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    • 3. 发明授权
    • Elastomers with improved processability
    • 具有改善加工性能的弹性体
    • US06376620B2
    • 2002-04-23
    • US09755700
    • 2001-01-08
    • Michael E. RowlandChe I. Kao
    • Michael E. RowlandChe I. Kao
    • C08F800
    • C08J3/244C08F8/00C08F2800/20C08F2810/20C08J2323/16C08K5/14C08F210/18C08L23/16
    • A process for improving the green strength of ethylene/&agr;-olefin/diene polymers is described comprising (A) selecting an ethylene/&agr;olefin/diene polymer having a Mooney viscosity at 125 C up to about 80 and a percent gel (% gel) up to about 30 percent and (B) partially crosslinking the ethylene/&agr;-olefin/diene polymer selected in step (A) to make a modified ethylene/&agr;-olefin/diene polymer satisfying the equations MV≦100 and MV ≤   ⁢ 100 W ≤   ⁢ ( MS 2 - MS 1 MS 1 ) wherein MV is the Mooney viscosity of the modified polymer, MS1 is the melt strength in centiNewtons of the polymer selected in step (A) at 110 C, when formulated according to ASTM D3568#2, MS2 is the melt strength in centiNewtons of the modified polymer produced by step (B) measured under the same conditions, and W is 0.3. Modified ethylene/&agr;-olefin/diene polymers obtainable according to the above process or satisfying the equation: MS 2 ≥   ⁢ ( MV X + % ⁢   ⁢ gel Y ) ⁢ Z is also described in which MS2, MV and % gel of the modified polymer are defined as defined above, X is 50, Y is 20, and Z is 40. Further described is a process for making an article comprising an ethylene/&agr;-olefin/diene polymer and intermediates for making the modified ethylene/&agr;-olefin/diene polymers.
    • 描述了一种用于改善乙烯/α-烯烃/二烯聚合物的生坯强度的方法,其包括(A)选择在125℃至约80的门尼粘度和凝胶百分比(%凝胶)上的乙烯/α-烯烃/二烯聚合物 至约30%,和(B)部分交联在步骤(A)中选择的乙烯/α-烯烃/二烯聚合物,以制备满足式MV = 100的改性乙烯/α-烯烃/二烯聚合物,其中MV为门尼粘度 的改性聚合物,MS1是在110℃下在步骤(A)中选择的聚合物的熔体强度,以当量配制的ASTM D3568#2时的熔体强度,MS2是由步骤(B)制备的改性聚合物的熔体强度, )在相同条件下测量,W为0.3。 还描述了根据上述方法获得的或满足以下等式可获得的改性乙烯/α-烯烃/二烯聚合物:其中改性聚合物的MS2,MV和%凝胶如上定义,X​​为50,Y为20,和 Z是40.进一步描述了制备包含乙烯/α-烯烃/二烯聚合物的制品和制备改性乙烯/α-烯烃/二烯聚合物的中间体的方法。
    • 4. 发明授权
    • Non-adiabatic olefin solution polymerization
    • 非绝热烯烃溶液聚合
    • US5977251A
    • 1999-11-02
    • US831172
    • 1997-04-01
    • Che I. KaoR. Bruce CombsGary A. CampDavid A. EversdykPradeep JainGreg A. WinterJeff H. Stultz
    • Che I. KaoR. Bruce CombsGary A. CampDavid A. EversdykPradeep JainGreg A. WinterJeff H. Stultz
    • B01J19/24C08F2/06C08F10/00C08F210/16
    • C08F10/00B01J19/2435B01J19/245B01J19/2465B01J2219/00085B01J2219/00103B01J2219/00159B01J2219/00162B01J2219/00168B01J2219/00765C08F210/16Y02P20/584Y10S526/905
    • A solution polymerization system for polymerizing a olefin monomer by reacting the monomer with catalyst and solvent has been invented. The system in one aspect including a flow loop with a product polymer outlet, the flow loop forming a recycling reactor, a catalyst inlet on the flow loop through which catalyst and solvent flow into the flow loop, a monomer inlet on the flow loop through which monomer and solvent flow into the flow loop and, with the catalyst, form a reactant materials stream, a first heat exchanger on the flow loop for receiving the reactant materials stream and any formed polymer and for removing heat of reaction or polymerization from the flow loop, and pump apparatus for pumping the reactant materials stream and formed polymer in the flow loop and from the first heat exchanger to the product polymer outlet. In one aspect, the system includes at least one additional heat exchanger on the flow loop for receiving the reactant materials stream and formed polymer and for removing heat of reaction or polymerization from the flow loop, the pump apparatus pumping formed polymer and remaining reactant materials to the product polymer outlet, and a portion of the formed polymer and remaining reactant materials flowing out from the product polymer outlet and the remainder recycling through the flow loop. In one aspect systems and methods according to the present invention are used to make polyethylene.
