羰基化合物的方法
公开(公告)号：US6072087A
公开(公告)日：2000-06-06
申请号：US331068
申请日：1999-06-16
申请人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
发明人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
IPC分类号： C07B61/00 , C07C45/38 , C07C45/39 , C07C47/127 , C07C45/29
CPC分类号： C07C45/39 , C07C45/38
摘要： The present invention relates to a process for the preparation of carbonyl compounds of the formula ##STR1## in which R.sup.1 denotes a hydrogen atom or an alkyl radical containing from 1 to 3 carbon atoms, R.sup.2 denotes a hydrogen atom or a radical of the formula ##STR2## in which R.sup.3 denotes a hydrogen atom or, together with R.sup.4, an oxygen atom, R.sup.4 denotes the radical OR.sup.6 or, together with R.sup.3, an oxygen atom, R.sup.5 denotes a hydrogen atom or an alkyl radical containing from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical, and R.sup.6 denotes an alkyl radical containing from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula--CH.sub.2 --CHO or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CHO,by gas-phase oxidation of methanol or alcohols of the formula ##STR3## in which R.sup.1 and R.sup.5 have the meanings specified above and R.sup.7 denotes a hydrogen atom or a radical OR.sup.8, and R.sup.8 denotes a hydrogen atom, an alkyl radical containing from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula --CH.sub.2 --CH.sub.2 --OH or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --OH, using an oxygen-containing gas in the presence of a (copper and/or silver)-containing catalyst and a phosphorus compound which is volatile under the conditions of the reaction and is present in an amount such that the weight of phosphorus (calculated as P), based on the weight of alcohol used, is not more than 20 ppm, wherein the amount of phosphorus used is divided into at least two portions, of whicha) the first portion is added together with the mixture of gaseous starting materials before this reaches the catalyst bed andb) at least one further portion is added within the catalyst bed.
摘要翻译： PCT No.PCT / EP97 / 06855 Sec。 371日期1999年6月16日第 102（e）日期1999年6月16日PCT 1997年12月9日PCT公布。 WO98 / 28250 PCT出版物日期：1998年7月2日本发明涉及制备式中羰基化合物的方法，其中R 1表示氢原子或含有1至3个碳原子的烷基，R 2表示氢原子或式中R 3表示氢原子，或与R 4一起形成氧原子，R 4表示基团OR 6，或与R 3一起形成氧原子，R 5表示氢原子或含有1〜8个碳原子的烷基，或环己基或环戊基，R6表示含有1至4个碳原子的烷基，环己基或环戊基或式-CH2-CHO或-CH2-CH2-O-CH2-CHO的基团，其中R1和R5具有上述含义的甲醇或醇的相氧化，R7表示氢原子或OR8基，R8表示氢原子，含有1至4个碳原子的烷基，环己基或环戊基或基团使用含氧气体在含（铜和/或银）催化剂和挥发性的磷化合物的存在下，使用含氧气体，-CH2-CH2-OH或-CH2-CH2-O-CH2-CH2-OH 反应条件以使得基于所使用的醇的重量计算的磷重量（以P计）不超过20ppm的量存在，其中使用的磷的量被分成至少两个部分，其中a）第一部分在气体原料混合物到达催化剂床之前一起加入，以及b）在催化剂床内加入至少另外一部分。

3. 发明授权

US06255534B1 Preparation of carbonyl compounds 失效
标题翻译：羰基化合物的制备
公开(公告)号：US06255534B1
公开(公告)日：2001-07-03
申请号：US09240851
申请日：1999-02-01
申请人： Dirk Demuth , Thomas Fetzer , Volker Pratsch , Thomas Wendrich , Helmuth Menig , Ludwig Wambach , Klaus Harth
发明人： Dirk Demuth , Thomas Fetzer , Volker Pratsch , Thomas Wendrich , Helmuth Menig , Ludwig Wambach , Klaus Harth
IPC分类号： C07C4529
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127
摘要： Carbonyl compounds of the formula where R1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R2 is a hydrogen atom, an unsubstituted or C1-C3-alkyl-monosubstituted to -trisubstituted C2-C4-alkenyl radical or a radical of the formula where R3 is a hydrogen atom or together with R4 is an oxygen atom, R4 is the radical OR6 or together with R3 is an oxygen atom, R5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms, an unsubstituted or C1-C3-alkyl-monosubstituted to -trisubstituted C2-C4-alkenyl radical or a cyclohexyl or cyclopentyl radical and R6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula —CH2—CHO or —CH2—CH2—O—CH2—CHO, are prepared by gas-phase oxidation of methanol or alcohols of the formula where R1 and R5 are as defined above, by means of an oxygen-containing gas in the presence of copper- and/or silver-containing catalysts, the catalyst system used comprising at least one phosphorus-containing copper- and/or silver-containing catalyst.
摘要翻译：式R 1的羰基化合物是氢原子或具有1至3个碳原子的烷基，R 2是氢原子，未取代的或C 1 -C 3烷基单取代的至三取代的C 2 -C 4 - 烯基或基团其中R 3是氢原子或与R 4一起是氧原子，R 4是基团OR 6或与R 3一起是氧原子，R 5是氢原子，具有1至8个碳原子的烷基，未取代的或C 1 -C 3烷基单取代至三取代的C 2 -C 4 - 烯基或环己基或环戊基，R 6是具有1至4个碳原子的烷基，环己基或环戊基或式-CH 2 -CHO或-CH2-CH2-O-CH2-CHO，通过在含铜的气体存在下，通过含氧气体，通过气相氧化甲醇或式（I）的化合物，其中R 1和R 5如上定义，和/或含银催化剂，所用的催化剂体系包含至少一个p 含胡磷铜和/或含银催化剂。

