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    • 3. 发明授权
    • Magnetic recording media and thermoplastic polyurethane resins therefor
    • 磁记录介质及其热塑性聚氨酯树脂
    • US06545119B2
    • 2003-04-08
    • US09520204
    • 2000-03-07
    • Hirotoshi KizumotoTakeshi YatsukaChikara SugitawaKuniyuki Doi
    • Hirotoshi KizumotoTakeshi YatsukaChikara SugitawaKuniyuki Doi
    • C08G1842
    • G11B5/7021C08G18/4202C08G18/4211C08G18/4238C09D175/06
    • A magnetic recording medium possessing a magnetic layer formed by application onto a non-magnetic support, of a magnetic coating containing magnetic particles dispersed in a binder which contains a polyurethane resin, together with carbon black particles at 5% by weight or higher, based on the weight of the magnetic particles. The polyurethane resin to be used herein is composed of: (a) a polyester polyol having a molecular weight of 2000 or lower and containing at least one selected from the group consisting of aromatic dibasic acids and alicyclic dibasic acids at a ratio of 90 mol % or higher of acid components; (b) a high molecular weight polyol having a molecular weight of 5000 or lower, which is at least one selected from the group consisting of (b1) polyester polyols each containing an aliphatic dibasic acid at a ratio of 90 mol % or higher of acid components, (b2) polylactones, (b3) polyester polyols, and (b4) polycarbonate polyols; (c) an organic diisocyanate compound; and (d) an optional compound having a molecular weight of 500 or lower and containing at least two functional groups in one molecule, which are reactive with isocyanate groups.
    • 一种具有磁性层的磁记录介质,其特征在于,在非磁性载体上形成磁性涂层,所述磁性涂层含有分散在含有聚氨酯树脂的粘合剂中的磁性颗粒以及基于5重量%以上的碳黑颗粒,基于 磁性颗粒的重量。 本说明书中使用的聚氨酯树脂由以下组成:(a)分子量为2000以下且含有选自芳族二元酸和脂环族二元酸中的至少一种的聚酯多元醇的比例为90摩尔% 或更高的酸组分; (b)分子量为5000以下的高分子量多元醇,其为选自(b1)各自含有比例为90摩尔%以上的脂肪族二元酸的(b1)的聚酯多元醇中的至少一种 组分,(b2)聚内酯,(b3)聚酯多元醇和(b4)聚碳酸酯多元醇; (c)有机二异氰酸酯化合物; 和(d)分子量为500以下且在一个分子中含有至少两个与异氰酸酯基团反应的官能团的任选的化合物。
    • 4. 发明申请
    • Receptor layer forming resin for thermal transfer image receptor sheet and thermal transfer image receptor sheet using the same
    • 用于热转印图像受体片的受体层形成树脂和使用其的热转印图像接收片
    • US20060229202A1
    • 2006-10-12
    • US11393112
    • 2006-03-30
    • Masahiro YukiKazuya YoshidaKuniyuki DoiHirotoshi Kizumoto
    • Masahiro YukiKazuya YoshidaKuniyuki DoiHirotoshi Kizumoto
    • B41M5/035
    • B41M5/5281C08G18/0828C08G18/4676C08G18/664
    • A main object of the present invention is to provide a receptor layer forming resin which makes it possible to obtain a receptor layer for a thermal transfer image receptor sheet having excellent dyeing property. The present invention achieves the above object by providing a receptor layer forming polyurethane resin for a thermal transfer image receptor sheet obtained by copolymerizing: a high molecular weight polyol having a number average molecular weight of 1000 or higher (A) ; an organic isocyanate (B); and according to need, a polyol compound having a number average molecular weight of 500 or lower (C), wherein the receptor layer forming polyurethane resin for a thermal transfer image receptor sheet meets the following requirements (1) to (4): (1) the resin has at least two glass transition temperatures; (2) at least one of the glass transition temperatures is between −200 to 0° C., and at least one is between 20 to 100° C.; (3) the high molecular weight polyol (A) is a mixture comprising; an aromatic polyester polyol containing metallic base sulfonate (A-1); and a polyol other than said (A-1) (A-2); and (4) the ratio of (A-2) in the high molecular weight polyol (A) is 20 mass percent or higher.
