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1. 发明申请

US20110319527A1 MICROPARTICLE/POLYROTAXANE-CONTAINING COATING, MICROPARTICLE/POLYROTAXANE-CONTAINING COATING FILM AND COATED ARTICLE 有权
标题翻译：包含微晶/聚氨酯的涂层，含微晶/聚氨酯涂层膜和涂层物品
公开(公告)号：US20110319527A1
公开(公告)日：2011-12-29
申请号：US13148412
申请日：2010-02-09
申请人： Tatsuya Suzuki , Kentarou Watanabe , Tetsurou Kikugawa , Masahiko Yamanaka , Changming Zhao , Yuki Hayashi , Yuki Amamoto
发明人： Tatsuya Suzuki , Kentarou Watanabe , Tetsurou Kikugawa , Masahiko Yamanaka , Changming Zhao , Yuki Hayashi , Yuki Amamoto
IPC分类号： C09D105/16
CPC分类号： C23C24/08 , C08B37/0012 , C08G83/007 , C08K3/22 , C08K3/36 , C09D5/1637 , C09D7/61 , C09D7/67 , C09D7/68 , C09D105/16 , C09D171/02 , C23C26/00 , C23C26/02 , C23C30/00 , Y02T50/67 , C08L2666/26
摘要： There is provided a microparticle/polyrotaxane-containing coating with high abrasion resistance and chemical resistance. There are also provided a microparticle/polyrotaxane-containing coating film and a coated article. The microparticle/polyrotaxane-containing coating includes a solvent-based coating material, a modified polyrotaxane having a caprolactone modification group (—CO(CH2)5OH) and microparticles having an average particle size of smaller than 380 nm. The microparticle/polyrotaxane-containing coating film is in the form of a layer of the microparticle/polyrotaxane-containing coating on an article to be coated. The coated article includes the microparticle/polyrotaxane-containing coating film and an article to be coated.
摘要翻译：提供了具有高耐磨性和耐化学性的含微粒/聚轮烷的涂层。还提供了含微粒/含有聚轮烷的涂膜和涂布制品。含有微粒/聚轮烷的涂层包括溶剂型涂料，具有己内酯改性基团（-CO（CH 2）5 OH）的改性聚轮烷）和平均粒径小于380nm的微粒。含微粒/含有聚轮烷的涂膜是待被涂物品的含有微粒/聚轮烷的涂层的层的形式。涂布制品包括含微粒/含有聚轮烷的涂膜和待涂布的制品。

2. 发明授权

US08957139B2 Microparticle/polyrotaxane—containing coating, microparticle/polyrotaxane—containing coating film and coated article 有权
标题翻译：含微粒/聚轮烷的涂料，含微粒/聚轮烷的涂膜和涂布制品
公开(公告)号：US08957139B2
公开(公告)日：2015-02-17
申请号：US13148412
申请日：2010-02-09
申请人： Tatsuya Suzuki , Kentarou Watanabe , Tetsurou Kikugawa , Masahiko Yamanaka , Changming Zhao , Yuki Hayashi , Yuki Amamoto
发明人： Tatsuya Suzuki , Kentarou Watanabe , Tetsurou Kikugawa , Masahiko Yamanaka , Changming Zhao , Yuki Hayashi , Yuki Amamoto
IPC分类号： C08K3/22 , C08K3/36 , C23C24/08 , C08B37/16 , C08G83/00 , C09D5/16 , C09D7/12 , C09D105/16 , C09D171/02 , C23C26/00 , C23C26/02 , C23C30/00
CPC分类号： C23C24/08 , C08B37/0012 , C08G83/007 , C08K3/22 , C08K3/36 , C09D5/1637 , C09D7/61 , C09D7/67 , C09D7/68 , C09D105/16 , C09D171/02 , C23C26/00 , C23C26/02 , C23C30/00 , Y02T50/67 , C08L2666/26
摘要： There is provided a microparticle/polyrotaxane-containing coating with high abrasion resistance and chemical resistance. There are also provided a microparticle/polyrotaxane-containing coating film and a coated article. The microparticle/polyrotaxane-containing coating includes a solvent-based coating material, a modified polyrotaxane having a caprolactone modification group (—CO(CH2)5OH) and microparticles having an average particle size of smaller than 380 nm. The microparticle/polyrotaxane-containing coating film is in the form of a layer of the microparticle/polyrotaxane-containing coating on an article to be coated. The coated article includes the microparticle/polyrotaxane-containing coating film and an article to be coated.
摘要翻译：提供了具有高耐磨性和耐化学性的含微粒/聚轮烷的涂层。还提供了含微粒/含有聚轮烷的涂膜和涂布制品。含有微粒/聚轮烷的涂层包括溶剂型涂料，具有己内酯改性基团（-CO（CH 2）5 OH）的改性聚轮烷）和平均粒径小于380nm的微粒。含微粒/含有聚轮烷的涂膜是待被涂物品的含有微粒/聚轮烷的涂层的层的形式。涂布制品包括含微粒/含有聚轮烷的涂膜和待涂布的制品。

