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1. 发明授权

US5523437A Tertiary phosphine compound and transition metal complex comprising the same as ligand 失效
标题翻译：包含与配体相同的叔膦化合物和过渡金属络合物
公开(公告)号：US5523437A
公开(公告)日：1996-06-04
申请号：US280814
申请日：1994-07-26
申请人： Tamio Hayashi , Yasuhiro Uozumi , Kazunori Iwakura , Isao Kurimoto , Masayoshi Minai
发明人： Tamio Hayashi , Yasuhiro Uozumi , Kazunori Iwakura , Isao Kurimoto , Masayoshi Minai
IPC分类号： B01J31/24 , C07B53/00 , C07B59/00 , C07C1/213 , C07F9/50 , C07F15/00 , C07C2/02 , C07F7/08 , C07F9/02
CPC分类号： B01J31/2447 , C07B53/00 , C07B59/001 , C07C1/213 , C07F15/0066 , C07F9/5022 , B01J2231/323 , B01J2231/641 , B01J2531/824 , B01J31/04 , B01J31/223 , C07C2531/24
摘要： A tertiary phosphine compound of the formula (1): ##STR1## wherein R.sup.1 and R.sup.2 represent independently from each other a hydrogen atom or a methyl group, or together form --CH.dbd.CH--CH.dbd.CH--; R.sup.3 is a hydrogen atom or a cycloalkyl group having 5 to 7 carbon atoms or a lower alkyl group which may be substituted with a halogen atom, a lower alkoxy group, a lower alkoxyalkoxy group or a phenyl group; X.sup.1 is a halogen atom when both R.sup.1 and R.sup.2 are hydrogen atoms, or a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group when at least one of R.sup.1 and R.sup.2 is not a hydrogen atoms; and m is an integer of 1 to 5, which is useful as a ligand of a transition metal complex that can catalyze various reactions.
摘要翻译：式（1）的叔膦化合物：氢原子或甲基彼此相同，或一起形成-CH = CH-CH = CH-; R3是氢原子或碳原子数5〜7的环烷基或可以被卤素原子，低级烷氧基，低级烷氧基烷氧基或苯基取代的低级烷基; 当R1和R2中的至少一个不是氢原子时，当R1和R2都是氢原子时，X1是卤素原子，或者氢原子，卤原子，低级烷基或低级烷氧基; m为1〜5的整数，可用作催化各种反应的过渡金属络合物的配体。

2. 发明授权

US5621129A Optically active tertiary phosphine compound, transition metal complex comprising the same as ligand and process for preparing optically active organic silicon compound using said transition metal complex 失效
标题翻译：光活性叔膦化合物，与配体相同的过渡金属络合物和使用所述过渡金属络合物制备光学活性有机硅化合物的方法
公开(公告)号：US5621129A
公开(公告)日：1997-04-15
申请号：US612108
申请日：1996-03-07
申请人： Tamio Hayashi , Masayoshi Minai , Kazunori Iwakura
发明人： Tamio Hayashi , Masayoshi Minai , Kazunori Iwakura
IPC分类号： B01J31/24 , C07F7/14 , C07F9/50 , C07F15/00 , C07F9/02
CPC分类号： B01J31/2447 , C07F15/0066 , C07F7/14 , C07F9/5022 , B01J2231/323 , B01J2531/0266 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2540/225
摘要： A tertiary phosphine compound of the formula (1): ##STR1## in which R.sup.1 and R.sup.1' are hydrogen atoms or together form --CH.dbd.CH--CH.dbd.CH--; R.sup.2 and R.sup.3 together form a group of the formula (a): ##STR2## in which --.circle-solid. represent a bond to be bonded to the R.sup.3 group, and --.smallcircle. represents a bond to be bonded to the R.sup.2 group when R.sup.1 and R.sup.1 ' together form --CH.dbd.CH--CH.dbd.CH--, or when R.sup.1 is a hydrogen atom, R.sup.2 and R.sup.3 together form --CH.dbd.CH--CH.dbd.CH-- or R.sup.2 is a hydrogen atom and R.sup.3 is a substituted or unsubstituted alkyl group, or a substituted or unsubstituted phenyl group; A.sup.1 is a 3-trifluoromethylphenyl group or a 3,5-bis(trifluoromethyl)phenyl group when R.sup.1 is a hydrogen atom and R.sup.2 and R.sup.3 together form --CH.dbd.CH--CH.dbd.CH--, or a substituted or unsubstituted phenyl group when R.sup.1 is not a hydrogen atom or when R.sup.2 and R.sup.3 do not together form --CH.dbd.CH--CH.dbd.CH--.
摘要翻译：式（1）的叔膦化合物：原子或一起形成-CH = CH-CH = CH-; R2和R3一起形成式（a）的基团：其中 - + 574表示与R3基团键合的键， - + 602表示当R 1和R 2中键合到R 2基团时的键 R 1'一起形成-CH = CH-CH = CH-，或当R 1为氢原子时，R 2和R 3一起形成-CH = CH-CH = CH-或R 2为氢原子，且R 3为取代或未取代的烷基基团或取代或未取代的苯基; 当R1是氢原子时，A1是3-三氟甲基苯基或3,5-双（三氟甲基）苯基，当R 1和R 3一起形成-CH = CH-CH = CH-时，R 3和R 3一起形成取代或未取代的苯基不是氢原子或当R2和R3不一起形成-CH = CH-CH = CH-时。

