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    • 4. 发明授权
    • Magnetic black toner
    • 磁性黑色调色剂
    • US06803164B2
    • 2004-10-12
    • US10238782
    • 2002-09-11
    • Yuichi MizooTadashi DojoNene ShibayamaYusuke Hasegawa
    • Yuichi MizooTadashi DojoNene ShibayamaYusuke Hasegawa
    • G03G9083
    • G03G9/0834G03G9/0819G03G9/0827G03G9/0833G03G9/0835G03G9/0838
    • A magnetic black toner comprising magnetic black toner particles containing at least a binder resin and a magnetic material. The toner has a weight-average particle diameter of from 5 &mgr;m to 12 &mgr;m, and the toner has, in its particles of 3 &mgr;m or more in diameter, at least 90% by number of particles with a circularity of 0.900 or more and has an average circularity of from 0.940 to 0.970. The magnetic material comprises iron oxide particles which have an average particle diameter of from 0.10 &mgr;m to 0.30 &mgr;m, contain titanium or a titanium compound in an amount of from 0.3% by weight to 1.5% by weight in terms of titanium, based on the total weight of the iron oxide particles, and have the ratio of the proportion of FeO to the total Fe content in 10% by weight from the particle surface, A %, to the proportion of FeO to the total Fe content in the remainder 90% by weight, B %, which satisfies the expression: 0.7≦A/B≦1.0. Also, an inorganic fine powder is externally added to the toner particle surfaces.
    • 一种包含至少含有粘合剂树脂和磁性材料的磁性黑色调色剂颗粒的磁性黑色调色剂。 调色剂的重均粒径为5〜12μm,调色剂的直径为3μm以上的颗粒的至少90个数量的圆形度为0.900以上的颗粒,并且具有 平均圆形0.940至0.970。 磁性材料包含平均粒径为0.10μm至0.30μm的氧化铁颗粒,以钛为基准,钛或钛化合物的含量为0.3重量%至1.5重量%,基于总计 氧化铁颗粒的重量,并且FeO与总Fe含量的比例为10重量%,从颗粒表面的A%与FeO的总Fe含量之比为90%,余量为90% 重量,B%,满足表达式:0.7 <= A / B <= 1.0。 此外,无机细粉末外部添加到调色剂颗粒表面。
    • 8. 发明授权
    • Toner for developing electrostatic images
    • 用于显影静电图像的调色剂
    • US5773183A
    • 1998-06-30
    • US749640
    • 1996-11-15
    • Tadashi DoujoYuichi MizooTakaaki KotakiYushi Mikuriya
    • Tadashi DoujoYuichi MizooTakaaki KotakiYushi Mikuriya
    • G03G9/083G03G9/087G03G9/09
    • G03G9/091G03G9/08755G03G9/08795G03G9/0833G03G9/08782
    • A toner for developing an electrostatic image has a binder resin, a colorant and a charge control agent. The binder resin has a polyester resin having an acid value of from 15 to 40 and a hydroxyl value of 45 or less. The toner has, in its molecular weight distribution as measured by gel permeation chromatography, tetrahydrofuran-soluble matter having a weight average molecular weight Mw of 100,000 or more, having a ratio of weight average molecular weight Mw to number average molecular weight Mn, Mw/Mn, of not less than 35, containing from 70% to 94% of a low-molecular weight region component having a molecular weight of less than 150,000, containing from 1% to 10% of a medium-molecular weight region component having a molecular weight of from 150,000 to 500,000, and containing from 5% to 25% of a high-molecular weight region component having a molecular weight of more than 500,000. The high-molecular weight region component is more than the medium-molecular weight region component.
    • 用于显影静电图像的调色剂具有粘合剂树脂,着色剂和电荷控制剂。 粘合剂树脂具有酸值为15〜40,羟值为45以下的聚酯树脂。 调色剂在通过凝胶渗透色谱法测定的分子量分布中,具有重均分子量Mw为100,000以上的四氢呋喃可溶性物质,重均分子量Mw与数均分子量Mn的比,Mw / Mn不低于35,含有70%至94%的分子量小于150,000的低分子量成分,含有1%至10%的具有分子量 重量为15万至500,000,并含有5%至25%的分子量大于500,000的高分子量成分。 高分子量区域成分大于中等分子量区域成分。