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1. 发明授权

US5601699A Method for cracking hydrocarbons 失效
标题翻译：碳氢化合物裂化方法
公开(公告)号：US5601699A
公开(公告)日：1997-02-11
申请号：US444978
申请日：1995-05-19
申请人： Thomas F. Degnan , Terry E. Helton , Grant H. Yokomizo
发明人： Thomas F. Degnan , Terry E. Helton , Grant H. Yokomizo
IPC分类号： C07D249/18 , C10L1/14 , C10L1/18 , C10L1/22 , C10L1/232 , C10L1/238 , C10L10/00 , C10L10/02 , C10L10/04 , C10M133/44 , C10M159/12 , C10G11/02
CPC分类号： C10L10/08 , C07D249/18 , C10L1/143 , C10L1/221 , C10L1/232 , C10L1/238 , C10L10/02 , C10L10/04 , C10M133/44 , C10M159/12 , C10L1/1881 , C10L1/1883 , C10L1/189 , C10L1/1895 , C10L1/2335 , C10L1/2383 , C10L1/2387 , C10M2207/08 , C10M2207/10 , C10M2207/129 , C10M2207/28 , C10M2207/34 , C10M2215/02 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/223 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2217/041 , C10M2227/00 , C10N2240/02 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106
摘要： Methods for preparing phosphorus containing catalysts comprising a large-pore zeolite, e.g., zeolite Beta, zeolite ZSM-12, or zeolite ZSM-20, and a matrix which have improved attrition resistance. The present invention includes the catalyst compositions produced by the above methods. Also included in the present invention are methods for the use of catalysts prepared by the present method in hydrocarbon cracking processes. It is desired to develop cracking catalysts for organic compound conversion that have improved cracking yields and have good attrition resistance. This invention involves the use of large pore siliceous zeolites and a highly siliceous matrix to produce a cracking catalyst with improved cracking yields and good attrition resistance. The invention further involves the use of phosphorus and the use of selected sequences for combining the compounds in the manufacture of the catalyst to enhance the attrition resistance of the catalyst.
摘要翻译：制备含有大孔沸石的含磷催化剂的方法，例如β沸石沸石，沸石ZSM-12或沸石ZSM-20，以及具有改进耐磨性的基体。本发明包括通过上述方法制备的催化剂组合物。本发明还包括使用本方法制备的催化剂在烃裂解方法中的方法。需要开发有机化合物转化的裂化催化剂，其具有改善的裂化产率并具有良好的耐磨性。本发明涉及使用大孔硅质沸石和高度硅质基质来生产具有改进的裂化产率和良好耐磨性的裂化催化剂。本发明进一步涉及磷的使用和选择的序列用于在催化剂制造中组合化合物以提高催化剂耐磨耗性的用途。

2. 发明授权

US5472922A Manufacture of improved catalyst 失效
标题翻译：改良催化剂的制造
公开(公告)号：US5472922A
公开(公告)日：1995-12-05
申请号：US140936
申请日：1993-10-25
申请人： Thomas F. Degnan , Terry E. Helton , Grant H. Yokomizo
发明人： Thomas F. Degnan , Terry E. Helton , Grant H. Yokomizo
IPC分类号： B01J29/70 , B01J29/04
CPC分类号： B01J29/7007 , B01J2229/26 , B01J2229/36 , B01J2229/42
摘要： Methods for preparing phosphorus containing catalysts comprising a large-pore zeolite, e.g., zeolite Beta, zeolite ZSM-12, or zeolite ZSM-20, and a matrix which have improved attrition resistance. The present invention includes the catalyst compositions produced by the above methods. Also included in the present invention are methods for the use of catalysts prepared by the present method in hydrocarbon cracking processes. It is desired to develop cracking catalysts for organic compound conversion that have improved cracking yields and have good attrition resistance. This invention involves the use of large pore siliceous zeolites and a highly siliceous matrix to produce a cracking catalyst with improved cracking yields and good attrition resistance. The invention further involves the use of phosphorus and the use of selected sequences for combining the compounds in the manufacture of the catalyst to enhance the attrition resistance of the catalyst.
摘要翻译：制备含有大孔沸石的含磷催化剂的方法，例如β沸石沸石，沸石ZSM-12或沸石ZSM-20，以及具有改善耐磨性的基体。本发明包括通过上述方法制备的催化剂组合物。本发明还包括使用本方法制备的催化剂在烃裂解方法中的方法。需要开发有机化合物转化的裂化催化剂，其具有改善的裂化产率并具有良好的耐磨性。本发明涉及使用大孔硅质沸石和高度硅质基质来生产具有改进的裂化产率和良好耐磨性的裂化催化剂。本发明进一步涉及磷的使用和选择的序列用于在催化剂制造中组合化合物以提高催化剂耐磨耗性的用途。