3. 发明授权

US06623810B2 Phenylacetylene compound, liquid crystal composition, and liquid crystal element produced with the same 失效
标题翻译：苯乙炔化合物，液晶组合物，及其制造的液晶元件
公开(公告)号：US06623810B2
公开(公告)日：2003-09-23
申请号：US09840983
申请日：2001-04-25
申请人： Chizu Sekine , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
发明人： Chizu Sekine , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
IPC分类号： C09K1942
CPC分类号： C07C25/24 , C07C22/08 , C07C255/50 , C07C309/65 , C07C2601/14 , C09K19/18 , Y10T428/10
摘要： The present invention provides novel phenylacetylene compounds, liquid crystal compositions having a large refractive index anisotropy (&Dgr;n), and liquid crystal elements produced with the same. The liquid crystal composition contains at least one compound of formula (3A), and at least one compound selected from the group consisting of compounds of any one of formulae (3B) to (3C), wherein A1 to A12: alkyl group optionally substituted with F; R1, R2: H, F; A13 to A24: H, F; m: 0 or 1; Rings A to D: 1,4-phnylene, 1,4-cyclohexylene; R5, R6: H, F; Z1 to Z3: —COO—, —OCO—; b to d: 0 or 1 with b+c+d□1; B1 to B12: alkyl or alkoxy group; R7, R8: H, F:
摘要翻译：本发明提供了新的苯乙炔化合物，具有大的折射率各向异性（Deltan）的液晶组合物和由其生产的液晶元件。液晶组合物含有至少一种式（3A）化合物和至少一种选自式（3B）至（3C）中任一项的化合物的化合物，其中A 1至A 12，：任选被F取代的烷基; R 1，R 2：H，F; A <13>至A 24：H，F; m：0或1; 环A至D：1,4-亚苯基，1,4-亚环己基; R 5，R 6：H，F; Z 1至Z 3：-COO - ， - OCO-; b至d：0或1，b + c + d□1; B 1至B 12：烷基或烷氧基; R 7，R 8：H，F：

4. 发明授权

US07135579B2 Dibenzothiophene oxide compound, and process for producing the same 有权
标题翻译：二苯并噻吩氧化物，及其制造方法
公开(公告)号：US07135579B2
公开(公告)日：2006-11-14
申请号：US10873211
申请日：2004-06-23
申请人： Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
发明人： Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
IPC分类号： C07D333/76
CPC分类号： C09K19/3059 , C07D333/76 , C09K19/18 , C09K19/3491 , C09K19/42 , C09K2019/0448 , C09K2019/0496 , C09K2019/188 , Y10T428/10
摘要： There are disclosed novel compounds, liquid crystal compositions, polymers, optically anisotropic producgs, and optical or liquid crystal elements that have large refractive index anisotropy, mix easily with other liquid crystals, have advantageous stability against light, and exhibit absorption at practically short wavelength in the ultraviolet region. The compounds are represented by the formula (1) and have a phenylacetylene structure, wherein difference ΔE in energy of HOMO of parts (1-1), (1-2) and (1-3) calculated by the method of molecular orbitals is not less than 0.3 electronvolt, and the polarizability anisotropy Δα of a molecule represented by the formula (1) calculated in the same way is not lower than 500 A.U.: P1—H (1-2) P2—H (1-3) (A1 to A4: H, F, alkyl or alkoxy group of C1 to C10 optionally substituted with F; P1, P2: structure fulfilling the conditions of HOMO energy and polarizability).
摘要翻译：公开了具有大的折射率各向异性，容易与其他液晶混合的新型化合物，液晶组合物，聚合物，光学各向异性产物和光学或液晶元件，对光具有有利的稳定性，并且在实际短波长下表现出吸收紫外线区域。化合物由式（1）表示并具有苯乙炔结构，其中通过分子轨道方法计算的部分（1-1），（1-2）和（1-3）的HOMO的能量差ΔE为不小于0.3电子伏特，并且以相同方式计算的由式（1）表示的分子的极化率各向异性Δalpha不低于500AU：<？in-line-formula description =“In-line Formulas”end = “lead”？> P <1> H（1-2）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula 描述=“在线公式”end =“lead”？> P <2> -H（1-3）<？in-line-formula description =“In-line Formulas”end =“tail （A 1至A 4）：任选被F取代的C至C 10的H，F，烷基或烷氧基; P 1，，满足HOMO能量和极化率条件的结构）。