4. 发明授权

US07071363B2 Structured catalyst bed 失效
标题翻译：结构催化剂床
公开(公告)号：US07071363B2
公开(公告)日：2006-07-04
申请号：US10617859
申请日：2003-07-14
申请人： Hartmut Hibst , Sebastian Storck , Dirk Demuth , Wolfram Stichert , Jens Klein , Stephan A. Schunk , Andreas Sundermann
发明人： Hartmut Hibst , Sebastian Storck , Dirk Demuth , Wolfram Stichert , Jens Klein , Stephan A. Schunk , Andreas Sundermann
IPC分类号： C07C45/00 , B01J23/48 , B01J23/50
CPC分类号： C07C45/34 , B01J8/0453 , B01J23/002 , B01J23/50 , B01J23/66 , B01J23/8885 , B01J27/1806 , B01J35/0006 , B01J2208/025 , B01J2523/00 , C07C45/58 , C07C47/21 , B01J2523/18 , B01J2523/31 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/11 , B01J2523/51
摘要： The invention relates to a novel structured catalyst bed which optionally comprises at least one part bed comprising at least one catalytically active mixture of oxides of the main group metals and transition metals and additionally comprises at least one catalytically active part bed comprising at least silver, at least one alkali metal and a porous support material and finally and necessarily at least one catalytically active part bed comprising at least one alkali metal phosphate and at least one sheet silicate.
摘要翻译：本发明涉及一种新颖的结构化催化剂床，其任选地包含至少一部分床，其包含至少一种主要金属和过渡金属的氧化物的催化活性混合物，并且还包含至少一种至少包含银的催化活性部分床，至少一种碱金属和多孔载体材料，最后并且必需至少一种包含至少一种碱金属磷酸盐和至少一种片状硅酸盐的催化活性部分床。

5. 发明申请

US20050033035A1 Mutants of igf binding proteins and methods of production of antagonists thereof 审中-公开
标题翻译： igf结合蛋白的突变体及其拮抗剂的生产方法
公开(公告)号：US20050033035A1
公开(公告)日：2005-02-10
申请号：US10479819
申请日：2002-06-05
申请人： Hans-Georg Beisel , Dirk Demuth , Richard Engh , Tadeusz Holak , Robert Huber , Kurt Lang , Ralf Schumacher , Wojciech Zeslawski
发明人： Hans-Georg Beisel , Dirk Demuth , Richard Engh , Tadeusz Holak , Robert Huber , Kurt Lang , Ralf Schumacher , Wojciech Zeslawski
IPC分类号： C12N15/09 , A61K38/00 , C07K1/30 , C07K14/47 , C07K14/65 , C07K19/00 , G06F19/00 , G01N33/48 , G01N33/50
CPC分类号： C07K14/65 , A61K38/00 , C07K14/4743 , C07K2299/00
摘要： The present invention provides a crystal suitable for X-ray diffraction, comprising a complex of insulin-like growth factor I or II (IGF) and a polypeptide consisting of the amino acids 39-91 of IGFBP-1, the amino acids 55-107 of IGFBP-2, the amino acids 47-99 of IGFBP-3, the amino acids 39-91 of IGFBP-4, the amino acids 40-92 of IGFBP-5, or the amino acids 40-92 of IGFBP-6 or a fragment thereof consisting at least of the 9th to 12th cysteine of IGFBP-1, IGFBP-2, IGFBP-3, IGFBP-4, or IGFBP-5 or at least of the 7th to 10th cysteine of IGFBP-6; methods for the determination of the atomic coordinates of such a crystal; IGFBP mutants with enhanced binding affinity for IGF-I and/or IGF-II, and methods to identify and optimize small molecules which displace IGFs from their binding proteins.
摘要翻译：本发明提供了适用于X射线衍射的晶体，其包含胰岛素样生长因子I或II（IGF）的复合物和由IGFBP-1的氨基酸39-91，氨基酸55-107 的IGFBP-2，IGFBP-3的氨基酸47-99，IGFBP-4的氨基酸39-91，IGFBP-5的氨基酸40-92或IGFBP-6的氨基酸40-92或其IGFBP-1，IGFBP-2，IGFBP-3，IGFBP-4或IGFBP-5的至少9个至12个半胱氨酸或至少7个至10个的片段 IGFBP-6的半胱氨酸; 用于确定这种晶体的原子坐标的方法; 对IGF-I和/或IGF-II具有增强的结合亲和力的IGFBP突变体以及鉴定和优化从其结合蛋白取代IGF的小分子的方法。