3. 发明授权

US5536894A MCM-56 as sorbent and catalyst component 失效
标题翻译： MCM-56作为吸附剂和催化剂组分
公开(公告)号：US5536894A
公开(公告)日：1996-07-16
申请号：US266082
申请日：1994-06-27
申请人： Thomas F. Degnan , Anthony S. Fung , Terry E. Helton , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth
发明人： Thomas F. Degnan , Anthony S. Fung , Terry E. Helton , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth
IPC分类号： B01J20/18 , B01J29/03 , B01J29/06 , B01J29/40 , B01J29/70 , C01B33/38 , C01B35/00 , C01B39/00 , C01B39/02 , C01B39/48 , C07C2/66 , C07C15/02 , C10G35/06 , C10G35/095 , C07C2/56 , C07C4/02 , C07C7/12
CPC分类号： B01J29/70 , B01J37/0009 , C01B33/38 , B01J2229/42
摘要： This invention relates to use of synthetic layered material MCM-56 as a sorbent and as a catalyst component in catalytic conversion of organic compounds. Examples of sorbent use include rapid sorption of hydrocarbons and separating at least one hydrocarbon component from a mixture of hydrocarbon components having differential sorption characteristics with respect to MCM-56. Examples of catalytic use include acid catalyzed reactions, such as cracking, aromatic compound alkylation, and isoalkane alkylation.
摘要翻译：本发明涉及合成层状材料MCM-56作为吸附剂和作为有机化合物催化转化的催化剂组分的用途。吸附剂使用的实例包括快速吸附烃并从相对于MCM-56的差异吸附特性的烃组分的混合物中分离至少一种烃组分。催化用途的实例包括酸催化反应，例如裂解，芳族化合物烷基化和异烷烃烷基化。

4. 发明授权

US5486284A Catalytic cracking with MCM-49 失效
标题翻译： MCM-49催化裂化
公开(公告)号：US5486284A
公开(公告)日：1996-01-23
申请号：US297468
申请日：1994-08-15
申请人： Thomas F. Degnan , Terry E. Helton , Daria N. Lissy
发明人： Thomas F. Degnan , Terry E. Helton , Daria N. Lissy
IPC分类号： B01J29/04 , B01J29/70 , B01J29/74 , C10G11/02 , C10G11/05 , C10G35/04 , C10G35/095
CPC分类号： C10G11/05 , B01J29/70 , B01J29/74 , B01J2229/26 , B01J2229/42
摘要： This invention relates to use of MCM-49 in catalytic cracking. Large amounts of light olefins are produced.
摘要翻译：本发明涉及MCM-49在催化裂化中的应用。生产大量的轻质烯烃。

5. 发明授权

US5629463A Naphthalene alkylation with RE and mixed H/NH3 form catalyst 失效
标题翻译：用RE和N / N混合的H / NH 3形成催化剂进行萘烷基化
公开(公告)号：US5629463A
公开(公告)日：1997-05-13
申请号：US519381
申请日：1995-08-25
申请人： Susan C. Ardito , Henry Ashjian , Thomas F. Degnan , Terry E. Helton , Quang N. Le , Augusto R. Quinones
发明人： Susan C. Ardito , Henry Ashjian , Thomas F. Degnan , Terry E. Helton , Quang N. Le , Augusto R. Quinones
IPC分类号： B01J29/08 , B01J37/30 , C07C2/66 , C07C2/64 , C07C15/107
CPC分类号： B01J37/30 , B01J29/08 , C07C2/66 , C07C2529/08
摘要： Long chain alkyl substituted naphthalenes are produced by alkylating naphthalene with an olefin or other alkylating agent with at least 6, and usually 12 to 20 carbon atoms, in the presence of an alkylation catalyst comprising a zeolite having rare earth cations, and both ammonium and protonic species, associated with the exchangeable sites of the zeolite. The zeolite is usually a large pore size zeolite such as USY. The presence of rare earths and both ammonium and protonic species increases selectivity for production of long chain mono-alkyl substituted naphthalenes in preference to more highly substituted products.
摘要翻译：长链烷基取代的萘是通过在含有具有稀土阳离子的沸石，铵和质子的烷基化催化剂的存在下，用具有至少6个碳原子，通常12-20个碳原子的烯烃或其它烷基化剂将萘烷基化与沸石的可交换位点相关联的物质。沸石通常是诸如USY的大孔径沸石。稀土和铵和质子物质的存在提高了生产长链单烷基取代萘的选择性，优于更高取代的产物。

