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    • 7. 发明授权
    • Image-recording medium containing self-developing leuco dye
    • 包含自我发展的无色染料的图像记录介质
    • US06432876B1
    • 2002-08-13
    • US09539411
    • 2000-03-30
    • Tatsuhiko ObayashiAtsuhiro Ohkawa
    • Tatsuhiko ObayashiAtsuhiro Ohkawa
    • B41M520
    • G03C1/73B41M5/323B41M5/327G03C1/685
    • According to the present invention, a coloring property-improved novel leuco dye which can develop color by heat even with single molecule without requiring excess developer can be obtained, and an image recording medium having high sensitivity and excellent resolution effected by including the dye and a high sensitivity image recording medium further combined with an acid generator can also be obtained. Particularly, it relates to a leuco dye represented by a formula (1) (LD—(A—P1)n) and to an image recording medium which contains the leuco dye (wherein LD represents an acid-sensitive leuco dye mother nucleus, —A represents the residue of an acidic group (—AH) selected from —SO3H, —CO2H and —P(═O)(OH)xRy, R represents a hydrogen atom or a substituent group, x and y are x=1 and y=1 or x=2 and y=0, P1 represents a protecting group which can be removed by the action of light, heat or acid, and n is an integer of 1 or more).
    • 根据本发明,可以获得即使不需要过量的显影剂即使使用单分子也可以通过加热而显色的着色性能改善的新颖的无色染料,并且可以通过包含染料和 还可以获得与酸发生剂进一步组合的高灵敏度图像记录介质。特别涉及由式(1)表示的无色染料(LD-(A-P1)n)和涉及包含 无色染料(其中LD表示酸敏感的无色染料母核,-A表示选自-SO 3 H,-CO 2 H和-P(= O)(OH)x R y的酸性基团(-AH)的残基,R表示 氢原子或取代基,x和y分别为x = 1和y = 1或x = 2,y = 0,P1表示可以通过光,热或酸的作用除去的保护基,n为 1以上的整数)。
    • 8. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US5326680A
    • 1994-07-05
    • US885359
    • 1992-05-19
    • Atsuhiro OhkawaTatsuhiko ObayashiKeiji Mihayashi
    • Atsuhiro OhkawaTatsuhiko ObayashiKeiji Mihayashi
    • G03C7/305G03C7/26G03C1/42G03C7/32
    • G03C7/30576Y10S430/156Y10S430/158Y10S430/16
    • A silver halide color photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer formed on a support wherein the light-sensitive material contains a compound represented by the following general formula (I): ##STR1## wherein A is a coupler residual or an oxidation-reduction group, X.sub.1 is an oxygen atom or a sulfur atom, X.sub.2 is an oxygen atom, a sulfur atom or NX.sub.6 group, W is a carbon atom or a sulfur atom, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 are each a hydrogen atom or an organic residual, any two of X.sub.3, X.sub.4 and X.sub.5 can be bivalent groups which form a ring, PUG is a photographically useful group capable of bonding at a hetero-atom and, in the formula (I), n.sub.1 is 1 if W is a carbon atom, and either 1 or 2 if W is a sulfur atom. If n.sub.1 is 2, two X.sub.1 can either be identical or different. On the other hand, n.sub.2 is either 1 or 2. If n.sub.2 is 2, two X.sub.3, two X.sub.4, and two x.sub.5 are either identical or different.
    • 一种卤化银彩色摄影感光材料,其在支持体上形成有至少一个感光卤化银乳剂层,其中感光材料含有由以下通式(I)表示的化合物:通式(I)其中A是成色剂残基或氧化还原基团,X 1是氧原子或硫原子,X 2是氧原子,硫原子或NX 6基团,W是碳原子或硫原子,X 3,X 4 X 5和X 6各自为氢原子或有机残基,X3,X4和X5中的任意两个可以是形成环的二价基团,PUG是能够在杂原子键合的照相用的基团,并且在式 (I)中,如果W是碳原子,则n1为1,如果W为硫原子,n1为1。 如果n1为2,则两个X1可以相同或不同。 另一方面,n2为1或2.如果n2为2,则两个X3,两个X4和两个x5相同或不同。