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1. 发明授权

US5489701A Process for the preparation of silane polysulfides 失效
标题翻译：硅烷多硫化物的制备方法
公开(公告)号：US5489701A
公开(公告)日：1996-02-06
申请号：US383480
申请日：1995-02-02
申请人： Thomas E. Childress , James S. Ritscher , Curtis L. Schilling, Jr. , Okey G. Tucker, Jr. , Donald G. Beddow
发明人： Thomas E. Childress , James S. Ritscher , Curtis L. Schilling, Jr. , Okey G. Tucker, Jr. , Donald G. Beddow
IPC分类号： C07F7/08 , C07F7/18
CPC分类号： C07F7/1892
摘要： Sulfur-containing organosilicon compounds useful as coupling agents in vulcanizable rubbers to enhance various properties, including low rolling resistance for automobile tires, are prepared. Preferred compounds include .OMEGA.,.OMEGA.'-bis (trialkoxysilylalkyl) polysulfides. The compounds are prepared by reacting sodium ethoxylate with hydrogen sulfide gas to yield a sodium sulfide solution, and then reacting this product with a slurried mixture of elemental sulfur and chloropropyltriethoxysilane to form the compound 3,3'-bis (triethoxysilylpropyl) tetrasulfide. The use of hydrogen sulfide gas and sodium metal alcoholates provides an efficient and economical process.
摘要翻译：制备可硫化橡胶中用作偶联剂的硫磺有机硅化合物，以增强各种性能，包括汽车轮胎的低滚动阻力。优选的化合物包括OMEGA，OMEGA'-双（三烷氧基甲硅烷基烷基）多硫化物。该化合物通过使乙氧基钠与硫化氢气体反应制得，得到硫化钠溶液，然后使该产物与元素硫和氯丙基三乙氧基硅烷的浆状混合物反应形成化合物3,3'-双（三乙氧基甲硅烷基丙基）四硫化物。使用硫化氢气体和金属醇钠提供了一个有效和经济的过程。

2. 发明授权

US5166384A Method for the removal of siloxane dissolved in the solvent employed in the preparation of trimethoxysilane via methanol-silicon metal reaction 失效
标题翻译：通过甲醇 - 硅金属反应去除溶解在用于制备三甲氧基硅烷的溶剂中的硅氧烷的方法
公开(公告)号：US5166384A
公开(公告)日：1992-11-24
申请号：US864795
申请日：1992-04-07
申请人： Donald L. Bailey , Thomas E. Childress , Robert L. Ocheltree , James S. Ritscher
发明人： Donald L. Bailey , Thomas E. Childress , Robert L. Ocheltree , James S. Ritscher
IPC分类号： C07F7/02 , C07F7/04 , C07F7/20
CPC分类号： C07F7/025 , C07F7/045 , C07F7/20
摘要： In a trimethoxysilane preparation from silicon metal and methanol which preparation uses a solvent, a method for removing a siloxane dissolved in the solvent, which method comprises contacting the solvent with a boron-oxygen compound, and optionally an alkali metal alkoxide such as sodium methoxide.

3. 发明授权

US5084590A Trimethoxysilane preparation via the methanol-silicon reaction using a continuous process and multiple reactors 失效
标题翻译：通过使用连续工艺和多个反应器的甲醇 - 硅反应制备三甲氧基硅烷
公开(公告)号：US5084590A
公开(公告)日：1992-01-28
申请号：US719938
申请日：1991-06-24
申请人： James S. Ritscher , Thomas E. Childress
发明人： James S. Ritscher , Thomas E. Childress
IPC分类号： C07F7/02 , C07F7/04
CPC分类号： C07F7/025 , C07F7/045
摘要： A continuous process for producing trimethoxysilane by reacting methanol and silicon metal in the presence of a copper catalyst, and optionally in an inert solvent, in a multiple reactor system containing at least three reactors by having methanol in substantially vapor form flow countercurrently to a stream containing the silicon metal.
摘要翻译：在含有至少三个反应器的多反应器系统中，在铜催化剂和任选的惰性溶剂的存在下，通过使甲醇和硅金属反应生成三甲氧基硅烷的连续方法，其中含有基本上蒸汽形式的甲醇与含有硅金属。

