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1. 发明授权

US08173570B2 Hydroconversion processes employing multi-metallic catalysts and method for making thereof 有权
标题翻译：采用多金属催化剂的加氢转化方法及其制备方法
公开(公告)号：US08173570B2
公开(公告)日：2012-05-08
申请号：US12259467
申请日：2008-10-28
申请人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman , Bi-Zeng Zhang , Andrew Rainis , Christopher J. Dillon
发明人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman , Bi-Zeng Zhang , Andrew Rainis , Christopher J. Dillon
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A catalyst precursor composition and methods for making such catalyst precursor are disclosed. The catalyst precursor comprises at least a Promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and a cellulose-containing material. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. In one embodiment, the sulfidation is carried out by contacting the catalyst precursor with hydrogen and a sulfur containing compound, wherein the contacting is carried out ex-situ. Catalysts prepared from such catalyst precursors have a fouling rate of less than 8° F. (4.4° C.) per 1000 hour.
摘要翻译：公开了催化剂前体组合物和制备这种催化剂前体的方法。催化剂前体至少包含选自VIII族，IIB族，IIA族，IVA族及其组合的至少一种促进剂金属，至少一种VIB族金属，至少一种有机，含氧配体和含纤维素材料。由这些催化剂前体的硫化制备的催化剂用于烃进料的加氢处理。在一个实施方案中，硫化是通过使催化剂前体与氢和含硫化合物接触进行的，其中接触是非原位进行的。由这种催化剂前体制备的催化剂每1000小时的结垢率小于8°F（4.4℃）。

2. 发明授权

US08563456B2 Hydrodemetallization catalyst and process 有权
标题翻译：加氢脱金属催化剂和工艺
公开(公告)号：US08563456B2
公开(公告)日：2013-10-22
申请号：US12245531
申请日：2008-10-03
申请人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
发明人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
IPC分类号： B01J21/16 , C01B33/26 , C01B33/24
CPC分类号： C10G45/04 , B01J21/16 , B01J23/24 , B01J23/28 , B01J23/40 , B01J23/74 , B01J23/85 , B01J23/883 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/20 , B01J37/28 , C01B33/40 , C10G2300/1022 , C10G2300/1074 , C10G2300/1077 , C10G2300/206 , C10G2300/4018
摘要： This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrodemetallization catalysts and processes.
摘要翻译：本发明涉及使用硅铝酸镁粘土的加氢脱金属催化剂和加氢脱金属化方法。硅铝酸镁粘土具有特征29 Si NMR光谱。铝硅酸镁粘土是一系列具体反应步骤的产物。简而言之，本发明的催化剂和方法中所用的硅铝酸镁粘土是通过在含水条件下和酸性pH下混合硅组分，铝组分和镁组分来形成第一反应混合物，随后将将第一反应混合物的pH调节至大于约7.5以形成第二反应混合物。允许第二反应混合物在足以形成硅铝酸镁粘土的条件下反应。所得到的硅铝酸镁粘土具有高表面积和活性，用于加氢脱金属催化剂和工艺。

3. 发明申请

US20120000828A1 HYDRODEMETALLIZATION CATALYST AND PROCESS 有权
标题翻译：氢化催化剂和工艺
公开(公告)号：US20120000828A1
公开(公告)日：2012-01-05
申请号：US13236438
申请日：2011-09-19
申请人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
发明人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
IPC分类号： C10G29/04
CPC分类号： C10G45/04 , B01J21/16 , B01J23/24 , B01J23/28 , B01J23/40 , B01J23/74 , B01J23/85 , B01J23/883 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/20 , B01J37/28 , C01B33/40 , C10G2300/1022 , C10G2300/1074 , C10G2300/1077 , C10G2300/206 , C10G2300/4018
摘要： This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrodemetallization catalysts and processes.
摘要翻译：本发明涉及使用硅铝酸镁粘土的加氢脱金属催化剂和加氢脱金属化方法。硅铝酸镁粘土具有特征29 Si NMR光谱。铝硅酸镁粘土是一系列具体反应步骤的产物。简而言之，本发明的催化剂和方法中所用的硅铝酸镁粘土是通过在含水条件下和酸性pH下混合硅组分，铝组分和镁组分来形成第一反应混合物，随后将将第一反应混合物的pH调节至大于约7.5以形成第二反应混合物。允许第二反应混合物在足以形成硅铝酸镁粘土的条件下反应。所得到的硅铝酸镁粘土具有高表面积和活性，用于加氢脱金属催化剂和工艺。

