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1. 发明授权

US4581125A Hydrotreating using self-promoted molybdenum and tungsten sulfide catalysts formed from bis(tetrathiometallate) precursors 失效
标题翻译：使用由双（四金属硫酸盐）前体形成的自身促进的钼和硫化钨催化剂进行加氢处理
公开(公告)号：US4581125A
公开(公告)日：1986-04-08
申请号：US518361
申请日：1983-07-29
申请人： Edward I. Stiefel , Wie-Hin Pan , Russell R. Chianelli , Teh C. Ho
发明人： Edward I. Stiefel , Wie-Hin Pan , Russell R. Chianelli , Teh C. Ho
IPC分类号： B01J23/85 , B01J27/04 , C10G45/08 , C10G45/50 , C10G47/06
CPC分类号： B01J23/85 , B01J27/04 , C10G45/08
摘要： Hydrocarbon feeds are upgraded by contacting same, at elevated temperature and in the presence of hydrogen, with a self-promoted catalyst formed by heating one or more carbon-containing, bis(tetrathiometallate) catalyst precursor salts selected from the group consisting of (NR.sub.4).sub.2 [M(WS.sub.4).sub.2 ], (NR.sub.4).sub.x [M(MoS.sub.4).sub.2 ] and mixtures thereof wherein R is one or more alkyl groups, aryl groups or mixture thereof, wherein promoter metal M is covalently bound in the anion and is Ni, Co or Fe and wherein x is 2 if M is Ni and x is 3 if M is Co or Fe composite in a non-oxidizing atmosphere in the presence of sulfur, hydrogen, and a hydrocarbon to form said supported catalyst.
摘要翻译：通过在升高的温度和氢气存在下使其与通过加热一种或多种选自（NR 4）的含碳的双（四金属氧酸盐）催化剂前体盐形成的自促进催化剂相接触来提高烃进料， 2 [M（WS4）2]，（NR4）x [M（MoS4）2]及其混合物，其中R是一个或多个烷基，芳基或其混合物，其中助催化剂金属M共价键合在阴离子中， Ni，Co或Fe，其中如果M是Ni，x是2，如果M是在非氧化性气氛中，在硫，氢和烃的存在下，M是Co或Fe复合物，则x是3，以形成所述负载的催化剂。

2. 发明授权

US4514517A Supported, self-promoted molybdenum and tungsten sulfide catalysts formed from bis(tetrathiometallate) precursors, and their preparation 失效
标题翻译：由双（四金属硫酸盐）前体形成的负载，自我推荐的钼和硫化钨催化剂及其制备
公开(公告)号：US4514517A
公开(公告)日：1985-04-30
申请号：US518360
申请日：1983-07-29
申请人： Teh C. Ho , Wie-Hin Pan
发明人： Teh C. Ho , Wie-Hin Pan
IPC分类号： C10G45/04 , B01J23/85 , B01J27/04 , B01J27/049 , B01J31/02 , B01J31/22 , B01J31/34 , C10G45/08 , B01J27/02 , B01J31/12
CPC分类号： C10G45/08 , B01J21/04 , B01J23/85 , B01J27/04 , B01J27/049 , B01J27/0515 , B01J31/0239 , B01J31/0254 , B01J31/34 , B01J35/026
摘要： Hydrocarbon feeds are upgraded by contacting a feed, at an elevated temperature and in the presence of hydrogen, with a supported, self-promoted catalyst formed by compositing a porous, refractory inorganic oxide, support with one or more complex salts selected from the group consisting of (NR.sub.4).sub.2 [M(WS.sub.4).sub.2 ], (NR.sub.4).sub.x [M(MoS.sub.4).sub.2 ] and mixtures thereof wherein R is one or more alkyl groups, aryl groups or mixture thereof, wherein promoter metal M is covalently bound in the anion and is Ni, Co or Fe and wherein x is 2 if M is Ni and x is 3 if M is Co or Fe and heating said composite in a non-oxidizing atmosphere in the presence of sulfur and hydrogen and a hydrocarbon to form said supported catalyst.
摘要翻译：通过使进料在升高的温度和在氢存在下使进料接触与通过将多孔耐火无机氧化物载体与一种或多种选自下组的复合盐形成的负载的自促进催化剂接触来提高烃进料：的（NR4）2 [M（WS4）2]，（NR4）x [M（MoS4）2]及其混合物，其中R是一个或多个烷基，芳基或其混合物，其中助催化剂金属M共价结合阴离子为Ni，Co或Fe，其中如果M为Ni，x为2，如果M为Co或Fe则x为3，并在硫和氢和烃存在下，在非氧化性气氛中加热所述复合材料，形成所述负载催化剂。

