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1. 发明授权

US4840878A Method of color image formation using a high chloride emulsion and a developer free of benzyl alcohol 失效
标题翻译：使用高氯化物乳液和不含苄醇的显影剂进行彩色图像形成的方法
公开(公告)号：US4840878A
公开(公告)日：1989-06-20
申请号：US251932
申请日：1988-09-30
申请人： Takeshi Hirose , Nobuo Furutachi , Kozo Aoki , Kiyoshi Nakazyo , Genichi Furusawa
发明人： Takeshi Hirose , Nobuo Furutachi , Kozo Aoki , Kiyoshi Nakazyo , Genichi Furusawa
IPC分类号： G03C7/34 , G03C1/035 , G03C7/30 , G03C7/32 , G03C7/36 , G03C7/38 , G03C7/407 , G03C7/42
CPC分类号： G03C7/3022 , G03C7/3225 , G03C2007/3024 , G03C2200/20 , G03C7/413
摘要： A method for forming a color image is disclosed, which comprises imagewise exposing a multi-layer silver halide color photographic material comprising a reflective support having provided thereon at least three silver halide emulsion layers different in color sensitivity, each of which separately contains at least one coupler selected from a specific combination of cyan, magenta, and yellow couplers, and processing the exposed material with a color developing solution containing substantially no benzyl alcohol for a period of not more than 2 minutes and a half. A color image excellent in color reproducibility and preservability can be obtained rapidly without using benzyl alcohol.
摘要翻译：公开了一种用于形成彩色图像的方法，其包括成像曝光多层卤化银彩色照相材料，所述多层卤化银彩色照相材料包括其上提供有至少三种颜色敏感度不同的卤化银乳剂层的反射性支持体，其中每一种卤化银乳剂层分别包含至少一种选自青色，品红色和黄色成色剂的特定组合的成色剂，并且用不含苄醇的显色溶液处理暴露的材料不超过2分钟半的时间。快速地获得色彩再现性和保存性优异的彩色图像，而不使用苄醇。

2. 发明授权

US4865963A Silver halide color photographic materials containing novel magenta coupler 失效
标题翻译：含有新品红色成色剂的卤化银彩色照相材料
公开(公告)号：US4865963A
公开(公告)日：1989-09-12
申请号：US913792
申请日：1986-09-30
申请人： Nobuo Furutachi , Tadahisa Sato , Seiki Sakanoue , Akio Mitsui , Minoru Sakai , Masakazu Morigaki , Hidetoshi Kobayashi , Nobuo Sakai , Kiyoshi Nakazyo , Takeshi Hirose , Toshio Kawagishi
发明人： Nobuo Furutachi , Tadahisa Sato , Seiki Sakanoue , Akio Mitsui , Minoru Sakai , Masakazu Morigaki , Hidetoshi Kobayashi , Nobuo Sakai , Kiyoshi Nakazyo , Takeshi Hirose , Toshio Kawagishi
IPC分类号： C07D487/04 , G03C7/30 , G03C7/305 , G03C7/38
CPC分类号： C07D487/04 , G03C7/301 , G03C7/30529 , G03C7/3835
摘要： A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said silver halide emulsion layer containing a pyrazoloazole series magenta coupler represented by general formula [I] ##STR1## wherein, R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a releasing group which is released at the reaction with the oxidation product of an aromatic primary amine developing agent; at least one of said R.sup.1 and R.sup.2 is an alkyl group having a secondary or tertiary carbon atom directly bonded to the skeleton, at least one of said R.sub.1 and R.sub.2 is a sulfonamidoalkyl group or a sulfamoylalkyl group; and the magenta coupler may form a dimer or more polymer at the position of said R.sup.1, R.sup.2 or X.By the combined use of high boiling point organic solvent and ultraviolet absorbent, light fastness and coloring property are markedly improved.
摘要翻译：一种卤化银彩色照相材料，包括其上具有至少一个卤化银乳剂层的载体，所述卤化银乳剂层含有由通式[I]表示的吡唑并苯系列品红成色剂，其中R1和R2各自表示氢原子或取代基; X表示在与芳族伯胺显影剂的氧化产物反应时释放的氢原子或释放基团; 所述R 1和R 2中的至少一个是具有与所述骨架直接键合的仲或叔碳原子的烷基，所述R 1和R 2中的至少一个是亚磺酰氨基烷基或氨磺酰基烷基; 并且品红色成色剂可以在所述R1，R2或X的位置形成二聚体或更多聚合物。通过组合使用高沸点有机溶剂和紫外线吸收剂，耐光性和着色性显着提高。