4. 发明申请

US20100084311A1 HYDRODEMETALLIZATION CATALYST AND PROCESS 有权
标题翻译：氢化催化剂和工艺
公开(公告)号：US20100084311A1
公开(公告)日：2010-04-08
申请号：US12245531
申请日：2008-10-03
申请人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
发明人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
IPC分类号： C10G65/00 , C01B33/26 , B01J21/02 , B01J21/16 , B01J21/10 , B01J21/06
CPC分类号： C10G45/04 , B01J21/16 , B01J23/24 , B01J23/28 , B01J23/40 , B01J23/74 , B01J23/85 , B01J23/883 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/20 , B01J37/28 , C01B33/40 , C10G2300/1022 , C10G2300/1074 , C10G2300/1077 , C10G2300/206 , C10G2300/4018
摘要： This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrodemetallization catalysts and processes.
摘要翻译：本发明涉及使用硅铝酸镁粘土的加氢脱金属催化剂和加氢脱金属化方法。硅铝酸镁粘土具有特征29 Si NMR光谱。铝硅酸镁粘土是一系列具体反应步骤的产物。简而言之，本发明的催化剂和方法中所用的硅铝酸镁粘土是通过在含水条件下和酸性pH下混合硅组分，铝组分和镁组分来形成第一反应混合物，随后将将第一反应混合物的pH调节至大于约7.5以形成第二反应混合物。允许第二反应混合物在足以形成硅铝酸镁粘土的条件下反应。所得到的硅铝酸镁粘土具有高表面积和活性，用于加氢脱金属催化剂和工艺。

5. 发明授权

US08716164B2 Hydrodemetallization catalyst and process 有权
标题翻译：加氢脱金属催化剂和工艺
公开(公告)号：US08716164B2
公开(公告)日：2014-05-06
申请号：US13236438
申请日：2011-09-19
申请人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
发明人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
IPC分类号： B01J21/16 , B01J23/58 , C01B33/26 , C01B33/24
CPC分类号： C10G45/04 , B01J21/16 , B01J23/24 , B01J23/28 , B01J23/40 , B01J23/74 , B01J23/85 , B01J23/883 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/20 , B01J37/28 , C01B33/40 , C10G2300/1022 , C10G2300/1074 , C10G2300/1077 , C10G2300/206 , C10G2300/4018
摘要： This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrodemetallization catalysts and processes.
摘要翻译：本发明涉及使用硅铝酸镁粘土的加氢脱金属催化剂和加氢脱金属化方法。硅铝酸镁粘土具有特征29 Si NMR光谱。铝硅酸镁粘土是一系列具体反应步骤的产物。简而言之，本发明的催化剂和方法中所用的硅铝酸镁粘土是通过在含水条件下和酸性pH下混合硅组分，铝组分和镁组分来形成第一反应混合物，随后将将第一反应混合物的pH调节至大于约7.5以形成第二反应混合物。允许第二反应混合物在足以形成硅铝酸镁粘土的条件下反应。所得到的硅铝酸镁粘土具有高表面积和活性，用于加氢脱金属催化剂和工艺。

6. 发明申请

US20090111683A1 Hydroconversion Processes Employing Multi-Metallic Catalysts and Method for Making Thereof 有权
标题翻译：采用多金属催化剂的加氢转化方法及其制备方法
公开(公告)号：US20090111683A1
公开(公告)日：2009-04-30
申请号：US12259467
申请日：2008-10-28
申请人： Bi-Zeng Zhan , Alexander Kuperman , Theodorus Maesen , Andrew Rainis , Christopher J. Dillon
发明人： Bi-Zeng Zhan , Alexander Kuperman , Theodorus Maesen , Andrew Rainis , Christopher J. Dillon
IPC分类号： B01J31/04 , B01J27/049 , B01J27/051 , B01J27/047
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A catalyst precursor composition and methods for making such catalyst precursor are disclosed. The catalyst precursor comprises at least a Promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and a cellulose-containing material. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. In one embodiment, the sulfidation is carried out by contacting the catalyst precursor with hydrogen and a sulfur containing compound, wherein the contacting is carried out ex-situ. Catalysts prepared from such catalyst precursors have a fouling rate of less than 8° F. (4.4° C.) per 1000 hour.
摘要翻译：公开了催化剂前体组合物和制备这种催化剂前体的方法。催化剂前体至少包含选自VIII族，IIB族，IIA族，IVA族及其组合的至少一种促进剂金属，至少一种VIB族金属，至少一种有机，含氧配体和含纤维素材料。由这些催化剂前体的硫化制备的催化剂用于烃进料的加氢处理。在一个实施方案中，硫化是通过使催化剂前体与氢和含硫化合物接触进行的，其中接触是非原位进行的。由这种催化剂前体制备的催化剂每1000小时的结垢率小于8°F（4.4℃）。

