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    • 4. 发明授权
    • Oriented film including polystyrene polymer having syndiotactic
configuration
    • 取向膜包括具有间同构型的聚苯乙烯聚合物
    • US5707719A
    • 1998-01-13
    • US654583
    • 1996-05-29
    • Tomonori YoshinagaNaonobu OdaTadashi Okudaira
    • Tomonori YoshinagaNaonobu OdaTadashi Okudaira
    • B29C55/14B29D7/01B32B3/26B32B7/12
    • B29C55/14B29D7/01B29K2025/00Y10S428/91Y10T428/268Y10T428/269
    • An oriented polystyrene film including a polystyrene polymer having a syndiotactic configuration, the film having a thickness of 25 .mu.m or more, and a rectangular sample of the film having a value C expressed by equation (I) of 0.007 or less: ##EQU1## wherein A.sub.max is obtained by designating four squares respectively in four apices of the rectangular sample, each square having sides of 100 mm in length, and setting an orientation direction of molecules of a first square to 0.degree., A.sub.max being an absolute value of a maximum angle among angles defined by the orientation direction of molecules of the first square and an orientation direction of molecules of each of the other three squares, R is expressed by equation (II) but is defined as 1 when exceeding 1: R=D/1000 (II), and D is a distance (mm) between a center of gravity of the first square and a center of gravity of the square having the orientation direction which defines A.sub.max with the first square, and HS.sub.max is a size change ratio of a square sample which is cut from the rectangular sample and dry-heated at a temperature of 150.degree. C. for 30 minutes, the square sample being designated in an apex of the rectangular sample and having sides of 100 mm in length.
    • 包含具有间同立构构型的聚苯乙烯聚合物的膜的取向聚苯乙烯膜,厚度为25μm以上的膜和由式(I)表示的值C的膜的矩形样品为0.007以下:< IMAGE> (I)其中通过在矩形样品的四个顶点中分别指定四个正方形来获得Amax,每个正方形具有100mm长的边,并将第一个正方形的分子的取向方向设定为0°,Amax为绝对值 在由第一正方形的分子的取向方向和其他三个正方形中的每一个的分子的取向方向限定的角度之间的最大角度R由等式(II)表示,但是当超过1时被定义为1:R = D / 1000(II),D是第一正方形的重心与具有定义方向的方位的重心之间的距离(mm),其定义为具有第一平方的Amax,HSmax是尺寸变化 慧慧 从矩形样品切割并在150℃温度下干热30分钟的正方形样品,方形样品指定在矩形样品的顶点中,长度为100mm的边。
    • 6. 发明授权
    • Multi-ply vessel and method for production thereof
    • 多层容器及其生产方法
    • US4398642A
    • 1983-08-16
    • US269056
    • 1981-06-02
    • Tadashi OkudairaAkio TsuboiShigeharu SugiharaYoshihisa Hama
    • Tadashi OkudairaAkio TsuboiShigeharu SugiharaYoshihisa Hama
    • B32B27/08B65D65/40B65D23/00
    • B32B27/08Y10S428/91Y10T428/1352Y10T428/31736Y10T428/31786
    • A multi-ply vessel which comprises an inner layer (A) composed of a thermoplastic polyester resin, a middle layer (B) composed of a metaxylylene group-containing polyamide resin and an outer layer (C) composed of a synthetic resin having impermeability to moisture, said inner layer (A) and middle layer (B) being oriented in at least one direction at the thin part of the vessel wall. This vessel is produced by orienting a parison having a multi-ply structure of the inner layer (A), the middle layer (B) and the outer layer (C) in a draw ratio of 1 to 4 times in longitudinal direction and of 2 to 7 times in crosswise direction at a temperature of from Tg+15.degree. C. to 2(Tg)+15.degree. C. (wherein Tg is the glass transition temperature of the thermoplastic polyester resin). This vessel has high transparency as well as excellent chemical resistance, impact resistance and the like because a thermoplastic polyester resin is used as the inner layer (A) and also has excellent gas barrier properties against oxygen because the metaxylylene group-containing polyamide resin is used as the middle layer (B).
    • PCT No.PCT / JP80 / 00269 Sec。 371日期:1981年6月2日 102(e)日期1981年6月2日PCT提交1980年10月29日PCT公布。 公开号WO81 / 01265 日期:1981年5月14日。一种多层容器,其特征在于,包括由热塑性聚酯树脂构成的内层(A),由含有间亚甲苯基的聚酰胺树脂构成的中间层(B)和由 具有不透水性的合成树脂,所述内层(A)和中间层(B)在容器壁的薄部至少沿一个方向取向。 该容器是通过将内层(A),中间层(B)和外层(C)的多层结构的型坯的纵向取向为1〜4倍的拉伸倍数和2 在Tg + 15℃至2(Tg)+15℃的温度下横向上为7倍(其中Tg是热塑性聚酯树脂的玻璃化转变温度)。 由于使用热塑性聚酯树脂作为内层(A),该容器具有高透明性以及优异的耐化学性,耐冲击性等,并且由于使用含有间亚二甲苯基团的聚酰胺树脂,所以具有优异的耐氧气的阻气性 作为中间层(B)。