3. 发明授权

US4900655A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US4900655A
公开(公告)日：1990-02-13
申请号：US125796
申请日：1987-11-27
申请人： Kiyoshi Nakazyo , Takeshi Hirose , Genichi Hurusawa , Osamu Takahashi , Nobuo Furutachi , Hidetoshi Kobayashi
发明人： Kiyoshi Nakazyo , Takeshi Hirose , Genichi Hurusawa , Osamu Takahashi , Nobuo Furutachi , Hidetoshi Kobayashi
IPC分类号： G03C7/30 , G03C7/38
CPC分类号： G03C7/3835 , G03C7/301
摘要： A silver halide color photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer, wherein at least one magenta coupler represented by the formula ##STR1## where the groups in the formula are defined in the specification; is dispersed in the silver halide emulsion layer in the presence of at least one high-boiling organic solvent represented by one of the formulae (II), (III), (IV) and (V): ##STR2## where the groups in the formulae are described in the specification. The a high boiling point organic solvent has a dielectric constant of not less than 4.00 at 25.degree. C. and 10 KHz.
摘要翻译：一种卤化银彩色照相感光材料，其包括在其上提供有至少一个卤化银乳剂层的载体，其中至少一种由式（VIII）表示的品红成色剂，其中式中的基团在说明书中定义 ; 在由式（II），（III），（IV）和（V）之一表示的至少一种高沸点有机溶剂的存在下分散在卤化银乳剂层中：R3COOR4（II）（IV）R3OR4（V）其中式中的基团在说明书中描述。高沸点有机溶剂在25℃和10KHz下的介电常数不低于4.00。

4. 发明授权

US4822730A Silver halide color photographic light-sensitive materials containing a pyrazoloazole magenta coupler 失效
标题翻译：含卤吡唑品红色成色剂的卤化银彩色照相感光材料
公开(公告)号：US4822730A
公开(公告)日：1989-04-18
申请号：US56312
申请日：1987-05-28
申请人： Nobuo Furutachi , Toshio Kawagishi , Kiyoshi Nakazyo
发明人： Nobuo Furutachi , Toshio Kawagishi , Kiyoshi Nakazyo
IPC分类号： C07D487/04 , G03C7/305 , G03C7/38 , C03C1/08
CPC分类号： C07D487/04 , G03C7/30529 , G03C7/3825
摘要： A silver halide color photographic material comprising a support having formed thereon at least one silver halide emulsion layer containing a pyrazoloazole series magenta coupler having at least one group expressed by the formula [S] below at a position other than the coupling active position.--(A).sub.n --L--B [S]wherein A represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted arylene group, or a substituted or unsubstituted aralkylene group, in which in the main chain of said alkylene group, cycloalkylene group, arylene group, or aralkylene group, --O--, --S--, --CO--, --CO.sub.2 --, --OCO--, ##STR1## may be contained; L represents ##STR2## B represents a hydrogen atom or a substituted or unsubstituted alkyl or aryl group which does not contain therein --SO.sub.2 --; n is 0 or 1; and R and R' each represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group. In the above, in the case that the pyrazoloazole series magenta coupler is a 1H-pyrazolo[5,1-c][1,2,4]triazole derivative, A does not represent an aralkylene group containing an arylene group directly connected to L. The silver halide color photographic light-sensitive material has improved coloring properties.
摘要翻译：一种卤化银彩色照相材料，其包含在其上形成有至少一个卤化银乳剂层的载体，所述卤化银乳剂层含有具有下式[S]表示的至少一个基团的吡唑并咪唑系品红成色剂，除了偶联活性位置之外。 - （A）nLB [S]其中A表示取代或未取代的亚烷基，取代或未取代的亚环烷基，取代或未取代的亚芳基或取代或未取代的芳亚烷基，其中在所述亚烷基的主链，亚环烷基，亚芳基或亚芳基，可以含有-O - ， - S-，-CO-，-CO 2 - ， - OCO-，＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆ L表示B表示氢原子或其中不含有-SO 2的取代或未取代的烷基或芳基; n为0或1; R和R'各自表示氢原子，取代或未取代的烷基或取代或未取代的芳基。在上述中，在吡唑并
恶唑系品红成色剂为1H-吡唑并[5,1-c] [1,2,4]三唑衍生物的情况下，A不表示含有与L直接连接的亚芳基的亚芳基卤化银彩色摄影感光材料具有改善的着色性能。