3. 发明授权

US5777009A Flame retardant low Tg polyestercarbonate 失效
标题翻译：阻燃低Tg聚酯碳酸酯
公开(公告)号：US5777009A
公开(公告)日：1998-07-07
申请号：US738213
申请日：1996-10-25
申请人： Wie-Hin Pan , Dwight J. Patterson , Omar M. Boutni , Luca P. Fontana
发明人： Wie-Hin Pan , Dwight J. Patterson , Omar M. Boutni , Luca P. Fontana
IPC分类号： C08K5/42 , C08L27/18 , C08L67/02 , C08L69/00
CPC分类号： C08L69/005 , C08K5/42
摘要： A polyestercarbonate copolymer blend which exhibits a glass transition temperature lower than bisphenol-A carbonate homopolymer, shows improved processability and fire-retardancy. The desired lower Tg and improved flow can be achieved by the polycondensation of a dihydric phenol and aliphatic dicarboxylic acid. The condensate is polymerized with a carbonate forming reagent. The resin is fire-retarded with a mixture of halogenated polycarbonate, potassium diphenylsulfone sulfonate and polytetrafluoroethylene.
摘要翻译：显示玻璃化转变温度低于双酚A碳酸酯均聚物的聚酯碳酸酯共聚物共混物显示出改善的加工性和阻燃性。所需的较低Tg和改善的流动可以通过二元酚和脂族二羧酸的缩聚来实现。冷凝物与碳酸酯形成试剂聚合。该树脂用卤代聚碳酸酯，二苯基砜磺酸钾和聚四氟乙烯的混合物阻燃。

4. 发明授权

US06469072B1 Finely dispersed shell/core solid additives in polymers and products made therewith 失效
标题翻译：在聚合物和由其制成的产品中精细分散的壳/固体添加剂
公开(公告)号：US06469072B1
公开(公告)日：2002-10-22
申请号：US09653931
申请日：2000-09-01
申请人： Qamar S. Bhatia , Paul Buckley , Gary Davis , Robert L. Howe , Wie-Hin Pan , Elliott Shanklin
发明人： Qamar S. Bhatia , Paul Buckley , Gary Davis , Robert L. Howe , Wie-Hin Pan , Elliott Shanklin
IPC分类号： C08K904
CPC分类号： C08L67/02 , C08J3/005 , C08J3/215 , C08L27/12 , C08L27/18 , C08L69/00 , C08L101/00 , C08L2666/02
摘要： A method for dispersing solid forms of additives in polymers involves adding dispersions or solutions of additive(s) to a solution of polymer in a tubular mixer (preferably in the presence of a stationary mixer). The mixer leads to a steam precipitation step wherein all fluid ingredients in the mixture are volatilized leaving the solid additive and resin in the desired ratio. This results in a uniform dispersion of the additives in the polymer matrix. As a result of the high dispersion, physical properties of a thermoplastic resin, to which the polymer matrix has been added are preserved. In one illustration, PTFE as a drip inhibitor additive, is added to polycarbonate to obtain a highly dispersed PTFE concentrate of improved-drip-inhibition without loss of mechanical properties when added to a thermoplastic molding resin.
摘要翻译：将固体形式的添加剂分散在聚合物中的方法包括将添加剂的分散体或溶液加入到管式混合器中的聚合物溶液（优选在固定式混合器的存在下）。混合器导致蒸汽沉淀步骤，其中混合物中的所有流体成分挥发，留下固体添加剂和树脂所需的比例。这导致添加剂在聚合物基质中的均匀分散。作为高分散性的结果，保留了加入了聚合物基质的热塑性树脂的物理性能。在一个例子中，将PTFE作为滴液抑制剂添加剂加入到聚碳酸酯中，以获得高分散的PTFE浓缩物，其在加入到热塑性模塑树脂中时不丧失机械性能。