6. 发明授权

US5457254A Naphthalene alkylation process using mixed H/NH3 form catalyst 失效
标题翻译：使用混合H / NH 3形式催化剂的萘烷基化方法
公开(公告)号：US5457254A
公开(公告)日：1995-10-10
申请号：US173006
申请日：1993-12-27
申请人： Susan C. Ardito , Henry Ashjian , Thomas F. Degnan , Terry E. Helton , Quang N. Le , Augusto R. Quinones
发明人： Susan C. Ardito , Henry Ashjian , Thomas F. Degnan , Terry E. Helton , Quang N. Le , Augusto R. Quinones
IPC分类号： C07C2/70 , B01J29/08 , B01J37/30 , C07B61/00 , C07C2/66 , C07C2/86 , C07C15/24 , C07C2/64 , C07C2/68 , C07C15/067 , C07C15/107
CPC分类号： B01J37/30 , B01J29/08 , C07C2/66 , C07C2529/08
摘要： Long chain alkyl substituted naphthalenes are produced by alkylating naphthalene with an olefin or other alkylating agent with at least 6, and usually 12 to 20 carbon atoms, in the presence of an alkylation catalyst comprising a zeolite having both ammonium and protonic species associated with the exchangeable sites of the zeolite. The zeolite is usually a large pore size zeolite such as USY. The presence of both ammonium and protonic species increases selectivity for production of long chain mono-alkyl substituted naphthalenes in preference to more highly substituted products.
摘要翻译：长链烷基取代的萘是通过在包含具有铵和质子相互作用的沸石的烷基化催化剂存在下，用具有至少6个碳原子，通常12-20个碳原子的烯烃或其它烷基化剂将萘烷基化而制得的沸石的位置。沸石通常是诸如USY的大孔径沸石。铵和质子物质的存在增加了生产长链单烷基取代萘的选择性，优于更高取代的产物。

7. 发明授权

US5308475A Use of ZSM-12 in catalytic cracking for gasoline octane improvement and co-production of light olefins 失效
标题翻译：在催化裂化中使用ZSM-12进行汽油辛烷值改进和轻质烯烃的共同生产
公开(公告)号：US5308475A
公开(公告)日：1994-05-03
申请号：US979963
申请日：1992-11-23
申请人： Thomas F. Degnan , Terry E. Helton
发明人： Thomas F. Degnan , Terry E. Helton
IPC分类号： B01J29/70 , B01J29/08 , B01J29/80 , C10G11/02 , C10G11/05 , C10G11/00
CPC分类号： C10G11/05 , B01J29/80 , B01J29/088 , B01J29/70
摘要： Heavy oils are subjected to catalytic cracking in the absence of added hydrogen using a catalyst containing a zeolite having the structure of ZSM-12 and a large-pore crystalline zeolite having a Constraint Index less than about 1. The process is able to effect a bulk conversion of the oil while at the same time yielding a higher octane gasoline and increased light olefin content.
摘要翻译：使用含有ZSM-12结构的沸石和约束指数小于约1的大孔结晶沸石的催化剂，重油在不加氢的情况下进行催化裂化。该方法能够实现油的转化同时产生更高辛烷值的汽油和增加的轻烯烃含量。

