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    • 1. 发明专利
    • Polylactic acid resin composition and polylactic acid resin molded article
    • 聚酸树脂组合物和聚酰胺酸树脂模塑制品
    • JP2009256412A
    • 2009-11-05
    • JP2008104244
    • 2008-04-14
    • Takemoto Oil & Fat Co LtdToyota Motor Corpトヨタ自動車株式会社竹本油脂株式会社
    • KITA KENJIKICHISE YOSHIFUMIURAYAMA YUJIHATTA AKIONISHI HIRONORI
    • C08L67/04C08J5/00C08K5/20C08L101/16
    • PROBLEM TO BE SOLVED: To provide a polylactic acid resin composition in which a crystallization rate of a polylactic acid resin forming a stereo complex is sufficiently increased as well as a stereo complex crystal ratio is increased, and to provide a polylactic acid resin molded article by melt-molding and crystallizing the polylactic acid resin composition. SOLUTION: The polylactic acid resin composition contains, with respect to 100 pts.mass of the following polylactic acid resin, 0.05 to 30 pts.mass of a nitrogen-containing compound expressed by the formula. In the formula, R 1 represents an 8-22C aliphatic acyl group; and A 1 and A 2 each represents a hydrogen atom or 2-hydroxyethyl group, provided that, at least one of A 1 and A 2 is a 2-hydroxyethyl group. The polylactic resin comprises a polylactic acid blend that can generate a stereo complex crystal, and/or a polylactic acid stereo block copolymer. COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题提供一种聚合乳液树脂组合物,其中形成立体络合物的聚乳酸树脂的结晶速率以及立体络合物结晶比率增加,并且提供聚乳酸树脂 通过熔融成型并使聚乳酸树脂组合物结晶而成型。 &lt; P&gt;解决方案:聚乳酸树脂组合物相对于100重量份以下聚乳酸树脂含有0.05〜30重量份的由式表示的含氮化合物。 在该式中,R“SP”1表示8-22个脂肪族酰基; 并且A 1 和A 2 各自表示氢原子或2-羟乙基,条件是A 1 和A < SP> 2 是2-羟基乙基。 聚乳酸树脂包括可产生立体络合物晶体的聚乳酸共混物和/或聚乳酸立体嵌段共聚物。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Crystal nucleus agent for polylactic acid resin, and polylactic acid resin composition
    • 聚酰胺酸树脂的水晶核剂和聚酸树脂组合物
    • JP2010150365A
    • 2010-07-08
    • JP2008329399
    • 2008-12-25
    • Takemoto Oil & Fat Co Ltd竹本油脂株式会社
    • SUZUKI MASAHIRONISHI HIRONORIWADA MIHOKO
    • C08L67/04C08K5/42C08L101/16
    • PROBLEM TO BE SOLVED: To provide a crystal nucleus agent for a polylactic acid resin which can satisfactorily enhance crystallization even being used for a polylactic acid resin having a low content ratio of a constituent unit formed from L-lactic acid or a constituent unit formed from D-lactic acid, that is the polylactic acid resin having low optical purity, has excellent operability upon being handled and does not worsen operational environment and to provide a polylactic acid resin composition. SOLUTION: An aromatic sulfonate which is represented by formula (1) and whose average particle diameter is adjusted in 0.1 to 10 μm range is used as the crystal nucleus agent for the polylactic acid resin. (In formula (1), X: a residue formed by removing three hydrogen atoms from benzene, R 1 , R 2 : 1-6C hydrocarbon, M: an alkali metal atom or an alkaline earth metal atom, n: 1 or 2, wherein n=1 when M is the alkali metal atom and n=2 when M is the alkaline earth metal atom). COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供一种用于聚乳酸树脂的晶核剂,其可以令人满意地提高结晶,甚至用于由L-乳酸或其组分形成的构成单元的低含量比的聚乳酸树脂 由D-乳酸形成的单元,即具有低光学纯度的聚乳酸树脂,在处理时具有优异的可操作性,并且不会恶化操作环境并提供聚乳酸树脂组合物。 溶液:将由式(1)表示的平均粒径调节为0.1〜10μm的芳香族磺​​酸盐用作聚乳酸树脂的结晶核剂。 (式(1)中,X:通过从苯中除去三个氢原子形成的残基,R 1 SPC,R 6 SPC:1-6C烃,M:碱金属 原子或碱土金属原子n:1或2,其中当M是碱金属原子时n = 1,当M是碱土金属原子时n = 2)。 版权所有(C)2010,JPO&INPIT