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    • 5. 发明授权
    • High-strength stainless steel pipe excellent in sulfide stress cracking resistance and high-temperature carbonic-acid gas corrosion resistance
    • 高强度不锈钢管具有优异的耐硫化应力开裂性和高温碳酸气体耐腐蚀性能
    • US08608872B2
    • 2013-12-17
    • US13082432
    • 2011-04-08
    • Kunio KondoHisashi AmayaHideki TakabeTaro Ohe
    • Kunio KondoHisashi AmayaHideki TakabeTaro Ohe
    • C22C38/42C22C38/44
    • C22C38/42C22C38/001C22C38/02C22C38/04C22C38/06C22C38/44
    • The problem to be solved is the provision of a high-strength stainless steel pipe having a sufficient corrosion resistance in a high-temperature carbonic acid gas environment and having an excellent sulfide stress cracking resistance at normal temperature. A high-strength stainless steel pipe consist of, by mass %, C: 0.05% or less, Si: 1.0% or less, P: 0.05% or less, S: less than 0.002%, Cr: more than 16% and 18% or less, Mo: more than 2% and 3% or less, Cu: 1% to 3.5%, Ni: 3% or more and less than 5%, Al: 0.001% to 0.1% and O: 0.01% or less, Mn: 1% or less and N: 0.05% or less, and Mn and N in the above ranges satisfy formula (1), and the balance being Fe and impurities; and the metal micro-structure of the stainless steel pipe mainly includes a martensitic phase and comprises 10 to 40% of a ferritic phase by volume fraction and 10% or less of a retained γ-phase by volume fraction. [Mn]×([N]−0.0045)≦0.001  (1) wherein the symbols of elements in formula (1) respectively represent the contents (unit: mass %) of the elements in the steel.
    • 要解决的问题是在高温碳酸气体环境中提供具有足够耐腐蚀性的高强度不锈钢管,并且在常温下具有优异的耐硫化物应力开裂性。 高强度不锈钢管以质量%计含有C:0.05%以下,Si:1.0%以下,P:0.05%以下,S:小于0.002%,Cr:16%以上18以下 %以下,Mo:大于2%,3%以下,Cu:1〜3.5%,Ni:3%以上且小于5%,Al:0.001〜0.1%,O:0.01%以下 ,Mn:1%以下,N:0.05%以下,上述范围的Mn和N满足式(1),余量为Fe和杂质; 并且不锈钢管的金属微结构主要包括马氏体相,并且包含10〜40体积%的铁素体相和10体积%以下的γ相。 [Mn]×([N] -0.0045)@ 0.001(1)其中,式(1)中的元素的符号分别表示钢中元素的含量(单位:质量%)。
    • 6. 发明申请
    • HIGH-STRENGTH STAINLESS STEEL PIPE EXCELLENT IN SULFIDE STRESS CRACKING RESISTANCE AND HIGH-TEMPERATURE CARBONIC-ACID GAS CORROSION RESISTANCE
    • 高强度不锈钢管优良的耐硫酸盐耐应力和高温碳酸气体耐腐蚀性
    • US20110226378A1
    • 2011-09-22
    • US13082432
    • 2011-04-08
    • Kunio KONDOHisashi AmayaHideki TakabeTaro Ohe
    • Kunio KONDOHisashi AmayaHideki TakabeTaro Ohe
    • F16L9/00
    • C22C38/42C22C38/001C22C38/02C22C38/04C22C38/06C22C38/44
    • The problem to be solved is the provision of a high-strength stainless steel pipe having a sufficient corrosion resistance in a high-temperature carbonic acid gas environment and having an excellent sulfide stress cracking resistance at normal temperature.A high-strength stainless steel pipe consist of by mass %, C: 0.05% or less, Si: 1.0% or less, P: 0.05% or less, S: less than 0.002%, Cr: more than 16% and 18% or less, Mo: more than 2% and 3% or less, Cu: 1% to 3.5%, Ni: 3% or more and less than 5%, Al: 0.001% to 0.1% and O: 0.01% or less, Mn: 1% or less and N: 0.05% or less, and Mn and N in the above ranges satisfy formula (1), and the balance being Fe and impurities; and the metal micro-structure of the stainless steel pipe mainly includes a martensitic phase and comprises 10 to 40% of a ferritic phase by volume fraction and 10% or less of a retained γ-phase by volume fraction. [Mn]×([N]−0.0045)≦0.001  (1) wherein the symbols of elements in formula (1) respectively represent the contents (unit: mass %) of the elements in the steel.