4. 发明授权

US4999446A Trimethoxysilane preparation via the methanol-silicon reaction with recycle 失效
标题翻译：通过甲醇 - 硅反应制备三甲氧基硅烷，再循环
公开(公告)号：US4999446A
公开(公告)日：1991-03-12
申请号：US541516
申请日：1990-06-21
申请人： Lawrence G. Moody , Thomas E. Childress , Robert L. Pitrolo , James S. Ritscher , Ronald P. Leichliter
发明人： Lawrence G. Moody , Thomas E. Childress , Robert L. Pitrolo , James S. Ritscher , Ronald P. Leichliter
IPC分类号： B01J23/72 , C07B61/00 , C07F7/02 , C07F7/04 , C07F7/20
CPC分类号： C07F7/20 , C07F7/025 , C07F7/045
摘要： A process for producing trimethoxysilane by reacting methanol and silicon metal in the presence of a copper catalyst, and optionally an inert solvent, in which the trimethoxysilane-methanol azeotrope is recycled, characterized by maintaining a 60% methanol conversion.

5. 发明授权

US06489500B2 Continuous transesterification process for alkoxyorganosilicon compounds 有权
标题翻译：烷氧基有机硅化合物的连续酯交换法
公开(公告)号：US06489500B2
公开(公告)日：2002-12-03
申请号：US10081192
申请日：2002-02-25
申请人： Mark P. Bowman , Thomas E. Childress , Frank D. Mendicino , R. Ingrid Warren
发明人： Mark P. Bowman , Thomas E. Childress , Frank D. Mendicino , R. Ingrid Warren
IPC分类号： C07F708
CPC分类号： C07F7/188
摘要： A process is disclosed for the continuous transesterification of alkoxysilanes wherein an alkoxysilane is transformed to a different alkoxysilane in the presence of a catalyst and at least one alcohol that provides the different alkoxy group.
摘要翻译：公开了一种用于连续酯交换烷氧基硅烷的方法，其中烷氧基硅烷在催化剂和至少一种提供不同烷氧基的醇的存在下转化为不同的烷氧基硅烷。

6. 发明授权

US5466848A Process for the preparation of silane polysulfides 失效
标题翻译：硅烷多硫化物的制备方法
公开(公告)号：US5466848A
公开(公告)日：1995-11-14
申请号：US314204
申请日：1994-09-28
申请人： Thomas E. Childress
发明人： Thomas E. Childress
IPC分类号： C07F7/18 , C07F7/04
CPC分类号： C07F7/1892
摘要： Sulfur-containing organosilicon compounds useful as coupling agents in vulcanizable rubbers to enhance various properties, including low rolling resistance for automobile tires, are prepared. Preferred compounds include .OMEGA., 106 '-bis (trialkoxysilylalkyl) polysulfides. In the preferred process scheme, sodium ethoxylate is reacted with hydrogen sulfide gas to yield sodium sulfide. The sodium sulfide is then reacted with sulfur to form the tetrasulfide. The product of that reaction is then reacted with chloropropyltriethoxysilane to form the compound 3,3'- bis (triethoxysilylpropyl) tetrasulfide. The use of hydrogen sulfide gas and sodium metal alcoholates provides an efficient and economical process.
摘要翻译：制备可硫化橡胶中用作偶联剂的硫磺有机硅化合物，以增强各种性能，包括汽车轮胎的低滚动阻力。优选的化合物包括OMEGA，106'-双（三烷氧基甲硅烷基烷基）多硫化物。在优选的方法中，乙氧基化钠与硫化氢气体反应产生硫化钠。然后硫化钠与硫反应形成四硫化物。然后将该反应产物与氯丙基三乙氧基硅烷反应，形成四硫化合物3,3'-双（三乙氧基甲硅烷基丙基）化合物。使用硫化氢气体和金属醇钠提供了一个有效和经济的过程。

