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1. 发明授权

US4929469A Method of forming a tentative surface protective coating 失效
公开(公告)号：US4929469A
公开(公告)日：1990-05-29
申请号：US215564
申请日：1988-07-06
申请人： Tetsuya Kimura , Toshihiro Fujii , Hiroki Nii
发明人： Tetsuya Kimura , Toshihiro Fujii , Hiroki Nii
IPC分类号： B05D1/32 , B05D5/00 , H05K3/00 , H05K3/18 , H05K3/28
CPC分类号： H05K3/287 , H05K3/184 , B05D1/325 , H05K2203/0264 , H05K3/0076
摘要： A splendid tentative surface protective coating which is useful in treating a surface of a substance by soldering or plating and which is peeled off easily from the surface after the treating is formed by preparing a solventless or solvent free type screen ink based on essentially an ultraviolet ray-curable rubbery elastomer, applying a coating of the ink on the surface of the substrate by screen printing or thin film coating, and curing the coating of the ink by irradiation with an ultraviolet ray. The tentative surface protective coating can reproduce exactly a pattern of a mask or screen, have a high chemical resistance and heat resistance, even if it has a thin thickness of 30 .mu.m, and have no afraid of deformation caused by heat curing, whereby a precise and shortened surface treatment of the surface of the substance can be afforded. Also, working environment is improved, and air conditioning equipment can be dispensed with owing to an absence or diminishment of an organic solvent. In addition, according to the present invention, an excellent ink composition is provided which is much suited to screen printing.

2. 发明授权

US5085697A Method of forming a tentative surface protective coating 失效
标题翻译：形成临时表面保护涂层的方法
公开(公告)号：US5085697A
公开(公告)日：1992-02-04
申请号：US491865
申请日：1990-03-12
申请人： Tetsuya Kimura , Toshihiro Fujii , Hiroki Nii
发明人： Tetsuya Kimura , Toshihiro Fujii , Hiroki Nii
IPC分类号： B05D1/32 , B05D5/00 , H05K3/00 , H05K3/18 , H05K3/28
CPC分类号： H05K3/287 , H05K3/184 , B05D1/325 , H05K2203/0264 , H05K3/0076
摘要： A splendid tentative surface protective coating which is useful in treating a surface of a substance by soldering or plating and which is peeled off easily from the surface after the treating is formed by preparing a solventless or solvent free type screen ink based on essentially an ultraviolet ray-curable rubbery elastomer, applying a coating of the ink on the surface of the substrate by screen printing or thin film coating, and curing the coating of the ink by irradiation with an ultraviolet ray. The tentative surface protective coating can reproduce exactly a pattern of a mask or screen, have a high chemical resistance and heat resistance, even if it has a thin thickness of 30 .mu.m, and have no afraid of deformation caused by heat curing, whereby a precise and shortened surface treatment of the surface of the substance can be afforded. Also, working environment is improved, and air conditioning equipment can be dispensed with owing to an absence or diminishment of an organic solvent. In addition, according to the present invention, an excellent ink composition is provided which is much suited to screen printing.
摘要翻译：用于通过焊接或电镀处理物质表面的极好的暂时性表面保护涂层，并且通过制备基本上基本上为紫外线的无溶剂或无溶剂型屏幕油墨而形成后，可以容易地从处理后的表面剥离通过丝网印刷或薄膜涂布在基材的表面上涂布油墨，并通过紫外线照射来固化油墨的涂层。临时表面保护涂层可以精确地再现掩模或筛网的图案，具有高耐化学性和耐热性，即使其具有30μm的薄的厚度，并且不会因热固化而引起变形，因此可以提供物质表面的精确和缩短的表面处理。此外，改善了工作环境，并且由于有机溶剂的不存在或减少，可以省去空调设备。此外，根据本发明，提供了非常适合丝网印刷的优异的油墨组合物。

