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1. 发明授权

US5354822A Methods for preparing functionalized polymer and elastomeric compounds having reduced hysteresis 失效
标题翻译：制备具有降低滞后性的功能化聚合物和弹性体化合物的方法
公开(公告)号：US5354822A
公开(公告)日：1994-10-11
申请号：US941558
申请日：1992-09-08
申请人： Thomas A. Antkowiak , David F. Lawson , Russell W. Koch , Mark L. Stayer, Jr.
发明人： Thomas A. Antkowiak , David F. Lawson , Russell W. Koch , Mark L. Stayer, Jr.
IPC分类号： B60C1/00 , C08C19/26 , C08C19/44 , C08F4/00 , C08F4/42 , C08F4/48 , C08F8/42 , C08F12/00 , C08F12/08 , C08F36/00 , C08F36/04 , C08F36/06 , C08F297/04 , C08K3/02 , C08K3/04 , C08L21/00 , C08F8/30
CPC分类号： C08F4/48 , C08C19/44 , C08F36/04
摘要： An anionic polymerization initiator comprising the reaction product of a functionalizing agent selected from the group consisting of substituted aldimines, ketimines and secondary amines and, an organolithium compound. Elastomeric polymers prepared with these initiators have functional sites incorporated at the initiator end of the polymer chain and provide vulcanizable rubber compounds exhibiting reduced hysteresis. Articles such as tires, produced with low hysteresis elastomeric polymers have lower rolling resistance. Methods are also provided for preparing the initiators, functionalized polymers and vulcanizable elastomeric compounds having reduced hysteresis.
摘要翻译：一种阴离子聚合引发剂，其包含选自取代的醛亚胺，酮亚胺和仲胺的官能化试剂的反应产物和有机锂化合物。用这些引发剂制备的弹性体聚合物具有并入聚合物链的引发剂末端的功能性位点，并提供具有降低的滞后性的可硫化橡胶化合物。用低滞后弹性体聚合物制成的轮胎等制品具有较低的滚动阻力。还提供了用于制备具有降低的滞后的引发剂，官能化聚合物和可硫化弹性体化合物的方法。

2. 发明授权

US5066729A Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines 失效
标题翻译：通过与N-烷基和N-亚氨基反应终止的二烯聚合物和共聚物
公开(公告)号：US5066729A
公开(公告)日：1991-11-19
申请号：US506306
申请日：1990-04-09
申请人： Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
发明人： Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
IPC分类号： C08C19/22 , B60C1/00 , C08C19/44 , C08F8/30 , C08F36/00 , C08F36/04 , C08F136/04 , C08F236/10 , C08L47/00
CPC分类号： C08C19/44 , B60C1/0016
摘要： A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.
摘要翻译：提供了一种通过二烯单体或二烯单体和乙烯基芳族烃单体的混合物的阴离子聚合获得的活性聚合物制备末端官能化聚合物的方法，其包括使活性聚合物与具有下式的化合物反应：其中R 1和R 2选自H，烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 其中R 3选自烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 条件是R1，R2和R3基团中的至少一个必须是二烷基氨基芳基，并且不是所有的R 1，R 2和R 3基团都可以是芳基。所得的末端官能化聚合物具有降低的滞后性能，并且可用于制备具有降低的滚动阻力的弹性体组合物和轮胎胎面。

3. 发明授权

US5268413A Elastomers and products having reduced hysteresis 失效
标题翻译：弹性体和滞后性降低的产品
公开(公告)号：US5268413A
公开(公告)日：1993-12-07
申请号：US791910
申请日：1991-11-13
申请人： Thomas A. Antkowiak , David F. Lawson , Russell W. Koch , Mark L. Stayer, Jr.
发明人： Thomas A. Antkowiak , David F. Lawson , Russell W. Koch , Mark L. Stayer, Jr.
IPC分类号： C08C19/44 , C08F4/48 , C08F36/04 , C08K3/04
CPC分类号： C08F4/48 , C08C19/44 , C08F36/04
摘要： An anionic polymerization initiator comprising the reaction product of a functionalizing agent selected from the group consisting of substituted aldimines, ketimines and secondary amines and, an organolithium compound. Elastomeric polymers prepared with these initiators have functional sites incorporated at the initiator end of the polymer chain and provide vulcanizable rubber compounds exhibiting reduced hysteresis. Articles such as tires, produced with low hysteresis elastomeric polymers have lower rolling resistance. Methods are also provided for preparing the initiators, functionalized polymers and vulcanizable elastomeric compounds having reduced hysteresis.
摘要翻译：一种阴离子聚合引发剂，其包含选自取代的醛亚胺，酮亚胺和仲胺的官能化试剂的反应产物和有机锂化合物。用这些引发剂制备的弹性体聚合物具有并入聚合物链的引发剂末端的功能性位点，并提供具有降低的滞后性的可硫化橡胶化合物。用低滞后弹性体聚合物制成的轮胎等制品具有较低的滚动阻力。还提供了用于制备具有降低的滞后的引发剂，官能化聚合物和可硫化弹性体化合物的方法。