5. 依法登记的发明

USH131H Silver halide color photographic material 失效
公开(公告)号：USH131H
公开(公告)日：1986-09-02
申请号：US773892
申请日：1985-09-09
申请人： Nobuo Furutachi , Tadahisa Sato , Toshio Kawagishi , Kiyoshi Nakazyo
发明人： Nobuo Furutachi , Tadahisa Sato , Toshio Kawagishi , Kiyoshi Nakazyo
IPC分类号： C07D487/04 , G03C7/38
CPC分类号： C07D487/04 , G03C7/3825
摘要： Silver halide color photographic materials contain pyrazoloazole type magenta couplers having at least one hydroxyphenyl group bonded thereto. The silver halide color photographic materials are improved in color developability and color image light fastness. The pyrazoloazole type magenta couplers are 5-membered ring/5-membered ring condensed nitrogen heterocyclic type couplers.

6. 发明授权

US4559297A Silver halide color photographic light-sensitive material containing stabilizer 失效
标题翻译：卤化银彩色摄影感光材料含稳定剂
公开(公告)号：US4559297A
公开(公告)日：1985-12-17
申请号：US699091
申请日：1985-02-07
申请人： Nobuo Seto , Nobuo Furutachi , Masakazu Morigaki , Kiyoshi Nakazyo
发明人： Nobuo Seto , Nobuo Furutachi , Masakazu Morigaki , Kiyoshi Nakazyo
IPC分类号： C07F7/08 , G03C7/392 , G03C7/26
CPC分类号： G03C7/39288 , C07F7/0812 , C07F7/0818
摘要： A silver halide photographic light-sensitive material is described, the material comprising a support having thereon at least one photographic layer containing at least one compound represented by formula (I): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, ##STR2## a substituted or unsubstituted silyl group, a substituted or unsubstituted phosphoric acid group, or a divalent group derived from the above-described groups which forms a ring together with the oxygen atom linking to --R and the carbon atom which is in the ortho-position to --O--R and to which ##STR3## is not bonded; R.sub.1, R.sub.2 and R.sub.3 which may be the same or different each represents a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group or a substituent thereof; Q represents an atomic group necessary to form a substituted or unsubstituted aromatic ring; R.sub.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a cycloamino group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group or a substituent thereof; and R.sub.5 represents an H atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group or a substituent thereof.
摘要翻译：描述了一种卤化银照相感光材料，该材料包括其上具有至少一个含有至少一种由式（I）表示的化合物的照相层的载体：其中R表示氢原子，取代的或未取代的烷基，取代或未取代的烯基，取代或未取代的环烷基，取代或未取代的芳基，取代或未取代的杂环基，取代或未取代的甲硅烷基，取代或未取代的磷酸基或衍生自上述基团的二价基团，其与连接到-R的氧原子和与-OR邻位并且未键合的碳原子一起形成环; 可以相同或不同的R 1，R 2和R 3表示氢原子，烷基，烯基，环烷基，芳烷基，芳基或其取代基; Q表示形成取代或未取代的芳环所必需的原子团; R4表示氢原子，烷基，环烷基，烯基，芳基，烷氧基，芳氧基，氨基，环氨基，烷硫基，芳硫基，酰基，烷氧基羰基或其取代基; R5代表H原子，烷基，环烷基，烯基，芳基或取代基。

7. 发明授权

US4564586A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US4564586A
公开(公告)日：1986-01-14
申请号：US696610
申请日：1985-01-30
申请人： Kozo Aoki , Michio Ono , Kiyoshi Nakazyo
发明人： Kozo Aoki , Michio Ono , Kiyoshi Nakazyo
IPC分类号： C07D215/22 , C07D215/227 , C07D215/38 , C09B53/00 , G03C7/34 , G03C7/26
CPC分类号： C07D215/227 , C07D215/38 , G03C7/34
摘要： A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, wherein the silver halide color photographic light-sensitive material contains a cyan dye forming coupler represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sub.2, R.sub.3, R.sub.4 and R.sub.5, which may be the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted arylcarbonyl group, a substituted or unsubstituted carbonyl group or a nitrile group, or R.sub.2 and R.sub.3 or R.sub.4 and R.sub.5 may together represent an alkylidene group, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 may combine each other to form a ring, three or more of R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are not hydrogen atom at the same time and when two of R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen atoms at the same time, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 combine each other to form a ring or R.sub.2 and R.sub.3 or R.sub.4 and R.sub.5 are hydrogen atoms; X represents a hydrogen atom or a group capable of being released upon an oxidative coupling with a developing agent; and n represents 0 or 1.The cyan dye forming coupler can provide a cyan color image having excellent fastness to light and heat and have good solubility in an organic solvent having a high boiling point.
摘要翻译：一种卤化银彩色照相感光材料，其包含涂覆有至少一个卤化银乳剂层的载体，其中所述卤化银彩色照相感光材料含有由以下通式（I）表示的形成青色染料的成色剂：（I）其中R1表示取代或未取代的烷基，取代或未取代的芳基或取代或未取代的杂环基; R 2，R 3，R 4和R 5可以相同或不同，各自表示氢原子，卤素原子，取代或未取代的烷基，取代或未取代的烯基，取代或未取代的芳基，取代或未取代的芳基，未取代的烷氧基，取代或未取代的芳氧基，取代或未取代的烷硫基，取代或未取代的芳硫基，取代或未取代的酰氨基，取代或未取代的亚磺酰氨基，取代或未取代的烷氧基羰基，取代或未取代的芳基羰基，取代或未取代的羰基或腈水泥浆，或R 2和R 3或R 4和R 5可以一起代表亚烷基，R 2，R 3，R 4和R 5可以相互结合形成环，R 3 R 3，R 4和R 5同时不是氢原子，当R2，R3，R4和R5中的两个同时为氢原子时，R2，R3，R4和R5相互结合形成环或R 2，R 3或R 4和R 5为氢原子; X表示氢原子或与显影剂氧化偶联时能够释放的基团; 并且n表示0或1.青色染料形成成色剂可以提供具有优异的耐光性和耐热性的青色图像，并且在具有高沸点的有机溶剂中具有良好的溶解性。