3. 发明授权

US5200438A Ultraviolet ray-curable ink 失效
标题翻译：紫外线固化油墨
公开(公告)号：US5200438A
公开(公告)日：1993-04-06
申请号：US815579
申请日：1991-12-30
申请人： Toshihiro Fujii , Hiroki Nii , Makoto Ikeda , Masao Etori , Ban Tanaka
发明人： Toshihiro Fujii , Hiroki Nii , Makoto Ikeda , Masao Etori , Ban Tanaka
IPC分类号： C08F2/48 , C08G18/67 , C08G18/69 , C09D11/10
CPC分类号： C09D11/101 , C08G18/672 , C08G18/675 , C08G18/69
摘要： An excellent ultraviolet ray-curable ink for printing which shrinks little at the time of curing, and exhibits high adhesion, followability, aging-crack resistance, elasticity, elongation, tenacity, chemical resistance, and a scratch resistant property, by a novel ultraviolet ray-curable ink comprising by weight; 100 parts of an ultraviolet ray-curable rubbery copolymer having the general formula ##STR1## wherein R represents an alkylene group having 2-8 carbon atoms, R.sub.1 is H or CH.sub.3, R.sub.2 is a residue of diisocyanate, R.sub.3 is a residue of dihydric alcohol from which at least one or more hydroxyl group is removed, X is a moiety of dienic liquidus rubber having at least one or more hydroxyl groups from which at least one or more hydroxyl groups is removed, l is a number of 1-4, m is a number of 1.0
摘要翻译：用于印刷的优异的紫外线固化型油墨，在固化时几乎不收缩，并且通过新的紫外线显示出高附着力，随动性，耐老化裂纹性，弹性，伸长率，韧度，耐化学性和抗划伤性包含重量的可固化油墨; 100份具有通式（1）的紫外线固化性橡胶共聚物，其中R表示碳原子数为2〜8的亚烷基，R 1为H或CH 3，R 2为二异氰酸酯的残基，R 3 是从其除去至少一个或多个羟基的二元醇的残基，X是具有至少一个或多个羟基的二烯液相线橡胶的部分，至少一个或多个羟基被除去，l是数为1-4，m为1.0

4. 发明授权

US5587405A Ink compositions 失效
标题翻译：油墨组合物
公开(公告)号：US5587405A
公开(公告)日：1996-12-24
申请号：US471449
申请日：1995-06-06
申请人： Ban Tanaka , Hiroki Nii , Kosaku Yamada , Hideo Kushida , Takashi Miya , Shuichi Koshio , Tadashi Hayakawa
发明人： Ban Tanaka , Hiroki Nii , Kosaku Yamada , Hideo Kushida , Takashi Miya , Shuichi Koshio , Tadashi Hayakawa
IPC分类号： B41M1/30 , B41M7/00 , C08F2/48 , C09D11/10 , C08F2/46
CPC分类号： C09D11/101 , B41M1/30 , B41M7/0081 , Y10S260/38
摘要： A radiation-curable ink composition contains a vehicle mixture comprising: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and free of a polymerizable double bond in a molecule, wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid wherein the acid has at least one acid group, and/or carboxylic ester of the said acid, and/or carboxylic amide of the said acid, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester, wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, and/or mixture thereof, (E) a double bond-containing carboxylic ester, having at least 2 double bonds and free of an acid group, provided that it is excluded from the above-mentioned ingredient (A), and (F) at least one single double bond-containing carboxylic ester and/or amide and/or imide free of an acid group, and/or mixture thereof, wherein the acid value of the vehicle mixture is from 5 to 100, is provided. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.
摘要翻译：可辐射固化油墨组合物含有载体混合物，其包含：（A）至少一种基本上不含酸基并且在分子中不含可聚合双键的直链聚酯低聚物和/或聚合物，其中1至10个双键是侧链和/或其混合物，（B）至少一种含有至少一个酸基团的单双键的羧酸，和/或所述酸的羧酸酯和/或羧酸酰胺的所述酸和/或其混合物，（C）含双键的多元羧酸酯，其中存在2至10个酸基团，并且至少2个双键从具有2至10个酸基团的酯（D ）至少一种含双键的氟化羧酸酯和/或包含含氟烷基的聚合物链段和（甲基）丙烯酸类聚合物链段的嵌段共聚物，和/或包含含硅氧烷基团的聚合物链段和/ （甲基）丙烯酸酯（E）具有至少2个双键并且不含酸基团的双键的羧酸酯，其不包括在上述成分（A）中，和（F）至少一种含有单个含双键的羧酸酯和/或不含酸基团的酰胺和/或酰亚胺，和/或其混合物，其中车辆混合物的酸值为5至100。油墨可用于在特定的热塑性产品上显示和装饰商品名称，设计，注释，条形码等，并且固化的油墨膜易于与碱性水溶液分离。