6. 发明授权

US6087538A Addition reaction of hydroxyl-containing compounds with alkynes or allenes 失效
标题翻译：含羟基的化合物与炔或丙烯的加成反应
公开(公告)号：US6087538A
公开(公告)日：2000-07-11
申请号：US92059
申请日：1998-06-05
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Christopher William Rieker , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Christopher William Rieker , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
IPC分类号： B01J23/06 , B01J37/02 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C07C67/04 , C07C69/145 , C07C69/16 , C07C43/30 , B01J21/08 , C07C2/02
CPC分类号： B01J37/0203 , B01J23/06 , C07C41/06 , C07C41/08 , C07C41/54
摘要： Compounds of the formula I and II ##STR1## where R.sup.1 is hydrogen or an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical or an acyl radical, it being possible for these radicals to carry further substituents which do not react with acetylenes or allenes, and the radicals R, independently of one another, are hydrogen or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radicals which may be linked to one another with formation of a ring and m is 0 or 1, are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R have the abovementioned meanings, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used contains, as an active component, an X-ray amorphous zinc silicate or cadmium silicate containing from 1 to 40% by weight, calculated as oxide, of zinc or cadmium and is obtainable by applying a zinc salt or cadmium salt of an organic acidic compound which is decomposable at below 400.degree. C., to an amorphous silica and forming the catalyst at from 50 to 500.degree. C., in the presence of a hydroxyl-containing compound selected from the group consisting of water, alkanols with up to 10 carbon atoms, diols and polyols having 2 to 6 carbon atoms and 2 or 3 OH groups and carboxylic acids of 1 to 6 carbon atoms.
摘要翻译：式I和II的化合物，其中R 1是氢或脂族，脂环族，芳脂族，芳族或杂环基或酰基，这些基团可能携带另外不与炔或炔反应的取代基和基团 R 2彼此独立地是氢或脂族，脂环族，芳脂族，芳族或杂环基团，其可以通过形成环而彼此连接并且m为0或1，其通过将化合物式IIIR1OHIII具有式IV或V的乙炔或二烯，其中R1和R具有上述含义，在气相中，在非均相含硅酸盐催化剂存在下，在升高的温度下，通过所用催化剂包含的方法，作为活性成分，含有以氧化物计为1〜40重量％的锌或镉的X射线无定形硅酸锌或铯硅酸盐，可通过应用在低于400℃下可分解的有机酸性化合物的锌锌盐或镉盐加入到无定形二氧化硅中，并在50-500℃下，在含羟基化合物存在下，在选自具有至多10个碳原子的链烷醇，具有2至6个碳原子的二醇和多元醇以及2或3个OH基团以及1至6个碳原子的羧酸组成的组。