    • 要解决的问题是在高温碳酸气体环境中提供具有足够耐腐蚀性的高强度不锈钢管,并且在常温下具有优异的耐硫化物应力开裂性。 高强度不锈钢管以质量%计,C:0.05%以下,Si:1.0%以下,P:0.05%以下,S:小于0.002%,Cr:16%以上18% 以下,Mo:大于2%和3%以下,Cu:1〜3.5%,Ni:3%以上且小于5%,Al:0.001〜0.1%,O:0.01%以下, Mn:1%以下,N:0.05%以下,上述范围的Mn和N满足式(1),余量为Fe和杂质; 并且不锈钢管的金属微结构主要包括马氏体相,并且含有10〜40体积%的铁素体系相和10体积%以下的γ相。 [Mn]×([N] -0.0045)≦̸ 0.001(1)其中,式(1)中的元素的符号分别表示钢中的元素的含量(单位:质量%)。
    • 7. 发明授权
    • High strength Cr-Ni alloy material and seamless pipe for oil well
    • 高强度Cr-Ni合金材料和油井无缝管
    • US08071020B2
    • 2011-12-06
    • US12485270
    • 2009-06-16
    • Yohei OtomeMasaaki IgarashiHisashi AmayaHirokazu Okada
    • Yohei OtomeMasaaki IgarashiHisashi AmayaHirokazu Okada
    • C22C28/00C22C38/42C22C38/44
    • C22C38/02C22C38/001C22C38/005C22C38/04C22C38/06C22C38/42C22C38/44Y10S148/909
    • A high strength Cr—Ni alloy material excellent in hot workability and stress corrosion cracking resistance, and seamless pipe for oil well application which consists of, by mass percent, C: 0.05% or less, Si: 0.05 to 1.0%, Mn: 0.01% or more and less than 3.0%, P: 0.05% or less, S: 0.005% or less, Cu: 0.01 to 4%, Ni: 25% or more and less than 35%, Cr: 20 to 30%, Mo: 0.01% or more and less than 4.0%, N: 0.10 to 0.30%, Al: 0.03 to 0.30%, O (oxygen): 0.01% or less, and REM (rare earth metal): 0.01 to 0.20% with the balance being Fe and impurities, and also satisfies the conditions in the following formula (1). N×P/REM≦0.40  formula (1) where P, N, and REM in the formula (1) respectively denote the contents (mass %) of P, N, and REM. The high strength Cr—Ni alloy material may further contain one or more types of W, Ti, Nb, Zr, V, Ca, and Mg, instead of part of Fe.
    • C:0.05%以下,Si:0.05〜1.0%,Mn:0.01%以下的质量%以上的油井用无缝管,耐热加工性和耐应力腐蚀开裂性优异的高强度Cr-Ni合金材料 %以上且小于3.0%,P:0.05%以下,S:0.005%以下,Cu:0.01〜4%,Ni:25%以上且小于35%,Cr:20〜30%,Mo :0.01%以上且小于4.0%,N:0.10〜0.30%,Al:0.03〜0.30%,O(氧):0.01%以下,REM(稀土金属):0.01〜0.20% 为Fe和杂质,也满足下式(1)的条件。 式(1)中的P,N,REM分别表示P,N,REM的含量(质量%),N×P / REM&nlE 0.40。 高强度Cr-Ni合金材料可以进一步含有一种或多种W,Ti,Nb,Zr,V,Ca和Mg而不是Fe的一部分。
    • 8. 发明申请
    • HIGH STRENGTH Cr-Ni ALLOY MATERIAL AND SEAMLESS PIPE FOR OIL WELL
    • 高强度Cr-Ni合金材料和无缝管油
    • US20090291017A1
    • 2009-11-26
    • US12485270
    • 2009-06-16
    • Yohei OtomeMasaaki IgarashiHisashi AmayaHirokazu Okada
    • Yohei OtomeMasaaki IgarashiHisashi AmayaHirokazu Okada
    • C22C30/02
    • C22C38/02C22C38/001C22C38/005C22C38/04C22C38/06C22C38/42C22C38/44Y10S148/909
    • [Object] To provide a high strength Cr—Ni alloy material excellent in hot workability and stress corrosion cracking resistance, and seamless pipe for oil well.[Solution] A high strength Cr—Ni alloy material which consists of, by mass percent, C: 0.05% or less, Si: 0.05 to 1.0%, Mn: 0.01% or more and less than 3.0%, P: 0.05% or less, S: 0.005% or less, Cu: 0.01 to 4%, Ni: 25% or more and less than 35%, Cr: 20 to 30%, Mo: 0.01% or more and less than 4.0%, N: 0.10 to 0.30%, Al: 0.03 to 0.30%, O (oxygen): 0.01% or less, and REM (rare earth metal): 0.01 to 0.20%, with the balance being Fe and impurities, and also satisfies the conditions in the following formula (1). N×P/REM≦0.40  formula (1) where P, N, and REM in the formula (1) respectively denote the contents (mass %) of P, N, and REM. The high strength Cr—Ni alloy material may further contain one or more types of W, Ti, Nb, Zr, V, Ca, and Mg, instead of part of Fe.
    • 本发明提供热加工性和耐应力腐蚀开裂性优异的高强度Cr-Ni合金材料,以及油井无缝管。 [方案]一种高强度Cr-Ni合金材料,以质量%计含有C:0.05%以下,Si:0.05〜1.0%,Mn:0.01%以上且小于3.0%,P:0.05%以上 较少,S:0.005%以下,Cu:0.01〜4%,Ni:25%以上且小于35%,Cr:20〜30%,Mo:0.01%以上且4.0%以下N:0.10 至0.30%,Al:0.03〜0.30%,O(氧)0.01%以下,REM(稀土金属):0.01〜0.20%,余量为Fe和杂质,也满足以下条件 公式1)。 NxP / REM其中,式(1)中的P,N和REM分别表示P,N和REM的含量(质量%)。 高强度Cr-Ni合金材料可以进一步含有一种或多种W,Ti,Nb,Zr,V,Ca和Mg而不是Fe的一部分。