8. 发明申请

US20140234207A1 MCM-56 Manufacture 有权
标题翻译： MCM-56制造
公开(公告)号：US20140234207A1
公开(公告)日：2014-08-21
申请号：US14238274
申请日：2012-08-16
申请人： Ivy D. Johnson , Nadya Ann Hrycenko , Wieslaw J. Roth , Terry E. Helton
发明人： Ivy D. Johnson , Nadya Ann Hrycenko , Wieslaw J. Roth , Terry E. Helton
IPC分类号： C01B39/48
CPC分类号： C01B39/48 , B01J29/70 , B01J29/74 , B01J29/76 , B01J29/78 , B01J2229/186 , B01J2229/42 , C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： The present invention provides an improved method for manufacturing high quality porous crystalline MCM-56 material. It also relates to the MCM-56 material manufactured by the improved method, catalyst compositions comprising same and use thereof in a process for catalytic conversion of hydrocarbon compounds. One such conversion process involves production of monoalkylated aromatic compounds, particularly ethylbenzene and cumene, by the liquid or partial liquid phase alkylation of alkylatable aromatic compound, particularly benzene.
摘要翻译：本发明提供了制造高品质多孔结晶MCM-56材料的改进方法。它还涉及通过改进方法制造的MCM-56材料，包含其的催化剂组合物以及在烃化合物的催化转化方法中的用途。一种这样的转化方法包括通过液体或部分液相烷基化的可烷基化芳族化合物，特别是苯来生产单烷基化芳族化合物，特别是乙苯和枯烯。

9. 发明授权

US08217213B2 Hydroalkylation of aromatic compounds using EMM-12 有权
标题翻译：使用EMM-12对芳族化合物进行加氢烷基化
公开(公告)号：US08217213B2
公开(公告)日：2012-07-10
申请号：US12994304
申请日：2009-07-15
申请人： Wieslaw J. Roth , Terry E. Helton , Jane C. Cheng , Michael J. Brennan
发明人： Wieslaw J. Roth , Terry E. Helton , Jane C. Cheng , Michael J. Brennan
IPC分类号： C07C2/58
CPC分类号： B01J29/7676 , B01J29/70 , B01J29/7038 , B01J29/7276 , B01J29/7476 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C2/66 , C07C2/74 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C15/085
摘要： This disclosure relates to a process for manufacturing a mono-cycloalkyl-substituted aromatic compound, said process comprising contacting a feedstock comprising an aromatic compound and hydrogen under hydroalkylation reaction conditions with a catalyst system comprising a molecular sieve and at least one metal with hydrogenation activity, wherein said molecular sieve has, in its as-synthesized form and in calcined form, an X-ray diffraction pattern including peaks having a d-spacing maximum in the range of 14.17 to 12.57 Angstroms, a d-spacing maximum in the range of 12.1 to 12.56 Angstroms.
摘要翻译：本公开涉及制备单环烷基取代的芳族化合物的方法，所述方法包括在加氢烷基化反应条件下将包含芳族化合物和氢的原料与包含分子筛和至少一种具有氢化活性的金属的催化剂体系接触，其中所述分子筛具有其合成形式和煅烧形式的X射线衍射图，其包括在d。间距最大值在14.17至12.57埃范围内的峰，d间距最大值在12.1范围内至12.56埃。

10. 发明申请

US20110224469A1 Alkylated Aromatics Production 有权
标题翻译：烷基化芳烃生产
公开(公告)号：US20110224469A1
公开(公告)日：2011-09-15
申请号：US12721326
申请日：2010-03-10
申请人： Matthew J. Vincent , Vijay Nanda , Maruti Bhandarkar , Brian Maerz , Terry E. Helton
发明人： Matthew J. Vincent , Vijay Nanda , Maruti Bhandarkar , Brian Maerz , Terry E. Helton
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C6/126 , C07C7/13 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C15/04 , C07C15/073 , C07C15/085 , C07C15/02
摘要： Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of first and second alkylation catalysts wherein the water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and a portion of impurities are removed in a dehydration zone. A first alkylation zone having a first alkylation catalyst which, in some embodiments is a large pore molecular sieve, acts to remove a larger portion of impurities, such as nitrogenous and other species, and to alkylate a smaller portion of the alkylatable aromatic compound. A second alkylation zone, which in some embodiments is a medium pore molecular sieve, acts to remove a smaller portion of impurities, and to alkylate a larger portion of the alkylatable aromatic compound.
摘要翻译：公开了通过在第一和第二烷基化催化剂存在下使包含可烷基化芳族化合物，烷基化剂和痕量水和杂质的进料流接触来生产烷基化芳族化合物的方法，其中除去水和杂质以改善这种烷基化催化剂的循环长度。在脱水区中除去水和一部分杂质。具有第一烷基化催化剂的第一烷基化区，在一些实施方案中为大孔分子筛，起到除去较大部分杂质如氮和其它物质的作用，并将较小部分的可烷基化芳族化合物烷基化。在一些实施方案中，第二烷基化区是中孔分子筛，起到除去较少部分杂质的作用，并使大部分可烷基化芳族化合物烷基化。

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