3. 发明授权

US09205104B2 Hydrophilic modified polyrotaxane composition 有权
标题翻译：亲水改性聚轮烷组合物
公开(公告)号：US09205104B2
公开(公告)日：2015-12-08
申请号：US14005137
申请日：2011-12-05
申请人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
发明人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
IPC分类号： A61K31/724 , C08G65/06 , C08L5/16 , C08L71/02 , C08B37/16 , C08G83/00 , A61K31/192 , A61K31/216 , A61K31/353 , C08L101/00
CPC分类号： A61K31/724 , A61K31/192 , A61K31/216 , A61K31/353 , C08B37/0015 , C08G65/2606 , C08G65/3331 , C08G65/33396 , C08G83/007 , C08G2650/04 , C08K5/005 , C08K5/053 , C08K5/16 , C08L5/16 , C08L71/02 , C08L101/005
摘要： The present invention aims to provide a hydrophilic modified polyrotaxane composition having excellent storage stability. The present invention relates to a hydrophilic modified polyrotaxane composition comprising: a hydrophilic modified polyrotaxane produced by modifying, with hydrophilic modifying groups, all or part of hydroxy groups on a cyclodextrin of a polyrotaxane containing the cyclodextrin, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a polyphenol antioxidant.
摘要翻译：本发明的目的在于提供一种具有优异储存稳定性的亲水性改性聚轮烷组合物。亲水性改性聚轮烷组合物本发明涉及一种亲水改性聚轮烷组合物，它包括：亲水改性聚轮烷，其通过亲水改性基团改性含有环糊精的聚轮烷的环糊精上的全部或部分羟基，包含在空腔中的聚乙二醇的双环糊精分子，并且封端基团放置在聚乙二醇的每一端，并防止环糊精分子与聚乙二醇的解离; 和多酚抗氧化剂。

4. 发明授权

US09266972B2 Polyrotaxane composition 有权
标题翻译：聚轮烷组成
公开(公告)号：US09266972B2
公开(公告)日：2016-02-23
申请号：US14004855
申请日：2011-12-05
申请人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
发明人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
IPC分类号： C08L5/16 , C08L71/02 , C08K5/053 , C08G65/06 , C08B37/16 , C08G83/00
CPC分类号： C08B37/0015 , C08G65/2606 , C08G65/3331 , C08G65/33396 , C08G83/007 , C08G2650/04 , C08K5/005 , C08K5/053 , C08L5/16 , C08L71/02
摘要： The present invention aims to provide a polyrotaxane composition having excellent storage stability. The present invention relates to a polyrotaxane composition comprising: a polyrotaxane containing a cyclodextrin, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a polyphenol antioxidant.
摘要翻译：本发明的目的在于提供一种储存稳定性优异的聚轮烷组合物。本发明涉及一种聚轮烷组合物，其包含：含有环糊精的聚轮烷，以串列方式包含在环糊精分子的空腔中的聚乙二醇和位于聚乙二醇的两端的封端基，并防止环糊精分子与聚乙二醇的解离; 和多酚抗氧化剂。

5. 发明申请

US20140058078A1 POLYROTAXANE COMPOSITION 有权
标题翻译：聚氨酯组合物
公开(公告)号：US20140058078A1
公开(公告)日：2014-02-27
申请号：US14004855
申请日：2011-12-05
申请人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
发明人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
IPC分类号： C08B37/16
CPC分类号： C08B37/0015 , C08G65/2606 , C08G65/3331 , C08G65/33396 , C08G83/007 , C08G2650/04 , C08K5/005 , C08K5/053 , C08L5/16 , C08L71/02
摘要： The present invention aims to provide a polyrotaxane composition having excellent storage stability. The present invention relates to a polyrotaxane composition comprising: a polyrotaxane containing a cyclodextrin, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a polyphenol antioxidant.
摘要翻译：本发明的目的在于提供一种储存稳定性优异的聚轮烷组合物。本发明涉及一种聚轮烷组合物，其包含：含有环糊精的聚轮烷，以串列方式包含在环糊精分子的空腔中的聚乙二醇和位于聚乙二醇的两端的封端基，并防止环糊精分子与聚乙二醇的解离; 和多酚抗氧化剂。