8. 发明授权

US5063143A Process for forming color image 失效
标题翻译：形成彩色图像的过程
公开(公告)号：US5063143A
公开(公告)日：1991-11-05
申请号：US506201
申请日：1990-04-09
申请人： Takeshi Hirose , Akira Abe , Kiyoshi Nakazyo
发明人： Takeshi Hirose , Akira Abe , Kiyoshi Nakazyo
IPC分类号： G03C1/035 , G03C7/30 , G03C7/407
CPC分类号： G03C7/3003 , G03C7/407 , G03C2001/03517 , G03C2200/09
摘要： A process for forming a color image wherein a color photographic material is developed with a processing solution containing a solvent for the silver halide in the presence of an aromatic primary amino color devloping agent. The color photographic material comprises, on a support, at least one layer containing (1) a coupler capable of forming a dye by reaction with an oxidized aromatic primary amino color developing agent and having a dye covering power of at least 0.75 and (2) a silver chlorobromide emulsion or silver chlorobromide emulsion containing at least 90 molar % of silver chloride.
摘要翻译：一种用于形成彩色图像的方法，其中在芳族伯氨基脱色剂存在下，用含有卤化银溶剂的处理溶液显影彩色照相材料。彩色照相材料在载体上包含至少一层，其含有（1）能够通过与氧化的芳族伯氨基显色剂反应形成染料并具有至少0.75的染料覆盖功率的成色剂的成色剂，和（2）含有至少90摩尔％氯化银的氯化氯溴化银乳液或氯溴化银乳液。

9. 发明授权

US4783394A Color image forming process 失效
标题翻译：彩色图像形成过程
公开(公告)号：US4783394A
公开(公告)日：1988-11-08
申请号：US37288
申请日：1987-04-10
申请人： Takeshi Hirose , Kiyoshi Nakazyo , Hideaki Naruse
发明人： Takeshi Hirose , Kiyoshi Nakazyo , Hideaki Naruse
IPC分类号： G03C7/26 , G03C1/815 , G03C7/30 , G03C7/392 , G03C7/407 , G03C1/84
CPC分类号： G03C7/39256 , Y10S430/132
摘要： A color image forming process is described, which comprises developing an imagewise exposed silver halide color photographic material with a color developer containing an aromatic primary amine developing agent and being substantially free of benzyl alcohol for a period of up to about 2 minutes and 30 seconds, wherein the silver halide color photographic material comprises a reflective support having thereon a blue-sensitive silver halide emulsion layer containing a yellow color-forming coupler, a green-sensitive silver halide emulsion layer contaning a magenta color-forming coupler, and a red-sensitive silver halide emulsion layer containing a cyan color-forming coupler in this order, the material further containing light-insensitive hydrophilic colloid layers between the blue-sensitive silver halide emulsion layer and the green-sensitive silver halide emulsion layer and between the green-sensitive silver halide emulsion layer and the red-sensitive silver halide emulsion layer and at least one light-insensitive hydrophilic colloid layer on the red-sensitive silver halide emulsion layer, the volume ratio of the oil component to the hydrophilic colloid in each of the light-insensitive layers is at most about 0.2 and both the light-insensitive layer between the green-sensitive silver halide emulsion layer and the red-sensitive silver halide emulsion layer and the light-insensitive layer on the red-sensitive silver halide emulsion layer each contains at least one ultraviolet absorbent compound represented by formula (F): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5, which may be the same or different, each may represent a hydrogen atom or a substituent, and the R.sub.4 and R.sub.5 may bond together to form a 5-membered or 6-membered aromatic ring.
摘要翻译：描述了彩色图像形成方法，其包括用含有芳族伯胺显影剂的显色剂显影成像曝光的卤化银彩色照相材料，并基本上不含苄醇至多约2分30秒，其中所述卤化银彩色照相材料包括其上具有含有黄色成色成色剂的感蓝卤化银乳剂层的反射性载体，含有品红色成色剂的感绿卤化银乳剂层和红色敏感剂卤化银乳剂层依次含有青色成色剂，该材料在蓝敏感卤化银乳剂层和感绿卤化银乳剂层之间以及绿敏银之间还含有不透光的亲水胶体层卤化物乳剂层和红色感光卤化银乳剂层在感光卤化银乳剂层上的至少一个不透光的亲水胶体层，每个不透光层中的油组分与亲水胶体的体积比最多约为0.2，并且两者之间的光不敏感层感光卤化银乳剂层和感红卤化银乳剂层和感红卤化银乳剂层上的不透光层各自含有至少一种由式（F）表示的紫外线吸收剂化合物：（F）其中R 1，R 2，R 3，R 4和R 5可以相同或不同，各自表示氢原子或取代基，并且R 4和R 5可以键合在一起形成5元或6元芳香环。