    • 已经发明了通过使单体与催化剂和溶剂反应来使烯烃单体聚合的溶液聚合体系。 该系统在一个方面包括具有产物聚合物出口的流动回路,形成循环反应器的流动回路,流动回路上的催化剂入口,催化剂和溶剂通过该回路进入流动回路,流动回路上的单体入口, 单体和溶剂流入流动回路,并且与催化剂形成反应物料流,流动回路上用于接收反应物料流和任何形成的聚合物的第一热交换器,以及用于从流动回路除去反应或聚合的热量 以及泵装置,用于将反应物料流和形成的聚合物泵送在流动回路中并从第一热交换器泵送到产物聚合物出口。 在一个方面,该系统在流动回路上包括至少一个额外的热交换器,用于接收反应物料流和形成的聚合物,并用于从流动回路除去反应或聚合的热量,泵设备将形成的聚合物和剩余的反应物材料泵送到 产物聚合物出口,以及形成的聚合物的一部分和剩余的反应物料从产物聚合物出口流出,其余反应物质通过流动回路循环。 一方面,根据本发明的系统和方法用于制备聚乙烯。
    • 9. 发明授权
    • Elastomers with improved processability
    • 具有改善加工性能的弹性体
    • US06232410B1
    • 2001-05-15
    • US09140575
    • 1998-08-26
    • Michael E. RowlandChe I. Kao
    • Michael E. RowlandChe I. Kao
    • C08F800
    • C08J3/244C08F8/00C08F2800/20C08F2810/20C08J2323/16C08K5/14C08F210/18C08L23/16
    • A process for improving the green strength of ethylene/&agr;-olefin/diene polymers is described comprising (A) selecting an ethylene/&agr;-olefin/diene polymer having a Mooney viscosity at 125 C up to about 80 and a percent gel (% gel) up to about 30 percent and (B) partially crosslinking the ethylene/&agr;-olefin/diene polymer selected in step (A) to make a modified ethylene/&agr;-olefin/diene polymer satisfying the equations MV≦100 and W ≤ ( MS 2 - MS 1 MS 1 ) wherein MV is the Mooney viscosity of the modified polymer, MS1 is the melt strength in centiNewtons of the polymer selected in step (A) at 110 C, when formulated according to ASTM D3568#2, MS2 is the melt strength in centiNewtons of the modified polymer produced by step (B) measured under the same conditions, and W is 0.3. Modified ethylene/&agr;-olefin/diene polymers obtainable according to the above process or satisfying the equation: MS 2 ≥ ( MV X + % ⁢   ⁢ gel Y ) ⁢ Z is also described in which MS2, MV and % gel of the modified polymer are defined as defined above, X is 50, Y is 20, and Z is 40. Further described is a process for making an article comprising an ethylene/&agr;-olefin/diene polymer and intermediates for making the modified ethylene/&agr;-olefin/diene polymers.
    • 描述了一种用于改善乙烯/α-烯烃/二烯聚合物的生坯强度的方法,其包括(A)选择在125℃至约80的门尼粘度和凝胶百分比(%凝胶)的乙烯/α-烯烃/二烯聚合物 )至多约30%,和(B)部分交联在步骤(A)中选择的乙烯/α-烯烃/二烯聚合物,以制备满足式MV = 100的改性乙烯/α-烯烃/二烯聚合物,其中MV为 改性聚合物的门尼粘度MS1是在步骤(A)中在110℃选择的聚合物的熔体强度,以110℃的摩尔数计,当根据ASTM D3568#2配制时,MS2是以步骤1制备的改性聚合物的熔体强度, (B)在相同条件下测量,W为0.3。 还描述了根据上述方法获得的或满足以下等式可获得的改性乙烯/α-烯烃/二烯聚合物:其中改性聚合物的MS2,MV和%凝胶如上定义,X​​为50,Y为20,和 Z是40.进一步描述了制备包含乙烯/α-烯烃/二烯聚合物的制品和制备改性乙烯/α-烯烃/二烯聚合物的中间体的方法。