4. 发明授权

US5109907A Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines 失效
标题翻译：通过与N-烷基和N-芳基亚胺反应终止二烯聚合物和共聚物
公开(公告)号：US5109907A
公开(公告)日：1992-05-05
申请号：US732851
申请日：1991-07-19
申请人： Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
发明人： Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
IPC分类号： B60C1/00 , C08C19/44
CPC分类号： C08C19/44 , B60C1/0016
摘要： A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.
摘要翻译：提供了一种通过二烯单体或二烯单体和乙烯基芳族烃单体的混合物的阴离子聚合获得的活性聚合物制备末端官能化聚合物的方法，其包括使活性聚合物与具有下式的化合物反应：其中R 1和R 2选自H，烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 其中R 3选自烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 条件是R1，R2和R3基团中的至少一个必须是二烷基氨基芳基，并且不是所有的R 1，R 2和R 3基团都可以是芳基。所得的末端官能化聚合物具有降低的滞后性能，并且可用于制备具有降低的滚动阻力的弹性体组合物和轮胎胎面。

5. 发明授权

US5153159A Elastomers and products having reduced hysteresis 失效
标题翻译：弹性体和具有减少滞后性的产品
公开(公告)号：US5153159A
公开(公告)日：1992-10-06
申请号：US506305
申请日：1990-04-09
申请人： Thomas A. Antkowiak , David F. Lawson , Russell W. Koch , Mark L. Stayer, Jr.
发明人： Thomas A. Antkowiak , David F. Lawson , Russell W. Koch , Mark L. Stayer, Jr.
IPC分类号： B60C1/00 , C08C19/26 , C08C19/44 , C08F4/00 , C08F4/42 , C08F4/48 , C08F8/42 , C08F12/00 , C08F12/08 , C08F36/00 , C08F36/04 , C08F36/06 , C08F297/04 , C08K3/02 , C08K3/04 , C08L21/00
CPC分类号： C08F4/48 , C08C19/44 , C08F36/04
摘要： An anionic polymerization initiator comprising the reaction product of a functionalizing agent selected from the group consisting of substituted aldimines, ketimines and secondary amines and, an organolithium compound. Elastomeric polymers prepared with these initiators have functional sites incorporated at the initiator end of the polymer chain and provide vulcanizable rubber compounds exhibiting reduced hysteresis. Articles such as tires, produced with low hysteresis elastomeric polymers have lower rolling resistance. Methods are also provided for preparing the initiators, fuctionalized polymers and vulcanizable elastomeric compounds having reduced hysteresis.

6. 发明授权

US08022817B2 Tire with monitoring device 有权
标题翻译：轮胎带监控装置
公开(公告)号：US08022817B2
公开(公告)日：2011-09-20
申请号：US12563811
申请日：2009-09-21
申请人： Paul B. Wilson , Russell W. Koch , Robert J. Trew
发明人： Paul B. Wilson , Russell W. Koch , Robert J. Trew
IPC分类号： B60R25/10
CPC分类号： H01Q1/2241 , B29D2030/0072 , B29D2030/0077 , B60C23/0433 , B60C23/0493 , H01Q1/22 , Y10T29/49018
摘要： The invention provides a monitoring device and tire combination wherein an antenna is mounted to the tire in a location spaced from the monitoring device. In one embodiment, the antenna may be mounted to the tire sidewall outside the body cords of the tire. The antenna may be mounted on the outer surface of the sidewall or embedded within the body of the sidewall. The antenna is connected to the monitoring device with a connector. The connector may be electrically coupled to the monitoring device or may be connected to the monitoring device with a plug and socket connection. When the antenna is outside the body cord, the connector may extend from the antenna through the bead filler, over the top of the turn up, or under the bead ring.
摘要翻译：本发明提供了一种监测装置和轮胎组合，其中在与监测装置间隔开的位置处将天线安装到轮胎上。在一个实施例中，天线可以安装到轮胎的主体帘线外侧的轮胎胎侧。天线可以安装在侧壁的外表面上或嵌入在侧壁的主体内。天线通过连接器连接到监控设备。连接器可以电耦合到监视装置，或者可以通过插头和插座连接连接到监视装置。当天线在身体线外时，连接器可以从天线穿过胎圈填充物，在翻转的顶部或胎圈环下方延伸。