7. 发明授权

US07202088B2 Arrangement for the parallel testing of materials 有权
标题翻译：材料并行测试的安排
公开(公告)号：US07202088B2
公开(公告)日：2007-04-10
申请号：US10333850
申请日：2001-07-27
申请人： Alfred Haas , Stephan Andreas Schunk , Dirk Demuth , Wolfgang Strehlau , Armin Brenner , Wolfram Stichert
发明人： Alfred Haas , Stephan Andreas Schunk , Dirk Demuth , Wolfgang Strehlau , Armin Brenner , Wolfram Stichert
IPC分类号： G01N31/10
CPC分类号： B01J19/0093 , B01J19/0046 , B01J2219/00313 , B01J2219/00319 , B01J2219/00351 , B01J2219/00495 , B01J2219/00585 , B01J2219/0068 , B01J2219/00698 , B01J2219/00704 , B01J2219/00747 , B01J2219/0081 , B01J2219/00835 , B01J2219/00871 , B01J2219/00873 , B01L7/00
摘要： The present invention relates to an arrangement, in particular for the parallel testing of a plurality of building blocks of a material library for performance characteristics, in which the arrangement has a block containing at least one reaction module and at least two heating/cooling modules.
摘要翻译：本发明涉及一种布置，特别是用于并行测试用于性能特征的材料库的多个结构单元，其中该装置具有包含至少一个反应模块和至少两个加热/冷却模块的块。

8. 发明申请

US20060127287A1 Combinatorial preparation and testing of heterogeneous catalysts 审中-公开
标题翻译：组合制备和非均相催化剂的试验
公开(公告)号：US20060127287A1
公开(公告)日：2006-06-15
申请号：US11336843
申请日：2006-01-23
申请人： Hartmut Hibst , Andreas Tenten , Dirk Demuth , Ferdi Schueth , Stephan Schunk
发明人： Hartmut Hibst , Andreas Tenten , Dirk Demuth , Ferdi Schueth , Stephan Schunk
IPC分类号： D21C11/00
CPC分类号： B01J19/0046 , B01J37/0215 , B01J37/0217 , B01J2219/00286 , B01J2219/00306 , B01J2219/00511 , B01J2219/00585 , B01J2219/0059 , B01J2219/00599 , B01J2219/00747
摘要： The array of heterogeneous catalysts and/or their precursors, is made up of a body which has, preferably parallel, through-channels and in which at least n channels comprise n different heterogeneous catalysts and/or their precursors, where n is 2, preferably 10, particularly preferably 100, in particular 1000, especially 10,000. A process for preparing arrays comprising the following steps: a1) preparing solutions, emulsions and/or dispersions of elements and/or element compounds of the elements present in the catalyst and/or catalyst precursor and, if appropriate preparing dispersions of inorganic support materials, a2) if appropriate introducing adhesion promoters, binders, viscosity regulators, pH regulators and/or solid inorganic supports into the solutions, emulsions and/or dispersions, a3) simultaneously or successively coating the channels of the body with the solutions, emulsions and/or dispersions, a predetermined amount of the solutions, emulsions and/or dispersions being introduced into each channel to obtain a predetermined composition and a4) if appropriate heating the coated body in the presence or absence of inert gases or reactive gases to a temperature in the range from 20 to 1500° C. to dry, with or without sintering or calcining, the catalysts and/or catalyst precursors.
摘要翻译：非均相催化剂和/或其前体的阵列由具有优选平行的通道的主体组成，其中至少n个通道包含n个不同的非均相催化剂和/或其前体，其中n为2，优选为 10，特别优选100，特别是1000，特别是10,000。一种制备阵列的方法，包括以下步骤：a1）制备存在于催化剂和/或催化剂前体中的元素和/或元素化合物的溶液，乳液和/或分散体，以及如果合适的话，制备无机载体材料的分散体， a2）如果合适，将粘合促进剂，粘合剂，粘度调节剂，pH调节剂和/或固体无机载体引入溶液，乳液和/或分散体中，a3）用溶液，乳液和/或分散体同时或连续地涂覆身体的通道分散体，预定量的溶液，乳液和/或分散体被引入每个通道以获得预定的组合物和a）如果在存在或不存在惰性气体或反应气体的情况下适当地加热涂覆体到达该范围内的温度 20至1500℃，用或不用烧结或煅烧来干燥催化剂和/或催化剂前体。

