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    • 1. 发明申请
    • TONER AND IMAGE FORMING METHOD
    • 调色剂和图像形成方法
    • US20130157193A1
    • 2013-06-20
    • US13709746
    • 2012-12-10
    • Tatsuru MORITANIHiroshi YamashitaTsuyoshi SugimotoDaisuke AsahinaRintaro TakahashiSusumu Chiba
    • Tatsuru MORITANIHiroshi YamashitaTsuyoshi SugimotoDaisuke AsahinaRintaro TakahashiSusumu Chiba
    • G03G9/087
    • G03G9/08728G03G9/08755G03G9/08764G03G9/08797G03G9/09321G03G9/09371G03G9/09378
    • A toner containing colorant, releasing agent, and binder resin containing crystalline polyester resin, and non-crystalline polyester resin containing urethane bond, urea bond, or both, the non-crystalline polyester resin containing first and second non-crystalline polyester resins, both containing urethane bond, or urea bond, or both, wherein monomers constituting the first non-crystalline polyester resin contains isocyanate monomer for forming the urethane bond, the urea bond, or the both, in an amount of 0.5 mol % or greater to total amount of the monomers, monomers constituting the second non-crystalline polyester resin contain isocyanate monomer for forming the urethane bond, the urea bond, or the both, in an amount of 0.5 mol % or greater to total amount of the monomers, the first non-crystalline polyester resin has Tg of −60° C. or higher but lower than 10° C., and the second non-crystalline polyester resin has Tg of 30° C. or higher but lower than 70° C.
    • 含有着色剂,脱模剂和含有结晶性聚酯树脂的粘合剂树脂的调色剂,以及含有氨基甲酸酯键,脲键或二者的非结晶性聚酯树脂,含有第一和第二非结晶性聚酯树脂的非结晶性聚酯树脂均含有 氨基甲酸酯键或脲键,或两者,其中构成第一非结晶性聚酯树脂的单体含有用于形成氨基甲酸酯键的异氰酸酯单体,尿素键或二者,其量为0.5摩尔%以上 构成第二非结晶性聚酯树脂的单体单体含有形成氨基甲酸酯键的异氰酸酯单体,脲键或二者的单体量相对于单体的总量为0.5摩尔%以上的量,第一非结晶性 聚酯树脂的Tg为-60℃以上且低于10℃,第二非结晶性聚酯树脂的Tg为30℃以上且低于70℃。
    • 7. 发明授权
    • Toner, developer, and image forming apparatus
    • 调色剂,显影剂和成像装置
    • US09557669B2
    • 2017-01-31
    • US14916911
    • 2014-08-29
    • Shinsuke NagaiShinya NakayamaTsuyoshi SugimotoSusumu ChibaKohsuke NagataDaisuke Asahina
    • Shinsuke NagaiShinya NakayamaTsuyoshi SugimotoSusumu ChibaKohsuke NagataDaisuke Asahina
    • G03G9/08G03G15/08G03G9/087
    • G03G9/0821G03G9/08755G03G9/08764G03G9/08791G03G9/08795G03G9/08797G03G15/08
    • A toner, wherein the toner has glass transition temperature [Tg1st (toner)] of 20° C. to 50° C., where the glass transition temperature [Tg1st (toner)] is measured in a first heating in differential scanning calorimetry (DSC) of the toner, wherein tetrahydrofuran (THF) insoluble matter of the toner has glass transition temperature [Tg2nd (THF insoluble matter)] of −40° C. to 30° C., where the glass transition temperature [Tg2nd (THF insoluble matter)] is measured in a second heating in differential scanning calorimetry (DSC) of the tetrahydrofuran (THF) insoluble matter, wherein the THF insoluble matter has a storage modulus at 100° C. [G′(100) (THF insoluble matter)] of 1.0×105 Pa to 1.0×107 Pa, and wherein a ratio of a storage modulus of the THF insoluble matter at 40° C. [G′(40) (THF insoluble matter)] to the storage modulus of the THF insoluble matter at 100° C. [G′(100) (THF insoluble matter)] is 3.5×10 or less.
    • 调色剂,其中调色剂具有20℃至50℃的玻璃化转变温度[Tg1st(调色剂)],其中在差示扫描量热法(DSC)中在第一次加热中测量玻璃化转变温度[Tg1st(调色剂)] )调色剂,其中调色剂的四氢呋喃(THF)不溶物质的玻璃化转变温度[Tg2nd(THF不溶物))为-40℃至30℃,其中玻璃化转变温度[Tg2nd(THF不溶性物质 )]在四氢呋喃(THF)不溶物质的差示扫描量热法(DSC)中的第二次加热中测量,其中THF不溶物在100℃下具有储能模量[G'(100)(THF不溶物)] 为1.0×10 5 Pa〜1.0×10 7 Pa,其中THF不溶物在40℃下的储能模量与[THF]不溶物的储能模量[G'(40)(THF不溶物)]的比例 在100℃下[G'(100)(THF不溶物)]为3.5×10以下。