5. 发明授权

US06005025A Method of dispersing solid additives in polymers and products made therewith 失效
标题翻译：将固体添加剂分散在聚合物和由其制成的产品中的方法
公开(公告)号：US06005025A
公开(公告)日：1999-12-21
申请号：US2811
申请日：1998-01-05
申请人： Qamar S. Bhatia , Paul Buckley , Gary Davis , Robert L. Howe , Wie-Hin Pan , Elliott Shanklin
发明人： Qamar S. Bhatia , Paul Buckley , Gary Davis , Robert L. Howe , Wie-Hin Pan , Elliott Shanklin
IPC分类号： C08J3/00 , C08J3/215 , C08L27/12 , C08L27/18 , C08L67/02 , C08L69/00 , C08L101/00 , C08K9/10
CPC分类号： C08L67/02 , C08J3/005 , C08J3/215 , C08L69/00 , C08L101/00 , C08L27/12 , C08L27/18
摘要： A method for dispersing solid forms of additives in polymers involves adding dispersions or solutions of additive(s) to a solution of polymer in a tubular mixer (preferably in the presence of a stationary mixer). The mixer leads to a steam precipitation step wherein all fluid ingredients in the mixture are volatilized leaving the solid additive and resin in the desired ratio. This results in a uniform dispersion of the additives in the polymer matrix. As a result of the high dispersion, physical properties of a thermoplastic resin, to which the polymer matrix has been added are preserved. In one illustration, PTFE as a drip inhibitor additive, is added to polycarbonate to obtain a highly dispersed PTFE concentrate of improved drip-inhibition without loss of mechanical properties when added to a thermoplastic molding resin.
摘要翻译：将固体形式的添加剂分散在聚合物中的方法包括将添加剂的分散体或溶液加入到管式混合器中的聚合物溶液（优选在固定式混合器的存在下）。混合器导致蒸汽沉淀步骤，其中混合物中的所有流体成分挥发，留下固体添加剂和树脂所需的比例。这导致添加剂在聚合物基质中的均匀分散。作为高分散性的结果，保留了加入了聚合物基质的热塑性树脂的物理性能。在一个例子中，将PTFE作为滴液抑制剂添加剂加入到聚碳酸酯中以获得高分散的PTFE浓缩物，其在加入到热塑性模塑树脂中时不丧失机械性能。

6. 发明授权

US5023067A Manufacturing method for ceramics and products thereof 失效
标题翻译：陶瓷及其制品的制造方法
公开(公告)号：US5023067A
公开(公告)日：1991-06-11
申请号：US237268
申请日：1988-08-26
申请人： Nicholas D. Spencer , Wie-Hin Pan , John A. Rudesill
发明人： Nicholas D. Spencer , Wie-Hin Pan , John A. Rudesill
IPC分类号： C04B35/00 , B32B18/00 , C01B13/18 , C01B13/36 , C01G3/00 , C01G5/00 , C01G7/00 , C01G51/00 , C04B35/45 , H01L39/12 , H01L39/24
CPC分类号： B32B18/00 , C01B13/363 , C01G3/006 , C01G5/006 , C01G51/68 , C01G7/006 , C04B35/4504 , C04B35/4508 , H01L39/126 , H01L39/248 , C01P2002/34 , C01P2002/36 , C01P2002/54 , C01P2006/40 , C01P2006/80 , C04B2235/6567 , C04B2235/658 , C04B2237/34 , C04B2237/343 , Y10S505/738
摘要： An extremely pure oxide containing two or more metals, homogeneous at the atomic level, is prepared by (1) reacting in water, soluble salts of two or more metals with quaternary ammonium carbonate; the metals being those that form water-insoluble carbonates, thereby to precipitate mixed carbonates of the metals; (2) recovering and drying the precipitate; (3) calcining the precipitate to provide an oxide of mixed metals homogeneous at the atomic level and substantially free from extraneous contaminants. The calcined oxide can be shaped and compressed as greenware and sintered to form useful ceramic products.
摘要翻译：含有两种或更多种原子含量均匀的金属的极纯氧化物是通过（1）在水中，两种或多种金属的可溶性盐与碳酸季铵反应而制备的; 金属是形成水不溶性碳酸盐的金属，从而沉淀金属的混合碳酸盐; （2）回收和干燥沉淀物; （3）煅烧沉淀物以提供在原子级别均匀且基本上不含外来污染物的混合金属的氧化物。煅烧氧化物可以成形并压缩成绿色软件并烧结形成有用的陶瓷产品。