6. 发明申请

US20140066403A1 HYDROPHILIC MODIFIED POLYROTAXANE COMPOSITION 有权
标题翻译：水解改性聚氨酯组合物
公开(公告)号：US20140066403A1
公开(公告)日：2014-03-06
申请号：US14005137
申请日：2011-12-05
申请人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
发明人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao , Minoru Iwata , Yuki Hayashi
IPC分类号： A61K31/724 , A61K31/192 , A61K31/353 , A61K31/216
CPC分类号： A61K31/724 , A61K31/192 , A61K31/216 , A61K31/353 , C08B37/0015 , C08G65/2606 , C08G65/3331 , C08G65/33396 , C08G83/007 , C08G2650/04 , C08K5/005 , C08K5/053 , C08K5/16 , C08L5/16 , C08L71/02 , C08L101/005
摘要： The present invention aims to provide a hydrophilic modified polyrotaxane composition having excellent storage stability. The present invention relates to a hydrophilic modified polyrotaxane composition comprising: a hydrophilic modified polyrotaxane produced by modifying, with hydrophilic modifying groups, all or part of hydroxy groups on a cyclodextrin of a polyrotaxane containing the cyclodextrin, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a polyphenol antioxidant.
摘要翻译：本发明的目的在于提供一种具有优异储存稳定性的亲水性改性聚轮烷组合物。亲水性改性聚轮烷组合物本发明涉及一种亲水改性聚轮烷组合物，它包括：亲水改性聚轮烷，其通过亲水改性基团改性含有环糊精的聚轮烷的环糊精上的全部或部分羟基，包含在空腔中的聚乙二醇的双环糊精分子，并且封端基团放置在聚乙二醇的每一端，并防止环糊精分子与聚乙二醇的解离; 和多酚抗氧化剂。

7. 发明授权

US09938382B2 Method for producing pseudopolyrotaxane 有权
公开(公告)号：US09938382B2
公开(公告)日：2018-04-10
申请号：US13994515
申请日：2011-12-05
申请人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao
发明人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao
IPC分类号： C08G83/00 , C08J3/12 , C08B37/16 , C08L5/16 , C08L71/02
CPC分类号： C08G83/007 , C08B37/0015 , C08J3/12 , C08J2371/02 , C08L5/16 , C08L71/02
摘要： The present invention aims to provide an industrially advantageous method of producing a powdery pseudopolyrotaxane with a high inclusion ratio. The present invention relates to a method for producing a pseudopolyrotaxane, including: an inclusion step of mixing a polyethylene glycol and a cyclodextrin in an aqueous medium to form an aqueous dispersion of pseudopolyrotaxane that contains pseudopolyrotaxane particles in which the polyethylene glycol is included in the cavities of the cyclodextrin molecules in a skewered manner; and a drying step of drying the aqueous dispersion of pseudopolyrotaxane produced in the inclusion step to obtain the pseudopolyrotaxane. In the drying step, the aqueous dispersion of pseudopolyrotaxane is sprayed and dried in a heated gas-stream.

8. 发明授权

US07847049B2 Polyrotaxane and process for producing the same 有权
标题翻译：聚轮烷及其制备方法
公开(公告)号：US07847049B2
公开(公告)日：2010-12-07
申请号：US10580795
申请日：2004-11-24
申请人： Kohzo Ito , Jun Araki , Changming Zhao
发明人： Kohzo Ito , Jun Araki , Changming Zhao
IPC分类号： C08F251/00
CPC分类号： C08G65/332 , C08B37/0015 , C08G83/007 , C08L5/16 , C08L71/02 , C08L2666/14
摘要： A process for producing a polyrotaxane in a high yield and at a satisfactory cost without using a large excess of a pseudopolyrotaxane and/or without using a large excess of an activated reagent. The process for polyrotaxane production comprises: an inclusion step in which a carboxylated polyethylene glycol which is a polyethylene glycol carboxylated at each end is mixed with cyclodextrin molecules to obtain a pseudopolyrotaxane which comprises cyclodextrin molecules which include the carboxylated polyethylene glycol in their cavities as if the cyclodextrin molecules are spitted with the carboxylated polyethylene glycol; and a capping step in which the pseudopolyrotaxane is reacted with capping groups having —NH2 or —OH to obtain a polyrotaxane terminated at each end by a —CO—NH-(capping group) or —CO—O-(capping group).
摘要翻译：一种以高产率和令人满意的成本生产聚轮烷的方法，而不使用大量过量的预聚轮烷和/或不使用大量过量的活化剂。聚轮烷生产方法包括：包含步骤，其中将在每端羧化的聚乙二醇的羧化聚乙二醇与环糊精分子混合以获得包含环糊精分子的假聚轮烷，所述环糊精分子在其空腔中包括羧化聚乙二醇，如同环糊精分子与羧化聚乙二醇分散; 和封端步骤，其中准聚轮烷与具有-NH 2或-OH的封端基团反应，得到每端用-CO-NH-（封端基团）或-CO-O-（封端基团）封端的聚轮烷。