7. 发明授权

US07186845B2 Polymer-filler coupling additives 有权
标题翻译：聚合物 - 填料偶联添加剂
公开(公告)号：US07186845B2
公开(公告)日：2007-03-06
申请号：US10969573
申请日：2004-10-20
申请人： Yasuo Fukushima , Russell W. Koch , William L. Hergenrother , Shunji Araki
发明人： Yasuo Fukushima , Russell W. Koch , William L. Hergenrother , Shunji Araki
IPC分类号： C07D249/16 , C08K9/00 , C08F36/00
CPC分类号： C08K5/353 , C07D263/14 , C07D277/10 , C08K5/32 , C08L21/00
摘要： Dispersion of filler(s) in polymeric compositions are improved by the use of a polymer-filler coupling compound, Q—A—B, wherein Q comprises a dipolar nitrogen-containing moiety that can form a 1,3 dipolar addition to an unsaturated carbon-carbon bond; B is an oxazoline, thiazoline, alkoxysilane or allyltin moiety, and A is a linking atom or group that forms a bridge between Q and B.
摘要翻译：通过使用聚合物 - 填料偶联化合物Q-A-B改善了填料在聚合物组合物中的分散性，其中Q包括可以形成不饱和碳 - 碳键的1,3-偶极加成的偶极含氮部分; B是恶唑啉，噻唑啉，烷氧基硅烷或烯丙基锡部分，A是在Q和B之间形成桥的连接原子或基团。

8. 发明授权

US07009506B2 Electronic monitoring device and patch assembly 有权
公开(公告)号：US07009506B2
公开(公告)日：2006-03-07
申请号：US10192567
申请日：2002-07-09
申请人： Paul B. Wilson , John D. Rensel , Russell W. Koch
发明人： Paul B. Wilson , John D. Rensel , Russell W. Koch
IPC分类号： B60C23/00
CPC分类号： B60C23/0493 , B29D2030/0072 , B29D2030/0077 , B60C23/04 , B60C23/0433
摘要： A monitoring device and patch assembly includes a patch that removably and re-attachably holds the monitoring device. The patch is adapted to connect the monitoring device to a pneumatic tire when the monitoring device is held by the patch. The patch is configured to hold a monitoring device having a rounded outer surface. The patch holds the rounded monitoring device by having a resilient tube with an outlet having a diameter smaller than the diameter of the monitoring device. The monitoring device of the invention includes a feature that allows it to be removed from the patch.

9. 发明授权

US06719279B1 Air spring sleeve 失效
标题翻译：空气弹簧套
公开(公告)号：US06719279B1
公开(公告)日：2004-04-13
申请号：US10225806
申请日：2002-08-21
申请人： Russell W. Koch , John D. Rensel
发明人： Russell W. Koch , John D. Rensel
IPC分类号： F16F904
CPC分类号： F16F9/05 , B60G2206/424 , F16F9/0409 , F16F9/0463
摘要： A flexible sleeve for an air spring terminates in end portions which define a pair of open ends. The sleeve has inner and outer layers of a flexible material with a plurality of reinforcement elements disposed within the materials with the reinforcement elements extending throughout the end portions. Inner and outer layers of the end portions are joined to the inner and outer layers of the sleeve, by non-overlapping joints with the inner and outer layers of the end portions having a higher modulus of elasticity than the inner and outer layers of the sleeve.
摘要翻译：用于空气弹簧的柔性套筒终止于限定一对开口端的端部。套筒具有柔性材料的内层和外层，其中多个加强元件设置在材料内，增强元件贯穿端部延伸。端部的内层和外层通过不重叠的接头连接到套筒的内层和外层，端部的内层和外层具有比套筒的内层和外层更高的弹性模量。

10. 发明授权

US06477894B1 Method for preparing an innerliner of a pneumatic tire for the quick bonding of an electronic monitoring device 有权
标题翻译：一种用于电子监控装置的快速接合的充气轮胎的内衬的制备方法
公开(公告)号：US06477894B1
公开(公告)日：2002-11-12
申请号：US09613130
申请日：2000-07-10
申请人： Russell W. Koch , Paul B. Wilson , Michelle R. Stalnaker
发明人： Russell W. Koch , Paul B. Wilson , Michelle R. Stalnaker
IPC分类号： G01M1702
CPC分类号： B60C23/0493 , B29D2030/0072 , B29D2030/0077 , B60C5/14
摘要： A method for preparing an innerliner of a pneumatic tire and adhering an electronic monitoring device to the innerliner includes the step of providing a patch having a cover and a layer of uncured rubber. The patch is placed at a selected area of the innerliner of a green tire before the green tire is cured. At least a portion of the patch is removed after the tire is cured to provide a prepared area at the selected area of the tire. The electronic monitoring device is then adhered to the prepared area.
摘要翻译：一种制备充气轮胎的内衬并将电子监测装置粘附到内衬的方法包括提供具有盖和未固化橡胶层的贴剂的步骤。在生轮胎固化之前，将补片放置在生胎的内衬层的选定区域。在轮胎固化之后，去除补片的至少一部分，以在轮胎的选定区域提供准备的区域。然后将电子监控装置粘贴到准备的区域。

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