7. 发明授权

US4588829A (Disulfido)tris(N,N-substituted dithiocarbamato)Mo(V) complexes 失效
标题翻译：（二硫化物）三（N，N-取代二硫代氨基甲酸根合）Mo（V）络合物
公开(公告)号：US4588829A
公开(公告)日：1986-05-13
申请号：US635283
申请日：1984-07-27
申请人： Wie-Hin Pan , Edward I. Stiefel
发明人： Wie-Hin Pan , Edward I. Stiefel
IPC分类号： C07F11/00 , C10M135/18
CPC分类号： C10M135/18 , C07F11/005
摘要： This invention relates to (disulfido)tris(N,N-substituted dithiocarbamato)Mo(V) complexes. More particularly, this invention relates to compounds of the formula MoS.sub.2 (S.sub.2 CNR.sub.2).sub.3 which are mononuclear, eight-coordinate, neutral Mo(V) complexes containing only eight sulfur atoms in the Mo coordination sphere. R is hydrogen, an alkyl, aryl, cycloalkyl group or mixture thereof. Preferably all of the R's are the same and are alkyl groups. These compounds are useful as lubricant additives.
摘要翻译：本发明涉及（二硫化物）三（N，N-取代二硫代氨基甲酰）钼（V）络合物。更具体地说，本发明涉及式MoS2（S2CNR2）3的化合物，它们是在Mo配位球中仅含有8个硫原子的单核，8位，中性Mo（V）络合物。 R是氢，烷基，芳基，环烷基或其混合物。优选地，所有的R都是相同的并且是烷基。这些化合物可用作润滑剂添加剂。

8. 发明授权

US06103827A Polycarbonate or polyestercarbonate/acrylic resin or methacrylic/resin/catalyst composition 有权
标题翻译：聚碳酸酯或聚碳酸酯/丙烯酸树脂或甲基丙烯酸/树脂/催化剂组合物
公开(公告)号：US06103827A
公开(公告)日：2000-08-15
申请号：US191588
申请日：1998-11-13
申请人： Akihiro Saito , Takashi Nagai , Takuro Kitamura , Wie-Hin Pan , Patrick McCloskey
发明人： Akihiro Saito , Takashi Nagai , Takuro Kitamura , Wie-Hin Pan , Patrick McCloskey
IPC分类号： C08L33/04 , C08L33/06 , C08L67/00 , C08L69/00 , C08L33/12
CPC分类号： C08L33/06 , C08L69/00 , C08L69/005
摘要： A thermoplastic resin composition having improved transparency and containing polycarbonate resin and/or polyester carbonate resin and acrylic resin and/or methacrylic resin comprisesA) (a) polycarbonate resin and/or (b) polyester carbonate resin andB) acrylic resin and/or methacrylic resin, having 0.000005-0.5 parts by weight of C) a basic compound catalyst and/or acidic compound catalyst added with respect to a total of 100 parts by weight of the aforementioned components A) and B).
摘要翻译：具有改进的透明度并且包含聚碳酸酯树脂和/或聚酯碳酸酯树脂和丙烯酸树脂和/或甲基丙烯酸树脂的热塑性树脂组合物包含A）（a）聚碳酸酯树脂和/或（b）聚酯碳酸酯树脂和B）丙烯酸树脂和/或甲基丙烯酸树脂，相对于总计100重量份的上述成分A）和B），添加碱金属化合物催化剂和/或酸性化合物催化剂，其含有0.000005-0.5重量份的C）。