5. 发明申请

US20080139824A1 DIBENZOTHIOPHENE OXIDE COMPOUND, AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：二苯氧基氧化物化合物及其制备方法
公开(公告)号：US20080139824A1
公开(公告)日：2008-06-12
申请号：US11943433
申请日：2007-11-20
申请人： Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
发明人： Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
IPC分类号： C07D333/76
CPC分类号： C09K19/3059 , C07D333/76 , C09K19/18 , C09K19/3491 , C09K19/42 , C09K2019/0448 , C09K2019/0496 , C09K2019/188 , Y10T428/10
摘要： There are disclosed novel compounds, liquid crystal compositions, polymers, optically anisotropic products, and optical or liquid or liquid crystal elements that have large refractive index anisotropy, mix easily with other liquid crystals, have advantageous stability against light, and exhibit absorption at practically short wavelength in the ultraviolet region. The compounds are represented by the formula (1) and have a phenylacetylene structure, wherein difference ΔE in energy of HOMO of parts (1-1), (1-2) and (1-3) calculated by the method of molecular orbitals is not less than 0.3 electronvolt, and the polarizability anisotropy Δα of a molecule represented by the formula (1) calculated in the same way is not lower than 500 A.U.: (A1 to A4: H, F, alkyl or alkoxy group of C1 to C10 optionally substituted with F; P1, P2; structure fulfilling the conditions of HOMO energy and polarizability).
摘要翻译：公开了新型化合物，液晶组合物，聚合物，光学各向异性产物，具有大的折射率各向异性的光学或液体或液晶元件，与其它液晶容易混合，对光具有有利的稳定性，并在几乎短时间内呈现吸收波长在紫外线区域。化合物由式（1）表示并具有苯乙炔结构，其中通过分子轨道方法计算的部分（1-1），（1-2）和（1-3）的HOMO的能量差ΔE为不小于0.3电子伏特，并且以相同方式计算的由式（1）表示的分子的极化率各向异性Δα不低于500AU：（A <1> 1 < H，F，任选被F取代的C 1至C 10的烷基或烷氧基; P 1，P 2;满足HOMO能量和极化率条件的结构）。

6. 发明授权

US06673267B2 Phenylacetylene compound, liquid crystal composition, polymer, optically anisotropic product, and liquid crystal or optical element 失效
标题翻译：苯乙炔化合物，液晶组合物，聚合物，光学各向异性产物，以及液晶或光学元件
公开(公告)号：US06673267B2
公开(公告)日：2004-01-06
申请号：US09742407
申请日：2000-12-22
申请人： Chizu Sekine , Koichi Fujisawa , Masayoshi Minai , Kazunori Iwakura
发明人： Chizu Sekine , Koichi Fujisawa , Masayoshi Minai , Kazunori Iwakura
IPC分类号： C09K1906
CPC分类号： C09K19/38 , C08F22/105 , C09K19/18 , C09K2019/0448 , C09K2019/0496 , G02B5/3016 , Y10T428/10
摘要： Phenylacetylene compounds are disclosed which are expected to exhibit high refractive index anisotropy, easy to mix with other liquid crystal compounds, has advantageous stability against light, and may be used as a material for producing various films and the like. The compounds are represented by the formula (1): wherein A1 to A12: H, F, etc.; B1, B2: H, CH3; p, q, r, s , t: 0 or 1, provided that when q=0, at least one of A2 and A4 to A10 stands for a C1 to C10 alkyl or alkoxy group optionally substituted with at least one F; m, n: an integer of 0 to 14, provided that when s=1, n is not 0, and when t=1, m is not 0; W: —CH2CH2—, —C≡C—.
摘要翻译：所公开的苯乙炔化合物预期具有高的折射率各向异性，容易与其它液晶化合物混合，对光具有有利的稳定性，并可用作生产各种膜等的材料。化合物由式（1）表示：其中A 1至A 12：H，F等; B 1，B 2：H，CH 3; p，q，r，s，t：0或1，条件是当q = 0时，A 2和A 4中至少一个与A 10代表C1至C10烷基或烷氧基任选被至少一个F取代; m，n：0〜14的整数，条件是当s = 1时，n不为0，当t = 1时，m不为0; W：-CH 2 CH 2 - ， - C = C-。