7. 再颁专利

USRE39650E1 Surface-active additives in the direct synthesis of trialkoxysilanes 有权
标题翻译：直接合成三烷氧基硅烷的表面活性添加剂
公开(公告)号：USRE39650E1
公开(公告)日：2007-05-22
申请号：US09488672
申请日：2000-01-20
申请人： Frank D. Mendicino , Kenrick M. Lewis , Sebastiano Magri , Hua Yu , Thomas E. Childress
发明人： Frank D. Mendicino , Kenrick M. Lewis , Sebastiano Magri , Hua Yu , Thomas E. Childress
IPC分类号： C07F7/04 , C07F7/18
CPC分类号： C07F7/025
摘要： Disclosed is a process in which surface-active additives are used in the slurry phase Direct Synthesis of trialkoxysilanes to shorten the period between the start of the reaction and the attainment of steady-state rates and selectivities, to improve product yields and to control or prevent foam formation. Compositions comprising silicone antifoam compounds and fluorosilicone polymers are the preferred surface-active additives of the instant process.
摘要翻译：公开了一种在浆料相中使用表面活性添加剂直接合成三烷氧基硅烷以缩短反应开始和获得稳态速率和选择性之间的时间段以提高产物产率并控制或防止的过程泡沫形成。包含硅氧烷消泡化合物和氟硅氧烷聚合物的组合物是本方法优选的表面活性添加剂。

8. 发明授权

US4864044A Tin containing activated silicon for the direct reaction 失效
标题翻译：含有活性硅的锡用于直接反应
公开(公告)号：US4864044A
公开(公告)日：1989-09-05
申请号：US702230
申请日：1985-02-15
申请人： Kenrick M. Lewis , Thomas E. Childress
发明人： Kenrick M. Lewis , Thomas E. Childress
IPC分类号： B01J21/14 , B01J23/14 , C07B61/00 , C07F7/16
CPC分类号： C07F7/16
摘要： An improved Direct Reaction process which comprises reacting an organohalide with an activated silicon composition, the improvement comprising maintaining the composition of the activated silicon so that it comprises, based on the amount of silicon, 0.05-10 wt. % catalyst; an effective amount of promoter, and 0.001-0.1 wt. % tin, wherein the promoter to tin ratio is 10-250. Activated silicon compositions and methods for selecting a catalyst composition also are provided.
摘要翻译：改进的直接反应方法，其包括使有机卤化物与活化的硅组合物反应，改进包括保持活化硅的组成，使得其基于硅的量包含0.05-10wt。％催化剂; 有效量的促进剂，和0.001-0.1wt。％锡，其中助催化剂与锡的比例为10-250。还提供活性硅组合物和选择催化剂组合物的方法。

9. 发明授权

US4761492A Process for recovering trimethoxysilane from a trimethoxysilane and methanol mixture 失效
标题翻译：从三甲氧基硅烷和甲醇混合物中回收三甲氧基硅烷的方法
公开(公告)号：US4761492A
公开(公告)日：1988-08-02
申请号：US101408
申请日：1987-09-28
申请人： Thomas E. Childress , George M. Omietanski , Frank D. Mendicino
发明人： Thomas E. Childress , George M. Omietanski , Frank D. Mendicino
IPC分类号： C07F7/04
CPC分类号： C07F7/04
摘要： An extractive distillation process for recovering trimethoxysilane from a trimethoxysilane-methanol mixture is provided using as the extractive solvent tetramethoxysilane.

10. 发明授权

US5783720A Surface-active additives in the direct synthesis of trialkoxysilanes 失效
标题翻译：直接合成三烷氧基硅烷的表面活性添加剂
公开(公告)号：US5783720A
公开(公告)日：1998-07-21
申请号：US729266
申请日：1996-10-10
申请人： Frank D. Mendicino , Thomas E. Childress , Sebastiano Magri , Kenrick M. Lewis , Hua Yu
发明人： Frank D. Mendicino , Thomas E. Childress , Sebastiano Magri , Kenrick M. Lewis , Hua Yu
IPC分类号： C07F7/02 , C07F7/04 , C07F7/18
CPC分类号： C07F7/025
摘要： Disclosed is a process in which surface-active additives are used in the slurry phase Direct Synthesis of trialkoxysilanes to shorten the period between the start of the reaction and the attainment of steady-state rates and selectivities, to improve product yields and to control or prevent foam formation. Compositions comprising silicone antifoam compounds and fluorosilicone polymers are the preferred surface-active additives of the instant process.
摘要翻译：公开了一种在浆料相中使用表面活性添加剂直接合成三烷氧基硅烷以缩短反应开始和获得稳态速率和选择性之间的时间段以提高产物产率并控制或防止的过程泡沫形成。包含硅氧烷消泡化合物和氟硅氧烷聚合物的组合物是本方法优选的表面活性添加剂。

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