9. 发明授权

US5883194A Polycarbonate or polyestercarbonatel acrylic resin or methacrylic/resin/catalyst composition 失效
标题翻译：聚碳酸酯或聚酯碳酸酯丙烯酸树脂或甲基丙烯酸/树脂/催化剂组合物
公开(公告)号：US5883194A
公开(公告)日：1999-03-16
申请号：US900069
申请日：1997-07-24
申请人： Akihiro Saito , Takashi Nagai , Takuro Kitamura , Wie-Hin Pan , Patrick McCloskey
发明人： Akihiro Saito , Takashi Nagai , Takuro Kitamura , Wie-Hin Pan , Patrick McCloskey
IPC分类号： C08L33/04 , C08L33/06 , C08L67/00 , C08L69/00 , C08G64/18 , C08G81/00 , C08L33/12
CPC分类号： C08L33/06 , C08L69/00 , C08L69/005
摘要： A thermoplastic resin composition having improved transparency and containing polycarbonate resin and/or polyester carbonate resin and acrylic resin and/or methacrylic resin comprisesA) (a) polycarbonate resin and/or (b) polyester carbonate resin andB) acrylic resin and/or methacrylic resin, having 0.000005-0.5 parts by weight of C) a basic compound catalyst and/or acidic compound catalyst added with respect to a total of 100 parts by weight of the aforementioned components A) and B).
摘要翻译：具有改进的透明度并且包含聚碳酸酯树脂和/或聚酯碳酸酯树脂和丙烯酸树脂和/或甲基丙烯酸树脂的热塑性树脂组合物包含A）（a）聚碳酸酯树脂和/或（b）聚酯碳酸酯树脂和B）丙烯酸树脂和/或甲基丙烯酸树脂，相对于总计100重量份的上述成分A）和B），添加碱金属化合物催化剂和/或酸性化合物催化剂，其含有0.000005-0.5重量份的C）。

10. 发明授权

US4975256A Process using catalysts for selective catalytic reduction denox technology 失效
标题翻译：使用催化剂进行选择性催化还原技术的工艺
公开(公告)号：US4975256A
公开(公告)日：1990-12-04
申请号：US417141
申请日：1989-10-04
申请人： Louis Hegedus , Jean W. Beeckman , Wie-Hin Pan , Jeffrey P. Solar
发明人： Louis Hegedus , Jean W. Beeckman , Wie-Hin Pan , Jeffrey P. Solar
IPC分类号： B01D53/86 , B01J21/06 , B01J35/10
CPC分类号： B01J21/063 , B01D53/8628 , B01J21/06 , B01J35/002 , B01J35/10 , B01J35/1019
摘要： Catalysts for the selective catalytic reduction of NOx by ammonia are made from porous formed supports having a certain fraction of the pores with pore diameters larger than 600 Angstrom units. Thus macropores can be introduced in a formed TiO.sub.2 support by adding burnout materials or some inorganic oxide prior to forming the titania into the formed support. Alternatively, titania is precipitated onto a porous inorganic oxide such as SiO.sub.2, Al.sub.2 O.sub.3, ZrO.sub.2, AlPO.sub.4, Fe.sub.2 O.sub.3 and B.sub.2 O.sub.3 to form the support. Then conventional DeNOx catalytic metals are added. The support can be made by first impregnating the inorganic oxide particles with titania via a soluble precursor, forming titania and then shaping the coated particles into the desired shape such as a monolith. In a second embodiment, the inorganic oxide particles are first formed into the desired shape and then impregnated with the titania forming material. Barium sulfate can be added to the surface of the porous inorganic oxide to make an improved support.
摘要翻译：用于由氨选择性催化还原NOx的催化剂由具有孔径大于600埃单位的孔的一定部分的多孔成形载体制成。因此，在将二氧化钛形成到形成的载体之前，可以通过添加烧制材料或一些无机氧化物将大孔引入形成的TiO 2载体中。或者，二氧化钛沉淀到诸如SiO 2，Al 2 O 3，ZrO 2，AlPO 4，Fe 2 O 3和B 2 O 3的多孔无机氧化物上以形成载体。然后加入常规的DeNOx催化金属。可以通过首先通过可溶性前体用二氧化钛浸渍无机氧化物颗粒，形成二氧化钛，然后将涂覆的颗粒成形为期望的形状如整料来制备载体。在第二实施方案中，首先将无机氧化物颗粒形成为所需形状，然后用二氧化钛形成材料浸渍。可以将硫酸钡加入到多孔无机氧化物的表面以形成改进的载体。

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