7. 发明授权

US07300317B2 Electrical connector having a housing including an asymmetrical surface 有权
标题翻译：电连接器，其具有包括不对称表面的外壳
公开(公告)号：US07300317B2
公开(公告)日：2007-11-27
申请号：US11296691
申请日：2005-12-08
申请人： Christopher J. Dillon , Ping Chen
发明人： Christopher J. Dillon , Ping Chen
IPC分类号： H01R13/64
CPC分类号： H01R12/716
摘要： The invention relates to a connector device that includes a plurality of terminals of varying heights that extend upwardly from the surface of a circuit board, and a connector housing that defines a receptacle portion. The connector housing includes an asymmetrical surface adapted to receive a plurality of terminals, and each of the plurality of terminals extends through a portion of the asymmetrical surface into the receptacle portion of the connector housing. The asymmetrical surface may include a plurality of substantially parallel vertical sections separated by at least one substantially horizontal section, may be angled relative to the surface of the circuit board, or may be curved relative to the surface of the circuit board. In addition, at least a portion of the asymmetrical surface of the connector housing may protrude over at least a portion of at least one of the terminals extending between the circuit board and the asymmetrical surface. In addition, the invention provides a connector device wherein the asymmetrical surface allows for the reduction of the packaging size of the terminals and a reduction of the size of the terminals.
摘要翻译：本发明涉及一种连接器装置，其包括从电路板的表面向上延伸的多个不同高度的端子以及限定插座部分的连接器壳体。连接器壳体包括适于容纳多个端子的不对称表面，并且多个端子中的每个端子延伸穿过不对称表面的一部分进入连接器壳体的容纳部分。不对称表面可以包括由至少一个基本上水平的部分分开的多个基本上平行的垂直部分，其可以相对于电路板的表面成角度，或者可以相对于电路板的表面弯曲。此外，连接器壳体的不对称表面的至少一部分可以突出到在电路板和不对称表面之间延伸的至少一个端子的至少一部分上。此外，本发明提供了一种连接器装置，其中非对称表面允许减小端子的封装尺寸并减小端子的尺寸。

8. 发明授权

US07019165B2 Polyoxometallate catalysts and catalytic processes 失效
标题翻译：多金属氧酸盐催化剂和催化工艺
公开(公告)号：US07019165B2
公开(公告)日：2006-03-28
申请号：US11103205
申请日：2005-04-11
申请人： Mark E. Davis , Christopher J. Dillon , Joseph H. Holles , Jay A. Labinger , Axel Brait
发明人： Mark E. Davis , Christopher J. Dillon , Joseph H. Holles , Jay A. Labinger , Axel Brait
IPC分类号： C07C63/14 , C07C63/307 , C07C68/313
CPC分类号： C07C51/215 , B01J27/186 , B01J27/19 , B01J27/195 , B01J37/082 , C07C57/145 , C07C57/04
摘要： An active and selective hydrocarbon partial oxidation catalyst comprises an activated partially-reduced polyoxometallate, preferably niobium polyoxomolybdate, that is prepared from a suitable polyoxoanion, which has been exchanged with a suitable cation and activated by heating to an activation effective temperature in the presence of a suitable reducing agent such as pyridinium. C3 and C4 hydrocarbons may be partially oxidized selectively to acrylic acid and maleic acid.
摘要翻译：活性和选择性烃部分氧化催化剂包含活化的部分还原的多金属氧酸盐，优选铌聚氧钼酸盐，其由合适的多氧阴离子制备，其已经与合适的阳离子交换并通过在存在下加热至活化有效温度而被活化合适的还原剂如吡啶鎓。 C 3和C 4烃可以部分地被氧化成丙烯酸和马来酸。