10. 发明授权

US5474883A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5474883A
公开(公告)日：1995-12-12
申请号：US249909
申请日：1994-05-26
申请人： Keiji Mihayashi , Kiyoshi Nakazyo
发明人： Keiji Mihayashi , Kiyoshi Nakazyo
IPC分类号： C07D209/08 , C07D231/16 , C07D233/02 , C07D233/04 , C07D233/54 , C07D251/12 , C07D263/44 , C07D277/82 , C07D307/12 , C07D405/06 , C07D405/12 , C07D409/06 , C07D411/06 , C07D417/12 , C07D487/04 , C07D493/08 , C08G63/181 , C08J5/18 , C08J7/00 , G03C1/795 , G03C1/81 , G03C3/00 , G03C7/36
CPC分类号： G03C7/365 , G03C1/7954 , G03C1/81 , G03C3/00
摘要： A silver halide color photographic material comprising a support having provided thereon a layer containing an acylacetamide-type coupler having an acyl group represented by the following formula (YI) and/or a coupler represented by the following formula (1) or (2), wherein the support is made of a poly(alkylene aromatic dicarboxylate) and has a glass transition point of from 50.degree. C. to 200.degree. C. and is heat-treated at a temperature falling within the range from 40.degree. C. to lower than the glass transition point before or after having been coated with a subbing layer and before being coated with silver halide light-sensitive layers, ##STR1## wherein R.sub.1 represents a substituent; and Q represents a non-metallic atomic group necessary for forming, along with C in the formula, a 3-membered to 5-membered hydrocarbon ring or a 3-membered to 6-membered hetero ring having in the ring structure at least one hetero atom selected from among N, O, S and P, ##STR2## wherein X.sub.1 and X.sub.2 each represents an alkyl group, an aryl group or a heterocyclic group; X.sub.3 represents an organic residue for forming a nitrogen-containing heterocyclic group along with >N-- in the formula; Y represents an aryl group or a heterocyclic group; and Z represents a group which splits off from the formula when the coupler represented by the formula reacts with an oxidation product of a developing agent.
摘要翻译：一种卤化银彩色照相材料，其包含在其上提供含有由下式（YI）表示的酰基的酰基乙酰胺型成色剂和/或下式（1）或（2）表示的成色剂的层的载体，其中载体由聚（亚烷基芳族二羧酸酯）制成，玻璃化转变温度为50℃至200℃，并在40℃至低于40℃的温度下进行热处理在涂覆有底层之前和之后的涂覆有卤化银感光层之前或之后的玻璃化转变点，其中R 1表示取代基; Q表示与上述式中的C一起形成的非金属原子团，在该环结构中具有至少一个杂原子的3元〜5元烃环或3元〜6元杂环选自N，O，S和P中的原子，（1）基，芳基或杂环基; X3表示在式中与> N一起形成含氮杂环基的有机残基; Y表示芳基或杂环基; Z表示当下式表示的成色剂与显影剂的氧化物反应时，从式中分离出来的基团。

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