7. 发明申请

US20070057229A1 COMPOUND HAVING PHENYLACETYLENE STRUCTURE, LIQUID CRYSTAL COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC PRODUCT, OPTICAL OR LIQUID CRYSTAL ELEMENT, DIBENZOTHIOPHENE COMPOUND, INTERMEDIATE, AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：具有苯乙烯结构的化合物，液晶组合物，聚合物，光学异相产物，光学或液体晶体元素，二苯并噻吩化合物，中间体及其制备方法
公开(公告)号：US20070057229A1
公开(公告)日：2007-03-15
申请号：US11554533
申请日：2006-10-30
申请人： Chizu Sekine , Misamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
发明人： Chizu Sekine , Misamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
IPC分类号： C09K19/02 , C09K19/34 , C07D333/02 , C07D409/14
CPC分类号： C09K19/3059 , C07D333/76 , C09K19/18 , C09K19/3491 , C09K19/42 , C09K2019/0448 , C09K2019/0496 , C09K2019/188 , Y10T428/10
摘要： There are disclosed novel compounds, liquid crystal compositions, polymers, optically anisotropic prodrugs, and optical or liquid crystal elements that have large refractive index anisotropy, mix easily with other liquid crystals, have advantageous stability against light, and exhibit absorption at practically short wavelength in the ultraviolet region. The compounds are represented by the formula (1) and have a phenylacetylene structure, wherein difference ΔE in energy of HOMO of parts (1-1), (1-2) and (1-3) calculated by the method of molecular orbitals is not less than 0.3 electronvolt, and the polarizability anisotropy Δα of a molecule represented by the formula (1) calculated in the same way is not lower than 500 A.U.: (A1 to A4: H, F, alkyl or alkoxy group of C1 to C10 optionally substituted with F; P1, P2: structure fulfilling the conditions of HOMO energy and polarizability).
摘要翻译：公开了具有大的折射率各向异性，容易与其它液晶混合的新型化合物，液晶组合物，聚合物，光学各向异性前药，以及光学或液晶元件，对光具有有利的稳定性，紫外线区域。化合物由式（1）表示并具有苯乙炔结构，其中通过分子轨道方法计算的部分（1-1），（1-2）和（1-3）的HOMO的能量差ΔE为不小于0.3电子伏特，并且以相同方式计算的由式（1）表示的分子的极化率各向异性Δα不低于500AU：（A <1> 1 < H，F，任选被F取代的C 1至C 10的烷基或烷氧基; P 1，P 2：满足HOMO能量和极化率条件的结构）。

8. 发明授权

US06849202B2 COMPOUND HAVING PHENYLACETYLENE STRUCTURE, LIQUID CRYSTAL COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC PRODUCT, OPTICAL OR LIQUID CRYSTAL ELEMENT, DIBENZOTHIOPHENE COMPOUND, INTERMEDIATE, AND PROCESS FOR PRODUCING THE SAME 失效
标题翻译：具有苯乙烯结构的化合物，液晶组合物，聚合物，光学异相产物，光学或液体晶体元素，二苯并噻吩化合物，中间体及其制备方法
公开(公告)号：US06849202B2
公开(公告)日：2005-02-01
申请号：US10067871
申请日：2002-02-08
申请人： Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
发明人： Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
IPC分类号： C07C43/20 , C07D333/76 , C09K19/18 , C09K19/34 , C09K19/42 , C09K19/52 , C07D495/00 , C09K19/32 , C09K19/38 , C09K19/54
CPC分类号： C09K19/3059 , C07D333/76 , C09K19/18 , C09K19/3491 , C09K19/42 , C09K2019/0448 , C09K2019/0496 , C09K2019/188 , Y10T428/10
摘要： There are disclosed novel compounds, liquid crystal compositions, polymers, optically anisotropic products, and optical or liquid crystal elements that have large refractive index anisotropy, mix easily with other liquid crystals, have advantageous stability against light, and exhibit absorption at practically short wavelength in the ultraviolet region. The compounds are represented by the formula (1) and have a phenylacetylene structure, wherein difference ΔE in energy of HOMO of parts (1-1), (1-2) and (1-3) calculated by the method of molecular orbitals is not less than 0.3 electronvolt, and the polarizability anisotropy Δα of a molecule represented by the formula (1) calculated in the same way is not lower than 500 A.U.: (A1 to A4: H, F, alkyl or alkoxy group of C1 to C10 optionally substituted with F; P1, P2: structure fulfilling the conditions of HOMO energy and polarizability).
摘要翻译：公开了具有大的折射率各向异性，容易与其他液晶混合的新型化合物，液晶组合物，聚合物，光学各向异性产物和光学或液晶元件，对光具有有利的稳定性，并且在几乎短的波长下表现出吸收紫外线区域。化合物由式（1）表示并具有苯乙炔结构，其中通过分子轨道方法计算的部分（1-1），（1-2）和（1-3）的HOMO的能量差ΔE为不小于0.3电子伏特，以相同方式计算的由式（1）表示的分子的极化率各向异性Δalpha不低于500A A（A 1至A 4）：H，F，烷基或 C1至C10的任选被F取代的烷氧基; P 1，P 2：满足HOMO能量和极化率条件的结构）。