    • 本发明的主要目的是提供一种形成受体层的树脂,其可以获得具有优异染色特性的热转印图像接受片的受体层。 本发明通过提供一种通过共聚合数均分子量为1000或更高(A)的高分子量多元醇获得的热转印图像接收片的形成聚氨酯树脂的受体层形成聚氨酯树脂来实现上述目的。 有机异氰酸酯(B); 根据需要,具有数均分子量为500以下的多元醇化合物(C),其中,用于热转印影像受体片的受体层形成性聚氨酯树脂满足以下要求(1)〜(4):(1) )树脂具有至少两个玻璃化转变温度; (2)至少一个玻璃化转变温度在-200至0℃之间,并且至少一个在20至100℃之间。 (3)高分子量多元醇(A)是包含: 含有金属基础磺酸酯(A-1)的芳族聚酯多元醇; 和(A-1)(A-2)以外的多元醇; 和(4)高分子量多元醇(A)中的(A-2)的比例为20质量%以上。
    • 5. 发明授权
    • Receptor layer forming resin for thermal transfer image receptor sheet and thermal transfer image receptor sheet using the same
    • 用于热转印图像受体片的受体层形成树脂和使用其的热转印图像接收片
    • US07691784B2
    • 2010-04-06
    • US11393112
    • 2006-03-30
    • Masahiro YukiKazuya YoshidaKuniyuki DoiHirotoshi Kizumoto
    • Masahiro YukiKazuya YoshidaKuniyuki DoiHirotoshi Kizumoto
    • B41M5/035B41M5/50
    • B41M5/5281C08G18/0828C08G18/4676C08G18/664
    • A main object of the present invention is to provide a receptor layer forming resin which makes it possible to obtain a receptor layer for a thermal transfer image receptor sheet having excellent dyeing property. The present invention achieves the above object by providing a receptor layer forming polyurethane resin for a thermal transfer image receptor sheet obtained by copolymerizing: a high molecular weight polyol having a number average molecular weight of 1000 or higher (A); an organic isocyanate (B); and according to need, a polyol compound having a number average molecular weight of 500 or lower (C), wherein the receptor layer forming polyurethane resin for a thermal transfer image receptor sheet meets the following requirements (1) to (4): (1) the resin has at least two glass transition temperatures; (2) at least one of the glass transition temperatures is between −200 to 0° C., and at least one is between 20 to 100° C.; (3) the high molecular weight polyol (A) is a mixture comprising; an aromatic polyester polyol containing metallic base sulfonate (A-1); and a polyol other than said (A-1) (A-2); and (4) the ratio of (A-2) in the high molecular weight polyol (A) is 20 mass percent or higher.
    • 本发明的主要目的是提供一种形成受体层的树脂,其可以获得具有优异染色特性的热转印图像接受片的受体层。 本发明通过提供一种通过共聚合数均分子量为1000或更高(A)的高分子量多元醇获得的热转印图像接收片的形成聚氨酯树脂的受体层形成聚氨酯树脂来实现上述目的。 有机异氰酸酯(B); 根据需要,具有数均分子量为500以下的多元醇化合物(C),其中,用于热转印影像受体片的受体层形成性聚氨酯树脂满足以下要求(1)〜(4):(1) )树脂具有至少两个玻璃化转变温度; (2)至少一个玻璃化转变温度在-200至0℃之间,并且至少一个在20至100℃之间。 (3)高分子量多元醇(A)是包含: 含有金属基础磺酸酯(A-1)的芳族聚酯多元醇; 和(A-1)(A-2)以外的多元醇; 和(4)高分子量多元醇(A)中的(A-2)的比例为20质量%以上。