5. 发明授权

US5712022A Printed thermoplastic resin products and method for printing such products 失效
标题翻译：印刷热塑性树脂产品及印刷方法
公开(公告)号：US5712022A
公开(公告)日：1998-01-27
申请号：US488408
申请日：1995-06-07
申请人： Ban Tanaka , Hiroki Nii , Kosaku Yamada , Hideo Kushida , Takashi Miya , Shuichi Koshio , Tadashi Hayakawa
发明人： Ban Tanaka , Hiroki Nii , Kosaku Yamada , Hideo Kushida , Takashi Miya , Shuichi Koshio , Tadashi Hayakawa
IPC分类号： B41M1/30 , C09D11/10 , B32B27/00
CPC分类号： C09D11/101 , B41M1/30 , Y10T428/1352 , Y10T428/24802 , Y10T428/3154 , Y10T428/31551 , Y10T428/31663 , Y10T428/31797 , Y10T428/31931 , Y10T428/31935
摘要： An easily regeneratable printed thermoplastic resin product is provided by printing it with a specific radiation-curable ink composition and curing the printed ink with radiation to form a cured ink film thereon. The ink composition comprises a vehicle mixture containing: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and a polymerizable double bond on the linear polyester chain wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid and/or ester and/or amide wherein the acid has at least one acid group, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the carboxylic ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, and/or mixture thereof, (E) a double bond-containing carboxylic ester, having at least 2 double bonds and free of an acid group, provided that it is excluded from the above-mentioned ingredient (A), and (F) at least one single double bond-containing carboxylic ester and/or amide and/or imide free of an acid group, and/or mixture thereof, wherein the acid value of the vehicle mixture is from 5 to 100. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.
摘要翻译：通过用特定的可辐射固化油墨组合物印刷并通过辐射固化印刷油墨以在其上形成固化的油墨膜来提供易于再生的印刷热塑性树脂产品。油墨组合物包含载体混合物，其包含：（A）至少一种线性聚酯链上基本上不含酸基团和可聚合双键的线性聚酯低聚物和/或聚合物，其中1至10个双键与直链聚酯链和/或其混合物，（B）至少一种含单个双键的羧酸和/或酯和/或酰胺，其中酸具有至少一个酸基，和/或其混合物，（C）双含有2〜10个酸基且至少2个双键与具有2〜10个酸基的羧酸酯侧基，（D）至少一个含双键的氟化羧酸酯和/或嵌段包含含氟基烷基的聚合物链段和（甲基）丙烯酸类聚合物链段的共聚物和/或包含含硅氧烷基团的聚合物链段和（甲基）丙烯酸类聚合物链段的嵌段共聚物和/或其混合物，（E）一个双重的具有至少2个双键且不含酸基团的含L键的羧酸酯，条件是其不包括在上述成分（A）中，和（F）至少一种含有单个双键的羧酸酯和 /或不含酸基的酰胺和/或酰亚胺，和/或其混合物，其中车辆混合物的酸值为5至100.油墨可用于显示和装饰商品名称，设计，说明注释，条代码等，并且固化的油墨膜易于与碱性水溶液分离。

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