9. 发明授权

US07741511B2 Process for the preparation of carboxylic acid esters 失效
标题翻译：羧酸酯的制备方法
公开(公告)号：US07741511B2
公开(公告)日：2010-06-22
申请号：US11837399
申请日：2007-08-10
申请人： Hiroshi Souda , Kazunori Iwakura
发明人： Hiroshi Souda , Kazunori Iwakura
IPC分类号： C07C69/24
CPC分类号： C07C67/08 , B01J31/0212 , C07F7/003 , C07C69/747
摘要： There is provided a process for preparing a carboxylic acid ester of formula (3): R2COOR1 (3) wherein R1 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, and R2 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aryl group which may be substituted, a heteroaryl which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, which process is characterized by the steps of reacting a monohydroxy compound of formula (1): R1OH (1) wherein R1 is as defined above, with a zirconium compound of formula (6): Zr(OR8)4 (6) wherein R8 is an alkyl group or an aryl group which may be substituted and is not the same as R1, to prepare a zirconium catalyst, and reacting a carboxylic acid of formula (2): R2COOH (2) wherein R2 is as defined above, with the monohydroxy compound of formula (1) in the presence of the zirconium catalyst.
摘要翻译：提供了制备式（3）的羧酸酯的方法：R2COOR1（3）其中R1是可被取代的烷基，可被取代的烯基，可被取代的炔基，芳烷基可以被取代的基团，或可以被取代的杂芳基烷基，R 2可以被取代的烷基，可以被取代的链烯基，可被取代的炔基，可被取代的芳基，可以被取代的杂芳基，可被取代的芳烷基或可被取代的杂芳烷基，该方法的特征在于以下步骤：使式（1）的单羟基化合物：R1OH（1）其中R1为与式（6）的锆化合物：Zr（OR8）4（6）其中R8是可以被取代且与R1不同的烷基或芳基，制备锆催化剂，以及反应一个碳式（2）的二甲酸：其中R 2如上所定义的R 2 COOH（2）与式（1）的单羟基化合物在锆催化剂存在下反应。

10. 发明授权

US07399873B2 Process for the preparation of carboxylic acid esters 失效
公开(公告)号：US07399873B2
公开(公告)日：2008-07-15
申请号：US11837404
申请日：2007-08-10
申请人： Hiroshi Souda , Kazunori Iwakura
发明人： Hiroshi Souda , Kazunori Iwakura
IPC分类号： C07F7/00
CPC分类号： C07C67/08 , B01J31/0212 , C07F7/003 , C07C69/747
摘要： There is provided a process for preparing a carboxylic acid ester of formula (3): R2COOR1 (3) wherein R1 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, and R2 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aryl group which may be substituted, a heteroaryl which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, which process is characterized by the steps of reacting a monohydroxy compound of formula (1): R1OH (1) wherein R1 is as defined above, with a zirconium compound of formula (6): Zr(OR8)4 (6) wherein R8 is an alkyl group or an aryl group which may be substituted and is not the same as R1, to prepare a zirconium catalyst, and reacting a carboxylic acid of formula (2): R2COOH (2) wherein R2 is as defined above, with the monohydroxy compound of formula (1) in the presence of the zirconium catalyst.

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