9. 发明申请

US20050037426A1 Combinatorial preparation and testing of heterogeneous catalysts 审中-公开
标题翻译：组合制备和非均相催化剂的试验
公开(公告)号：US20050037426A1
公开(公告)日：2005-02-17
申请号：US10726185
申请日：2003-12-03
申请人： Stephan Schunk , Dirk Demuth , Hartmut Hibst
发明人： Stephan Schunk , Dirk Demuth , Hartmut Hibst
IPC分类号： B01J19/00 , B01J35/04 , B01J37/02 , C40B30/08 , C40B40/18 , G01N33/53 , G01N33/543
CPC分类号： B01J37/02 , B01J19/0046 , B01J35/04 , B01J2219/0052 , B01J2219/00585 , B01J2219/00603 , B01J2219/00659 , B01J2219/00704 , B01J2219/00745 , B01J2219/00747 , C40B30/08 , C40B40/18 , Y10T436/175383 , Y10T436/18 , Y10T436/20 , Y10T436/205831 , Y10T436/25875
摘要： A process for preparing arrays of heterogeneous catalysts and/or their precursors, made up of a body which has, preferably parallel, through-channels and in which at least n channels comprise n different heterogeneous catalysts and/or their precursors, where n is 2, preferably 10, particularly preferably 100, comprises the following steps: a1) preparing solutions, emulsions and/or dispersions of elements and/or element compounds of the chemical elements present in the catalyst and/or catalyst precursor and, if appropriate preparing dispersions of inorganic support materials, a2) if appropriate introducing adhesion promoters, binders, viscosity regulators, pH regulators and/or solid inorganic supports into the solutions, emulsions and/or dispersions, a3) simultaneously or successively coating the channels of the body with the solutions, emulsions and/or dispersions, a predetermined amount of the solutions, emulsions and/or dispersions being introduced into each channel to obtain a predetermined composition, a4) treating and reacting with one or more reactive gases the freshly impregnated moist channels obtained after the coating, and a5) if appropriate heating the coated body in the presence or absence of inert gases or reactive gases to a temperature in the range from 20 to 1500° C. to dry, with or without sintering or calcining, the catalysts and/or catalyst precursors.
摘要翻译：一种制备非均相催化剂和/或其前体阵列的方法，其由具有优选平行通过通道并且其中至少n个通道包含n个不同的非均相催化剂和/或其前体的主体组成，其中n为2 ，优选10，特别优选100，包括以下步骤：a1）制备催化剂和/或催化剂前体中存在的化学元素的元素和/或元素化合物的溶液，乳液和/或分散体，并且如果合适，制备无机载体材料，a2）如果合适的话，将粘合促进剂，粘合剂，粘度调节剂，pH调节剂和/或固体无机载体引入溶液，乳液和/或分散体中，a3）用溶液同时或连续地涂覆身体的通道，乳液和/或分散体，将预定量的溶液，乳液和/或分散体引入每个通道以获得预 a4）在涂覆后获得的新鲜浸渍的湿通道处理和反应一种或多种反应性气体，以及a）如果在存在或不存在惰性气体或反应性气体的情况下适当地加热涂覆体到达该范围内的温度 20至1500℃，用或不用烧结或煅烧来干燥催化剂和/或催化剂前体。

10. 发明授权

US6060035A Addition reaction of hydroxyl-containing compounds with alkynes or allenes 失效
标题翻译：含羟基的化合物与炔或丙烯的加成反应
公开(公告)号：US6060035A
公开(公告)日：2000-05-09
申请号：US92058
申请日：1998-06-05
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
IPC分类号： B01J23/08 , B01J21/16 , B01J23/06 , B01J37/03 , C01B33/20 , C07B41/00 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C01B15/14
CPC分类号： B01J21/16 , B01J23/06 , B01J37/03 , C01B33/20 , C07B41/00 , C07C41/06 , C07C41/08 , C07C41/54
摘要： Compounds of the formulae I and II ##STR1## are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R are as defined, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used is one which contains or consists of, as the active component, a zinc silicate obtained by precipitation in aqueous solution from a soluble silicon compound and zinc compound, zinc silicate beinga) an essentially X-ray amorphous zinc silicate of the formula VIZn.sub.a Si.sub.c O.sub.a+2c-0.5e (OH).sub.e.fH.sub.2 O VI, where e is from 0 to 2a+4c and the ratio a:c is from 1 to 3.5, and the ratio f:a is from 0 to 200, and/orb) a crystalline zinc silicate having the structure of hemimorphite of the formula Zn.sub.4 Si.sub.2 O.sub.7 (OH).sub.2.H.sub.2 O.
摘要翻译：式I和II的化合物通过在存在下在升高的温度下在气相中通过式III R1OHIII的化合物与式IV或V的炔或其中R1和R如所定义的二烯的加成反应来制备，的不均一硅酸盐催化剂，其中使用的催化剂是含有或由作为活性组分的组成的方法，所述方法是通过在可溶性硅化合物和锌化合物的水溶液中沉淀而获得的硅酸锌，硅酸锌 a）基本上是式VI ZnaSicOa + 2c-0.5e（OH）e.fH2OVI的X射线无定形硅酸锌，其中e为0至2a + 4c，a:c为1至3.5，以及比例f：a为0至200，和/或b）具有式Zn 4 Si 2 O 7（OH）2·H 2 O的半偏氟结构的结晶硅酸锌。

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