9. 发明授权

US06914029B2 Polyoxometallate catalysts and catalytic processes 失效
标题翻译：多金属氧酸盐催化剂和催化工艺
公开(公告)号：US06914029B2
公开(公告)日：2005-07-05
申请号：US10286066
申请日：2002-11-01
申请人： Mark E. Davis , Christopher J. Dillon , Joseph H. Holles , Jay A. Labinger , Axel Brait
发明人： Mark E. Davis , Christopher J. Dillon , Joseph H. Holles , Jay A. Labinger , Axel Brait
IPC分类号： B01J27/198 , B01J27/186 , B01J27/19 , B01J27/195 , B01J37/08 , C07B61/00 , C07C51/215 , C07C57/05 , C07C57/145 , B01J31/00
CPC分类号： C07C51/215 , B01J27/186 , B01J27/19 , B01J27/195 , B01J37/082 , C07C57/145 , C07C57/04
摘要： An active and selective hydrocarbon partial oxidation catalyst comprises an activated partially-reduced polyoxometallate, preferably niobium polyoxomolybdate, that is prepared from a suitable polyoxoanion, which has been exchanged with a suitable cation and activated by heating to an activation effective temperature in the presence of a suitable reducing agent such as pyridinium. C3 and C4 hydrocarbons may be partially oxidized selectively to acrylic acid and maleic acid.
摘要翻译：活性和选择性烃部分氧化催化剂包含活化的部分还原的多金属氧酸盐，优选铌聚氧钼酸盐，其由合适的多氧阴离子制备，其已经与合适的阳离子交换并通过在存在下加热至活化有效温度而被活化合适的还原剂如吡啶鎓。 C 3和C 4烃可以部分地被氧化成丙烯酸和马来酸。

10. 发明授权

US06467942B2 Automotive lamp socket 失效
标题翻译：汽车灯座
公开(公告)号：US06467942B2
公开(公告)日：2002-10-22
申请号：US09837685
申请日：2001-04-18
申请人： Michael J. Alloway , Earl J. Hayes , Christopher J. Dillon , Thomas F. Rahrig
发明人： Michael J. Alloway , Earl J. Hayes , Christopher J. Dillon , Thomas F. Rahrig
IPC分类号： B60Q100
CPC分类号： H01R13/5208 , H01R13/504 , H01R24/20 , H01R33/965 , H01R2103/00 , H01R2201/26
摘要： A lamp assembly for use with a vehicle's electrical system, the electrical system including a plurality of terminals each having a wire insulating portion and an end connector portion. A main elastomeric housing includes a socket for receiving a bulb. A front seal encircles an exterior surface of the socket and seals around a periphery of the socket. A first plurality of sealing ridges extend along an open facing side of the main housing, opposite the bulb socket, and within which are received the wire insulating portions of the terminals and the end connector portions of each terminal conmmunicating with the bulb socket upon the terminals being located within the main housing. A back cap matingly aligns over an open facing side of the main housing and includes an opposingly facing side with a second plurality of sealing ridges which align with the first plurality of sealing ridges and to sandwich therebetween the wire insulating portions of the terminals. An inlet seal is seatingly received between aligning recesses defined between the opposingly facing sides of the main housing and the back cap and is located proximate the first and second pluralities of sealing ridges. Wire receiving apertures extend through the seal and into which are inserted the wire insulating portions of the terminals. An ultrasonic welding operation secures the back cap to the main elastomeric housing in a seal-tight manner.
摘要翻译：一种与车辆电气系统一起使用的灯组件，电气系统包括多个端子，每个端子均具有导线绝缘部分和端部连接器部分。主弹性体壳体包括用于接收灯泡的插座。前密封圈环绕插座的外表面并围绕插座的周边密封。第一多个密封脊沿着主壳体的面向开口的一侧延伸，与灯泡插座相对，并且其中接收端子的导线绝缘部分，并且每个端子的端部连接器部分与灯泡插座端接在端子上位于主壳体内。后盖匹配地对准主壳体的面向开口的一侧，并且包括相对的侧面，其具有与第一多个密封脊对准的第二多个密封脊，并且夹在其间的端子的线绝缘部分。入口密封件可靠地容纳在限定在主壳体和后盖的相对面对的侧面之间的对准凹部之间并且位于第一和第二多个密封脊附近。电线接收孔延伸穿过密封件，插入端子的电线绝缘部分。超声波焊接操作以密封的方式将后盖固定到主弹性体外壳。

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