9. 发明申请

US20130331562A1 METHOD FOR PRODUCING REFINED POLYROTAXANE 有权
标题翻译：生产精制聚氯乙烯的方法
公开(公告)号：US20130331562A1
公开(公告)日：2013-12-12
申请号：US13994566
申请日：2011-12-05
申请人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao
发明人： Tomoaki Yamasaki , Shinya Okazaki , Hiroki Okazaki , Shigeki Hamamoto , Changming Zhao
IPC分类号： C08G83/00
CPC分类号： C08G83/007 , C08B37/0015 , C08G83/006 , C08L71/02 , C08L5/16
摘要： The present invention aims to provide a method for producing a refined polyrotaxane which includes an industrially advantageous method of producing a polyrotaxane that has excellent storage stability. The method for producing a refined polyrotaxane includes the step of heat-cleaning a polyrotaxane with a cleaning medium, the polyrotaxane containing cyclodextrin molecules, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol.
摘要翻译：本发明的目的在于提供一种精制聚轮烷的制造方法，其特征在于，具有工业上优良的储存稳定性优异的聚轮烷的制造方法。精制聚轮烷的制造方法包括：利用清洗介质热处理聚轮烷，含有聚环氧丙烷的环糊精分子，以串列方式包含在环糊精分子的空腔中的聚乙二醇，以及封端基放置在聚乙二醇的每一端，并防止环糊精分子与聚乙二醇分解。

10. 发明授权

US08298307B2 Process for producing gel-like abrasive material and gel-like abrasive material 有权
标题翻译：生产凝胶状研磨材料和凝胶状研磨材料的方法
公开(公告)号：US08298307B2
公开(公告)日：2012-10-30
申请号：US12919608
申请日：2009-03-04
申请人： Keiji Mase , Shozo Ishibashi , Hirofumi Nakayama , Changming Zhao , Christian Ruslim
发明人： Keiji Mase , Shozo Ishibashi , Hirofumi Nakayama , Changming Zhao , Christian Ruslim
IPC分类号： C09K3/14 , C04B26/06 , C08K5/55 , C08K3/10 , C08K3/02 , C08K3/38 , C08K11/00 , C08F292/00 , C08L97/00 , C08L99/00
CPC分类号： B24C11/00 , B24C1/08 , C09K3/1409
摘要： An abrasive that can impart a mirror finish, glossiness, or the like to a surface of a workpiece by blasting is provided. A crosslinked polyrotaxane compound having a network structure where crosslinking points are circular molecules of polyrotaxane and also having abrasive grains dispersedly mixed therein is obtained by causing chemical bonding between the circular molecules of the polyrotaxane in a state where the abrasive grains and the polyrotaxane are mixed. Then, the crosslinked polyrotaxane compound is granulated to a predetermined grain diameter to obtain a gel-like abrasive where a part of the dispersedly mixed abrasive grain is exposed at the surface. By using the thus-obtained gel-like abrasive in blasting by projecting the abrasive at an angle tilted with respect to a surface of a workpiece, mirror finishing or the like is possible without making the surface of the workpiece pearskin-like.
摘要翻译：提供了可以通过喷砂赋予工件表面镜面光洁度等的磨料。通过在混合磨粒和聚轮烷的状态下引起聚轮烷的圆形分子之间的化学键合，获得具有交联点为聚轮烷的圆形分子并且还具有分散混合磨粒的网状结构的交联聚轮烷化合物。然后，将交联聚轮烷化合物造粒至规定的粒径，得到表面上分散混合的磨粒的一部分露出的凝胶状研磨剂。通过以相对于工件的表面倾斜的角度投影磨料，通过使用如此获得的凝胶状研磨剂进行喷砂处理，可以在不使工件表面类似梨子的情况下进行镜面精加工等。

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